CA2221147A1 - Bimodal, crosslinked toner resin and process for making same - Google Patents

Bimodal, crosslinked toner resin and process for making same

Info

Publication number
CA2221147A1
CA2221147A1 CA002221147A CA2221147A CA2221147A1 CA 2221147 A1 CA2221147 A1 CA 2221147A1 CA 002221147 A CA002221147 A CA 002221147A CA 2221147 A CA2221147 A CA 2221147A CA 2221147 A1 CA2221147 A1 CA 2221147A1
Authority
CA
Canada
Prior art keywords
resin
bimodal
crosslinked
precursor resin
toner resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002221147A
Other languages
French (fr)
Other versions
CA2221147C (en
Inventor
Francis L. Chupka, Jr.
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Image Polymers Co LLC
Original Assignee
Image Polymers Company
Francis L. Chupka, Jr.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/440,847 external-priority patent/US5684090A/en
Application filed by Image Polymers Company, Francis L. Chupka, Jr. filed Critical Image Polymers Company
Publication of CA2221147A1 publication Critical patent/CA2221147A1/en
Application granted granted Critical
Publication of CA2221147C publication Critical patent/CA2221147C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00Developers
    • G03G9/08Developers with toner particles
    • G03G9/087Binders for toner particles
    • G03G9/08784Macromolecular material not specially provided for in a single one of groups G03G9/08702 - G03G9/08775
    • G03G9/08786Graft polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F257/00Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00Developers
    • G03G9/08Developers with toner particles
    • G03G9/087Binders for toner particles
    • G03G9/08702Binders for toner particles comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • G03G9/08726Polymers of unsaturated acids or derivatives thereof
    • G03G9/08733Polymers of unsaturated polycarboxylic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • General Physics & Mathematics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Developing Agents For Electrophotography (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

A bimodal, crosslinked toner resin can be prepared in non-aqueous solvent, e.g., toluene, using standard solution polymerization techniques. The resin-forming process prepares a precursor resin from ethylenically unsaturated monomer(s), and then grafts malefic anhydride onto the precursor resin to form a modified precursor resin. The modified precursor resin is reacted with a polyfunctional molecule, e.g. a diol, to provide a crosslinked resin. The process is preferably conducted in the presence of a low molecular weight polymeric additive, e.g., polystyrene, to provide a bimodal as well as crosslinked toner resin composition. With the addition of a colorant, a toner powder may be formed.
CA002221147A 1995-05-15 1996-05-10 Bimodal, crosslinked toner resin and process for making same Expired - Fee Related CA2221147C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/440,847 1995-05-15
US08/440,847 US5684090A (en) 1995-05-15 1995-05-15 Bimodal, crosslinked toner resin and process for making same
PCT/US1996/006681 WO1996036652A1 (en) 1995-05-15 1996-05-10 Bimodal, crosslinked toner resin and process for making same

Publications (2)

Publication Number Publication Date
CA2221147A1 true CA2221147A1 (en) 1996-11-21
CA2221147C CA2221147C (en) 2006-10-31

Family

ID=37395802

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002221147A Expired - Fee Related CA2221147C (en) 1995-05-15 1996-05-10 Bimodal, crosslinked toner resin and process for making same

Country Status (1)

Country Link
CA (1) CA2221147C (en)

Also Published As

Publication number Publication date
CA2221147C (en) 2006-10-31

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Legal Events

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EEER Examination request
MKLA Lapsed