CA2237074A1 - A densified titanium diboride based ceramic composition - Google Patents
A densified titanium diboride based ceramic composition Download PDFInfo
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- CA2237074A1 CA2237074A1 CA002237074A CA2237074A CA2237074A1 CA 2237074 A1 CA2237074 A1 CA 2237074A1 CA 002237074 A CA002237074 A CA 002237074A CA 2237074 A CA2237074 A CA 2237074A CA 2237074 A1 CA2237074 A1 CA 2237074A1
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- 239000000203 mixture Substances 0.000 title claims abstract description 46
- QYEXBYZXHDUPRC-UHFFFAOYSA-N B#[Ti]#B Chemical compound B#[Ti]#B QYEXBYZXHDUPRC-UHFFFAOYSA-N 0.000 title claims abstract description 39
- 229910033181 TiB2 Inorganic materials 0.000 title claims abstract description 39
- 239000000919 ceramic Substances 0.000 title claims abstract description 31
- 239000010936 titanium Substances 0.000 claims abstract description 24
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 23
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 18
- 229910052751 metal Inorganic materials 0.000 claims description 25
- 239000002184 metal Substances 0.000 claims description 24
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 11
- 239000010937 tungsten Substances 0.000 claims description 11
- 229910052735 hafnium Inorganic materials 0.000 claims description 10
- 229910052726 zirconium Inorganic materials 0.000 claims description 9
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 7
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 6
- 229910052742 iron Inorganic materials 0.000 claims description 6
- 229910052750 molybdenum Inorganic materials 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- 239000013078 crystal Substances 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 229910052759 nickel Inorganic materials 0.000 claims description 5
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- 229910052758 niobium Inorganic materials 0.000 claims description 4
- 229910052715 tantalum Inorganic materials 0.000 claims description 4
- 238000005520 cutting process Methods 0.000 abstract description 45
- 238000003754 machining Methods 0.000 abstract description 42
- 229910045601 alloy Inorganic materials 0.000 abstract description 15
- 239000000956 alloy Substances 0.000 abstract description 15
- 239000000843 powder Substances 0.000 description 27
- 229910001069 Ti alloy Inorganic materials 0.000 description 23
- 239000000463 material Substances 0.000 description 16
- 238000007731 hot pressing Methods 0.000 description 11
- 239000002826 coolant Substances 0.000 description 10
- 238000003801 milling Methods 0.000 description 10
- 238000000280 densification Methods 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- 238000002441 X-ray diffraction Methods 0.000 description 8
- 238000007514 turning Methods 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 7
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 6
- 150000001247 metal acetylides Chemical class 0.000 description 6
- 239000007769 metal material Substances 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 238000005245 sintering Methods 0.000 description 6
- 229910000883 Ti6Al4V Inorganic materials 0.000 description 5
- 229910009043 WC-Co Inorganic materials 0.000 description 5
- 238000007792 addition Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 229910007948 ZrB2 Inorganic materials 0.000 description 4
- 230000002411 adverse Effects 0.000 description 4
- VWZIXVXBCBBRGP-UHFFFAOYSA-N boron;zirconium Chemical compound B#[Zr]#B VWZIXVXBCBBRGP-UHFFFAOYSA-N 0.000 description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 4
- 235000019589 hardness Nutrition 0.000 description 4
- 238000001513 hot isostatic pressing Methods 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 239000006104 solid solution Substances 0.000 description 4
- 229910052580 B4C Inorganic materials 0.000 description 3
- 229910003862 HfB2 Inorganic materials 0.000 description 3
- 229910052786 argon Inorganic materials 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 125000001475 halogen functional group Chemical group 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 239000006187 pill Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910052582 BN Inorganic materials 0.000 description 2
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
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- 239000011230 binding agent Substances 0.000 description 2
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- 229910010293 ceramic material Inorganic materials 0.000 description 2
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- 239000011159 matrix material Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
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- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
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- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000012300 argon atmosphere Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- INAHAJYZKVIDIZ-UHFFFAOYSA-N boron carbide Chemical compound B12B3B4C32B41 INAHAJYZKVIDIZ-UHFFFAOYSA-N 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- 239000011195 cermet Substances 0.000 description 1
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- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
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- MELCCCHYSRGEEL-UHFFFAOYSA-N hafnium diboride Chemical compound [Hf]1B=B1 MELCCCHYSRGEEL-UHFFFAOYSA-N 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
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- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 1
- 238000001238 wet grinding Methods 0.000 description 1
Landscapes
- Ceramic Products (AREA)
Abstract
A densified titanium diboride based ceramic composition is provided having W and Co therein and a fine grain size. The composition has particular usefulness as a cutting tool for machining of titanium based alloys at high speeds.
Description
BACKGROUND OF THE INVENTION
This is a divisional of application Serial Number 2,146,665 filed March 31, 1994 for Group IVB Boride Based Cutting Tools.
The present invention relates to Group IVB
(titanium, hafnium, zirconium) boride based articles, cutting tools and their densification techniques. It is especially related to titanium diboride based cutting tools and their use to machine Group IVB metals and alloys, especially titanium and its alloys.
It was recognized as early as 1955 that "machining of titanium and its alloys would always be a problem, no matter what techniques are employed to transform this metal into chips," (Siekmann, H. J. Tool Engng, Jan. 1955, Vol. 34, Pages 78-82).
Over approximately the past forty years, commercial machining technology for most workpiece materials has advanced significantly. Ceramic, cermet and ceramic coated cutting tools have been developed and commercialized which have significantly improved productivity in machining of steels, cast irons and superalloys. However, during that same time period, progress in the field of machining titanium alloys has been minor. The commercial cutting tool materials of choice for most titanium machining applications remain high speed tool steels and an uncoated, approximately 6 weight percent cobalt cemented tungsten carbide, such as Kennametal K313 cemented carbide grade. Where coated cemented carbide tools (e.g., Kennametal, KC720 and KC730 grades) have been applied to titanium alloy machining, they have met with only limited success. The use of uncoated cemented carbides to machine titanium based metallic materials has greatly limited productivity advances in the machining of these materials, since uncoated carbides are limited in most commercial applications to speeds of 250 surface feet/minute or less when machining titanium alloys (see Dearnley et al., "Evaluation of Principal Wear Mechanisms of Cemented Carbides and Ceramics used for Machining Titanium Alloy IMI318," Materials Science and Technology, January 1986, Vol. 2, Pages 47-58; Dearnley et al., "Wear Mechanisms of Cemented Carbides and Ceramics used for Machining Titanium," High Tech Ceramics, ed. by P.
Vincenzini, Elsevier Sci. Publ. (1987) Pages 2699-2712; Metals Handbook, Ninth Edition, Vol. 16, "Machining," (1989), Pages 844-857; Marchado et al., "Machining of Titanium and Its Alloys - A Review," Proc. Instn. Mech. Engrs., Vol. 204 (1990) Pages 53-60; and "Kennametal Tools, Tooling Systems and Services for the Global Metalworking Industry," Catalogue No.
A90-41(150)E1, (1991) Page 274.
Kennametal, KC, K313, KC720 and KC730 are trademarks of Kennametal Inc., of Latrobe, Pennsylvania, for its cutting tool grades.
The machining speed used when machining titanium alloys with uncoated cemented carbide tools may be increased to 500 to 1000 surface feet/minute, through the use of a high pressure coolant machining system (e.g., U. S. Patent No.
4,621,547). These systems are expensive, difficult to integrate into existing machine tools, and require a significant amount of maintenance. Their application in titanium alloy machining has, therefore, been limited.
Clearly, there has thus been an unfulfilled long-felt need for improved cutting tool materials, and improved methods for machining titanium based metallic materials.
SUMMARY OF THE INVENTION
The present inventors have now surprisingly discovered a new cutting tool material for machining titanium based metallic materials, which significantly advances titanium machining productivity and fulfils the long-felt need identified above. Applicants have found that the present invention may be utilized in the machining of a titanium alloy at a metal removal rate of about two to three times that obtained with uncoated carbide cutting tools using flood cooling while maintaining about the same amount of metal removed per cutting edge. This results in a significant reduction in the labor time required to machine a given titanium alloy workpiece while significantly increasing machine availability. These results are achieved using standard flood cooling techniques. The present invention, therefore, has the further advantage that it does not require the use of a high pressure coolant system to achieve high machining speeds.
In a broad aspect, this invention provides a densified ceramic composition comprising the following phases:
a first TixlMyl boride phase, where xl > Yl, Yl 2 0, and M includes tungsten;
This is a divisional of application Serial Number 2,146,665 filed March 31, 1994 for Group IVB Boride Based Cutting Tools.
The present invention relates to Group IVB
(titanium, hafnium, zirconium) boride based articles, cutting tools and their densification techniques. It is especially related to titanium diboride based cutting tools and their use to machine Group IVB metals and alloys, especially titanium and its alloys.
It was recognized as early as 1955 that "machining of titanium and its alloys would always be a problem, no matter what techniques are employed to transform this metal into chips," (Siekmann, H. J. Tool Engng, Jan. 1955, Vol. 34, Pages 78-82).
Over approximately the past forty years, commercial machining technology for most workpiece materials has advanced significantly. Ceramic, cermet and ceramic coated cutting tools have been developed and commercialized which have significantly improved productivity in machining of steels, cast irons and superalloys. However, during that same time period, progress in the field of machining titanium alloys has been minor. The commercial cutting tool materials of choice for most titanium machining applications remain high speed tool steels and an uncoated, approximately 6 weight percent cobalt cemented tungsten carbide, such as Kennametal K313 cemented carbide grade. Where coated cemented carbide tools (e.g., Kennametal, KC720 and KC730 grades) have been applied to titanium alloy machining, they have met with only limited success. The use of uncoated cemented carbides to machine titanium based metallic materials has greatly limited productivity advances in the machining of these materials, since uncoated carbides are limited in most commercial applications to speeds of 250 surface feet/minute or less when machining titanium alloys (see Dearnley et al., "Evaluation of Principal Wear Mechanisms of Cemented Carbides and Ceramics used for Machining Titanium Alloy IMI318," Materials Science and Technology, January 1986, Vol. 2, Pages 47-58; Dearnley et al., "Wear Mechanisms of Cemented Carbides and Ceramics used for Machining Titanium," High Tech Ceramics, ed. by P.
Vincenzini, Elsevier Sci. Publ. (1987) Pages 2699-2712; Metals Handbook, Ninth Edition, Vol. 16, "Machining," (1989), Pages 844-857; Marchado et al., "Machining of Titanium and Its Alloys - A Review," Proc. Instn. Mech. Engrs., Vol. 204 (1990) Pages 53-60; and "Kennametal Tools, Tooling Systems and Services for the Global Metalworking Industry," Catalogue No.
A90-41(150)E1, (1991) Page 274.
Kennametal, KC, K313, KC720 and KC730 are trademarks of Kennametal Inc., of Latrobe, Pennsylvania, for its cutting tool grades.
The machining speed used when machining titanium alloys with uncoated cemented carbide tools may be increased to 500 to 1000 surface feet/minute, through the use of a high pressure coolant machining system (e.g., U. S. Patent No.
4,621,547). These systems are expensive, difficult to integrate into existing machine tools, and require a significant amount of maintenance. Their application in titanium alloy machining has, therefore, been limited.
Clearly, there has thus been an unfulfilled long-felt need for improved cutting tool materials, and improved methods for machining titanium based metallic materials.
SUMMARY OF THE INVENTION
The present inventors have now surprisingly discovered a new cutting tool material for machining titanium based metallic materials, which significantly advances titanium machining productivity and fulfils the long-felt need identified above. Applicants have found that the present invention may be utilized in the machining of a titanium alloy at a metal removal rate of about two to three times that obtained with uncoated carbide cutting tools using flood cooling while maintaining about the same amount of metal removed per cutting edge. This results in a significant reduction in the labor time required to machine a given titanium alloy workpiece while significantly increasing machine availability. These results are achieved using standard flood cooling techniques. The present invention, therefore, has the further advantage that it does not require the use of a high pressure coolant system to achieve high machining speeds.
In a broad aspect, this invention provides a densified ceramic composition comprising the following phases:
a first TixlMyl boride phase, where xl > Yl, Yl 2 0, and M includes tungsten;
a second TiX2My2Z phase, where x2 ~ Y2l Y2 > 0 and M
includes tungsten;
wherein Y2/X2 > Y1/Xli wherein said phases are distributed throughout the densified ceramic composition; and the densified ceramic composition has an average grain size of 8~m or less.
In a second broad aspect, this invention provides a metal boride ceramic composition comprising:
a first metal diboride phase having a first metal selected from the group of titanium, hafnium, zirconium, alone or in combination with each other and a second diboride based phase having a first metal selected from the group of Ti, Hf and Zr, alone or in combination with each other, and a second metal selected from the group of W, Mo, Ta, Nb, Fe, Ni, Co, Al, Cr, alone or in combination wlth each other;
and wherein said ceramic has an average grain size of 6~m or less.
In a third broad aspect, this invention provides a titanium diboride based densified ceramic composition comprising:
a microstructure having a TiXlMylB2 first phase with a second phase of a TiX2My2Z about said first phase, wherein xl > yl;
wherein yl 2 0;
whereln x2 > Y2 wherein Y2 ' ~;
wherein Y2/X2 ~ Yl/Xl; and wherein M includes tungsten.
In a fourth broad aspect, this invention provides a densified titanium diboride based ceramic article of manufacture comprising:
a microstructure composed of phases consisting essentially of a TiB2 crystal structure; and wherein said phases include phases containing tungsten at differing concentration levels;
a density of at least 97~ of theoretical density;
a hardness of 94.3 to 96.5 Rockwell A at room temperature; and wherein said microstructure has an average grain size of 8~m or less.
These and other aspects of the present invention will become more apparent upon review of the figures briefly described below in conjunction with the detailed description of the invention which follows.
BRIEF DESCRIPTION OF THE DRAWINGS
Figure 1 shows an embodiment of a cutting tool in accordance with the present invention.
Figure 2 shows an embodiment of the microstructure of the present invention as obtained by a scanning electron microscopy back scattered imaging technique.
Figure 3 shows an embodiment of the microstructure of the present invention at five times the magnification used in Figure 2.
Figure 4 is a graph of nose wear against cutting time for the present invention and a prior art uncoated cemented carbide tool during the turning of a Ti-6Al-4V alloy.
Figure 5 is a graph of maximum flank wear as a function of cutting time in the turning of a Ti-6Al-4V alloy for the present invention and a prior art uncoated cemented carbide.
Figure 6 is a graph of maximum flank wear as a function of cutting time in the machining of Ti-6Al-4V alloy for the present invention and the prior art uncoated cemented carbide at 152 and 213 surface meters/minute (500 and 700 surface feet/minute).
DETAILED DESCRIPTION OF THE INVENTION
A preferred embodiment of an article of manufacture in accordance with the present invention is shown in Figure 1.
While the present invention may find use in many applications, the present inventors have found it to be particularly useful as a cutting tool.
Figure 1 shows an embodiment of an indexable metalcutting insert 10 composed of the ceramic material discovered by the present inventors. The present invention is preferably used in the high speed (>400 surface feet/minute) chip forming machining (e.g., turning, milling, grooving, threading, drilling, boring, sawing) of Group IVB metallic materials (i.e., zirconium and its alloys, titanium and its alloys, and hafnium and its alloys). The inventors have found the present invention to be particularly useful in the high speed machining of titanium alloys. Preferably, the speed should be at least 500 sfm, and preferably, 1,000 sfm or less, to obtain the most advantageous use of the present invention when machining these materials. Preferred feed rates contemplated for machining titanium alloys are .002 to .015 inch/revolution, and more preferably, .002 to .010 inch/revolution. Preferred depths of cut contemplated for machining titanium alloys are about 0.01 to about 0.2 inch, and more preferably, about 0.01 to about 0.15 inch.
The cutting tool 10 has a rake face 30 over which chips formed during said high speed machining of a Group IVB
metallic material flow. Joined to the rake face 30 is at least one flank face 50. At at least one juncture of the rake face 30 and flank faces 50, a cutting edge 70 is formed, for cutting into the Group IVB metallic material.
While the cutting edge 70 may be in a sharp, honed, chamfered, or chamfered and honed condition, it is preferred that it be in a chamfered condition, an embodiment of which is illustrated in Figure 1.
Preferably, the cutting insert 10 has a cutting edge lifetime of at least 3 minutes, and more preferably, at least 5 minutes during the high speed machining (e.g., turning) of a titanium alloy. In addition, the tool in accordance with the present invention has a maximum flank wear rate preferably no greater than one-half, and more preferably, no greater than one-third that of an uncoated cemented carbide tool when machining (e.g., turning) a titanium alloy under the same high speed cutting conditions, including flood cooling.
The cutting tool shown in Figure 1 is, preferably, composed of the TiB2 based ceramic material in accordance with the present invention. Figures 2 and 3 show typical microstructures of a preferred embodiment (see Example No. 1, Table I) of the present invention at two different magnifications. From Figure 2, it can be seen that the grain structure is substantially fine and uniform, with an average grain size estimated to be about 4~m. It can be most clearly seen in Figure 3 that the grain structure is typically characterized by a dark central phase, or central portion, which may, preferably, be TiB2 or TiXlMylB2l where M may preferably include W and/or Co and y 2 0. This first phase appears to be embedded in a matrix composed of a second, and possibly, a third phase. In many instances, adjacent to and substantially surrounding the central grain is a light grey second phase which is believed to be composed of a TiX2My2Z
phase, where x2 > Y2 and Y2 ' ~~ Y2/X2 ' Y1/X1 and M
preferably includes W and/or Co. Around many of these phases is a third phase which is of a shade of grey intermediate that of the central portion and the second phase. This third phase is believed to be composed of a TiX3My3Z phase, where My3 is preferably W and/or Co and where X3 > y3, y3 > 0 and y2/x2 >
y3/x3 > yl/x1 (e.g., the second phase has a greater concentration of tungsten in it than the third phase matrix).
The concentration of titanium, however, is preferably greatest in the central portion of the grain. X-ray diffraction analysis has also shown that the major phase(s) present is of the TiB2 type crystal structure; however, because of the lack of sensitivity of x-ray diffraction to minor levels of phases and minor levels of solid solutioning, it is unclear, based on x-ray diffraction alone, as to what minor phases or solid solutions may be present.
It is also unclear from the x-ray diffraction work alone what phases form the second and third phases mentioned above. However, since from the photomicrographs there appears to be substantial amounts of the second and third phases present, their absence from the x-ray diffraction studies done is believed to be explainable if these phases are also TiXnMynB2 (i.e., Z=B2) phases containing minor amounts of W
and/or Co in solid solution (e.g., TiX2Wy2B2 and TiX3Wy3B2).
In this case, their absence from the x-ray diffraction trace would be explained by the almost identical lattice constants they would have with TiB2. That is, the TiB2 peaks are substantially identical to, and therefore mask, the peaks of the second and third phases.
While it is believed that the phases forming the halos about the first phase (see Figure 3) are diborides, they may also possibly contain minor amounts of, boroncarbide, boronitride, boronoxide, borocarbonitride, boroxycarbide, boroxynitride or a boroxycarbonitride; however, this has not been confirmed. What appears to be definite, however, is that the inner halo, or second phase, has a greater concentration of tungsten than the outer halo, or third phase, and all three phases contain titanium as the major metallic element present.
In addition to the TiB2 phase observed by x-ray diffraction, other phases that have been at times observed in minor amounts by x-ray diffraction include CoW2B2, CoWB5, WB, 68188-7lD
CA 02237074 l998-07-03 W2B, W3CoB, TiB and Ti3B4. The white phase visible in Figure 3 is believed to be one of the tungsten rich phases mentioned above. The black spots shown in Figure 3 are believed to be porosity.
In the alternative, similar compositions may be made based on ZrB2 or HfB2, or their mixtures and solid solutions with each other or TiB2. These compositions are less preferred than the TiB2 based composition described above because of their higher cost. In general, therefore, it can be stated that the present invention includes a densified composition, including a first metal diboride phase having a first metal selected from the group of titanium, hafnium and zirconium alone, or in combination with each other, and optionally in combination with W and/or Co, and preferably a second metal diboride phase having a metal which includes W
and/or Co, in combination with Ti, Hf and/or Zr, Mo, Nb, Ta may be partially or wholly substituted for the W in the material, while iron and/or nickel may be partially or wholly substituted for the Co in the material. In addition, W, Mo, Al and/or Cr may be partially substituted for the cobalt in the material.
The densification of the present invention may be achieved either by hot pressing a blend of the appropriate powders or by cold pressing the blended powders to form a compact which is then sintered and hot isostatically pressed.
These processes will be illustrated by the following discussion directed to TiB2 based compositions, but it should be understood that the techniques described are also applicable to ZrB2 and HfB2 based compositions and their mixtures and solid solutions with each other and/or TiB2 in accordance with the present invention.
In accordance with the present invention, a blend of powders is prepared, composed of at least 60 w/o; preferably, at least 75 w/o; more preferably, at least 85 w/o; and most preferably, at least 90 w/o TiB2.
It is preferred that the level of TiB2 utilized should be as high as possible commensurate with the ability of the composition to be densified by either the hot pressing or the cold pressing-sintering-hot isostatic pressing route in order to achieve the high wear resistance while machining titanium alloys. Applicants have found that TiB2 has excellent resistance to reactivity with titanium during titanium alloy machining and has good thermal conductivity compared with other ceramics; however, it is very difficult to densify, while maintaining a fine grain size.
Applicants have surprisingly discovered that TiB2 based ceramics can be readily densified if WC and Co are added to the TiB2 powder blend. The WC and Co may be added: (1) directly as individual WC (or W and C) and Co powders; or (2) as a result of the attrition of the cemented WC-Co milling media during milling of the TiB2 powder; (3) as a cemented WC-Co powder; or (4) by a combination of (1), (2) and/or (3).
At least 2.5 w/o total of WC + Co should be added to the TiB2 powder to assure densification at 2000~C or less in hot pressing. Where densification is to be achieved by cold compaction-sintering and hot isostatic pressing, it is preferred that there be at least 3.0 w/o total of WC + Co.
While not optimized, the inventors have found that the ratio of W/Co on a weight percent basis may be about 9:1 to about 20:1. It has been found that the addition of the combination of Co and WC in the minimum amounts indicated significantly improves the ease with which densification is achieved, without an adverse effect on the grain size of the resulting material. It is believed that this effect is due to a low melting point eutectic alloy formed by the WC and Co during the sintering process. It is, therefore, believed that W/Co ratios as low as 1:20 may also be useful and may result in a further lowering of the sintering or hot pressing temperatures required to achieve substantial densification.
The total WC + Co addition preferably should be less than about 12 w/o, and more preferably, less than 10 w/o, since increasing WC + Co content increases the observed wear rate during the high speed machining of titanium alloys.
The inventors have also found that the grain size of the densified article may be further controlled by the addition of an effective amount of a grain growth inhibitor to the powder blend. The inventors, therefore, prefer to add BN
powder to the blend at a preferred level of about 0.25 to 1.0 v/o of the powder blend.
Limited amounts (not exceeding about 35 v/o total) of other elements and/or compounds may be added to the powder blend to improve various properties of the material for specific applications. Such additions that are now contemplated may include: (1) TiC, ZrC, B4C, TaC and MO2C to improve wear resistance; (2) TiN, TiC to assist in densification. Hafnium diboride and/or zirconium diboride may also be substituted for TiB2 to improve wear resistance, preferably, the total content of HfB2 and ZrB2 in the composition is also held below 35 v/o. It is also contemplated that a portion of the Co addition may be partially replaced by, or supplemented by, small amounts of W, Fe, Mo, Ni, Al and Cr, and totally replaced by Fe and/or Ni.
Fracture toughness may be further improved through the use of starting powders having an elongated or whisker morphology. For example, some of the TiB2 starting powder may be replaced by TiB2 whiskers, or SiC, B4C, TiC, ZrC, TaC or MO2C may be added as elongated particles or whiskers.
The foregoing powders are preferably blended for a time appropriate to provide the desired pick up in WC and Co from the WC-Co cemented carbide milling media. Preferably, at least about 2.5 w/o of WC + Co is added to the blend in this manner.
The blended powder is then densified. If it is densified by uniaxial hot pressing, then the hot pressing temperatures and pressures used are preferably about 1800-2000~C and about 1 to 5 Ksi, and more preferably, 1 to 2 Ksi. It is desirable that the hot pressing temperature be minimized to minimize grain growth. In order to achieve maximum densification during hot pressing, the pressure should be maintained sufficiently low during temperature elevation to allow gases generated during heat-up to escape. After these gases have escaped, the full hot pressing pressure may then be applied.
Alternatively, the powder blend may also be densified by cold compaction to form a green compact, followed by sintering, preferably at 1800 to 2200~C, preferably followed by hot isostatic pressing, preferably at 1700 to 2100~C, and up to 30,000 psi using argon or helium or other inert gas, but not nitrogen. This manufacturing route is preferable over the hot pressing route if equivalent levels of densification and a fine grain size can be achieved for a given composition, since the cutting and grinding of a hot pressed ceramic billets is avoided, thereby reducing the manufacturing cost.
- The inventors believe that the grain size in the densified article is very important to achieving the best metalcutting properties and, therefore, prefer that the average grain size be 8~m, or less, more preferably, 6~m, or less, and most preferably, 4~m or less. The inventors believe that a fine grain size is important because TiB2 has a very high modulus of elasticity, E, and an anisotropic thermal expansion coefficient, ~, which would tend to reduce the thermal shock resistance of a ceramic containing large TiB2 grains. The inventors, however, believe that they have minimized any adverse consequences of these properties by maintaining the fineness of the grains, as described above, which are believed to be substantially randomly oriented.
The resulting articles made in accordance with the present invention preferably have a Rockwell A room temperature hardness of about 94.3 to 96.5, more preferably, about 94.7 to 96.0, and most preferably, 95.0 to 96Ø Their density is, preferably, at least 97~, and more preferably, at least 98~ of the theoretical calculated density. The KIC
(Evans & Charles) fracture toughness of these articles is difficult to measure, but is estimated to be (using 300 to 500 gm loads), by the Palmqvist indentation method of fracture toughness measurement, about 3.5 to about 4.5 MPam~. Despite this low mechanical fracture toughness, the articles in accordance with the present invention have been surprisingly found to have excellent toughness during the turning of a titanium alloy as described in the examples which follow.
These examples are provided to further illustrate the significant benefit provided by the present invention in the high speed machining of titanium alloys.
In accordance with the present invention, articles were made of the compositions shown in Table I.
N ~ E ~
~n P~~
t q ,-I O L
U oP O U
a u, ~ a " ~O CD a~
U O
a bl ~, _ -rl U~ ~ X r~ r~ ~ r~ r~ r~ r~
a) O o o o o o o o _ . o In O O ~ O O
Q~ Ul ~ -~ r~ ~I r~ r~ r1 O
tl r~
~~ r~ O ~ ~ ~ ~
r- J~ + ~ I 111 ~ -, o 3 3 E~
u ~ a, ~ ,~~NO ~1'1 ~ ~
E
.r -rl U ~UL
O -, O ~ o L
O O
0 ~0 0 ~V
r~l U N O ~ r ~D ~ O O
~ O ~ O N~
+~ +' + ~ + ~a m~ a:) 3 b- r-~ In O
O o O oo ,~ oo ~ o ~~ ~ ~~ O ~ N
m a + + + -rl rcN r~ N NN U NN C~~D
n ~. ~2 . . 3 3 (L
r ~L
Izr; N(~1 ~ Il~D ~ L
a lC rl The titanium diboride starting powder used was Grade F obtained from Hermann C. Starck Berlin GmbH & Co. KG, P.O.B.
1229, D-7887 Laufenburg/Baden, Germany. This powder is composed of crushed and milled irregular shape particles having an hexagonal crystal structure. The specification, along with an example of the actual properties for this grade of TiB2 powder, are shown in Table II.
TABLE II
SPecification Measured Property BET Specific Surface Area > 4 m2/g 4. m2/g Scott TAP Density/Apparent Density-- 9.2 g/in3 FSSS Particle Size max. 0.9~m 0.9 ~m Max. Particle Size 98~ < 6~m Ti 2 66.5 wt. ~ remainder B 2 28.5 wt. ~ 29.8 Nonmetallic Impurities C s 0.25 wt. ~ 0.21 O s 2.0 wt. ~ 1.92 N s 0.25 wt. ~ 0.11 Metallic Impurities Fe s 0.25 wt. ~ 0.18 Other - Total s 0.2 wt. ~ c 0.2 The boron nitride starting powder was obtained from Union Carbide as grade HCP.
The WC powder had the following properties:
Total Carbon 6.11 w/o Cr .01 w/o Free Carbon .01 w/o Ta .12 w/o ~2 .17 w/o Ca .21 w/o Ni .01 w/o Fe .02 w/o BET 1.36 m2/g The cobalt powder was an extra fine grade cobalt.
These powders were milled together in the ratios shown in Table I to form 100 gm lots. Wet milling was performed in a polyurethane lined ball mill with isopropanol and about 3900 gm of WC-Co cemented carbide cycloids for the times shown in Table I. These cemented carbide cycloids have a nominal composition containing about 5.7 w/o Co, 1.9 w/o Ta and a nominal Rockwell A hardness and nominal magnetic saturation value of about 92.7 and about 92 percent, respectively.
From our experience in milling these powders under the conditions described, it is estimated that, for a milling time of 45 to 50 minutes, about 2.4 to about 2.7 w/o of WC +
Co, and for a milling time of 120 minutes, about 4.1 to about 5.8 w/o WC + Co, is added to the blend due to the attrition of the WC-Co cemented carbide cycloids during milling.
After milling, powder blends were dried, screened and then uniaxially hot pressed according to the conditions shown in Table I in an argon atmosphere. During heating, pressure was not applied. The pressing pressure was first applied at the hot pressing temperature and held for typically one hour. The resulting articles produced were essentially fully dense and have the densities, hardnesses and grain sizes shown in Table I. Billets made in accordance with Example 1 were cut and ground to produce SNGN-453T (.002-.004 inch x 20~
chamfer) style indexable metalcutting inserts (see Figure 1).
These inserts were tested in the metalcutting tests described below in Table III against prior art sharp edged K313 grade cemented carbide SNGN-433 style cutting inserts.
These tests were run under flood coolant at 600, 800 and 1,000 surface feet/minute, 0.005 ipr and 0.050 inch depth of cut as described in Table III. The cutting tools composed of material in accordance with the present invention had more than twice the life of the prior art cemented carbide tools.
It was observed that chemical reaction between the titanium alloy workpiece and the cutting tool according to the present invention was the dominant wear mechanism on the rake and flank faces. The present invention, however, had a significantly lower wear rate than the prior art tool, as illustrated by the graphs of nose wear and maximum flank wear shown in Figures 4 and 5, respectively, which are based on the results of the 600 sfm test shown in Table III.
A water soluble coolant, which may be used in these applications, is Cimtech 500. Cimtech 500 is a synthetic fluid concentrate for machining and stamping ferrous metals.
It is supplied by Cincinnati Milicron Marketing Co., of Cincinnati, Ohio. It is typically diluted in water at a water to coolant ratio of 30:1 to 20:1 for machining applications.
TABLE III
METALCUTTING TEST RESULTS
Tool Life in Minutes 600 sfm 800 sfm 1,000 sfm Invention > 5.0 > 1.5 1.5 BK
Prior Art 2.5 FW c 0.5 BK Not Run Conditions Operation: Turning Workpiece Material: Ti-6Al-4V titanium alloy (Annealed at 1300~F for 2 hours and air cooled) Cutting Speed: as noted above Feed: .005 inch/revolution Depth of Cut: .050 inch Lead Angle: 45 degrees Rake Angle: -5 degrees back rake and -5 degrees side rake Cutting Fluid: Flood water soluble coolant diluted 20:1 with water End of Life Criteria Breakage (BK) Flank Wear (FW) 2 . 030 inch Maximum Flank Wear (MW) 2 . 040 inch Nose Wear (NW) 2 . 040 inch Depth of Cut Notching (DN) 2 . 80 inch It was further surprisingly found that the low fracture toughness, mentioned above, of the invention did not adversely affect the ability of the material to turn the above titanium alloy. It was further surprisingly found that the use of flood coolant did not cause the invention to break from excessive thermal shock. These results demonstrate that the present invention has at least twice the cutting edge lifetime of the prior art cemented carbide tools at machining speeds far beyond those recommended (i.e., ~250 sfm) for uncoated carbide.
While uncoated cemented carbides can achieve similar lifetimes to those found for the present invention at lower speeds (c250 sfm), these lower speeds greatly reduce the metal removal rate, which is important in determining machining costs and machine availability.
In another example, the composition used in Example 1 was blended in accordance with Example 1. After milling, the powders were dried, pelletized with a lubricant/fugitive binder (e.g., rosin/polyethylene glycol) and then uniaxially cold pressed to form green cutting inserts. The green inserts were heated in a vacuum up to about 460~C to volatilize the lubricant and fugitive binder. Heating was then continued in one atmosphere of argon to a sintering temperature of about 2000~C, which was held for 60 minutes and then cooled to room temperature. The sintered inserts were then hot isostatically pressed at 1850~C for 60 minutes under 15 Ksi argon.
Sintering and hot isostatic pressing were performed by placing the inserts on a bed of boron nitride setting powder. The inserts were then ground to final size. In this manner, RNGN-45T (.002-.004 inch x 20~ chamfer) style cutting inserts were fabricated. These cutting inserts were tested against prior art K313 grade cemented carbide cutting inserts in the RNGN-45 style with a sharp cutting edge in the turning of Ti-6Al-4V titanium alloy. The test conditions, as well as the results of these tests, are shown in Table IV and Figure 6, and are summarized below.
A single test trial was run at 152 m/minute (500 sfm), comparing the pill pressed-sinter-Hipped inserts to the prior art K313 grade of cemented carbide. Figure 6 is a plot of maximum flank wear. The important observation is that the wear rate for the present invention is relatively uniform through the end of life, at 10 minutes (based on .040 inch maximum flank wear). The 152 m/minute cutting speed is too high for the prior art, which had less than three minutes of tool life due to maximum flank wear exceeding 0.040 inch.
T~3LE IV
CONDITION Time MAXIMUM FLANK WEAR (inch) 500 sfm/ (minutes) RUN 1 RUN 2 .0072 IPR/ INVENTION PRIOR ART INVENTION PRIOR ART
.050"DOC/
Flood Coolant 1 .0151 .0081 2 .0169 .0203 3 .0182 .0428 4 .0214 0.223 6 .0255 7 .0286 8 .0301 9 .0345 .0401 700 sfm/
.0072 IPR/
.050" DOC/
68188-7lD
Flood Coolant 1 .0163.0263 .0170 .0354 2 .0228.0984 .0230 .0510 3 .0285 .0296 4 .0367 .0359 .0445 .0434 1000 sfm/
.005 IPR/
.050" DOC/
Flood Coolant 1 .0202 .1436 2 broken Two test trials were run at 212 m/minute (700 sfm) (see Table IV and Figure 6). It was found that the pill pressed-sintered and Hipped inserts (~) had equal or better wear rate compared to the hot pressed inserts (~) under these conditions. (The hot pressed insert (RNGN-43T) failed prematurely by cracking because it was too thin for this application.) At 700 sfm, the present invention maintains a uniform wear rate that is significantly superior to that produced in the prior art cutting tool. The 700 sfm cutting speed is also clearly out of the useful range of the uncoated carbide tested, which experienced extreme localized wear in less than two minutes.
In an attempt to determine the upper limit of the cutting speed for the present invention, a test was run at 1000 sfm (see Table IV). The invention failed at two minutes due to breakage. The prior art cemented carbide tool experienced extreme localized wear and resulting rake and flank face chipping in less than one minute.
Based on the foregoing examples, it is clear that the pill pressed, sintered and Hipped cutting tools according to the present invention have the same capabilities for machining titanium based materials as the hot pressed cutting tools according to the present invention. The present invention is capable of withstanding cutting speeds which are significantly beyond the useful operating range of uncoated cemented carbide. It was further found that the present invention can withstand larger wear scars without experiencing the acceleration in wear rate that is typical of cemented carbide cutting tools.
It is further believed that the metalcutting performance of the present invention may be further improved, allowing longer cutting edge lifetime and/or higher machining speed capabilities, through the application of a refractory coating to the rake face, flank face and cutting edge. The coating may be applied by known PVD or CVD techniques now used to coat cutting tools. A refractory coating having one or more layers is preferably composed of one or more of the following refractory materials: alumina, and the borides, carbides, nitrides and carbonitrides of zirconlum, hafnium and tltanlum, thelr solld solutlons with each other and thelr alloys. It ls further proposed that use of such a refractory coatlng may allow the use of hlgher levels of toughenlng agents or WC + Co to further lmprove the slnterabillty of the present lnventlon, while minimizing the adverse lmpact of such increases on the wear rate when machining tltanium alloys.
It ls also contemplated that cuttlng lnserts ln accordance with the present lnventlon may be fabrlcated wlth elther a ground ln, or molded, chlpbreaker structure.
Examples of chlpbreaker structures whlch may be used hereln are descrlbed ln Unlted States Patent No. 5,141,367. Titanium alloy chlps are notorlously hard to break. Thls may be partlally due to the slow speeds used when uncoated cemented carbldes are utlllzed to turn tltanlum alloys. It ls our bellef that the hlgher machlnlng speeds now posslble wlth the present lnvention, ln comblnatlon wlth a chipbreaker structure, may lead to lmproved chlp control durlng the turnlng of tltanlum alloys.
Other embodlments of the lnventlon wlll be apparent to those skllled ln the art from a conslderatlon of thls speclflcation or practlce of the lnventlon disclosed hereln.
It ls lntended that the speclflcatlon and examples be consldered as exemplary only, wlth the true scope and splrlt of the lnventlon belng lndlcated by the followlng clalms.
includes tungsten;
wherein Y2/X2 > Y1/Xli wherein said phases are distributed throughout the densified ceramic composition; and the densified ceramic composition has an average grain size of 8~m or less.
In a second broad aspect, this invention provides a metal boride ceramic composition comprising:
a first metal diboride phase having a first metal selected from the group of titanium, hafnium, zirconium, alone or in combination with each other and a second diboride based phase having a first metal selected from the group of Ti, Hf and Zr, alone or in combination with each other, and a second metal selected from the group of W, Mo, Ta, Nb, Fe, Ni, Co, Al, Cr, alone or in combination wlth each other;
and wherein said ceramic has an average grain size of 6~m or less.
In a third broad aspect, this invention provides a titanium diboride based densified ceramic composition comprising:
a microstructure having a TiXlMylB2 first phase with a second phase of a TiX2My2Z about said first phase, wherein xl > yl;
wherein yl 2 0;
whereln x2 > Y2 wherein Y2 ' ~;
wherein Y2/X2 ~ Yl/Xl; and wherein M includes tungsten.
In a fourth broad aspect, this invention provides a densified titanium diboride based ceramic article of manufacture comprising:
a microstructure composed of phases consisting essentially of a TiB2 crystal structure; and wherein said phases include phases containing tungsten at differing concentration levels;
a density of at least 97~ of theoretical density;
a hardness of 94.3 to 96.5 Rockwell A at room temperature; and wherein said microstructure has an average grain size of 8~m or less.
These and other aspects of the present invention will become more apparent upon review of the figures briefly described below in conjunction with the detailed description of the invention which follows.
BRIEF DESCRIPTION OF THE DRAWINGS
Figure 1 shows an embodiment of a cutting tool in accordance with the present invention.
Figure 2 shows an embodiment of the microstructure of the present invention as obtained by a scanning electron microscopy back scattered imaging technique.
Figure 3 shows an embodiment of the microstructure of the present invention at five times the magnification used in Figure 2.
Figure 4 is a graph of nose wear against cutting time for the present invention and a prior art uncoated cemented carbide tool during the turning of a Ti-6Al-4V alloy.
Figure 5 is a graph of maximum flank wear as a function of cutting time in the turning of a Ti-6Al-4V alloy for the present invention and a prior art uncoated cemented carbide.
Figure 6 is a graph of maximum flank wear as a function of cutting time in the machining of Ti-6Al-4V alloy for the present invention and the prior art uncoated cemented carbide at 152 and 213 surface meters/minute (500 and 700 surface feet/minute).
DETAILED DESCRIPTION OF THE INVENTION
A preferred embodiment of an article of manufacture in accordance with the present invention is shown in Figure 1.
While the present invention may find use in many applications, the present inventors have found it to be particularly useful as a cutting tool.
Figure 1 shows an embodiment of an indexable metalcutting insert 10 composed of the ceramic material discovered by the present inventors. The present invention is preferably used in the high speed (>400 surface feet/minute) chip forming machining (e.g., turning, milling, grooving, threading, drilling, boring, sawing) of Group IVB metallic materials (i.e., zirconium and its alloys, titanium and its alloys, and hafnium and its alloys). The inventors have found the present invention to be particularly useful in the high speed machining of titanium alloys. Preferably, the speed should be at least 500 sfm, and preferably, 1,000 sfm or less, to obtain the most advantageous use of the present invention when machining these materials. Preferred feed rates contemplated for machining titanium alloys are .002 to .015 inch/revolution, and more preferably, .002 to .010 inch/revolution. Preferred depths of cut contemplated for machining titanium alloys are about 0.01 to about 0.2 inch, and more preferably, about 0.01 to about 0.15 inch.
The cutting tool 10 has a rake face 30 over which chips formed during said high speed machining of a Group IVB
metallic material flow. Joined to the rake face 30 is at least one flank face 50. At at least one juncture of the rake face 30 and flank faces 50, a cutting edge 70 is formed, for cutting into the Group IVB metallic material.
While the cutting edge 70 may be in a sharp, honed, chamfered, or chamfered and honed condition, it is preferred that it be in a chamfered condition, an embodiment of which is illustrated in Figure 1.
Preferably, the cutting insert 10 has a cutting edge lifetime of at least 3 minutes, and more preferably, at least 5 minutes during the high speed machining (e.g., turning) of a titanium alloy. In addition, the tool in accordance with the present invention has a maximum flank wear rate preferably no greater than one-half, and more preferably, no greater than one-third that of an uncoated cemented carbide tool when machining (e.g., turning) a titanium alloy under the same high speed cutting conditions, including flood cooling.
The cutting tool shown in Figure 1 is, preferably, composed of the TiB2 based ceramic material in accordance with the present invention. Figures 2 and 3 show typical microstructures of a preferred embodiment (see Example No. 1, Table I) of the present invention at two different magnifications. From Figure 2, it can be seen that the grain structure is substantially fine and uniform, with an average grain size estimated to be about 4~m. It can be most clearly seen in Figure 3 that the grain structure is typically characterized by a dark central phase, or central portion, which may, preferably, be TiB2 or TiXlMylB2l where M may preferably include W and/or Co and y 2 0. This first phase appears to be embedded in a matrix composed of a second, and possibly, a third phase. In many instances, adjacent to and substantially surrounding the central grain is a light grey second phase which is believed to be composed of a TiX2My2Z
phase, where x2 > Y2 and Y2 ' ~~ Y2/X2 ' Y1/X1 and M
preferably includes W and/or Co. Around many of these phases is a third phase which is of a shade of grey intermediate that of the central portion and the second phase. This third phase is believed to be composed of a TiX3My3Z phase, where My3 is preferably W and/or Co and where X3 > y3, y3 > 0 and y2/x2 >
y3/x3 > yl/x1 (e.g., the second phase has a greater concentration of tungsten in it than the third phase matrix).
The concentration of titanium, however, is preferably greatest in the central portion of the grain. X-ray diffraction analysis has also shown that the major phase(s) present is of the TiB2 type crystal structure; however, because of the lack of sensitivity of x-ray diffraction to minor levels of phases and minor levels of solid solutioning, it is unclear, based on x-ray diffraction alone, as to what minor phases or solid solutions may be present.
It is also unclear from the x-ray diffraction work alone what phases form the second and third phases mentioned above. However, since from the photomicrographs there appears to be substantial amounts of the second and third phases present, their absence from the x-ray diffraction studies done is believed to be explainable if these phases are also TiXnMynB2 (i.e., Z=B2) phases containing minor amounts of W
and/or Co in solid solution (e.g., TiX2Wy2B2 and TiX3Wy3B2).
In this case, their absence from the x-ray diffraction trace would be explained by the almost identical lattice constants they would have with TiB2. That is, the TiB2 peaks are substantially identical to, and therefore mask, the peaks of the second and third phases.
While it is believed that the phases forming the halos about the first phase (see Figure 3) are diborides, they may also possibly contain minor amounts of, boroncarbide, boronitride, boronoxide, borocarbonitride, boroxycarbide, boroxynitride or a boroxycarbonitride; however, this has not been confirmed. What appears to be definite, however, is that the inner halo, or second phase, has a greater concentration of tungsten than the outer halo, or third phase, and all three phases contain titanium as the major metallic element present.
In addition to the TiB2 phase observed by x-ray diffraction, other phases that have been at times observed in minor amounts by x-ray diffraction include CoW2B2, CoWB5, WB, 68188-7lD
CA 02237074 l998-07-03 W2B, W3CoB, TiB and Ti3B4. The white phase visible in Figure 3 is believed to be one of the tungsten rich phases mentioned above. The black spots shown in Figure 3 are believed to be porosity.
In the alternative, similar compositions may be made based on ZrB2 or HfB2, or their mixtures and solid solutions with each other or TiB2. These compositions are less preferred than the TiB2 based composition described above because of their higher cost. In general, therefore, it can be stated that the present invention includes a densified composition, including a first metal diboride phase having a first metal selected from the group of titanium, hafnium and zirconium alone, or in combination with each other, and optionally in combination with W and/or Co, and preferably a second metal diboride phase having a metal which includes W
and/or Co, in combination with Ti, Hf and/or Zr, Mo, Nb, Ta may be partially or wholly substituted for the W in the material, while iron and/or nickel may be partially or wholly substituted for the Co in the material. In addition, W, Mo, Al and/or Cr may be partially substituted for the cobalt in the material.
The densification of the present invention may be achieved either by hot pressing a blend of the appropriate powders or by cold pressing the blended powders to form a compact which is then sintered and hot isostatically pressed.
These processes will be illustrated by the following discussion directed to TiB2 based compositions, but it should be understood that the techniques described are also applicable to ZrB2 and HfB2 based compositions and their mixtures and solid solutions with each other and/or TiB2 in accordance with the present invention.
In accordance with the present invention, a blend of powders is prepared, composed of at least 60 w/o; preferably, at least 75 w/o; more preferably, at least 85 w/o; and most preferably, at least 90 w/o TiB2.
It is preferred that the level of TiB2 utilized should be as high as possible commensurate with the ability of the composition to be densified by either the hot pressing or the cold pressing-sintering-hot isostatic pressing route in order to achieve the high wear resistance while machining titanium alloys. Applicants have found that TiB2 has excellent resistance to reactivity with titanium during titanium alloy machining and has good thermal conductivity compared with other ceramics; however, it is very difficult to densify, while maintaining a fine grain size.
Applicants have surprisingly discovered that TiB2 based ceramics can be readily densified if WC and Co are added to the TiB2 powder blend. The WC and Co may be added: (1) directly as individual WC (or W and C) and Co powders; or (2) as a result of the attrition of the cemented WC-Co milling media during milling of the TiB2 powder; (3) as a cemented WC-Co powder; or (4) by a combination of (1), (2) and/or (3).
At least 2.5 w/o total of WC + Co should be added to the TiB2 powder to assure densification at 2000~C or less in hot pressing. Where densification is to be achieved by cold compaction-sintering and hot isostatic pressing, it is preferred that there be at least 3.0 w/o total of WC + Co.
While not optimized, the inventors have found that the ratio of W/Co on a weight percent basis may be about 9:1 to about 20:1. It has been found that the addition of the combination of Co and WC in the minimum amounts indicated significantly improves the ease with which densification is achieved, without an adverse effect on the grain size of the resulting material. It is believed that this effect is due to a low melting point eutectic alloy formed by the WC and Co during the sintering process. It is, therefore, believed that W/Co ratios as low as 1:20 may also be useful and may result in a further lowering of the sintering or hot pressing temperatures required to achieve substantial densification.
The total WC + Co addition preferably should be less than about 12 w/o, and more preferably, less than 10 w/o, since increasing WC + Co content increases the observed wear rate during the high speed machining of titanium alloys.
The inventors have also found that the grain size of the densified article may be further controlled by the addition of an effective amount of a grain growth inhibitor to the powder blend. The inventors, therefore, prefer to add BN
powder to the blend at a preferred level of about 0.25 to 1.0 v/o of the powder blend.
Limited amounts (not exceeding about 35 v/o total) of other elements and/or compounds may be added to the powder blend to improve various properties of the material for specific applications. Such additions that are now contemplated may include: (1) TiC, ZrC, B4C, TaC and MO2C to improve wear resistance; (2) TiN, TiC to assist in densification. Hafnium diboride and/or zirconium diboride may also be substituted for TiB2 to improve wear resistance, preferably, the total content of HfB2 and ZrB2 in the composition is also held below 35 v/o. It is also contemplated that a portion of the Co addition may be partially replaced by, or supplemented by, small amounts of W, Fe, Mo, Ni, Al and Cr, and totally replaced by Fe and/or Ni.
Fracture toughness may be further improved through the use of starting powders having an elongated or whisker morphology. For example, some of the TiB2 starting powder may be replaced by TiB2 whiskers, or SiC, B4C, TiC, ZrC, TaC or MO2C may be added as elongated particles or whiskers.
The foregoing powders are preferably blended for a time appropriate to provide the desired pick up in WC and Co from the WC-Co cemented carbide milling media. Preferably, at least about 2.5 w/o of WC + Co is added to the blend in this manner.
The blended powder is then densified. If it is densified by uniaxial hot pressing, then the hot pressing temperatures and pressures used are preferably about 1800-2000~C and about 1 to 5 Ksi, and more preferably, 1 to 2 Ksi. It is desirable that the hot pressing temperature be minimized to minimize grain growth. In order to achieve maximum densification during hot pressing, the pressure should be maintained sufficiently low during temperature elevation to allow gases generated during heat-up to escape. After these gases have escaped, the full hot pressing pressure may then be applied.
Alternatively, the powder blend may also be densified by cold compaction to form a green compact, followed by sintering, preferably at 1800 to 2200~C, preferably followed by hot isostatic pressing, preferably at 1700 to 2100~C, and up to 30,000 psi using argon or helium or other inert gas, but not nitrogen. This manufacturing route is preferable over the hot pressing route if equivalent levels of densification and a fine grain size can be achieved for a given composition, since the cutting and grinding of a hot pressed ceramic billets is avoided, thereby reducing the manufacturing cost.
- The inventors believe that the grain size in the densified article is very important to achieving the best metalcutting properties and, therefore, prefer that the average grain size be 8~m, or less, more preferably, 6~m, or less, and most preferably, 4~m or less. The inventors believe that a fine grain size is important because TiB2 has a very high modulus of elasticity, E, and an anisotropic thermal expansion coefficient, ~, which would tend to reduce the thermal shock resistance of a ceramic containing large TiB2 grains. The inventors, however, believe that they have minimized any adverse consequences of these properties by maintaining the fineness of the grains, as described above, which are believed to be substantially randomly oriented.
The resulting articles made in accordance with the present invention preferably have a Rockwell A room temperature hardness of about 94.3 to 96.5, more preferably, about 94.7 to 96.0, and most preferably, 95.0 to 96Ø Their density is, preferably, at least 97~, and more preferably, at least 98~ of the theoretical calculated density. The KIC
(Evans & Charles) fracture toughness of these articles is difficult to measure, but is estimated to be (using 300 to 500 gm loads), by the Palmqvist indentation method of fracture toughness measurement, about 3.5 to about 4.5 MPam~. Despite this low mechanical fracture toughness, the articles in accordance with the present invention have been surprisingly found to have excellent toughness during the turning of a titanium alloy as described in the examples which follow.
These examples are provided to further illustrate the significant benefit provided by the present invention in the high speed machining of titanium alloys.
In accordance with the present invention, articles were made of the compositions shown in Table I.
N ~ E ~
~n P~~
t q ,-I O L
U oP O U
a u, ~ a " ~O CD a~
U O
a bl ~, _ -rl U~ ~ X r~ r~ ~ r~ r~ r~ r~
a) O o o o o o o o _ . o In O O ~ O O
Q~ Ul ~ -~ r~ ~I r~ r~ r1 O
tl r~
~~ r~ O ~ ~ ~ ~
r- J~ + ~ I 111 ~ -, o 3 3 E~
u ~ a, ~ ,~~NO ~1'1 ~ ~
E
.r -rl U ~UL
O -, O ~ o L
O O
0 ~0 0 ~V
r~l U N O ~ r ~D ~ O O
~ O ~ O N~
+~ +' + ~ + ~a m~ a:) 3 b- r-~ In O
O o O oo ,~ oo ~ o ~~ ~ ~~ O ~ N
m a + + + -rl rcN r~ N NN U NN C~~D
n ~. ~2 . . 3 3 (L
r ~L
Izr; N(~1 ~ Il~D ~ L
a lC rl The titanium diboride starting powder used was Grade F obtained from Hermann C. Starck Berlin GmbH & Co. KG, P.O.B.
1229, D-7887 Laufenburg/Baden, Germany. This powder is composed of crushed and milled irregular shape particles having an hexagonal crystal structure. The specification, along with an example of the actual properties for this grade of TiB2 powder, are shown in Table II.
TABLE II
SPecification Measured Property BET Specific Surface Area > 4 m2/g 4. m2/g Scott TAP Density/Apparent Density-- 9.2 g/in3 FSSS Particle Size max. 0.9~m 0.9 ~m Max. Particle Size 98~ < 6~m Ti 2 66.5 wt. ~ remainder B 2 28.5 wt. ~ 29.8 Nonmetallic Impurities C s 0.25 wt. ~ 0.21 O s 2.0 wt. ~ 1.92 N s 0.25 wt. ~ 0.11 Metallic Impurities Fe s 0.25 wt. ~ 0.18 Other - Total s 0.2 wt. ~ c 0.2 The boron nitride starting powder was obtained from Union Carbide as grade HCP.
The WC powder had the following properties:
Total Carbon 6.11 w/o Cr .01 w/o Free Carbon .01 w/o Ta .12 w/o ~2 .17 w/o Ca .21 w/o Ni .01 w/o Fe .02 w/o BET 1.36 m2/g The cobalt powder was an extra fine grade cobalt.
These powders were milled together in the ratios shown in Table I to form 100 gm lots. Wet milling was performed in a polyurethane lined ball mill with isopropanol and about 3900 gm of WC-Co cemented carbide cycloids for the times shown in Table I. These cemented carbide cycloids have a nominal composition containing about 5.7 w/o Co, 1.9 w/o Ta and a nominal Rockwell A hardness and nominal magnetic saturation value of about 92.7 and about 92 percent, respectively.
From our experience in milling these powders under the conditions described, it is estimated that, for a milling time of 45 to 50 minutes, about 2.4 to about 2.7 w/o of WC +
Co, and for a milling time of 120 minutes, about 4.1 to about 5.8 w/o WC + Co, is added to the blend due to the attrition of the WC-Co cemented carbide cycloids during milling.
After milling, powder blends were dried, screened and then uniaxially hot pressed according to the conditions shown in Table I in an argon atmosphere. During heating, pressure was not applied. The pressing pressure was first applied at the hot pressing temperature and held for typically one hour. The resulting articles produced were essentially fully dense and have the densities, hardnesses and grain sizes shown in Table I. Billets made in accordance with Example 1 were cut and ground to produce SNGN-453T (.002-.004 inch x 20~
chamfer) style indexable metalcutting inserts (see Figure 1).
These inserts were tested in the metalcutting tests described below in Table III against prior art sharp edged K313 grade cemented carbide SNGN-433 style cutting inserts.
These tests were run under flood coolant at 600, 800 and 1,000 surface feet/minute, 0.005 ipr and 0.050 inch depth of cut as described in Table III. The cutting tools composed of material in accordance with the present invention had more than twice the life of the prior art cemented carbide tools.
It was observed that chemical reaction between the titanium alloy workpiece and the cutting tool according to the present invention was the dominant wear mechanism on the rake and flank faces. The present invention, however, had a significantly lower wear rate than the prior art tool, as illustrated by the graphs of nose wear and maximum flank wear shown in Figures 4 and 5, respectively, which are based on the results of the 600 sfm test shown in Table III.
A water soluble coolant, which may be used in these applications, is Cimtech 500. Cimtech 500 is a synthetic fluid concentrate for machining and stamping ferrous metals.
It is supplied by Cincinnati Milicron Marketing Co., of Cincinnati, Ohio. It is typically diluted in water at a water to coolant ratio of 30:1 to 20:1 for machining applications.
TABLE III
METALCUTTING TEST RESULTS
Tool Life in Minutes 600 sfm 800 sfm 1,000 sfm Invention > 5.0 > 1.5 1.5 BK
Prior Art 2.5 FW c 0.5 BK Not Run Conditions Operation: Turning Workpiece Material: Ti-6Al-4V titanium alloy (Annealed at 1300~F for 2 hours and air cooled) Cutting Speed: as noted above Feed: .005 inch/revolution Depth of Cut: .050 inch Lead Angle: 45 degrees Rake Angle: -5 degrees back rake and -5 degrees side rake Cutting Fluid: Flood water soluble coolant diluted 20:1 with water End of Life Criteria Breakage (BK) Flank Wear (FW) 2 . 030 inch Maximum Flank Wear (MW) 2 . 040 inch Nose Wear (NW) 2 . 040 inch Depth of Cut Notching (DN) 2 . 80 inch It was further surprisingly found that the low fracture toughness, mentioned above, of the invention did not adversely affect the ability of the material to turn the above titanium alloy. It was further surprisingly found that the use of flood coolant did not cause the invention to break from excessive thermal shock. These results demonstrate that the present invention has at least twice the cutting edge lifetime of the prior art cemented carbide tools at machining speeds far beyond those recommended (i.e., ~250 sfm) for uncoated carbide.
While uncoated cemented carbides can achieve similar lifetimes to those found for the present invention at lower speeds (c250 sfm), these lower speeds greatly reduce the metal removal rate, which is important in determining machining costs and machine availability.
In another example, the composition used in Example 1 was blended in accordance with Example 1. After milling, the powders were dried, pelletized with a lubricant/fugitive binder (e.g., rosin/polyethylene glycol) and then uniaxially cold pressed to form green cutting inserts. The green inserts were heated in a vacuum up to about 460~C to volatilize the lubricant and fugitive binder. Heating was then continued in one atmosphere of argon to a sintering temperature of about 2000~C, which was held for 60 minutes and then cooled to room temperature. The sintered inserts were then hot isostatically pressed at 1850~C for 60 minutes under 15 Ksi argon.
Sintering and hot isostatic pressing were performed by placing the inserts on a bed of boron nitride setting powder. The inserts were then ground to final size. In this manner, RNGN-45T (.002-.004 inch x 20~ chamfer) style cutting inserts were fabricated. These cutting inserts were tested against prior art K313 grade cemented carbide cutting inserts in the RNGN-45 style with a sharp cutting edge in the turning of Ti-6Al-4V titanium alloy. The test conditions, as well as the results of these tests, are shown in Table IV and Figure 6, and are summarized below.
A single test trial was run at 152 m/minute (500 sfm), comparing the pill pressed-sinter-Hipped inserts to the prior art K313 grade of cemented carbide. Figure 6 is a plot of maximum flank wear. The important observation is that the wear rate for the present invention is relatively uniform through the end of life, at 10 minutes (based on .040 inch maximum flank wear). The 152 m/minute cutting speed is too high for the prior art, which had less than three minutes of tool life due to maximum flank wear exceeding 0.040 inch.
T~3LE IV
CONDITION Time MAXIMUM FLANK WEAR (inch) 500 sfm/ (minutes) RUN 1 RUN 2 .0072 IPR/ INVENTION PRIOR ART INVENTION PRIOR ART
.050"DOC/
Flood Coolant 1 .0151 .0081 2 .0169 .0203 3 .0182 .0428 4 .0214 0.223 6 .0255 7 .0286 8 .0301 9 .0345 .0401 700 sfm/
.0072 IPR/
.050" DOC/
68188-7lD
Flood Coolant 1 .0163.0263 .0170 .0354 2 .0228.0984 .0230 .0510 3 .0285 .0296 4 .0367 .0359 .0445 .0434 1000 sfm/
.005 IPR/
.050" DOC/
Flood Coolant 1 .0202 .1436 2 broken Two test trials were run at 212 m/minute (700 sfm) (see Table IV and Figure 6). It was found that the pill pressed-sintered and Hipped inserts (~) had equal or better wear rate compared to the hot pressed inserts (~) under these conditions. (The hot pressed insert (RNGN-43T) failed prematurely by cracking because it was too thin for this application.) At 700 sfm, the present invention maintains a uniform wear rate that is significantly superior to that produced in the prior art cutting tool. The 700 sfm cutting speed is also clearly out of the useful range of the uncoated carbide tested, which experienced extreme localized wear in less than two minutes.
In an attempt to determine the upper limit of the cutting speed for the present invention, a test was run at 1000 sfm (see Table IV). The invention failed at two minutes due to breakage. The prior art cemented carbide tool experienced extreme localized wear and resulting rake and flank face chipping in less than one minute.
Based on the foregoing examples, it is clear that the pill pressed, sintered and Hipped cutting tools according to the present invention have the same capabilities for machining titanium based materials as the hot pressed cutting tools according to the present invention. The present invention is capable of withstanding cutting speeds which are significantly beyond the useful operating range of uncoated cemented carbide. It was further found that the present invention can withstand larger wear scars without experiencing the acceleration in wear rate that is typical of cemented carbide cutting tools.
It is further believed that the metalcutting performance of the present invention may be further improved, allowing longer cutting edge lifetime and/or higher machining speed capabilities, through the application of a refractory coating to the rake face, flank face and cutting edge. The coating may be applied by known PVD or CVD techniques now used to coat cutting tools. A refractory coating having one or more layers is preferably composed of one or more of the following refractory materials: alumina, and the borides, carbides, nitrides and carbonitrides of zirconlum, hafnium and tltanlum, thelr solld solutlons with each other and thelr alloys. It ls further proposed that use of such a refractory coatlng may allow the use of hlgher levels of toughenlng agents or WC + Co to further lmprove the slnterabillty of the present lnventlon, while minimizing the adverse lmpact of such increases on the wear rate when machining tltanium alloys.
It ls also contemplated that cuttlng lnserts ln accordance with the present lnventlon may be fabrlcated wlth elther a ground ln, or molded, chlpbreaker structure.
Examples of chlpbreaker structures whlch may be used hereln are descrlbed ln Unlted States Patent No. 5,141,367. Titanium alloy chlps are notorlously hard to break. Thls may be partlally due to the slow speeds used when uncoated cemented carbldes are utlllzed to turn tltanlum alloys. It ls our bellef that the hlgher machlnlng speeds now posslble wlth the present lnvention, ln comblnatlon wlth a chipbreaker structure, may lead to lmproved chlp control durlng the turnlng of tltanlum alloys.
Other embodlments of the lnventlon wlll be apparent to those skllled ln the art from a conslderatlon of thls speclflcation or practlce of the lnventlon disclosed hereln.
It ls lntended that the speclflcatlon and examples be consldered as exemplary only, wlth the true scope and splrlt of the lnventlon belng lndlcated by the followlng clalms.
Claims (13)
1. A densified ceramic composition comprising the following phases:
a first Tix1My1 boride phase, where x1 > y1, y1 ~ 0, and M includes tungsten;
a second Tix2My2Z phase, where x2 > y2/ y2 > 0 and M
includes tungsten;
wherein Y2/X2 > y1/X1;
wherein said phases are distributed throughout the densified ceramic composition; and the densified ceramic composition has an average grain size of 8µm or less.
a first Tix1My1 boride phase, where x1 > y1, y1 ~ 0, and M includes tungsten;
a second Tix2My2Z phase, where x2 > y2/ y2 > 0 and M
includes tungsten;
wherein Y2/X2 > y1/X1;
wherein said phases are distributed throughout the densified ceramic composition; and the densified ceramic composition has an average grain size of 8µm or less.
2. The composition according to Claim 1 wherein the average grain size is 6µm or less.
3. The composition according to Claim 1 wherein said Tix1My1 boride phase has a TiB2 crystal structure.
4. A metal boride ceramic composition comprising:
a first metal diboride phase having a first metal selected from the group of titanium, hafnium, zirconium, alone or in combination with each other and a second diboride based phase having a first metal selected from the group of Ti, Hf and Zr, alone or in combination with each other, and a second metal selected from the group of W, Mo, Ta, Nb, Fe, Ni, Co, Al, Cr, alone or in combination with each other;
and wherein said ceramic has an average grain size of 6µm or less.
a first metal diboride phase having a first metal selected from the group of titanium, hafnium, zirconium, alone or in combination with each other and a second diboride based phase having a first metal selected from the group of Ti, Hf and Zr, alone or in combination with each other, and a second metal selected from the group of W, Mo, Ta, Nb, Fe, Ni, Co, Al, Cr, alone or in combination with each other;
and wherein said ceramic has an average grain size of 6µm or less.
5. The metal boride ceramic composition according to Claim 4 further comprising a third diboride phase having a first metal selected from the group of titanium, hafnium, zirconium, alone or in combination with each other, and a second metal selected from the group of W, Mo, Ta, Nb, Fe, Ni, Co, Al, Cr, alone or in combination with each other.
6. A titanium diboride based densified ceramic composition comprising:
a microstructure having a Tix1My1B2 first phase with a second phase of a Tix2My2Z about said first phase, wherein x1 > y1;
wherein y1 ~ 0;
wherein x2 > y2;
wherein y2 > 0;
wherein y2/x2 > y1/X1; and wherein M includes tungsten.
a microstructure having a Tix1My1B2 first phase with a second phase of a Tix2My2Z about said first phase, wherein x1 > y1;
wherein y1 ~ 0;
wherein x2 > y2;
wherein y2 > 0;
wherein y2/x2 > y1/X1; and wherein M includes tungsten.
7. The titanium diboride based densified ceramic composition according to Claim 6 further comprising:
a third phase of a Tix3My3Z about said first phase, wherein y3 > 0;
wherein X3 > y3; and wherein y2/x2 > y3/x3.
a third phase of a Tix3My3Z about said first phase, wherein y3 > 0;
wherein X3 > y3; and wherein y2/x2 > y3/x3.
8. The titanium diboride based densified ceramic composition according to Claim 7 wherein x3 > x2.
9. The titanium diboride based densified ceramic composition according to Claim 6 wherein x1 > x3.
10. The titanium diboride based densified ceramic composition according to Claim 8 wherein x1 > x3.
11. The titanium diboride based densified ceramic composition according to claim 6 wherein z is B2.
12. A densified titanium diboride based ceramic article of manufacture comprising:
a microstructure composed of phases consisting essentially of a TiB2 crystal structure; and wherein said phases include phases containing tungsten at differing concentration levels;
a density of at least 97% of theoretical density;
a hardness of 94.3 to 96.5 Rockwell A at room temperature; and wherein said microstructure has an average grain size of 8µm or less.
a microstructure composed of phases consisting essentially of a TiB2 crystal structure; and wherein said phases include phases containing tungsten at differing concentration levels;
a density of at least 97% of theoretical density;
a hardness of 94.3 to 96.5 Rockwell A at room temperature; and wherein said microstructure has an average grain size of 8µm or less.
13. The article according to Claim 12 wherein said average grain size is 4µm or less.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/060,772 | 1993-05-10 | ||
US08/060,772 US5427987A (en) | 1993-05-10 | 1993-05-10 | Group IVB boride based cutting tools for machining group IVB based materials |
CA002146665A CA2146665A1 (en) | 1993-05-10 | 1994-03-31 | Group ivb boride based cutting tools |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002146665A Division CA2146665A1 (en) | 1993-05-10 | 1994-03-31 | Group ivb boride based cutting tools |
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Publication Number | Publication Date |
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CA2237074A1 true CA2237074A1 (en) | 1994-11-24 |
Family
ID=25677890
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CA002237074A Abandoned CA2237074A1 (en) | 1993-05-10 | 1994-03-31 | A densified titanium diboride based ceramic composition |
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1994
- 1994-03-31 CA CA002237074A patent/CA2237074A1/en not_active Abandoned
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