CA2177963A1 - A method and a feeding apparatus for controlling mixing conditions in a combustion or gasification plant - Google Patents

Abstract

In a combustion or gasification plant having a chamber (4) the mixing conditions or ratio are controlled via a fluid supplied by perforated tubes (13) to maintain a combustion or gasification process. To have an effect on the mixing of the fluid in the combustion gases the tubes (13) are displaced axially in mutual cooperation at longer or shorter time intervals in the chamber. Then the flue gas or gas parameters of the process can be optimized. Further, the tubes are rotatable around their axis and may for replacement purpose be completely withdrawable from the chamber. The tubes are cleaned in connection with their withdrawal. Object of protection are also a feeding means for use in a combustion or gasification plant of the mentioned type.

Description

WO95115463 2 1 7 7 9 ~ ~ pcrlsE94loll63 A method and a feeding apparatus for controlling mixing conditions in a combustion or aasif ication ~lant Field of Invention The present invention concerns a method of the kind stated in the preamble of Claim l.
lO The invention also concerns a feeding apparatus for implement-ing the method.
With different types of actual combustion and gasification processes there exists an increasing demand for quality and 15 quantity gas analysis. Nitrogen oxides are at present the most exposed flue ga6 components, especially when considering tariff which has been introduced in Sweden for plants larger than lO MW and with an annual energy production greater than 5 0 GWh .
These effect and energy limits, respectively, will most probably be reduced while at the same time greater demands will be made on the measurement of other types of flue gas components, i.e. C0 and N20 (laughing-gas).
The large majority of existing combustion systems are so designed that a minimum quantity of all unwanted f lue gas components is very difficult to attain simultaneously. In other words ",~ e agreements" e.g. high C0-concentra-30 tions - low N0-concentrations are unavoidable in these systems .
The fuel composition often varies from one operation condition to another, particularly with regard to different types of 35 waste fuels and also wood fuels.
Examples of a6h and/or slag enriched fuels comprise wood fuels, straw, waste such as industrial, municipal, hazardous and ~h~ 1 waste and also hard coal, lignite, peat, lime WO 95/1~463 2 ~ ~ ~ q 6 ~ PCT/SE94/01163 sludge and black liquor. Also crematories and cement kilns are included in this category of combustion/gaslf ication systems .
"Ash" is a term which designates an inorganic and unburnable 5 substance which is originally within the fuel.
"Slag" is a term which designates "additives" of inorganic and unburnable substances, such as metals, ceramics, glass, stone etcetera. "Ash" is often considered contained within the term 10 "slag". Examples of not ash and/or slag enriched fuels are oil, natural gas, LPG and certain biofuels.
Fuel price is another important parameter for optimization of f lue gas or gas parameters . Sulphur content and to a certain 15 degree also nitrogen content in the fuel are directly pro-portional to the emission level ahead o~ a flue gas cleaning system. This of cource has the consequence that the fuel price becomes higher when i . e . the nitrogen content in the fuel is lower. Of course also the economical result is influenced by 20 the market price and this will sometimes change quickly.
Trade in emission rights according to so called bubble models are systems which are expected to have a break-through on the market in the f uture .
The above parameters show a future need of flexible combustion/gasification systems which can be quickly adjusted to attain an optimal economical operation point on each occasion .
When using an optimization of this kind the perforated tubes in the combustion or gasification chamber are fed by a fluid comprising a gas or a liquid or possible solid particles.
Examples of gas are air, oxygen, oxygen-enriched air, flue 35 gas, inert gas (CO2, N2 etc), fuel for reburning (LPG, natural gas, ethanol, etc~ NO~ reducing substances (NH3, urea etc) and steam with an optimal flow, yL~s~uL~ and temperature. Examples of liquids are water, NH3, urea, ethanol and other organic solution agents, etc.

3 2 1 7 7 ~ 6 3 PCT/SE94/0~163 Examples of solid particles are powder from biofuel including peat, coal and waste (plastic etc). These can be used as a reburning f uel .
Actual oxidizing agents, e.g. air, shall oxidize unburnt gases, e.g. CO, while reducing agents, e.g. NH3 or for example LPG, shall reduce for example NO at different occasions in a desired optimal degree.
The tube or the tubes is/are suitably positioned in the combustion/gasif ication plant to present optimal conditions .
In for example a grate fired boiler with "over combustion", where the air beneath the fuel makes the flue gas move up-wards, the tube or tubes can be placed over the grate in connection with the first draught of the boiler. For a combustion process with so called "under combustion" the reverse will apply.
In for example a fluidized bed with variable pressure the tube or tubes can be positioned in the combustion chamber, f or instance above the bed in a bubbling bed.
Backqround Art Today combustion/gasification of fuels takes place in a variety of different apparatus and plants in the form of kilns, furnaces etc with burners, grates, fluidized and/or bubbling beds etc.
One characteristic of kilns and furnaces such as these is that the flue gas emissions of CO, C~Hy (hydrocarbonS), NO~, SO2, N2O, dioxine, PAH among others of ten are high due to poor combust-ion optimized plants. Some plants are also equipped with dif f erent types of f lue gas cleaning systems, e . g . electro-35 static precipitators or textile filters, SCR, scrubbers etcetera which are positioned after the combustion/gasifica-tion apparatus, which reduces the emission level in the sub-sequent stack/gas channel.

Wo95/15463 2 1 7 7 9 6 3 PCr/SEs4/01163 As an example of well known apparatuses to minimize emission levels EP-O 286 077 A2 (Mullverbrennungsanlage Wuppertal) describes a method of burning waste in which the f lue gas is drawn out of the furnace and made to make a swirling movement 5 by the addition of secondary air. The secondary air is fed through nozzles in such a way that the flow of flue gases is slowed down in a uniform temperature zone in the furnace and then allowed to remain there for approximately 8 seconds.
lo SE,C,139 072 (Larsson) describes a furnace, especially in a heating boiler or for connection to similar boilers~ fire rooms in which intakes for the primary air~are located on the side of the furnace, said intakes leading to one or several fixed tubes along the furnace, which in their turn contain a 15 rotatable tube which regulates the outlet area for air by twisting the tube about its axis and/r~r axial displacement of the tube.
DE,C,107 755 (T,ind~ nn) describes an apparatus for supplying 20 air over a layer of fuel, which apparatus has a tube grid with a net-like arrangement of tubes, one over the other and with openings pointing to the side so that several air jets cross one another.
SE,C,115 046 (Sinding) describes an apparatus for preheating and adjusting the supply of secondary air to furnaces, which apparatus is furnished with concentric tubes positioned close together and extending into a preheating chamber to supply air to the chamber and are mutually rotatable so that its openings can be set at an angle to one another for the adjustment of the area of passage and thereby the air supply.
Feeding apparatuses in the shape of a perforated tube which injects into a combustion chamber are known, for example through WO-A1-91/00134 (Fuel Tech Europe), US-A-4 883 003 (T~oskinRon) and SE,C,139 563 (Svenska Maskinverken).
Further examples of prior art are to be found in SE,C,45 212 (Reck) and SE,B,458 147 (Lantmannen ODAL) .

WO95/15463 2 l 7 7 ~ ~ 3 PCr/SEs4/01163 FI-B-87014 (T ~-11A) describes an apparatus for feeding granular lime with the aid of a gas stream to a f ire-place . To feed the lime there is used a nozzle mounted at the end of a tubular arm to which a means for displacing the nozzle is 5 coupled. The lime is fed to a place in the fire-place having a suitable position in the flue gas stream with regard to temperature. The preamble of the attached Claim l concerns a method of this kind which is deemed to constitute the closest prior art.
None of the above-mentioned methods and plants permits a careful optimization of the combustion process in the sense that a reliable adaption or adjustment to the variations of the process in the combustion or gasification chamber can be obtained.
Neither does any of the known systems permit an inf luence or effect on the mixing condition or mixing ratio between the combustion gases and/or between these and the fluid or fluids supplied or fed to the combustion chamber.
Obi ects of Invention On the basis thereof one object of the invention is to mini-mize inherent disturbances in known methods of combustion and gasification including associated plants, thereby increasing the efficiency and reducing the emission levels in the com-bustion and gasification processes, respectively.
Another object is to increase the flexibility of the method and the plant in order to, if so required, make possible a quick and simple ad~ustment from one desired emission level (e.g. high CO- low NO-concentration) to another (e.g. low CO-high NO-concentration) flPr~nrl; n~ on the economical output .
Yet another object is to achieve a method of minimizing dis-turbances and a feeding apparatus, respectively, which simpli-f ies and rhPArPnc cleaning of the tubes, thereby achieving an increased yield of the combustion and gasification processes, respectively .

WO 95/15463 2 1 7 7 9 6 ~ PcT/s~94mll63 Another object is to accomplish a method and a plant, respect-ively, which renders it possible to continuously or at least almost continuously operate the combustion process, i.e. with-out having it to be stopped for soot removal or cleaning of 5 the tubes for example feeding secondary air, and being con-tained in the combustion or gasification chamber, respective-ly .
ry of the InYentiQn 10 These and other objects are accomplished by a method according to this invention which is of the above mentioned type and the main features of which are stated in the characterizing part of Claim 1.
15 The stated displacement of at least one of the tubes results in that the mixing of the supplied fluid in the combustion gases will be more effective which makes a more efficient combustion and an optimization of current flue gas or gas parameters possible. With the invention it is, thus, possible 20 in every combustion process to choose the best possible mixing condition or ratio.
The same or different fluids, e.g. o~ the kind mentioned above, can be supplied via the tubes which mutually coact in 25 the way stated. For instance a reburning fuel can be supplied which improves the prere~uisites for controlling the tempera-ture prof ile in the combustion chamber .
To improve mixing it is preferred that the pipes to change the 30 speed, flowing picture and direction of the fluid in addition are rotated about their longitudinal axis.
Then it is preferred that the pipes are displaced and/or rotated at impulse from transmitters positioned outside of the 35 chamber and which sense the state of combustion.
Different types of transmitters may be used for the said purpose, e.g. transmitters for temperature, ~res~ur~, flow, W095/15463 2 1 77q63 PCrlSE94/01163 present flue gas components etcetera. Also optical trans-mitters may ~e used f or the purpose .
Signals generated by the transmitters can in addition be used 5 to regulate the supply of f luid and solid particles, respec-tivcly, to the tubes, said supply possibly being performed by jerks or intermittently. The rotation of the perforated tubes can ascertain that the supply, if so desired, takes place at predet~rm; n~d, varying angles within the combustion chamber.
In practice it is preferred that the pipes are displaced by holding and drive means positioned outside of the chamber and preferably engaging their ends so that the pipes are complete-ly withdrawable from the chamber.
Then it will be possible to combine the withdrawal movement with a cleaning operation, preferably so that mechanical brushes or other ~u~ onding means engage the outside of the tubes so that they are cleaned from soot and othe adhering 20 particles in connection with the withdrawal movement.
According to one embodiment the tubes are withdrawn to an inactive position outside of the chamber at impulse from one or several different transmitters activating the withdrawal 25 r?~-hz~nic~- at for instance power failure or failure of cooling fluid supply to the plant.
Further, the pipes are preferably mounted replaceable at the holder and drive means positioned outside of the chamber. Then 30 a very simple adaption to different operation conditions for the plant will be possible which, thus, can be accomplished by a simple replacement of one or more of the supply tubes. It is - realized that the arrrangement also facilitates preparation and service of the plant which is also made more cheap.
In general use the inventive method can be put into practice on existing as well as new combustion/gasification plants. New boilers and furnaces, respectively, can be manufactured with a smaller furnace volume due to a more effective mixing of the Wo 95/1~463 2 1 7 7 ~ ~ ~ Pcr/Sl 9~101163 8 ~--gases, which reduces costs. The best operation possible with optimal emission level at every separate occasion can more simply be obtained than with systems known heretofore.
5 Further, a cooling fluid can be added to reduce the tempera-ture of the jacket of the tube to make slag and other dust deposition of such a kind that the cleaning operation is facilitated or the number of such operations minimized.
lO Such a cooling fluid can possibly be supplied separately, possibly intermittently and preferably in connection with withdrawal of the pipes. It is preferably supplied via a ring column around each tube. Due to the cooling, slag and other dust deposition on the tubbs become less glass-like or sticky 15 whereby the rlp~nin~ operation will be simplified and speeded up .
The invention also refers to a feeding apparatus for control-ling the mixing condition or ratio in a combustion or gasif i-20 cation plant by means of the supplied fluid for optimizingflue gas or gas parameters, the essential features of said feeding apparatus being stated in Claim 8.
Advantageous embodiments of the feeding apparatus are defined 25 in the following Claims.
Further characteristics and advantages, respectively, of the method and the feeding apparatus according to the invention will be given in the following description of some preferred 30 PmhoA;--ntS of the invention. The description refers to the attached drawing.
Short Descri~tion of the Drawinq Fi~ures Fig. l is a partly cut-away perspective view of a combustion 35 plant for solid fuels having a feeding apparatus in accordance with the invention.
Fig. 2 is a side view showing a feeding means according to the invention comprising a perforated tube and means for dis-WO95115463 2 1 779~3 PcrlsEs4loll63 placing, rotation, controlling and cleaning the tube posi-tioned outside of the combustion chamber . The f igure shows the feeding means in inserted position in the combustion chamber.
5 Fig. 3 is a side view corresponding to Fig. 2 with the feeding means completely withdrawn from the combustion chamber.
Fig. 4 is a sectional view along the line IV-IV in Fig. 3.
lO Fig. 5 is a sectional horizontal view through the combustion chamber and shows three coacting f eeding means at one level thereof for increasing the action of int~rmi~ing the fluid in the combustion gases.
15 Fig. 6 is a schematic vertical sectional view through an alternative embodiment in which a number of different feeding devices for fluid are received in a "revolver-holder" posi-tioned outside of the combustion chamber for optional, alternative insertion into the combustion chamber.
Descri1~tion of l~referred embo~;m~nts In fig. l the digit l denotes a combustion plant comprising a furnace 2 for combustion of solid fuels with a grate 3 and an upper combustion chamber 4.
The fuel can be fed intermittently or continuously and com-bustion air in the form of primary air is blown from below and up through the grate 3.
30 Secondary air is fed through a number of feeding apparatuses according to the present invention entering the combustion chamber 4 through special ports in the furnace wall 5 and further described below. The s~r~n~l~ry air is supplied via said feeding apparatuses in order to complete the combustion 35 of formed reaction products in the shape of gas and solid particles .
Particles in the flue gas above the grate 3 consist of ash, slag and/or unburnt fuel. These can together form bigger WO95/15463 2 ~ 77~6~ PCr/S~94/01163 particles, so called agglomerates, or be reduced to smaller, more or less clean ash particles. Slag enriched fuels often offer higher concentrations of dust and slag in the flue gas.
5 Some of the particles form deposits on the inside of the combustion chamber which is of ten equipped with tubes 6 with an external insulation. Dust particles also deposit on the tubes 13 where the holes 13a for feeding C:Prnn~ry air are entirely or partially blocked thereby affecting the feed of 10 secondary air, alternatively coating will occur directly on the mantle of the tube.
This causes an incomplete combustion which is not optimal with further inherent problems of the mentioned type.
Poor mixing conditions in the gas chamber of this kind render the combustion plant a lower combustion efficiency. This is especially evident when steps are taken to reduce NO~ when concentrations of unburnt gases/particles are h~gher than 20 before the adjustment. Throttling down air supply and/or flow gas recirculation reduces the temperature in the combustion zone and, further, creates reducing conditions which lead to lower NO~ cul.cel-LL~tions and higher concentrations of unburnt gases and particles. The demand for efficient ;~gm;Yin~ of 25 se~nnrl~ry air becomes even more important which in turn leads to a demand of ~requent cleaning or soot removal of the secondary air tubes.
In the plant shown in fig. 1 the feeding tubes 13 for a fluid, 30 e.g. secondary air, are arranged forming a curtain system comprising a number of tubes 13, some of which are parallell, at one or more levels in the combustion chamber 4. The tubes 13 are equipped with perforations 13a alongside the mantle surface of the entire tubes. The holes can be equally dis-35 tributed and a row of holes can be positioned on each side ofthe tubes.
The through-flow area of the holes 13a detPrm;nP~ the flow of the fluid at a given pressure. When the speed profile over the 2 1 77~3 actual cross section in a combustion or gasification plant, where the apparatus shall be installed, often varies, a com-pensation must be made when supplying the f luids .
5 A fluid, e.g. secondary air at high ~leS2~ULt:, is supplied via a fan 10 connected to a collecting box 11, to which flexible tubes 12 are connected, which with quick-couplings are connec-ted to the end flanges 13b of the tubes 13. The opposite ends of the tubes can be plugged or provided with outlet openings 10 (not shown).
Depending on the actual combustion process the tubes 13 are inserted and withdrawn from the chamber 4 in an axial direct-ion at longer or shorter periods of time. In such a way the 15 emission level of the combustion process can be maintained optimal .
Figs 2 and 3 illustrate the r--h~ni~ that have been used for displacing the tubes 13 into and out from, respectively, the 20 combustion chamber 4 and for their rotation, guiding and cleaning .
The tubes 13 are received in a casing 14 supporting some of the stated ~--hAn; ~mc. To displace a tube an electric motor 25 16 is used the output axes of which drives a disc 17. An end-less belt or chain 20 is led around the disc and also around rollers 18, 19. To the belt 20 is securea a holder in the shape of a trolley 25 engaging the end of the tube 13 so as to form a bed 25b to make the tube at the same time rotatable 30 around its longitudinal axis. The holder 25 is displaceably guided via a guide 26.
Fig. 2 shows the tube 13 in inserted position in the com-bustion chamber whereas fig. 3 shows the tube completely with-35 drawn from the chamber. The holder 25 is then so adapted thatsimple replacement of tubes 13 can take part in the withdrawn position .

WO 95/15463 ~ I ~ 7 ~ ~ ~ 12 PCrlSEs4/0ll63 An electric motor 27 drives a belt 28 which extends over a number of rollers 29 engaging the periphery of the tubes 13 to turn it around.
5 As appears from fig. 4 the holder 25 is provided with forked legs 25a supporting the bed 25b in which the tube 13 rests.
The holder or the trolley 25 is displaceably guided on the guide 26.
lO In lts forward end the casing 14 is connected to a housing 30 which receives the opposite guide rollers 15 for the tube and also an arrangement of steel brushes 21 between which the tubes pass when being withdrawn and thereafter inserted. These brushes 21 perform an efficient cleaning of the tubes, so that 15 they are released from dust and slag depositions.
It appears that the shown arrangement considerably simplifies the cleaning of the tubes and that the tubes can be withdrawn one by one or a few at the same time thereby allowing the com-20 bustion process to continue, due to the fact that secondaryair is fed via rr~-inin~ tubes in the combustion chamber.
Alternatively or additionally an automatic shaking device (striking tool or similar, not shown) or acoustic sootblower 25 (infrasonics or ultrasonics) can be connected for continuous or intermittent slag removal.
Fig. 5 shows how the flow picture of a fluid supplied via adjacent tubes 13 can be changed, in part through displacement 30 of one or more tubes to different positions in the combustion chamber 4 and in part through turning or rotation of one or more of the tubes. Further actuation of such a kind can also be obtained by changing the pressure, speed and/or flow of the supplied fluid. As appears from fig. 5 different inrorm;Yin~
35 conditions can be obtained as a result of that the flow of fluid from adjacent pipes can amplify or intensify each other, more or less eXtinct each other or present an action there-between .

W0 95115463 2 1 7 7 9 6 3 PCT/SE94/0l 163 A reburning-fuel, such as ethanol, can be supplied via one, two or all tubes 13, whereby the temperature profile, i.e. the temperature in different zones of the chamber 4, can be controlled to give an optimal combustion process.
Fig. 6 shows a "revolver arrangement" in which casing 14 is replacea by a casing 14 ' which is rotatable on a shaft 40 and which receives a number of fluid supply tubes having different spacing and positions for perforations 13a thereon.
lo To cope with dif f erent combustion conditions in chamber 4 casing 14' is rotated so that the fluid supply tube 13 which is most suitable in the actual situation is lnserted into the combustion chamber 4. Attached to the ends of the tubes 13 are 15 bellows-shaped hoses 12 ' for the fluid supply to each tube.
In a plant used in practice the tubes 13 may have a length between 1 a 2 and 5 m and a diameter of 120-200 mm. The diameter of the perforations 13a may vary from 1 a z mm up to 20 2 a 4 cm and the distance between the perforations can amount to between 10 and 40 cm.
The regulation of fluid to each tube 13 can further be made via output signals from transmitters for different gas para-25 meters, gas _~ncellLLations, temperatures, pressure, flow etc(not shown). Said transmitters may also be used, e.g. via a computer, to decide when the cleaning or soot removal opera-tions are to be initiated. As mentioned above there is then no need to stop the combustion process . In f ig . 1 digit 42 30 denotes a sensor of this kind. 43, 44 denote presence of an optical sensor where 44 is a lens. At for instance power failure or failure on cooling fluid supply to the plant one or more transmitters are sensing this and give an impulse for withdrawal of the tubes to an inactive position outside of the 35 chamber. This is a very important safety measure within the scope of the inventive concept.
With an application according to the invention in a combustion chamber a better combustion result will be achieved with lower WO 95/15463 2 1 7 7 q ~ ~ 14 PCrISE94/01163 concentrations of NO~, CO, N~O, hydrocarbons and unburnt par-ticles as well as dioxine.
A plant with a feeding apparatus according to the invention is 5 simple to install and therefore particularly suitable when converting furnaces, combustion and gasification plants which are operating or ~lready existing on the market.
q he tubes need not be oriented horizontally in the combustion l0 chamber. One or more of the tubes may, thus, be inclined or extend vertically.

Claims (10)

Claims

1. A method of controlling mixing conditions in a com-bustion or gasification plant by means of a fluid supplied via a feeding apparatus for optimizing flue gas or gas parameters, said plant having a combustion or gasification chamber (4) housing an axially displaceable tube through which the fluid is supplied to the chamber to maintain a combustion or gasification process therein, c h a r a c t e r i z e d b y displacing at least one of the two or more perforated tubes (13) at longer or shorter intervals of time axially in the chamber (4) for predetermined, controlled influence on the intermixing of the fluid in the combustion gases by mutual cooperation between the tubes.

2. A method according to Claim 1, c h a r a c t e -r i z e d by displacing the tubes by means of an outside the chamber (4) preferably at their ends engaging holder and drive means (25; 16, 20), so that the tubes are completely with-drawable from the chamber.

3. A method according to Claim 2, c h a r a c t e -r i z e d by withdrawing the tubes (13) to an inactive position outside of the chamber at impulse from one or more transmitters activating the withdrawing mechanism at for instance power failure or failure on cooling fluid supply to the plant.

4. A method according to any of Claims 1-3, c h a r a c t e r i z e d by additionally turning the pipes around their longitudinal axis to change the pressure, flow structure and/or direction.

5. A method according to any of Claims 1-4, c h a r a c t e r i z e d by displacing and/or turning the pipes at impulse from one or more transmitters (42, 43, 44) positioned outside of the chamber and sensing the state of combustion in the chamber.

6. A method according to Claim 2, c h a r a c t e -r i z e d by arranging the tubes interchangable on the holder and drive means.

7. A method according to any of Claims 2-6, c h a r a c t e r i z e d by cleaning the tubes during their withdrawal.

8. A feeding means for controlling mixing conditions in a combustion or gasification plant by means of supplied fluid for optimizing flue gas or gas parameters, said plant compris-ing a combustion or gasification chamber (4) housing an axial-ly displaceable tube through which the fluid is supplied to the chamber to maintain a combustion or gasification process therein, c h a r a c t e r i z e d in two or more axially displaceable tubes (13) within the chamber (4);
holder and drive means (16, 20; 26; 15) engaging one or more of the ends of the tubes (13) outside of the chamber (4) for predetermined, controlled displacement of the tubes for influencing the intermixing of the fluid in the combustion gases by mutual cooperation between the tubes; and a means (e.g. 42-44) for guiding the displacement movements in dependence of time and/or in the chamber sensored state of combustion.

9. A feeding means according to Claim 8, c h a r a c -t e r i z e d by a means (27, 28, 29; 21, 38, 39) for rota-tion and/or cleaning of the tubes.

10. A feeding means according to Claims 8 or 9, c h a r a c t e r i z e d in that the holder and drive means are adapted to permit a complete withdrawal of the pipes (13) from the chamber and displacement of the tubes.