CA2172828A1 - Cold sealable cohesive polymers - Google Patents

Abstract

A copolymer preparable by the emulsion polymerisation of: a) at least one monomer which comprises an alkyl methacrylate having from 1 to 12 carbon atoms in the alkyl group; a vinyl aromatic; or a nitrile having ethylene unsaturation conjugated with the nitrile group, with at least one of the following: b) at least one copolymerisable soft monomer; and c) at least one copolymerisable functional monomer, the resulting copolymer having a glass transition temperature (Tg) from -35 °C to 50 °C and being formulatable into a coating which is cold sealable to itself under pressure but which has non-blocking characteristics.

Description

~7~2$
WO 95/09876 PCT/US9 ~/11216 COLD SEAIIABLE COHESIVE POLYMERS
THIS INVENTION relates to cold sealable cohesive polymers;
more particularly, this invention relates to copolymers preparable by emulsion copolymerisation; to their preparation;
to cold sealable compositions containing them; to cold sealable structures comprising them; to sealed such structures; and to the use of such cold sealable compositions for coating plastics film.
Plastics packaging structures, such as plastics films, can be provided with adhesive coatings to enable an effective seal to be obtained. These coatings may be heat sealable coatings which are adhesive coatings sealable at elevated temperatures;
or they may be cold sealable coatings which are sealable at a temperature from oo to 40C. In packaging comestibles, especially foodstuffs which are sensitive to heat (such as candy, chocolate and ice cream), the use of heated elements must be avoided to prevent spoiling of the packaged product.
Previous commercial cold sealable, pressure-sensitive coatings while not requiring the use of heated elements in the sealing process have high surface tack and a tendency to block.
This invention seeks to provide a polymer, ~ormulatable to furnish a cold sealable, pressure-sensitive cohesive coating which is cohesive only when placed under pressure in contact with like coated surfaces and has low surface tack to, and does not block with, commercial acrylic-based coatings. The coatings need also to have good wetting ability, good coating uniformity and good seal strength on diverse substrates, including plastics film and paper; they should be sealable at as low as possible a temperature also to facilitate increased time speeds.
Finally, the coatings should be free from objectionable odour;
should be usable with foodstuffs; and have excellent optical properties, such as gloss.
According, therefore, to one aspect of this invention there is provided a copolymer preparable by the emulsion polymerisation, preferably aqueous emulsion polymerisation, of:
a) at least one monomer which comprises an alkyl methacrylate having from 1 to 12 carbon atoms in the alkyl group; a vinyl SII~ITUTE S~EET ff~E 26~

W095/09876 2 1 7 2 ~ 2 8 - 2 - PCT~S94/11216 aromatic; or a nitrile having ethylenic unsaturation conjugated with the nitrile group with at least one of the following: b) at least one copolymerisable soft monomer; and c) at least one copolymerisable functional monomer, the resulting copolymer having a glass transition temperature (Tg) from -350C to 50C
and being formulatable into a coating which is cold sealable to itself under pressure but which has non-blocking characteristics.
Monomer (a) suitably comprises methyl methacrylate, ethyl methacrylate, propyl methacrylate, isopropyl methacrylate, n-butyl methacrylate, iso-butyl methacrylate, t-butyl methacrylate, n-pentyl methacrylate, isopentyl methacrylate, hexyl methacrylate, n-octyl methacrylate, 2-ethylhexyl methacrylate, decylmethacrylate, dodecylmethacrylate; styrene, an ~-alkyl styrene, vinyltoluene; acrylonitrile or methacrylonitrile, especially methyl methacrylate or acrylonitrile.
Where monomer (a) comprises an alkyl methacrylate or a vinyl aromatic, this is suitably employed in an amount from 21 to 55%, such as from 30 to 45%, especially 35 to 42%, by weight, based on the total weight of monomer mixture. Where monomer (a) comprises a nitrile in addition to other monomers (a), the nitrile is suitably employed in an amount up to 25% by weight, preferably up to 10%, such as from 3 to 9%, by weight. However, where (a) solely comprises a nitrile it is suitably employed in an amount from 10 to 65% by weight, based on the total weight of monomer mixture.
Monomer (b) suitably comprises an alkyl acrylate having from 1 to 12 carbon atoms in the alkyl group; 1,3-butadiene; or a vinyl or vinylidene ester, preferably methyl acrylate, ethyl acrylate, propyl acrylate, isopropyl acrylate, butyl acrylate, isobutyl acrylate, t-butyl acrylate, n-pentyl acrylate, isopentyl acrylate, hexyl acrylate, n-octyl acrylate, iso-octyl acrylate, 2-ethylhexyl acrylate, decyl acrylate, 1,3!-butadiene, vinyl acetate or vinylidene chloride, especially methyl acrylate -or ethyl acrylate.
Monomer (b) is suitably employed in an amount from 30 to S~STITUTE SHEET (RIJLE 26~

~ wog5/09876 ~ 1 ~ 2 ~ 2 ~ PCT/US9~/11216 85% by weight, suitably from 40 to 69% by weight, preferably from 48 to 60% by weight, based on the total weight of monomer mixture.
Monomer (c) suitably comprises an ethylenically unsaturated compound containing a carboxylic or a sulphonic acid group, desirably an ~ ethylenically unsaturated carboxylic acid, preferably acrylic acid, methacrylic acid, itaconic acid, crotonic acid, maleic acid; or sulfoethyl methacrylate, especially acrylic acid or methacrylic acid.
Monomer (c) is suitably employed in an amount from 1 to 15%, such as 1 to 5~, by weight, preferably from 2 to 8% by weight, based on the total weight of monomer mixture.
In one aspect of the invention, it is preferred that the Tg of the copolymer is from -30C to 15C. Desirably, such a copolymer comprises from 10 to 65 wt.% of copolymerised monomer (a); from 30 to 85 wt.% of copolymerised monomer (b); and from 1 to 5 wt.% of copolymerised monomer (c), and has a number average molec~ r weight to 150000 (GPC). Preferably, such a copolymer has a number average molecular weight from 50,000 to 90, 000.
In another aspect of the invention, it is preferred that the Tg of the copolymer is from 25C to 50C, preferably 30C to 50C. Desirably, such a copolymer comprises from 30 to 55 wt.%
of polymerised monomer (a) 40 to 69 wt.% of polymerised monomer (b); and from 1 to 15 wt.% of polymerised monomer (c).
Preferably, such a copolymer has a number average molecular weight in the range 8,000 to 12,000 (GPC against a polystyrene st~n~Ard and dissolved in tetrahydrofuran).
In general, the amount of each monomer will depend on the desired glass transition temperature of the copolymer of the invention. This is related as follows :

Wfa Wrb Wfc + +
Tg Tga Tgb Tgc where:
Tg represents the glass transition temperature of the copolymer of the invention;

ITUTE SHE~T (R~E 26~

2 ~ 7 ~ ~ 2 ~ 4 - PCT~S94/11216 Wfi represents the weight fraction of monomer (i); and T~ represents the glass transition temperature of a homopolymer of monomer (i).
The TABLE below gives representative T~

TABLE
Monomer (a) Tgj(C) Acrylonitrile 97 Monomer (b) Ethyl acrylate I -22 Hexyl acrylate I _57 Isopropyl acrylate ; -3 Iso-octyl acrylate -85 Butyl acrylate _54 Methyl acrylate 8 Vinylidene chloride -17 Isobutyl acrylate I -43 l,3-Butadiene -78 Vinylacetate ~ -32 Monomer (c) Acrylic acid 106 Methacrylic acid 185 Itaconic acid ---Sulfoethyl methacrylate , ---Maleic acid ---Crotonic acid ---It has been found that lower glass transition temperatures, typically less than 3C, more typically less than oC and even more typically about -5C, exhibit better pressure sealable properties, but this can vary depending upon the comonomers used. The mean diameter of the polymer particles is generally from 0.05 to 0.3 microns.
The acid numbers of the copolymer of the invention is typically from lO to lOo mg KOH/g.

SUBSrITUlE S~lET ~RU~E

, W095/09876 2 ~ 7 2 ~ 2 ~ PCT~S94111216 It may be desirable that the copolymer of this invention is crosslinked. Low levels, usually less than 5% by weight, of a crosslinking agent, such as divinylbenzene or l,3-butylene glycol dimethacrylate, or, indeed, any other crosslinking agent known in the art may be employed.
It is found that the desired effect of the chain transfer agent to lower the average molecular weight of the copolymer could be countered by the effect of the crosslinking agent;
therefore, when higher levels of crosslinking agent are used, higher levels of the chain transfer agent are usually used and vice versa. This helps to balance the properties of cohesive strength and sealability.
This invention, in another aspect, also provides a process ~or the preparation of a copolymer as herein defined, which process comprises (a) mixing at least one monomer (a) with at least one of monomers (b) and (c) in relative proportion so that the resulting copolymer has a Tg from -35C to 50C; and (b) polymerizing the monomers under emulsion polymerization conditions.
Copolymers of the present invention may typically be prepared by an emulsion polymerization process in known apparatus; for example in a stirred reactor with heating and cooling means. Any of the herein defined monomers, and their relative proportions, may be utilised. The polymerization may be effected in the presence of water, an emulsifying agent and a catalyst which may be a free radical catalyst or a redox system.
The procedure for charging the reactor may comprise forming a solution of all the monomers; the water; the emulsifier; and the catalyst. As an alternative, a portion of the catalyst may initially be charged and the remainder added, slowly, during the polymerization. It is also possible initially to charge a portion of the water and of the emulsifier and to prepare from the remainder and from the monomer mixture a preemulsion which is added slowly at the polymerization temperature, the catalyst again being initially charged separately or a portion thereof being added separately. It is also possible to add the monomer SWS~ITUTE S~

WO 95/09876 ~ :L 7 ?~ 8 - 6 - PCT/US94/11216 mixture in a first stage in the form of a preemulsion and in a second stage to add the monomer mixture in bulk, i.e. without water and emulsifier, and to add the catalyst separately but in parallel therewith. It is preferred initially to charge solution of water and emulsifier and slowly to add the monomer mixture and, separately therefrom but in parallel therewith, the catalyst in water, at the polymerization temperature.
Subsequently, after renewed addition of emulsifier, in the second polymerization stage the remainder of the monomer mixture is metered into the reactor. The remainder of the catalyst, which was not charged initially, can also be added completely after the addition of the monomers. However, this subsequent metered addition of catalyst is less advantageous.
Advantageously, the quantitative ratio of monomers to water is selected such that the resulting dispersion of acrylate copolymer has a solids content from 20 to 40%.
Typical catalysts include hydrogen peroxide; benzoyl peroxide; inorganic persulfates such as ammonium or potassium persulfate; inorganic perphosphates such as ammonium or potassium perphosphate; organic peresters such as perisopivalates. Redox systems require a combination of such oxidants with a water soluble reductant; for example sulfur compounds such as alkali metal bisulfites, thiosulfates or hydrosulfites; ascorbic acid; triethylamine; hydrazine;
hydroxylamine; glycolic acid; or tartaric acid. Generally, the total amount of catalyst employed may be from 0.1% by weight to 2% by weight based on the total weight of the monomer.
The emulsion polymerization may typically be carried out in the presence of one or more anionic, nonionic;or cationic emulsifiers; for example, alkyl carboxylic acid salts, phosphoric acid salts, alkyl sulfate salts, alkyl sulfonate salts, alkyl aryl ether alcohols and alkyl aryl polyether sulfate salts. More particularly, examples lof anionic emulsifiers include alkali metal or ammonium salts of sulfuric acid monoesters of alkylphenols or of alcohols; sulfuric acid monoesters of ethoxylated alkylphenols or ethoxylated alcohols;
or phosphoric esters of alkoxylated alkylphenols. Examples of Sl~l~UTE SH~El ~E 26~

L

WO9S/09876 2 1 7 ~ 8 2 ~ PCT~S9~111216 emulsifiers utilised include alkali metal salts of sulfuric acid monoesters of nonylphenol reacted with 23 mol of ethylene oxide per mole, alkyl- or arylsulfonate, sodium lauryl sulfate, sodium lauryl ethoxylate sulfate and the alkali metal salt of diesters of sulfosuccinic acid with alcohols having 6 to 20 car~on atoms.
The nonionic emulsifiers which are preferably used are ethers of nonylphenols reacted with 5 to 23 mol of ethylene oxide. It is preferred to employ phosphates of alkoxylated alkylphenols, especially phosphates of the reaction product of l mol of nonylphenol with 5 mol of ethylene oxide, having an acid number of 125. Generally, the total amount of emulsifier employed may be from O.Ol to 2.0 percent by weight based on the total amount of water.
The polymerization may be conducted in a redox system or in a higher temperature thermal process using a persulfate-type initiator or an azobisisobutryonitrile initiator.
In general, the polymerization may be carried out a temperature from 40C to lO0C, suitably from 70C to 90C, preferably 60C to 80C, at a pressure from lOl to 308 kPa (0 to 30 psig). A thermal polymerization may be carried out at the higher range of these temperatures typically above 70C. The reaction may be conducted in glassware with a reflux condenser.
This stage is usually carried out in the presence of an inert gas, such as nitrogen. The polymerization is generally carried out for a time from l to 8 hours, preferably 3 to 4 hours.
After completion of the polymerization reaction, the pH of the polymer can be adjusted up to lO, more specifically, from 6 to 10 .
A two-stage polymerization process is also contemplated.
In the first stage of the emulsion polymerization, from 5 to 20% by weight of the monomer mixture may be polymerized at a temperature from 70 to 90C. In the second stage of the polymerization, preferably after further addition of emulsifier, the remaining 80 to 95% by weight of the monomer mixture is polymerized in the presence of the polymer obtained in the first stage of the emulsion polymerization.
The resulting acrylate copolymer of the invention is at SUBSt!TUTE S~EET (RVLE 26) woss/09876 2 17 2 8 2 8 PCT~S94tll216 least partially neutralized by the addition of bases, and, if desired, conventional auxiliaries and additives for the production of the aqueous sealing coating are addeq. The bases employed are ammonia and/or amines, advantageously in the form of an aqueous solution of the neutralizing agent. Ammonia is particularly preferred. Generally, the second stage polymerization may be performed under the same temperature and pressure conditions as in the first stage. A preformed seed latex is made in the first stage to which up to 95% of the remaining amount of monomer feed is gradually fedlin a second stage over a period from 2 to 5 hours. The total reaction time of the second stage may usually be from 4 to 6 hours.
Examples of suitable chain transfer agents which may be included in the emulsion polymerization process of the invention include mercaptans; polyhalogen compounds; and bran¢hed aromatic hydrocarbons such as isooctyl thioglycolate, thioglycerol, dodecylmercaptan or trimethylbenzene. Usual amounts are from O.l to 5% by weight based on the weight of total monomer and the chain transfer agent is preferably employed at all stages of the emulsion polymerization.
In one embodiment of the invention there is a two-stage polymerization in which the seed, or core, latex comprises up to 50 wt.% of a different polymer such as a polymer described in U.S. Patent No. 5,070,164. To this is added, as the remaining monomer feed, a monomer feed of this invention.
After drying, the resulting latex formulation of the copolymer of this invention adheres to packaging film substrates even after exposure to moisture. That is, they retain a significant amount of their original bond strength even after immersion in water. Once solidified by drying, the coated surface does not adhere to non-treated, uncoated film surfaces such as untreated polypropylene or acrylic-based surface coatings.
This invention further provides a cold sealable composition comprising a polymer as herein defined.
A cold s~ hle composition of the invention may comprise any of the copolymers of the invention. The composition may be SI~BSTI~UT~ S~ RU~E 26) i 217282~
WO 95/09876 . PCT/US91J11216 an aqueous solution or dispersion of the copolymer, suitably with a solids content from 20 to 40 wt.~, and may contain suitable auxiliaries and additives as are conventional in seal-coating. These include antiblocking additives; hydrophobicizing agents; slip additives; and antifoaming additives. The hot-slip properties can be improved by the addition of solid, finely divided, water-insoluble inorganic materials, for example colloidal silica. Suitable antiblocking additives are finely dispersed minerals and finely divided waxes and wax-like materials which melt at temperatures above the maximum temperatures occurring during storage of sealable structures comprising them and which are not soluble in the copolymer of the invention at these temperatures. Examples of natural waxes are paraffin wax, microcrystalline wax, beeswax, carnauba wax, Japan wax and montan wax; examples of synthetic waxes are hydrogenated castor oil, chlorinated hydrocarbon waxes and long-chain fatty acid amides. The abovementioned waxes also lead to an improvement in the cold-slip properties of the coated plastics films, which should be understood as the ability of the films to slip over surfaces at room temperature.
The present invention also provides a sealable structure comprising a substrate coated on a surface thereof with such a cold sealable composition; and a sealed such structure cont~; n; ng perishable goods.
Before applying a cold sealable composition of the invention to a substrate, such as a plastics film, to form a sealable structure of the invention, the surface of the film is generally pretreated in order to ensure that the coating adheres firmly to the substrate. This treatment is carried out in accordance with known procedures; for example, by chlorinating the plastics film substrate; by oxidizing it with agents such as chromic acid or hot air; by steam treatment; by corona discharge; or flame treatment. The pretreatment used is preferably flame treatment or high-voltage corona discharge.
After being pretreated, the or each surface of the substrate is generally precoated with a primer that helps to anchor the topcoat in order to ensure the adhesion of the SllBSTITUTE SHEEf (RU~E 26) W095/09876 ~ ~ 7 ~ PCT/US94/11216 coating to the substrate film. Appropriate precoating agents, or primers, are known from the literature and include, for example, alkyl titanates; epoxy-type primers; melamine-formaldehyde and polyethyleneimines. The latter are particularly suitable for precoating plastics films as in polystyrene latex which contains at least one epoxy functionality. In this context, the polyethyleneimines can be applied to the optionally pretreated plastics films either from organic or from aqueous solution. In this case the concentration of the polyethyleneimine in the aqueous or organic solution may be, for example, 0.5% by weight. Suitable polyethyleneimine primers are described in, for example, DE-A-24 40 112 and US-A-3,753,769.
The uncoated plastics films generally have a thickness of from 0.015 to 0.060 mm. The aqueous sealing coating is applied to the plastics film in a conventional manner, for example by gravure application, roller application, dipping, or spraying with the aid of the intaglio or flexographic printing process or the reverse-roll application process. The excess aqueous solution can be removed by squeeze rollers or draw-off blades.
The sealing coatings should conventionally be applied in a quantity such that, during drying, a smooth, uniformly distributed layer having a weight of from 1 to 4 g/m2 is laid down.
The coating formed by the sealing coating on the plastics film is subsequently dried with hot air, radiated heat or by means of any other conventional means. It is not necessary to apply the release coating layer which is necessary when using cold-sealing coatings. I
The low adhesion to commercial acrylic-based coatings of the cold sealable composition of this invention is an important feature of the invention because these coatings limpart the combined properties of machinability and printability to untreated and release-treated polypropylene. The untreated and release-treated polypropylene, while being machineable, is not printable. The latex coating presents a smooth, non-tacky surface which will not block to acrylic-based surface coatings SL~BSTITUTE SHEET (RULE 26) 21728~
WO 95/09876 PCT/US9~/11216 under normal operating conditions. However, if similarly coated surfaces are placed in contact with each other, under pressure, and at an elevated temperature up to 66C (150F), at room temperature or even at below room temperatures; for example 16C
(60F), then the coated surfaces become cohesive forming a r strong bond between each other. With certain polymers, the bond created has been found to be stronger than the film itself. The seal temperature required can be affected by the thickness of the composition on the substrate; that is, thicker substrates can re~uire higher temperatures for pressure sealability.
Thus, the cold sealable compositions of the present invention are very useful in imparting high cold seal bond strength to packaging film substrates, particularly polyolefin film, such as polypropylene film substrates. Substrates which are particularly contemplated for use with these cold sealable compositions to provide sealable structures of the present invention include olefin polymers, such as case or oriented polypropylene, coextruded films, nylon, white opaque film, cellophane, paper, polyesters, high density polyethylene and linear low density polyethylene.
The polymeric portion of the contemplated acrylic based coatings should contain at least 80 wt.% acrylic, preferably greater than 90 wt.% acrylic. Small amounts of other materials such as acrylonitrile and ethylene acrylic acid can also be present in the acrylic-based polymer, typically less than 10 wt.~. The amount of non-acrylic materials should be limited as they can cause blocking. The acrylic-based coating can be formulated with particles such as polyethylene, silicon and silicone, silica, talc, or other particles from 0.5 to 3.0 microns.
Commonly known techn; ques can be employed to apply the emulsion polymer formulation of the present invention to the film or paper substrate. For example, when impregnating or saturating the substrate, it may be dipped or sprayed. If the substrate is coated, this may be accomplished by dipping, spraying or by employing a roller, spreading knife, brush or the like. Generally, for the best crimp sealability, the emulsion SU~ITUTE S~ JLE 26) Woss/09876 2 1 ~ ~ 8 ~ 8 PCT~S94/11216 polymer formulation should be applied at a low level, typically, applied in an amount of from about 0.5 to 5 g per 6,500 sq. cm.
(lO00 sq. in.), preferably about l to 1.5 g per 6,500 sq. cm.
to the film substrate.
The emulsion polymerization formulation of the present invention may be compounded with, or have mixed therein, other known ingredients or stabilizers, antifoaming agents, dying adjuvants, pigments, waxes, corn starch, silica, talc and the like other compounding aids to control surface tack and other surface properties. Thickeners or bodying agents may be added to the polymers so as to control the viscosity of the polymer and thereby achieve the proper flow properties for the particular application desired.
The sealing temperature at which a sealed structure according to the invention is fabricated is generally above ambient temperature. In general it is from 20C to 80C, preferably at least 30C and particularly preferably from 40C
to 70C. Sealing occurs with the application of temperature and pressure. During the application of pressure, the sealing coatings are brought into contact in such a way that they become matted together. The pressures applied are generally from 5-30 bar, preferably from 6-8 bar. Sealing times of Ifrom a few lOOOths of a second up to a few lOths of a second are generally adequate. The dry weight of the sealing coating in the film coating is in general from l to 4 g/m2.
The sealed structures, for example, packaging containers, produced according to the invention have outstanding properties with respect to their adhesion to the substrate and to their sealed-seam strength. The latter is preferably at least 250 g/2.54 cm. The sealing coatings are particularly suited to cont~;n;ng perishable goods, especially heat-sensitive comestibles and conform to current foodstuffs regulations and are stable in terms of odor. The coatings do not block with respect to untreated plastics films, for example oriented polypropylene. Despite the very good antiblocking properties, the sealing temperature is distinctly below the range of sealing temperatures which is usual for heat-sealing coatings. In SUBSTITUTE SH~ET (RULE ~

8 2 8 W095/09876 PCT~S94/11216 general, the sealing temperature is about 30C lower than isconventional with current sealing coatings.
The sealed packaging containers produced by the process according to the invention have excellent sealed-seam strengths and excellent optical properties. The coated plastics films have excellent antiblocking properties, i.e. they do not become stuck on contact with uncoated plastics films. In addition, it is particularly advantageous that sealing can be carried out at relatively low temperatures. The sealing temperature is generally from 20 to 30C lower than the sealing temperature when using conventional heat-sealing coatings. This enables the line speed, at the same sealing temperature, to be increased.
A further advantage is that the release coating on the other side of the film, which is required when using conventional cold-sealing coatings, is not absolutely necessary in the process according to the invention.
Preferred plastics films are polyolefin films, for example polyethylene and polypropylene films. These films are particularly preferably of polypropylene, especially oriented polypropylene.
In a further aspect, the present invention also provides the use of a cold sealable composition as herein defined for coating a plastics film.
The following Examples illustrate the invention; parts are by weight unless stated otherwise.
EXAMPL~ 1 This Example relates to the preparation of an acrylate emulsion (AE l) for use as an aqueous sealing coating.
31.l parts of demineralized water and 0.05 part of an anionic emulsifier (ester type) were weighed into a reaction vessel. The initial charge was heated at 80 to 82C. A mixture of 16.2 parts of methyl acrylate, ll.9 parts of methyl methacrylate, l.4 parts of acrylic acid, 0.5 parts of isooctyl thioglycolate and 0.4 part of water was then weighed into the monomer tank and premixed. 0.09 part of ammonium peroxodisulfate and 0.3 part of demineralized water were added.
10% of the contents of the monomer tank were metered uniformly SUBSrITUTE SHEET (Ri~E 26) wosslo9876 ~ 1 7 2 ~ 2 ~ - 14 - pcT~ss~tll2l6 into the reactor over the course of 30 min at approximately 80C. Subsequently, 0.8 part of the anionic emulsifier was added. I
The reaction mixture was maintained at the reaction temperature for 10 min, and then the remaining contents of the monomer tank were metered in uniformly over a period of 3 hours at 80C. Subsequently the batch was polymerized for 2 hours at 80C. Then, at a temperature of 60C, a mixture of 0.6 ~arts of ammonia (25% strength) and 6.0 parts of water was`added with stirring. The batch was subsequently adjusted, using a mixture of ammonia (25% strength) and water (mixing ratio 0.6:6.0), to a solids content of 30% and a viscosity of 30 mPa.s at 25C.
The content of ammonia (100%) in the finished coatlng (solids content 30%) was 0.15 parts.
The resulting acrylate copolymer had a number-average molecular weight Mn of 10,000, an acid number of 37 mg of KOH/g and a glass transition temperature (Tg) of 42C (measured by differential sc~nn;ng calorimetry (DSC)).

This Example relates to the preparation of an acrylate emulsion (AE 2) for use as an aqueous sealing coating.
20.8 parts of demineralized water and 0.03 ;part of an anionic emulsifier (ester type) were weighed into a reaction vessel. The initial charge was heated at 80 to 82OC. A mixture of 10.8 parts of methyl acrylate, 7.9 partsl of methyl methacrylate, 0.9 part of acrylic acid, 0.3 part of isooctyl thioglycolate and 0.2 part of water were weighed into the monomer tank and premixed. A solution of 0.06 part of ammonium peroxodisulfate in 0.3 part of demineralized water was added to the initial charge. 10% of the contents of the ~onomer tank were metered uniformly into the reactor over a period of 30 min at approximately 80C. 0.56 part of the anionic emulsifier was then added.
The reaction mixture was maintained at the reaction temperature for 10 min, and then the remaining contents of the monomer tank were metered in uniformly over a period of 3 hours ~tBSTITUTE SHEEr (llULE 26) ~1~282`~

at 80c. Subsequently the batch is polymerized for 2 hours at 80C. A mixture of 1.6 parts of ammonia (25% strength) and 42.5 parts of water were weighed into a dilution vessel and heated to 70C. The reactor contents were drained off over 45 min at This Example relates to the preparation of an acrylate emulsion (AE 3) for use as an aqueous sealing coating.
An acrylate emulsion AE 3 was prepared by analogy with the preparation of AE 1, using :
1.86 parts of acrylic acid 4.30 parts of methyl methacrylate ~23.34 parts of ethyl acrylate 0.79 parts of ammonia (25% strength) and 5.81 parts of water.
The resulting acrylate copolymer had a number-average mol~r~ r weight (GPC) of 10,000, an acid number of 49 mg of KOH/g and a glass transition temperature (Tg) of 4C (DSC).

This Example relates to the preparation of an acrylate emulsion (AE 4) for use as an aqueous sealing coating.
An acrylate emulsion AE 4 was prepared by analogy with the preparation of AE 1, using :
1.86 parts of acrylic acid

3.15 parts of acrylonitrile 24.49 parts of ethyl acrylate 0.79 parts of ammonia (25% strength) and 5.81 parts of water.
The resulting acrylate copolymer had a number-average molecular weight (GPC) of 10,000, an acid number of 49 mg/KOH/g and a glass transition temperature (Tg) of 5C (DSC).

- This Example relates to the preparation of an aqueous sealing coating (ASC).
200 parts of AE 1 were taken. 18.0 parts of a commercially SI~BSrITUTE S~EE~ (1~ 26~

woss/o9876 ~1 7..? ~ ~ ~ pcT~ss~lll2l6 available 25% strength emulsion of carnauba wax (MICHEMLUBE
(trade mark) 160 ex Michelman, USA) were added slowly with stirring and homogeneously dispersed by further stirring for 5 minutes to provide ASC l.

This Example relates to the preparation of lan aqueous sealing coating (ASC 2).
200 parts of AE 3 were taken. 79.60 parts of a commercially available colloidal silica paste (LUDOX (trade mark) AM) were added with stirring and homogeneously dispersed by further stirring. Adding ammonia is appropriate, the pH of the sealing coating was adjusted to a value between 7.2 and 7.5.

This Example relates to the preparation of an aqueous sealing coating (ASC 3).
200 parts of AE 4 were taken. 0.59 part of SYLOID (trade mark) ED 3 (5% strength dispersion in water) and 30 parts of a commercially available, colloidal silica paste (LUDOX AD 30) were added with stirring and homogeneously dispersed by further stirring. Adding ammonia if appropriate, the pH of the sealing coating was adjusted to a value between 7 and 8.

This Example relates to the application of the sealing coatings ASC l to 3.
The coatings were applied using a doctor blade to a polyethyleneimine-primed, oriented polypropylene film 29MB210 from Mobil Plastics Europe, Belgium. The application weight was l.5 + 0.2 g/m2. The coated film was dried in a HELIOS (trade mark) laboratory oven for l5 s at a max. surface temperature of 95C.

These coated films were used to determine the;coefficient of friction and the blocking resistance with respect to the coated or uncoated reverse of the film. In addition, the sealed-seam strength was determined. The measured results are SU~SrlTUTE SHEE~ (R~E 26) ~7282~
W09sl09876 PCT~S94/11216 shown in Table l.
Coefficient of friction The coefficient of friction was determined using the ALTEK
(trade mark) 9505A device, within a period of 30 min after application of the sealing coatings, in the application direction.
The blocking resistance was tested in 2 ways:
l.) 24 hours at 47C, 0.5 kg/cm2 Test coating against uncoated outer face 2.) 24 hours at 47C, 0.5 kg/cm2 Test coating against acrylic-coated outer face.
Assessment took place on the basis of the separation effect, the rating 0 denoting the complete absence of any blocking while the rating 5 indicates total blocking.
Sealed-seam strength Two 25 mm wide strips of the above-described coated polypropylene films were sealed at a sealing temperature of less than 80C and a sealing pressure of 5 bar. In each case the æealed-seam strength was determined using the TESTOMETRIC (trade mark) l00 D device from H. Messmer, London, at a speed of 300 mm/min and a measured width of 25 mm. The results are given in TABLE l.

ASC l ASC 2 ASC 3 Coefficient of friction 0.0l0 0.030-0.060 0.0~0.
Blocking resistance uncoated face 0.5 0.5 0.5 acrylic-coated face 0.5 Sealed-seam strength (g/25 mm) 300-400 300-400 138*

* Sealed-seam strength after sealing at room temperature.

EXAMPL~ g This Example relates to the preparation of an acrylic emulsion (AE 5) and an aqueous sealing coating (ASC 4) of the ~BSrlTUTE St~ R~

WO95/09876 2 1 7 2 ~ 2 ~ PCT~S9~/11216 invention.
Using a semi-continuous batch process, a latex was prepared by continuously adding an metering 404 g. of the total monomer feed over a period of 2.5 hours to a reactor containing 475 g of water, 1 g of 30% sodium lauryl sulfate, as emulsifier, and 1.6g 70% tert-butyl hydroperoxide, as free-radical catalyst.
The premixed total monomer feed comprised of 80.2 wt.% ethyl acrylate, 15.8 wt.% acrylonitrile, 3 wt.% methacrylic acid, and 1 wt.% isoctyl thioglycolate (as a chain transfer agent), based on the total monomer feed. A feed containing 7g of 30% sodium lauryl sulfate, 0.7g of sodium formaldehyde sulfoxolate (as a catalyst activator) and 45g water was added over a three hour period. The emulsion polymerization reaction was maintained at 60C to 70C and the reaction was performed in an atmospheric pressure reactor equipped with a reflux condenser and in the presence of inert nitrogen gas. Sufficient agitation was used to uniformly disperse the monomers in the reactor. The reactor batch was held for about 1 hour after the additionlof all the feeds.
After polymerization, the terpolymer was blended with a typical combination of wax and talc.
The latex was subsequently cooled and filtered through a 200 mesh screen. The latex stability of the resultant EA/ACN/MAA terpolymer was excellent.
EX~MPLE 10 This Example relates to the preparation of a crosslinked polymer (AE 6). The procedure of this example was substantially the same as that of Example 9 except that it was a thermally-initiated polymerization. Using a semi-continuous batch process, a latex was prepared by continuously adding and metering 406 g of the total monomer feed over a period of 2.5 hours to a reactor cont~;n;ng 475 g water, 1 g ofl30% sodium lauryl sulfate, as emulsifier, and 12 g of 10% aqueolus ammonium persulfate, as a free radical initiator that wals prepared immediately prior to the start of the polymerization and added to the reactor approximately two minutes prior to beginning the addition of the monomer feed. The pre-mixed total monomer feed SI~BSrITUTE SH~ JLE ~6) 2 1 ~ 3 79.8 wt.~ ethyl acrylate, 14.8 wt.% acrylonitrile, 3 wt.%
methacrylic acid, 1 wt.% divinyl benzene (85% pure), and 1.5 wt.% iso-octyl thioglycolate, as chain-transfer agent, based on the total monomer feed. A feed containing 9 g of 23% sodium dodecyl benzene sulfonate, as stabilizing emulsifier, and 41 g water was then added over a 3-hour period. The emulsion polymerization reaction was maintained at 75 to 85OC and the reaction was performed in the same laboratory glassware that was used in Example 9. After all feeds were in, the batch was held at 80C for 1 hour at which time 17 g of 30~ aqueous ammonia (diluted to 400 g with water) was added. When the temperature again reached 80C, the batch was held an additional hour at 80C and then cooled and removed from the glassware.
The properties of the polymers prepared by Examples 9 and 10 are summarized in TABLE 2 below:

~ITllTE SHEt (RUlE 263 woss/os876 PCT~S94/11216 ~7~2~ - 20 -Characteristics of PolYmer Latex Example 9 ExamPle 10 Latex Total Solids (%) 42.8 31.5 Particle Size (nm) 130 87 pH 6.1 9.5 EXAMPhE 11 Polymer latex formulations prepared in accordance with the emulsion polymerization process of both Examples g and lo were applied by direct gravure to the sealable portions of one side of a standard acrylic coated 92 gauge oriented polypropylene film primed with polyethyleneimine (which helps to lanchor the topcoat to the substrate). The other side of the film was primed with the polyethyleneimine and coated with an all-acrylic polymer formulation. The coatings were dried at a temperature of 220F.
The coating weights for both pressure sealable coatings were 1.2 (+/- 0.4) g/1000 sq. in. while the coating weight for the acrylic-based coating was 0.6 g/1000 sq. in.
The properties of the coated films were tested and the results of the testing, in comparison with the results of testing a cold sealable terpolymer described in U.S. Patent No.
5,070,164, made by a l-step polymerization process, are summarized in TABLE 3.

~ Ill ~ SH ~ ~ ~2 WO 95/09876 2 ~ 7 2 8 2 8 PCT/US94/11216 U

U ~to ~3 In O

oq ~ o ~

P. ~ O.
h~ _ ~ ~ h ~ D ~ ~7 ~s. ,C D
U U

3 ~
E5~ O
U ~

o V ~ h C
~ ~ , h ~
_I ~ U , ~ C

,_ o ~ h 1l) 0 H
a tr _ ~-- ~ SD
U ~
~m ~ - ~ ~ u ~ ~ c ~
a ~ ~ C ~

U ~A -- = = ~. ~. C C ~ -1 A C
S E ~5 ,¢ ,¢ '¢ Ql ~ El 3 ~

z ~ m~ a) N N O al N O ~ U ~A
a h h ~ ~ ~ h h o la ~ tn u o~
r~~ u ~ ~ u ~ ~ ~ u ~ a o E'l 3 N
a ~ a - ~oo ~ooX ~ooX

S~TIME ~HEEI ~RULE 26)

Claims (32)

- 22 -

1. A copolymer preparable by the emulsion polymerisation of :
a) at least one monomer which comprises an alkyl methacrylate having from 1 to 12 carbon atoms in the alkyl group; a vinyl aromatic; or a nitrile having ethylene unsaturation conjugated with the nitrile group.
with at least one of the following:
b) at least one copolymerisable soft monomer; and c) at least one copolymerisable functional monomer, the resulting copolymer having a glass transition temperature (Tg) from -35°C to 50°C and being formulatable into a coating which is cold sealable to itself under pressure but which has non-blocking characteristics.

2. A copolymer according to claim 1 wherein the monomer (a) comprises methyl methacrylate, ethyl methacrylate, propyl methacrylate, isopropyl methacrylate, n-butyl methacrylate, iso-butyl methacrylate, t-butyl methacrylate, n-pentyl methacrylate, isopentyl methacrylate, hexyl methacrylate, n-octyl methacrylate, 2-ethylhexyl methacrylate, decyl methacrylate, dodecyl methacrylate; styrene, an .alpha.-alkyl styrene, vinyltoluene;
acrylonitrile or methacrylonitrile.

3. A copolymer according to claim 1 or 2 wherein the monomer (b) comprises an alkyl acrylate having from 1 to 12 carbon atoms in the alkyl group; 1,3-butadiene; or a vinyl or vinylidene ester.

4. A copolymer according to claim 3, wherein the monomer (b) comprises methyl acrylate, ethyl acrylate, propyl acrylate, isopropyl acrylate, butyl acrylate, isobutyl acrylate, t-butyl acrylate, n-pentyl acrylate, isopentyl acrylate, hexyl acrylate, n-octyl acrylate, iso-octyl acrylate, 2-ethylhexyl acrylate, decyl acrylate, 1,3-butadiene, vinyl acetate or vinylidene chloride.

5. A copolymer according to any preceding claim wherein the monomer (c) comprises an ethylenically unsaturated compound containing a carboxylic or a sulphonic acid group.

6. A copolymer according to claim 5 wherein the monomer (c) comprises acrylic acid, methacrylic acid, itaconic acid, crotonic acid, maleic acid; or sulfoethyl methacrylate.

7. A copolymer according to any preceding claim, wherein the glass transition temperature is from -30°C to 15°C.

8. A copolymer according to claim 7 which comprises from 10 to 65 wt.% of copolymerised monomer (a); from 30 to 85 wt.%
of copolymerised monomer (b); and from 1 to 5 wt.% of copolymerised monomer (c).

9. A copolymer according to any preceding claim which has a number average molecular weight from 50,000 to 90,000.

10. A copolymer according to any preceding claim 1 to 6 wherein the glass transition temperature is from 25°C to 50°C.

11. A polymer according to claim 10, which comprises from 30 to 55 wt.% of polymerised monomer (a) 40 to 69 wt.% of polymerised monomer (b); and from 1 to 15 wt.% of polymerised monomer (c).

12. A polymer according to claim 11, which has a number average molecular weight in the range 8,000 to 12,000.

13. A copolymer according to any preceding claim which has been crosslinked.

14. A process for the preparation of a copolymer according to claim 1, which process comprises :

(a) mixing at least one monomer (a) with at least one of monomers (b) and (c) in relative proportion so that the resulting copolymer has a Tg from -35°C to 50°C;
and (b) polymerizing the monomers under emulsion polymerization conditions.

15. A process according to claim 14 wherein the respective monomers, and their relative proportions, are defined in any of claims 1 to 6, 8, 11 or 13.

16. A process according to claim 14 or 15, which is carried out in the presence of water, an emulsifying agent and a polymerization catalyst.

17. A process according to claim 14, 15 or 16, wherein the polymerization is carried out at a temperature of 40°C to 100°C at a pressure from 0 to 30 psig (101 to 308 kPa).

18. A process according to claim 14, 15, 16 or 17, wherein the polymerization is carried out in a two stage process.

19. A process according to claim 18, wherein the first stage of the polymerization process is carried out at a temperature from 70°C to 90°C with a total of 5 to 20 wt.% of the total monomer mixture; and the second stage of the polymerization process is carried out at a temperature from 70°C
to 90°C in the presence of the polymer obtained in the first stage, together with the remaining 80 to 95 wt.% of the monomer mixture.

20. A process according to claim 19, wherein after the second stage polymerization the resulting polymer is at least partially neutralised by the addition of a base.

21. A process according to any of claims 14 to 20, wherein the polymerization is carried out in the presence of a chain transfer agent.

22. A process according to any of claims 14 to 21 wherein at least one additive is added during or after step (a) or step (b) of the process, the additive being a stabiliser, antifoaming agent, drying adjuvant, pigment, wax or thickener.

23. A cold sealable composition comprising a polymer according to any of claims 1 to 13.

24. A cold sealable composition according to claim 23 comprising an aqueous solution or dispersion of said polymer.

25. A cold sealable composition according to claim 24, wherein the solids content of the aqueous solution or dispersion is from 20 to 40 wt.%.

26. A sealable structure comprising a substrate coated on a surface thereof with a composition according to any of claims 23 to 25.

27. A sealable structure according to claim 26, wherein the substrate is coated on another surface with an acrylic-based composition.

28. A sealable structure according to claim 27, wherein the substrate comprises a layer of an olefin polymer, a nylon, a polyester or paper.

29. A sealable structure according to claim 26, 27 or 28 wherein the or each surface of the substrate is pre-coated with a primer.

30. A sealed structure comprising a coated substrate defined in any of claims 26, 27, 28 or 29 and containing perishable goods.

31. A sealed structure according to claim 30 wherein the goods are heat-sensitive comestibles.

32. Use of a cold sealable composition according to any of claims 23 to 25 for coating a plastics film.