CA2159820A1 - Lavatory blocks containing enzymes - Google Patents
Lavatory blocks containing enzymesInfo
- Publication number
- CA2159820A1 CA2159820A1 CA 2159820 CA2159820A CA2159820A1 CA 2159820 A1 CA2159820 A1 CA 2159820A1 CA 2159820 CA2159820 CA 2159820 CA 2159820 A CA2159820 A CA 2159820A CA 2159820 A1 CA2159820 A1 CA 2159820A1
- Authority
- CA
- Canada
- Prior art keywords
- lavatory
- block according
- cleansing block
- lavatory cleansing
- blocks
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0056—Lavatory cleansing blocks
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38609—Protease or amylase in solid compositions only
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38645—Preparations containing enzymes, e.g. protease or amylase containing cellulase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
Abstract
A solid lavatory block an enzyme system. Said lavatory blocks are environmentally compatible and provide enhanced stain removal.
Description
W094/23006 ~ 8 2 0 PCT~S94/03164 LAVATORY BLOC~S CONTAINING ENZYMES
Field of the Invention The present invention relates to solid lavatory cleansing blocks containing enzymes. The block is designed to have good stain removal capacity.
Backqround of the Invention Lavatory blocks for cleansing and deodourizing the lavatory bowl are well known in the art. `Such lavatory blocks typically comprise surfactants and chlorinating compounds which provide the desired cleansing and deodourizing properties.
However, the lavatory blocks disclosed in the prior art do not efficiently address the problem of stain removal of W094/~006 PCT~S94/03164 ~ 2~5982U 2 physio~ogical soils which are frequently found in the lavatory bowl. The surfactants contained in the lavatory blocks on the market are not present in sufficiently high concentrations in order to achieve optimum improved stain removal. Chlorinating agents due to their bleaching action are known for their stain removal ability. The in-bowl sta1~:rèmoval action of said chlorinating agents is limited at~`low concentrations.
. ., It is therefore an object of the present invention to provide an efficient stain and grease removal system incorporated in a solid lavatory block which is completely environmentally safe.
In response to these objectives, the present invention proposes to formulate a lavatory block comprising an enzyme system as a stain removal active.
The blocks according to the present invention progressively dissolve in water, thereby releasing the ingredients in solution. Thus, a permanent aqueous solution is provided in the lavatory bowl which comprises a constant and predetermined amount of various ingredients.
An advantage of the present invention is that the enzymes are permanently active in the lavatory bowl water during the whole period in between lavatory flushes.
summarY of the Invention The present invention is a solid lavatory block characterized in that it comprises from 0.1% to 50% of an enzyme system, whereby said lavatory block provides a permanent aqueous solution comprising an effective amount of said enzyme system as said block is progressively dissolved in said lavatory bowl water.
All ratios, percentages and parts given herein are "by weight" unless otherwise specified.
~ W094/~006 2 ~ 5 9 8 Z ~ PCT~S94/03164 Detailed DescriPtlon of the Inventlon The present invention relates to a solid lavatory cleansing block. There are two types of lavatory blocks available on the market at present, in-rim and in-cistern type lavatory blocks.
The in-rim type blocks are distinct from in-cistern type blocks in that they are designed to be hung from the rim of the lavatory bowl, in a conventional type rim cage. The in-cistern type blocks are designed to be placed in the cistern itself.
Depending on the positioning of the block the properties of the active ingredients will vary, depending on the length of time the block is immersed in water. The lavatory blocks according to the present invention are designed to be used as both in-rim and in-cistern type lavatory blocks.
The blocks according to the present invention progressively dissolve in water, thereby releasing the ingredients in solution. Thus, a permanent aqueous solution is provided in the lavatory bowl which comprises a constant and predetermined amount of various ingredients.
The lavatory blocks of the present invention comprise as an essential feature from 0.1% to 50%, preferably from 1% to 40%, more preferably from 2% to 25% of an enzyme system. Suitable enzymes which may be used are selected from lipases, proteases, cellulases, amylases, polysaccharide hydrolases and mixtures thereof. The preferred enzyme for use herein is lipase.
Typically lavatory blocks according to the present invention comprise a lipase enzyme such that the lipolytic activity of the lavatory block is from O.Ol to 5000 KLU, preferably from O.1 to lOOO KLU, most preferably from 1 to 150 KLU per gram of the lavatory block. KLU are standard kilo units defined by Novo for measuring lipase activity.
The lavatory blocks according to the present invention typically comprise a protease enzyme such that the protolytic activity of the lavatory block is from O.Ol to 500 KNPU, W094l~006 2~5 9 82b PCT~S94/03164 preferably from 0.05 to 200 KNPU, most preferably from l to lO0 KNPU per gram of the lavatory block. KNPU denotes Kilo Novo Protease units.
The lavatory blocks according to the present invention typically comprise an amylase enzyme such that the amylolytic activity of the lavatory block is from 0.Ol to 500 KNU, preferably from O.l to 250, most preferably from l to lO0 KNPU
per gram of the lavatory block. KNU aFe Kilo Novo units used for measuring amylase activity. ~`
Typically, lavatory blocks according to the present invention comprise a cellulase enzyme such that the cellulytic activity of the lavatory block is from O.Ol to 50 000 CE W , preferably from O.l to lO 000 CEW , more preferably from l to 1500 CE W
per gram of the lavatory block. CEW are standard units for measuring cellulase activity.
Commercially available enzymes for use herein include :
- protease of Bacillus, especially from B. licheniformis (e.g.
Alcalase(R) and from alkalophilic Bacillus strains according to US 3 723 250 (e.g. Savinase(R)) (both available from Novo Industri A/S).
- Alpha-amylase of Bacillus, especially B. licheniformis, Termamyl(R) (Novo Industri A/S).
- Protease of Fusarium, especially F. oxysporum, US 3 652 399 (Takeda), PCT/DK 89/OOOOl.
- Cellulase of Humicola, especially H.Insolens. Celluzyme(R).
(Novo Industri A/S), Us 4 435 307 (Novo).
- Lipase of Humicola, especially H. lanuginosa, Lipolase(R) (Novo), EP 305 216 (Novo) and US 4 810 414 (Novo).
The enzyme system assists in t`he removal of faecal, urine and grease stains which are found in the lavatory bowl. It is believed that enzymes, especially lipases are effective in removing the stains found in the lavatory bowl by attacking the components present in faeces which represent a significant fraction of the faecal soil.
W094/23006 215 98 2 0 PCT~S94/03164 The lavatory blocks according to the present invention may also contain a number of optional ingredients. One such ingredient is a surfactant system. The incorporation of a surfactant provides increased cleansing of the lavatory blocks and provides a solid matrix in which all the other ingredients can be incorporated. The block comprises at least 10~ of a surfactant system. The surfactants that may be used herein can be anionic and nonionic surfactants or mixtures thereof.
The anionic surfactants which may be used in the present invention include for example alkali metal salts of alkyl substituted benzene sulphonates, alkali metal alkyl sulphonates, alkali metal alkyl sulphonates and alkali metal alkyl ether sulphates derived for example from fatty alcohols and alkyl phenols, alkali metal alkane sulphonates, alkali metal olefin sulphonates and alkali metal sulphosuccinates, whereby the sodium salts are preferred. Most preferred are sodium alkyl metal sulphonates and sulphates.
The nonionic surfactants which may be used can be chosen from any liquid or solid ethoxylated C6-C24 fatty alcohol nonionic surfactant, fatty acid C6-C24 alkanolamides, C6-C20 polyethylglycol ethers, polyethyleneglycol with molecular weight 1000 to 80000 and C6-C24 amine oxides.
The lavatory blocks of the present invention may further comprise from 0.001% to 10%, preferably from 0.001% to 3%
soluble calcium salts. The calcium salts can be used to stabilize the enzymes.
The lavatory blocks of the invention may further comprise 0%
to 50%, preferably from 5% to 3Q%, fillers of inorganic salts such as sodium sulphate, sod`ium carbonate, sodium silicate and less preferably phosphorous sodium salts, for example sodium triphosphate, or inert fillers such as clay, urea or calcite.
The fillers can be used to adjust the mechanistic properties of the lavatory blocks so that the active ingredients are released in the desired manner.
W094/23006 215 9 82 ~ PCT~S94/03164 ~
The differences in the composition of the in-rim and in-cistern type lavatory blocks of the present invention can be exclusively but not necessarily dependant upon the type of surfactants, fillers and polymers used therein, to determine the dissolution rate. The composition differences are well known in the art. In-cistern type ~avatory blocks can preferably contain surfactants;~I~h a lower solubilization rate and may be chosen from long.c~ain higher anionics or nonionics with a high degree of ethoxylation. In-cistern type lavatory blocks may also contain specific ingredients to decrease the solubilization rate such as slowly dissolving polymers or oils.
The lavatory blocks of the present invention may further comprise as an optional feature from lppm to 500ppm, preferably from 5ppm to 300ppm, more preferably from lOppm to 200ppm active oxygen in the lavatory bowl water. The source of active oxygen can be selected from hydrogen peroxide or sources thereof, preformed peroxyacids, organic peroxides and mixtures thereof. As used herein active oxygen concentration refers to the percentage concentration of elemental oxygen, with an oxidation number zero, that being reduced to water would be stoichiometrically equivalent to a given percentage concentration of a given peroxide compound, when the peroxide functionality of the peroxide compound is completely reduced to oxides.
A hydrogen peroxide source according to the present invention refers to any compound which produces hydrogen peroxide when said compound is in contact with water. Suitable water-soluble sources of hydrogen peroxide for use herein include persul-phates, percarbonates, metal oxides and perborates.
Suitable preformed peroxyacids for use in the lavatory blocks according to the present invention include diperoxydodecandioic acid DPDA, magnesium perphthalate, perlauric acid, perbenzoic acid, diperoxyazelaic acid and mixtures thereof. The blocks according to the present invention comprise from 0.01% to 30%
of said preformed peroxyacids.
~1.5~20 ~ W094/~006 PCT~S94/03164 Suitable organic peroxides for use in the lavatory blocks according to the present invention include diacyl and dialkyl peroxides such as dibenzoyl peroxide, dilauroyl peroxide, dicumyl peroxide and mixtures thereof. The blocks according to the present invention comprise from 0.01% to 30% of said organic peroxides.
optionally, the lavatory blocks may additionally comprise peracid precursors, i.e. compounds that upon reaction with hydrogen peroxide produce peroxyacids. Examples of peracid precursors suitable for use in the present invention can be found among the classes of esters, amides, imides and anhydrides such as acetyl triethyl citrate (ATC), tetra acetyl ethylene diamine (TAED), succinic or maleic anhydrides. All of these bleaching agents are environmentally compatible and odourless.
Another optional component of said system is an acid or alkali. The acid or alkali is used to ensure that the pH of the lavatory bowl water is in the range of pH 4 to pH 10. The stability and activity of the enzymes of the present invention can be optimized by ensuring that the pH of said lavatory bowl water is at the optimum level for the enzyme used herein.
The acids of the present invention that may be used for this purpose may in addition have the advantage that they can form small concentrations of the corresponding peracids by reaction with hydrogen peroxide in-situ, thus enhancing the overall performance of the lavatory block. These acids can be further selected so as to have chelating and/or building properties, which results in limescale removal. The acids that can be used in the present invention are organic or inorganic acids, preferably organic acids such as citric, maleic, oxalic succinic and tartaric acids, more preferably citric and maleic acids.
The alkalis that may be used in the present invention include sodium hydroxide, potassium hydroxide, alkali metal hydroxides, ' 2,~S982o W094/~006 - PCT~S94/03164 ~
alkaline earth metal hydroxides and amines, for example monoethylamine, monoethanolamine and triethanolamine.
Another additional ingredient of the lavatory block is a chelant system. The chelant system improves the overall limescale/rust removal performance. Furthermore, the chelant system may improve the stability of the bleaching agent in the formulation. Suitable chelants may be chosen from EDTA, NTA or preferably from biodegradable chelants such as s,s-ethylene diamino disuccinate and dipicolinic acid.
Further optional ingredients include perfumes and dyes used to improve the aesthetics of the lavatory block. These perfumes and dyes contained in the lavatory block are selected for their stability in the presence of the source of active oxygen. In a preferred embodiment of the present invention, where said blocks comprise perfumes and dyes, it is desirable to manufacture said blocks in a process whereby said perfumes and dyes can be premixed with the enzymes and the other optional ingredients, before the addition of the source of active oxygen if said compound is a component of the lavatory block.
The lavatory cleansing block is formed by conventional methods well known in the art as described for instance in EP-A
462 643. The ingredients are mixed to form a dough of suitable consistency which can then be extruded and cut into lengths to form blocks. The extrusion process can be carried out by using simple conventional extrusion equipment such as usually used for manufacturing soap bars. Alternatively, the lavatory blocks may be prepared by compressing all of the ingredients into a block.
The present invention is further illustrated by the following examples.
o W094/23006 ~ PCT~S94/03164 Examples The following compositions are made by combining the listed ingredients, in the listed proportions.
EXAMPLE8 No. 1,2,3,4 1 2 3 Ingredients Weight %
Sodium Coconut Alkyl Sulphate 50 53 55 55 Lutensol AO30 5 2 - -Sodium Sulphate 30 30 28 28 LipolaseR lOOL lO 5 5 5 SavinaseR 8.OL - 5 5 3 CelluzymeR - - 2 2 Perfume 4 4 4 4 Dyes or pigments, water Balance Balance Balance Balance EXAMPLE8 No. 5,6,7,8 5 6 7 8 Ingredients Weight ~
Sodium Coconut Alkyl Sulphate 50 50 50 55 Lauryl Ether Sulphate 3 3 3 Sodium Sulphate lO lO 13 15 LipolaseR lOOL 5 5 5 5 SavinaseR 8.OL 3 3 3 Sodium Persulphate - lO lO 8 Citric Acid 20 lO lO lO
Dipicolinic Acid 3 3 3 Perfumes 5 5 5 6 Dyes or pigments, water Balance Balance Balance Balance
Field of the Invention The present invention relates to solid lavatory cleansing blocks containing enzymes. The block is designed to have good stain removal capacity.
Backqround of the Invention Lavatory blocks for cleansing and deodourizing the lavatory bowl are well known in the art. `Such lavatory blocks typically comprise surfactants and chlorinating compounds which provide the desired cleansing and deodourizing properties.
However, the lavatory blocks disclosed in the prior art do not efficiently address the problem of stain removal of W094/~006 PCT~S94/03164 ~ 2~5982U 2 physio~ogical soils which are frequently found in the lavatory bowl. The surfactants contained in the lavatory blocks on the market are not present in sufficiently high concentrations in order to achieve optimum improved stain removal. Chlorinating agents due to their bleaching action are known for their stain removal ability. The in-bowl sta1~:rèmoval action of said chlorinating agents is limited at~`low concentrations.
. ., It is therefore an object of the present invention to provide an efficient stain and grease removal system incorporated in a solid lavatory block which is completely environmentally safe.
In response to these objectives, the present invention proposes to formulate a lavatory block comprising an enzyme system as a stain removal active.
The blocks according to the present invention progressively dissolve in water, thereby releasing the ingredients in solution. Thus, a permanent aqueous solution is provided in the lavatory bowl which comprises a constant and predetermined amount of various ingredients.
An advantage of the present invention is that the enzymes are permanently active in the lavatory bowl water during the whole period in between lavatory flushes.
summarY of the Invention The present invention is a solid lavatory block characterized in that it comprises from 0.1% to 50% of an enzyme system, whereby said lavatory block provides a permanent aqueous solution comprising an effective amount of said enzyme system as said block is progressively dissolved in said lavatory bowl water.
All ratios, percentages and parts given herein are "by weight" unless otherwise specified.
~ W094/~006 2 ~ 5 9 8 Z ~ PCT~S94/03164 Detailed DescriPtlon of the Inventlon The present invention relates to a solid lavatory cleansing block. There are two types of lavatory blocks available on the market at present, in-rim and in-cistern type lavatory blocks.
The in-rim type blocks are distinct from in-cistern type blocks in that they are designed to be hung from the rim of the lavatory bowl, in a conventional type rim cage. The in-cistern type blocks are designed to be placed in the cistern itself.
Depending on the positioning of the block the properties of the active ingredients will vary, depending on the length of time the block is immersed in water. The lavatory blocks according to the present invention are designed to be used as both in-rim and in-cistern type lavatory blocks.
The blocks according to the present invention progressively dissolve in water, thereby releasing the ingredients in solution. Thus, a permanent aqueous solution is provided in the lavatory bowl which comprises a constant and predetermined amount of various ingredients.
The lavatory blocks of the present invention comprise as an essential feature from 0.1% to 50%, preferably from 1% to 40%, more preferably from 2% to 25% of an enzyme system. Suitable enzymes which may be used are selected from lipases, proteases, cellulases, amylases, polysaccharide hydrolases and mixtures thereof. The preferred enzyme for use herein is lipase.
Typically lavatory blocks according to the present invention comprise a lipase enzyme such that the lipolytic activity of the lavatory block is from O.Ol to 5000 KLU, preferably from O.1 to lOOO KLU, most preferably from 1 to 150 KLU per gram of the lavatory block. KLU are standard kilo units defined by Novo for measuring lipase activity.
The lavatory blocks according to the present invention typically comprise a protease enzyme such that the protolytic activity of the lavatory block is from O.Ol to 500 KNPU, W094l~006 2~5 9 82b PCT~S94/03164 preferably from 0.05 to 200 KNPU, most preferably from l to lO0 KNPU per gram of the lavatory block. KNPU denotes Kilo Novo Protease units.
The lavatory blocks according to the present invention typically comprise an amylase enzyme such that the amylolytic activity of the lavatory block is from 0.Ol to 500 KNU, preferably from O.l to 250, most preferably from l to lO0 KNPU
per gram of the lavatory block. KNU aFe Kilo Novo units used for measuring amylase activity. ~`
Typically, lavatory blocks according to the present invention comprise a cellulase enzyme such that the cellulytic activity of the lavatory block is from O.Ol to 50 000 CE W , preferably from O.l to lO 000 CEW , more preferably from l to 1500 CE W
per gram of the lavatory block. CEW are standard units for measuring cellulase activity.
Commercially available enzymes for use herein include :
- protease of Bacillus, especially from B. licheniformis (e.g.
Alcalase(R) and from alkalophilic Bacillus strains according to US 3 723 250 (e.g. Savinase(R)) (both available from Novo Industri A/S).
- Alpha-amylase of Bacillus, especially B. licheniformis, Termamyl(R) (Novo Industri A/S).
- Protease of Fusarium, especially F. oxysporum, US 3 652 399 (Takeda), PCT/DK 89/OOOOl.
- Cellulase of Humicola, especially H.Insolens. Celluzyme(R).
(Novo Industri A/S), Us 4 435 307 (Novo).
- Lipase of Humicola, especially H. lanuginosa, Lipolase(R) (Novo), EP 305 216 (Novo) and US 4 810 414 (Novo).
The enzyme system assists in t`he removal of faecal, urine and grease stains which are found in the lavatory bowl. It is believed that enzymes, especially lipases are effective in removing the stains found in the lavatory bowl by attacking the components present in faeces which represent a significant fraction of the faecal soil.
W094/23006 215 98 2 0 PCT~S94/03164 The lavatory blocks according to the present invention may also contain a number of optional ingredients. One such ingredient is a surfactant system. The incorporation of a surfactant provides increased cleansing of the lavatory blocks and provides a solid matrix in which all the other ingredients can be incorporated. The block comprises at least 10~ of a surfactant system. The surfactants that may be used herein can be anionic and nonionic surfactants or mixtures thereof.
The anionic surfactants which may be used in the present invention include for example alkali metal salts of alkyl substituted benzene sulphonates, alkali metal alkyl sulphonates, alkali metal alkyl sulphonates and alkali metal alkyl ether sulphates derived for example from fatty alcohols and alkyl phenols, alkali metal alkane sulphonates, alkali metal olefin sulphonates and alkali metal sulphosuccinates, whereby the sodium salts are preferred. Most preferred are sodium alkyl metal sulphonates and sulphates.
The nonionic surfactants which may be used can be chosen from any liquid or solid ethoxylated C6-C24 fatty alcohol nonionic surfactant, fatty acid C6-C24 alkanolamides, C6-C20 polyethylglycol ethers, polyethyleneglycol with molecular weight 1000 to 80000 and C6-C24 amine oxides.
The lavatory blocks of the present invention may further comprise from 0.001% to 10%, preferably from 0.001% to 3%
soluble calcium salts. The calcium salts can be used to stabilize the enzymes.
The lavatory blocks of the invention may further comprise 0%
to 50%, preferably from 5% to 3Q%, fillers of inorganic salts such as sodium sulphate, sod`ium carbonate, sodium silicate and less preferably phosphorous sodium salts, for example sodium triphosphate, or inert fillers such as clay, urea or calcite.
The fillers can be used to adjust the mechanistic properties of the lavatory blocks so that the active ingredients are released in the desired manner.
W094/23006 215 9 82 ~ PCT~S94/03164 ~
The differences in the composition of the in-rim and in-cistern type lavatory blocks of the present invention can be exclusively but not necessarily dependant upon the type of surfactants, fillers and polymers used therein, to determine the dissolution rate. The composition differences are well known in the art. In-cistern type ~avatory blocks can preferably contain surfactants;~I~h a lower solubilization rate and may be chosen from long.c~ain higher anionics or nonionics with a high degree of ethoxylation. In-cistern type lavatory blocks may also contain specific ingredients to decrease the solubilization rate such as slowly dissolving polymers or oils.
The lavatory blocks of the present invention may further comprise as an optional feature from lppm to 500ppm, preferably from 5ppm to 300ppm, more preferably from lOppm to 200ppm active oxygen in the lavatory bowl water. The source of active oxygen can be selected from hydrogen peroxide or sources thereof, preformed peroxyacids, organic peroxides and mixtures thereof. As used herein active oxygen concentration refers to the percentage concentration of elemental oxygen, with an oxidation number zero, that being reduced to water would be stoichiometrically equivalent to a given percentage concentration of a given peroxide compound, when the peroxide functionality of the peroxide compound is completely reduced to oxides.
A hydrogen peroxide source according to the present invention refers to any compound which produces hydrogen peroxide when said compound is in contact with water. Suitable water-soluble sources of hydrogen peroxide for use herein include persul-phates, percarbonates, metal oxides and perborates.
Suitable preformed peroxyacids for use in the lavatory blocks according to the present invention include diperoxydodecandioic acid DPDA, magnesium perphthalate, perlauric acid, perbenzoic acid, diperoxyazelaic acid and mixtures thereof. The blocks according to the present invention comprise from 0.01% to 30%
of said preformed peroxyacids.
~1.5~20 ~ W094/~006 PCT~S94/03164 Suitable organic peroxides for use in the lavatory blocks according to the present invention include diacyl and dialkyl peroxides such as dibenzoyl peroxide, dilauroyl peroxide, dicumyl peroxide and mixtures thereof. The blocks according to the present invention comprise from 0.01% to 30% of said organic peroxides.
optionally, the lavatory blocks may additionally comprise peracid precursors, i.e. compounds that upon reaction with hydrogen peroxide produce peroxyacids. Examples of peracid precursors suitable for use in the present invention can be found among the classes of esters, amides, imides and anhydrides such as acetyl triethyl citrate (ATC), tetra acetyl ethylene diamine (TAED), succinic or maleic anhydrides. All of these bleaching agents are environmentally compatible and odourless.
Another optional component of said system is an acid or alkali. The acid or alkali is used to ensure that the pH of the lavatory bowl water is in the range of pH 4 to pH 10. The stability and activity of the enzymes of the present invention can be optimized by ensuring that the pH of said lavatory bowl water is at the optimum level for the enzyme used herein.
The acids of the present invention that may be used for this purpose may in addition have the advantage that they can form small concentrations of the corresponding peracids by reaction with hydrogen peroxide in-situ, thus enhancing the overall performance of the lavatory block. These acids can be further selected so as to have chelating and/or building properties, which results in limescale removal. The acids that can be used in the present invention are organic or inorganic acids, preferably organic acids such as citric, maleic, oxalic succinic and tartaric acids, more preferably citric and maleic acids.
The alkalis that may be used in the present invention include sodium hydroxide, potassium hydroxide, alkali metal hydroxides, ' 2,~S982o W094/~006 - PCT~S94/03164 ~
alkaline earth metal hydroxides and amines, for example monoethylamine, monoethanolamine and triethanolamine.
Another additional ingredient of the lavatory block is a chelant system. The chelant system improves the overall limescale/rust removal performance. Furthermore, the chelant system may improve the stability of the bleaching agent in the formulation. Suitable chelants may be chosen from EDTA, NTA or preferably from biodegradable chelants such as s,s-ethylene diamino disuccinate and dipicolinic acid.
Further optional ingredients include perfumes and dyes used to improve the aesthetics of the lavatory block. These perfumes and dyes contained in the lavatory block are selected for their stability in the presence of the source of active oxygen. In a preferred embodiment of the present invention, where said blocks comprise perfumes and dyes, it is desirable to manufacture said blocks in a process whereby said perfumes and dyes can be premixed with the enzymes and the other optional ingredients, before the addition of the source of active oxygen if said compound is a component of the lavatory block.
The lavatory cleansing block is formed by conventional methods well known in the art as described for instance in EP-A
462 643. The ingredients are mixed to form a dough of suitable consistency which can then be extruded and cut into lengths to form blocks. The extrusion process can be carried out by using simple conventional extrusion equipment such as usually used for manufacturing soap bars. Alternatively, the lavatory blocks may be prepared by compressing all of the ingredients into a block.
The present invention is further illustrated by the following examples.
o W094/23006 ~ PCT~S94/03164 Examples The following compositions are made by combining the listed ingredients, in the listed proportions.
EXAMPLE8 No. 1,2,3,4 1 2 3 Ingredients Weight %
Sodium Coconut Alkyl Sulphate 50 53 55 55 Lutensol AO30 5 2 - -Sodium Sulphate 30 30 28 28 LipolaseR lOOL lO 5 5 5 SavinaseR 8.OL - 5 5 3 CelluzymeR - - 2 2 Perfume 4 4 4 4 Dyes or pigments, water Balance Balance Balance Balance EXAMPLE8 No. 5,6,7,8 5 6 7 8 Ingredients Weight ~
Sodium Coconut Alkyl Sulphate 50 50 50 55 Lauryl Ether Sulphate 3 3 3 Sodium Sulphate lO lO 13 15 LipolaseR lOOL 5 5 5 5 SavinaseR 8.OL 3 3 3 Sodium Persulphate - lO lO 8 Citric Acid 20 lO lO lO
Dipicolinic Acid 3 3 3 Perfumes 5 5 5 6 Dyes or pigments, water Balance Balance Balance Balance
Claims (11)
1. A lavatory cleansing block characterized in that it comprises from 0.1% to 50% of an enzyme system, whereby said block provides a permanent aqueous solution comprising an effective amount of said enzyme system as it dissolved in the lavatory bowl water.
2. A lavatory cleansing block according to claim 1, wherein said enzyme system comprises enzymes selected from lipases, cellulases, proteases and amylases or mixtures thereof.
3. A lavatory cleansing block according to claim 2, wherein said enzyme is a lipase.
4. A lavatory cleansing block according to claims 1 to 3, wherein said permanent aqueous solution has a pH from 4 to 10.
5. A lavatory cleansing block according to claims 1 to 4, further comprising above 10% of a surfactant system.
6. A lavatory cleansing block according to claims 1 to 5, further comprising from 1ppm to 500ppm of active oxygen as said block is progressively dissolved in said lavatory bowl water.
7. A lavatory cleansing block according to claim 6, wherein said source of active oxygen is selected from hydrogen peroxide or a source thereof, preformed peroxyacids, peroxides and mixtures thereof.
8. A lavatory cleansing block according to claims 1 to 7, further comprising from 0% to 20% of a chelant system.
9. A lavatory cleansing block according to claims 1 to 8, further comprising from 0% to 50% of a filler system.
10. A lavatory cleansing block according to claims 1 to 9, further comprising from 0% to 20% of an peracid precursor.
11. The use of an enzyme system in a lavatory cleansing block to remove stains in the lavatory bowl.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP93201007A EP0619367A1 (en) | 1993-04-06 | 1993-04-06 | Lavatory blocks containing enzymes |
| EP93201007.7 | 1993-04-06 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2159820A1 true CA2159820A1 (en) | 1994-10-13 |
Family
ID=8213747
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA 2159820 Abandoned CA2159820A1 (en) | 1993-04-06 | 1994-03-23 | Lavatory blocks containing enzymes |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0619367A1 (en) |
| JP (1) | JPH08508770A (en) |
| AU (1) | AU6551694A (en) |
| CA (1) | CA2159820A1 (en) |
| WO (1) | WO1994023006A1 (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4337032C1 (en) * | 1993-10-29 | 1995-05-24 | Henkel Kgaa | Use of detergent mixtures for the production of toilet blocks |
| US5858117A (en) | 1994-08-31 | 1999-01-12 | Ecolab Inc. | Proteolytic enzyme cleaner |
| US5830839A (en) * | 1995-05-17 | 1998-11-03 | Sunburst Chemicals, Inc. | Solid detergents with active enzymes and bleach |
| BR9709668A (en) * | 1996-06-12 | 2000-05-09 | Unilever Nv | Blocks for holy vessels |
| PL343345A1 (en) * | 1998-04-09 | 2001-08-13 | Unilever Nv | Toilet cleaning blocks |
| HUP0102361A3 (en) * | 1998-04-09 | 2002-02-28 | Unilever Nv | Toilet cleaning blocks, its preparation and a method of preventing heating within the toilet block |
| DE19850896A1 (en) * | 1998-11-05 | 2000-05-11 | Buck Chemie Gmbh | Partial agent for the toilet area |
| GB0004130D0 (en) * | 2000-02-23 | 2000-04-12 | Procter & Gamble | Detergent tablet |
| BRPI0415729B1 (en) * | 2003-10-24 | 2015-05-19 | Novapharm Res Australia | Tablet for use in a drip tray and method for inhibiting the growth of a biofilm in a drip tray |
| AU2004284836B2 (en) * | 2003-10-24 | 2010-08-05 | Novapharm Research (Australia) Pty Ltd | Drip tray tablet |
| JP5047385B1 (en) * | 2011-08-26 | 2012-10-10 | 都市拡業株式会社 | Urine stone remover |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3798181A (en) * | 1970-11-03 | 1974-03-19 | Colgate Palmolive Co | Enzymatic detergent bar |
| US4248827A (en) * | 1978-06-12 | 1981-02-03 | The Procter & Gamble Company | Method for sanitizing toilets |
| JPH0788519B2 (en) * | 1985-06-07 | 1995-09-27 | ダウブランズ・インコーポレーテッド | Stain and stain remover for laundry |
| US4810414A (en) * | 1986-08-29 | 1989-03-07 | Novo Industri A/S | Enzymatic detergent additive |
| GB8629534D0 (en) * | 1986-12-10 | 1987-01-21 | Unilever Plc | Enzymatic detergent & bleaching composition |
| GB8813687D0 (en) * | 1988-06-09 | 1988-07-13 | Unilever Plc | Enzymatic dishwashing & rinsing composition |
| GB9013539D0 (en) * | 1990-06-18 | 1990-08-08 | Unilever Plc | Lavatory cleansing block |
| GB9015503D0 (en) * | 1990-07-13 | 1990-08-29 | Unilever Plc | Detergent composition |
| US5178787A (en) * | 1991-03-11 | 1993-01-12 | Block Drug Company, Inc. | Lavatory cleaning block comprising n,n-dichloro dialkyl hydantoin and aluminum hydroxide |
-
1993
- 1993-04-06 EP EP93201007A patent/EP0619367A1/en not_active Withdrawn
-
1994
- 1994-03-23 JP JP6522179A patent/JPH08508770A/en active Pending
- 1994-03-23 AU AU65516/94A patent/AU6551694A/en not_active Abandoned
- 1994-03-23 CA CA 2159820 patent/CA2159820A1/en not_active Abandoned
- 1994-03-23 WO PCT/US1994/003164 patent/WO1994023006A1/en active Application Filing
Also Published As
| Publication number | Publication date |
|---|---|
| AU6551694A (en) | 1994-10-24 |
| JPH08508770A (en) | 1996-09-17 |
| EP0619367A1 (en) | 1994-10-12 |
| WO1994023006A1 (en) | 1994-10-13 |
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| Date | Code | Title | Description |
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| EEER | Examination request | ||
| FZDE | Dead |