CA2241059A1 - Photocatalyst process for making surface hydrophillic - Google Patents
Photocatalyst process for making surface hydrophillicInfo
- Publication number
- CA2241059A1 CA2241059A1 CA002241059A CA2241059A CA2241059A1 CA 2241059 A1 CA2241059 A1 CA 2241059A1 CA 002241059 A CA002241059 A CA 002241059A CA 2241059 A CA2241059 A CA 2241059A CA 2241059 A1 CA2241059 A1 CA 2241059A1
- Authority
- CA
- Canada
- Prior art keywords
- coating
- photocatalytic
- substrate
- hydrogen bond
- gamma
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title abstract 3
- 239000011941 photocatalyst Substances 0.000 title abstract 2
- 239000011248 coating agent Substances 0.000 abstract 6
- 238000000576 coating method Methods 0.000 abstract 6
- 230000001699 photocatalysis Effects 0.000 abstract 5
- 239000001257 hydrogen Substances 0.000 abstract 3
- 229910052739 hydrogen Inorganic materials 0.000 abstract 3
- 239000000758 substrate Substances 0.000 abstract 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- 230000003373 anti-fouling effect Effects 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000004140 cleaning Methods 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 230000001443 photoexcitation Effects 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000011973 solid acid Substances 0.000 abstract 1
- 238000001179 sorption measurement Methods 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F13/00—Arrangements for modifying heat-transfer, e.g. increasing, decreasing
- F28F13/18—Arrangements for modifying heat-transfer, e.g. increasing, decreasing by applying coatings, e.g. radiation-absorbing, radiation-reflecting; by surface treatment, e.g. polishing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F8/00—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying
- F24F8/20—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by sterilisation
- F24F8/22—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by sterilisation using UV light
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F2245/00—Coatings; Surface treatments
- F28F2245/02—Coatings; Surface treatments hydrophilic
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Catalysts (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
- Laminated Bodies (AREA)
- Paints Or Removers (AREA)
Abstract
A method for hydrophilifying the surface of a substrate by taking advantage of photocatalytic action.
The substrate has a photocatalytic titanic coating (10).
The surface of the photocatalytic coating (10) bears the solid acid that increases a hydrogen bond component (.gamma.s h) in the surface energy in the solid/gas interface of the coating. Photoexcitation of the photocatalyst enhances the hydrogen bond component (.gamma.s h) in the surface energy of the photocatalytic coating (10), accelerating the physical adsorption of molecules of water in the atmosphere through a hydrogen bond (16) onto hydrogen atoms in a terminal OH
group (12), bonded to a titanium atom, and a bridge OH
group (14) on the surface of the coating. This results in the formation of a high density, physically adsorbed water layer (18) on the surface of the photocatalytic coating (10), thus permitting the surface of the substrate to be easily hydrophilified. The method is applicable to antifogging, antifouling, selfcleaning and cleaning of articles.
The substrate has a photocatalytic titanic coating (10).
The surface of the photocatalytic coating (10) bears the solid acid that increases a hydrogen bond component (.gamma.s h) in the surface energy in the solid/gas interface of the coating. Photoexcitation of the photocatalyst enhances the hydrogen bond component (.gamma.s h) in the surface energy of the photocatalytic coating (10), accelerating the physical adsorption of molecules of water in the atmosphere through a hydrogen bond (16) onto hydrogen atoms in a terminal OH
group (12), bonded to a titanium atom, and a bridge OH
group (14) on the surface of the coating. This results in the formation of a high density, physically adsorbed water layer (18) on the surface of the photocatalytic coating (10), thus permitting the surface of the substrate to be easily hydrophilified. The method is applicable to antifogging, antifouling, selfcleaning and cleaning of articles.
Applications Claiming Priority (11)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP35464995 | 1995-12-22 | ||
JP354649/1995 | 1995-12-22 | ||
JP4942096 | 1996-01-31 | ||
JP49420/1996 | 1996-01-31 | ||
JP20272696 | 1996-06-27 | ||
JP202726/1996 | 1996-06-27 | ||
JP25730496 | 1996-08-22 | ||
JP257304/1996 | 1996-08-22 | ||
JP27519396 | 1996-09-10 | ||
JP275193/1996 | 1996-09-10 | ||
PCT/JP1996/003694 WO1997023657A1 (en) | 1995-12-22 | 1996-12-18 | Method of feeding sintering material by use of magnetic forces |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2241059A1 true CA2241059A1 (en) | 1997-07-03 |
CA2241059C CA2241059C (en) | 2007-03-06 |
Family
ID=27522792
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002241059A Expired - Lifetime CA2241059C (en) | 1995-12-22 | 1996-12-18 | Photocatalyst process for making surface hydrophillic |
Country Status (8)
Country | Link |
---|---|
JP (2) | JP2917525B2 (en) |
KR (1) | KR100429933B1 (en) |
AT (1) | ATE252140T1 (en) |
CA (1) | CA2241059C (en) |
DE (1) | DE69630394T2 (en) |
DK (1) | DK0869156T3 (en) |
MY (1) | MY134705A (en) |
PT (1) | PT869156E (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113646067A (en) * | 2019-03-29 | 2021-11-12 | 旭化成医疗株式会社 | Porous membrane |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001010552A1 (en) | 1999-08-05 | 2001-02-15 | Kabushiki Kaisha Toyota Chuo Kenkyusho | Photocatalytic material, photocatalytic article and method for their preparation |
AU2001259451A1 (en) | 2000-05-04 | 2001-11-12 | Schott Donnelly Llc | Chromogenic glazing |
US6938546B2 (en) | 2002-04-26 | 2005-09-06 | Mitsubishi Heavy Industries, Ltd. | Printing press, layered formation and making method thereof, and printing plate and making method thereof |
EP1849835B1 (en) * | 2005-02-18 | 2017-08-30 | Nippon Soda Co., Ltd. | Organic-inorganic composite body |
AT505773B1 (en) * | 2007-10-24 | 2009-04-15 | Vaillant Austria Gmbh | FUEL-INDEPENDENT ENERGY SUPPLY SYSTEM |
DE102007054848B4 (en) | 2007-11-16 | 2018-09-27 | Erlus Aktiengesellschaft | Ceramic shaped body with a photocatalytically active, air-cleaning, transparent surface coating, method for producing the same and its use |
WO2009110236A1 (en) | 2008-03-04 | 2009-09-11 | 株式会社 東芝 | Hydrophilic member and hydrophilic articles made by using the same |
JP4829321B2 (en) | 2009-03-31 | 2011-12-07 | 株式会社東芝 | Photocatalyst |
KR102111006B1 (en) * | 2018-11-16 | 2020-05-14 | 한동대학교 산학협력단 | Method of manufacturing high hydrophilic titanium dioxide and method for analyzing titanium dioxide donor-acceptor interaction peak |
CN109509400A (en) * | 2018-12-03 | 2019-03-22 | 国网江苏省电力有限公司 | A kind of preparation method of open air atmospheric environment long-life two-dimension code label |
CN112997773B (en) * | 2021-03-25 | 2022-11-22 | 江苏嘉仁建设工程有限公司 | Illumination adjusting device for greenhouse |
-
1996
- 1996-12-18 PT PT96942560T patent/PT869156E/en unknown
- 1996-12-18 CA CA002241059A patent/CA2241059C/en not_active Expired - Lifetime
- 1996-12-18 KR KR10-1998-0704789A patent/KR100429933B1/en not_active IP Right Cessation
- 1996-12-18 DE DE69630394T patent/DE69630394T2/en not_active Expired - Lifetime
- 1996-12-18 AT AT96942560T patent/ATE252140T1/en active
- 1996-12-18 JP JP9515699A patent/JP2917525B2/en not_active Expired - Lifetime
- 1996-12-18 DK DK96942560T patent/DK0869156T3/en active
- 1996-12-20 MY MYPI96005397A patent/MY134705A/en unknown
-
1997
- 1997-05-12 JP JP9137823A patent/JPH10140046A/en active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113646067A (en) * | 2019-03-29 | 2021-11-12 | 旭化成医疗株式会社 | Porous membrane |
CN113646067B (en) * | 2019-03-29 | 2024-03-12 | 旭化成医疗株式会社 | Porous membrane |
Also Published As
Publication number | Publication date |
---|---|
JP2917525B2 (en) | 1999-07-12 |
KR100429933B1 (en) | 2005-04-20 |
DK0869156T3 (en) | 2004-02-16 |
KR19990076677A (en) | 1999-10-15 |
ATE252140T1 (en) | 2003-11-15 |
DE69630394T2 (en) | 2004-05-19 |
CA2241059C (en) | 2007-03-06 |
MY134705A (en) | 2007-12-31 |
DE69630394D1 (en) | 2003-11-20 |
PT869156E (en) | 2004-03-31 |
JPH10140046A (en) | 1998-05-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0869156A4 (en) | Photocatalytic process for making surface hydrophilic and composite material having photocatalytically hydrophilic surface | |
CA2241059A1 (en) | Photocatalyst process for making surface hydrophillic | |
EP0684075A1 (en) | Multi-functional material having photo-catalytic function and production method therefor | |
US5853866A (en) | Multi-functional material with photocalytic functions and method of manufacturing same | |
JP2918787B2 (en) | Photocatalyst and method for producing the same | |
EP1701779B1 (en) | Preparation method of a metal palladium composite membrane or alloy palladium composite membrane | |
EP1997565B1 (en) | Article with plasmopolymeric coating and method for its manufacture | |
CA2244752A1 (en) | Functional coated product and process for producing the same and the use thereof | |
WO1998005589A1 (en) | Method for coating amorphous titanium peroxide | |
ATE284842T1 (en) | METHOD FOR PRODUCING ALUMINUM OXIDES AND PRODUCTS MADE THEREFROM | |
HK1007889A1 (en) | Method for producing thick ceramic films by a sol gel coating process | |
AU2002333160A1 (en) | Self-cleaning ceramic layers for baking ovens and method for production of self-cleaning ceramic layers | |
CA2344945A1 (en) | Modified photocatalyst sol | |
TW375534B (en) | Titanium oxide photocatalyst and producing method | |
CA2204620A1 (en) | Treatment of aluminium or aluminium alloys | |
AU3800495A (en) | Process for coating electrically non-conducting surfaces with connected metal structures | |
JPH09313948A (en) | Resin having photocatalyst surface, resin coating material and its production | |
JPH10249985A (en) | Manufacture of organic/metal oxide composite thin film | |
JPH036653B2 (en) | ||
CN111530305A (en) | Polypyrrole/metal mesh porous filtering membrane with nanocone structure and preparation method and application thereof | |
US3672937A (en) | Process for the non-electrolytic metallizing of non-conductors | |
JP2001152362A (en) | Photocatalyst-coated metallic sheet | |
JP2000014755A (en) | Metal plate having photocatalytic function | |
CN1164436A (en) | Method for preparation of extra-thin palladium-ceramic compound film | |
CN1027087C (en) | Process for forming membrane |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKEX | Expiry |
Effective date: 20161219 |