CA2149978C - Centrifugal concentrator - Google Patents

Centrifugal concentrator

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Publication number
CA2149978C
CA2149978C CA 2149978 CA2149978A CA2149978C CA 2149978 C CA2149978 C CA 2149978C CA 2149978 CA2149978 CA 2149978 CA 2149978 A CA2149978 A CA 2149978A CA 2149978 C CA2149978 C CA 2149978C
Authority
CA
Canada
Prior art keywords
capture zone
liquid
hollow
slurry
drum
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CA 2149978
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French (fr)
Other versions
CA2149978A1 (en
Inventor
Steven A. Mcalister
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Individual
Original Assignee
Individual
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Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CA 2149978 priority Critical patent/CA2149978C/en
Priority to PCT/CA1996/000338 priority patent/WO1996037307A1/en
Priority to NZ308040A priority patent/NZ308040A/en
Priority to CN96194104A priority patent/CN1083737C/en
Priority to AU57567/96A priority patent/AU707961B2/en
Publication of CA2149978A1 publication Critical patent/CA2149978A1/en
Application granted granted Critical
Publication of CA2149978C publication Critical patent/CA2149978C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B04CENTRIFUGAL APPARATUS OR MACHINES FOR CARRYING-OUT PHYSICAL OR CHEMICAL PROCESSES
    • B04BCENTRIFUGES
    • B04B15/00Other accessories for centrifuges
    • B04B15/12Other accessories for centrifuges for drying or washing the separated solid particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B04CENTRIFUGAL APPARATUS OR MACHINES FOR CARRYING-OUT PHYSICAL OR CHEMICAL PROCESSES
    • B04BCENTRIFUGES
    • B04B1/00Centrifuges with rotary bowls provided with solid jackets for separating predominantly liquid mixtures with or without solid particles

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  • Centrifugal Separators (AREA)

Abstract

A centrifugal concentrator for separating higher density particles from a slurry provides reduced water consumption by providing a fluidized capture zone in the upper section of the bowl only, and provides an unob-structed interior migration surface in the lower part of the bowl to provide a preliminary separation of heavier particles.

Description

2lqg978 CENTRIFUGAL CONCENTRATOR

The present invention relates to centrifugal con-centrators of the rotating bowl type for the separation and recovery of particulate solids of higher specific gravity, such as gold, from a slurry containing such particulate solids as well as particulate solids of a lower specific gravity and liquid.

BACKGROUND OF THE INVENTION

The problem of separating particles of high den-sity such as precious metals from tailings and other slurry streams has attracted a great many attempted solutions. The problem is that of separating small particles of higher density from a slurry containing water and particles of lower density such as sand. One approach has been to use the centrifugal force created in a rotating bowl to sepa-rate the high density particles from the lower density slurry. In the past this had been generally done by placing obstructions such as ribs in the path of the rotating slurry to trap the heavier particles. This method has various problems. Where the slurry contained fine, dense particles such as magnetite, the grooves or depressions designed to retain the concentrate would rapidly pack with the unwanted fine particles.
The problem of packing has been largely solved by the present inventor's centrifugal concentrator which is the subject of U.S. Patent no. 4,824,431 issued April 25, 1989.
In that centrifugal concentrator, there are no obstacles to the flow of the slurry in the rotating drum. The slurry is delivered to the vicinity of the bottom of the rotating drum and travels up the smooth interior surface of the drum. The interior surface has three continuous zones: an outwardly inclined migration zone, a generally vertical retention zone above the migration zone, and an inwardly-inclined lip zone above the retention zone. The respective lengths and inclinations of the zones are selected to produce flow conditions in which less dense particles are 21~9978 expelled from the drum while denser particles migrate to and are retained in the retention zone. The result is that an enriched layer of concentrate accumulates in the reten-tion zone without the use of ridges or grooves which may become packed.
It remains that the above-described centrifugal concentrator is a batch device in which the concentrate retention capacity is quite limited, and so must be fre-quently stopped to empty it. In some situations, this periodic stoppage can add to the cost and complication of running the centrifuge. Also where the retention zone is flushed frequently the grade of concentrate is low, since a large proportion of non-enriched material is obtained with each flushing of the zone.
A second approach to the packing problem in cent-rifugal concentrators is that disclosed in Australian Patent no. 22,055/35 (MacNicol), complete specification published 23 April, 1936. Figure 1 of that patent dis-closes a centrifugal concentrator in which the entire inner wall of the rotating bowl is provided with a plurality of annular riffles and a plurality of orifices arranged at the deepest point between the riffles. Water under pressure is supplied to the orifices through a supply and pressure jacket around the bowl. The flow of liquid through the orifices causes the particles caught in the riffles to be agitated and allows the heavier particles to penetrate to the wall of the bowl.
Centrifugal concentrators of the fluidizing bed approach of Australian Patent no. 22,055/35 have a number of disadvantages. Since a large volume of water is re-quired to supply the water ]acket to fluidize the wall of the bowl, concentrators of this type consume a good deal of water. The added water consumption adds to the cost of operation and disposal of the waste slurry output, and in some cases such as grinding circuits can have a negative impact on the overall system. Due to the addition of the fluidizing water to the input slurry, the capacity of the bowl to process the input slurry is reduced, and more energy is required to rotate the added water required for the fluidization. The addition of internal ridges also adds to the concentrator weight.
There is therefore a need for a centrifugal concentrator which has the advantages of both the McAlister and MacNicol-type centrifugal concentrators, but which uses less water and requires less energy to operate than the MacNicol-type concentrator.

SUMMARY OF THE INVENTION

The present invention therefore provides a concentrator for separating particulate material of higher specific gravity from a liquid slurry comprising a liquid and particulate material of different specific gravities, the concentrator comprising:
(a) a hollow drum having an open end, a substantially closed end and an inner surface, mounted co-axially on a hollow shaft;
(b) means for rotatably supporting the hollow shaft on an axis;
(c) drive means for rotating the drum and hollow shaft about the axis;
(d) material supply means to deliver the liquid slurry into the end of the drum spaced from the open end;
wherein the inner surface of the hollow drum comprises an outwardly inclined migration surface and a capture zone above the migration surface, wherein the capture zone comprises a generally vertical annular wall located radial-ly outwardly of the migration zone and a flow-obstructing element extending perpendicularly from the vertical wall, and the capture zone is adapted to be fluidized from a source of liquid under pressure located radially outwardly of the capture zone, and the hollow drum further comprises a discharge outlet adjacent the closed end.

21~9978 The present invention further provides a method of separating particulate material of higher specific gravity from a liquid slurry comprising a liquid and particulate material of different specific gravities, the method comprising:
a) providing a concentrator comprising:
(i) a hollow drum having an open end, a substan-tially closed end and an inner surface, mounted co-axially on a hollow shaft;
(ii) means for rotatably supporting the hollow shaft on an axis;
(iii) drive means for rotating the drum and hollow shaft about the axis;
(iv) material supply means to deliver the liquid slurry into the end of the drum spaced from the open end;
wherein the inner surface of the hollow drum comprises an outwardly inclined migration surface and a capture zone above the migration surface, wherein the capture zone comprises a generally vertical annular wall located radially outwardly of the migration zone and a flow-obstructing element extending perpendicularly from the vertical wall, and the capture zone is adapted to be fluidized from a source of liquid under pressure located radially outwardly of the capture zone, and the hollow drum further com-prises a discharge outlet adjacent the closed end; and v) means for providing liquid under pressure to the capture zone;
b) rotating the hollow drum;
c) feeding the slurry through the material supply means;
d) providing liquid under pressure to provide radially inwardly directed fluidizing liquid in the capture zone to agitate the slurry in the capture zone;

e) stopping the supply of the slurry to the hollow bowl;
f) reducing the speed of the rotation of the bowl and substantially simultaneously providing a reduced volume of fluidizing liquid under pressure to the capture zone; and g) washing captured particles out of the capture zone through the discharge outlet.

BRIEF DESCRIPTION OF THE DRAWINGS

In drawings which illustrate a preferred embodi-ment of the invention:

Fig. 1 is a front perspective view of the centri-fuge of the invention;
Fig. 2 is a rear elevation view of the invention, with the shroud and frame partially cut away to illustrate the plumbing assembly;
Fig. 3 is a front elevation view of the inven-tion, partially cut away and partially in section, toillustrate the rotor bowl assembly of the invention;
Fig. 4 is a vertical cross-section of the inven-tion taken along lines 4-4 of Fig.l with the drive assembly removed and the flushing manifold slightly repositioned for ease of illustration;
Fig. 5 is a detail view taken along lines 5-5 of Fig.2;
Fig. 6 is a detail view taken along lines 6-6 of Fig.5; Fig. 7 is a detail view showing a section of the rotor bowl in cross-section;
Fig. 8 is a perspective view of the capture zone of the invention, shown in Figure 7;
Fig. 9 is an elevation of the rotor of the invention, partially cut away; and Fig. 10 is a cross-section taken along lines 10-10 of figure 9 with details of the water supply passages shown in phantom lines.

DETAILED DESCRIPTION OF A PREFERRED EMBODIMENT

With reference to the drawings, the centrifugal concentrator of the invention is designated by reference 5 numeral 1. It has a frame 3, a shroud 4 consisting of shroud lid 5 and tailings launder 14, and drive motor 9.
The frame is constructed of hollow steel sections which are sealed to provide water storage, as further described below. The shroud lid 5 has openings for a slurry feed pipe 18 and inspection ports 17 sealed by removable plugs, and an inner lining 6 of a wear resistant material such as LINATEXTM or a natural rubber. The flange of shroud lid 5 is bolted to the upper flange of tailings launder 14. Tailings launder 14 is provided with a tailings discharge port 19 15 (Fig. 2) . A concentrate launder 16 with a concentrate discharge port 20 (Fig. 2) is also provided. The floor 22 of launder 14 (Fig. 3) is sloped downwardly to assist in a smooth outward flow of the discharge and is preferably coated with an ultra-high molecular weight polyethylene or 20 other low friction, wear-resistant material.
Rotor 21 iS formed of rotor bowl 23 and hollow rotor shaft 24. The rotor 21 is mounted for rotation in the frame 3 by bearing assemblies 25. The inner surface of rotor bowl 23 forms a migration zone A and a capture zone 25 B (Fig. 3), which cause the denser, target particles from the slurry flow to be concentrated in the capture zone.
The rotor shaft 24 has a sheave 27 which is driven by a belt 32 in belt guard 7 driven by electric motor 9 through sheave 33. An impeller 34 is provided on the centre of a 30 baffle 36, which is raised above and secured to the floor of bowl 23. Impeller 34 has a plurality of upstanding vanes 31 to assist in the rotation of the slurry.
An external pipe 26 provides water under pressure from the frame 3 to a hollow flushing manifold 28 (Fig. 4, 35 7) secured to feed pipe 18 and provided with holes 29. A
plumbing assembly 31 (Fig. 2), described in more detail below, supplies water under pressure to a rotating union 37 through which the water passes to the hollow interior 35 of rotor shaft 24 from where it passes through one of four holes 40 into one of four radially extending passages 41 and thence into one of the four supply hoses 42 which carry the water under pressure to annular chamber 46.
Rotor bowl 23 is formed of a lower bowl section 60, (Figure 3, 7) which is bolted by bolts 61 to the sloping bowl section 62. Section 60 has four concentrate outlets 64. The inner surface of sections 60, 62 and the upper surface of baffle 36 have a lining 63 of a wear resistant material such as a l/4-inch layer of LINATEXTM or a natural rubber. Section 60 is fixed to rotor shaft 24.
The capture zone B of the present invention comprises a wall portion 47 and circular ribs 50, 52 upstanding from wall portion 47. Wall portion 47 has a plurality of holes 48 formed therethrough in the areas between ribs. Holes 48 communicate with hollow chamber 46 which in turn is supplied with water under pressure through the supply hoses 42. Preferably there are 6 horizontal rows of 1/16 inch diameter holes countersunk to the inter-ior of chamber 40, two rows between shoulder 65 and rib 52, two between ribs 50 and 52 and two between rib 50 and lip 58. The spacing of the holes varies from top to bottom. In the top two rows, preferably the holes are spaced 3/4 inches from centre to centre in each row. In the middle two rows, preferably the holes are spaced 7/8 inches from centre to centre in each row. In the bottom two rows, preferably the holes are spaced 1 inch from centre to centre in each row.
As shown in Figure 7, preferably rib 52 extends further radially inwardly than rib 50, but less than shoulder 65, and lip 58 extends less radially inwardly than rib 50. Thus the tops of ribs 52, 50 follow generally the slope of the migration zone A if it were extended. As seen in Figure 7, if the surface of the migration zone is extended as a straight line, the capture zone B takes up about 1/3 of the length of the surface (the "length" of the 21~9978 surface meaning the length of an imaginary straight line drawn on the intersection of a vertical plane trough the axis of rotation and the surface of the migration zone A, extended to lip 58), although it could be expanded to cover as much as 50~ of the surface length without losing the benefits of the invention. Circular rim 54 is bolted to the upper edge of rotor bowl 23 at 56, forming lip 58. A
second circular rim 60 is bolted to the upper surface of rim 56 by bolts 68 to provide a variable thickness or diameter in the lip area according to the particular slurry which is being processed. The "basket" consisting of cylindrical wall 48 and ribs 50, 52 sits in a groove in shoulder 65 and can be readily removed for cleaning by removing lid 5, and rim 54 by removing bolts 56.
Water is supplied to frame 3 through pipe 70, via water filter 72 having pressure gauges 74. External release valve 76 permits water to be released to clean filter 72. Pipe 71 with pressure gauge 82 supplies water from frame 3 to rotating union 37, via valve 73 which is variably throttled by manual lever 75, or by air-operated pinch valve 77. Pinch valve 77 is automatically shut when the motor 9 slows rotor shaft 24 to the rinse cycle, but water continues to flow through bypass pipe to the rotating union 37 during the rinse cycle. A manual lever and valve 80 permits bypass pipe 79 to be manually shut.
In operation, motor 9 is activated to rotate the rotor shaft 24. The slurry feed is introduced to the spin-ning rotor through feed pipe 18. Centrifugal forces cause the slurry to climb up the migration zone A on inner surface 63 of the rotor bowl section past capture area B
before being expelled past lip 58, into tailings launder 14 and thence out of the machine through discharge port 19.
The areas between shoulder 65, ribs 50, 52 and lip 58 are initially empty prior to introduction of the slurry. They rapidly fill with solids as the slurry is introduced. As the process advances, the heavier particles accumulate in these areas. The flow of water under pressure through 21qgg78 holes 48 from chamber 46 causes the particles to be agita-ted and permits the heavier concentrate to accumulate in the area closest to wall 47. Once there has been a suffi-cient accumulation of concentrate, the feed slurry is shut 5 off, the rotation of the bowl slows to a very gradual rotation, water is sprayed out through manifold 28 and the concentrate flows around baffle 36, out outlets 64 into concentrate launder 16 from where it is collected.
In order to avoid fine slurry particles penetrat-ing into chamber 46 through holes 48, which would neces-sitate cleaning of chamber 46, and to assist in emptying the rotor of concentrate when the rotor is slowly rotating in the rinse cycle, water is constantly supplied into chamber 46 under pressure, even during the rinse cycle.
15 During the rinse cycle, while the water supply through the main pipe 71 is automatically shut off, a reduced amount of water continues to flow through bypass 79.
An advantage of the present invention is that the action of the rotor 23 acts as a pump to create water 20 pressure in chamber 46, which permits the device to be operated with reduced pump requirements for the water supply pressure when the rotor is rotating. Since the water must flow radially outwardly through passages 41, it is angularly accelerated by the rotation of bowl 23 and is 25 under increased pressure therefore in chamber 46.
Since a smaller portion of the inner bowl surface is fluidized in the present invention than in MacNicol, less water is consumed. The bowl is also lighter and requires less energy to rotate. The placement of migration zone A prior to the capture zone B allows the heavier particles to migrate closer to the wall of the bowl before entering the capture zone and so a reduced capture zone is made possible.
As will be apparent to those skilled in the art, 3 5 various modifications and adaptations of the structure above described may be made without departing from the 2l~9978 spirit of the invention, the scope of which is to be construed in accordance with the accompanying claims.

Claims (11)

1. A concentrator for separating particulate material of higher specific gravity from a liquid slurry comprising a liquid and particulate material of different specific gravities, said concentrator comprising:
(a) a hollow drum having an open end, a substantially closed end and an inner surface, mounted co-axially on a hollow shaft;
(b) means for rotatably supporting said hollow shaft on an axis;
(c) drive means for rotating said drum and hollow shaft about said axis;
(d) material supply means to deliver said liquid slurry into the end of said drum spaced from said open end;
wherein said inner surface of said hollow drum comprises an outwardly inclined migration surface and a capture zone above said migration surface, wherein said capture zone comprises a generally vertical annular wall located radial-ly outwardly of said migration zone and a flow-obstructing element extending perpendicularly from said vertical wall, and said capture zone is adapted to be fluidized from a source of liquid under pressure located radially outwardly of the capture zone, and said hollow drum further comprises a discharge outlet adjacent said closed end; and e) means for providing liquid under pressure to said capture zone.
2. The centrifugal concentrator of claim 1 wherein said hollow drum further comprises an annular liquid supply chamber radially outwardly of said capture zone, and said substantially vertical wall of said capture zone comprises a plurality of apertures therethrough communicating with said liquid supply chamber.
3. The centrifugal concentrator of claim 1 wherein said capture zone covers less than 50% of the length of the inner surface of said hollow drum.
4. The centrifugal concentrator of claim 1 wherein said capture zone covers approximately one-third of the length of the inner surface of said hollow drum.
5. The centrifugal concentrator of claim 1 wherein said capture zone comprises upper and lower annular parallel flow-obstructing ribs extending perpendicularly from said substantially vertical wall.
6. The centrifugal concentrator of claim 5 wherein said substantially vertical wall in said capture zone is provi-ded with a plurality of apertures between said upper and lower parallel flow-obstructing ribs, above said upper rib and below said lower rib.
7. The centrifugal concentrator of claim 1 wherein said hollow drum further comprises an annular liquid supply chamber radially outwardly of said capture zone, and said substantially vertical wall of said capture zone comprises a plurality of apertures therethrough communicating with said liquid supply chamber.
8. The centrifugal concentrator of claim 2 wherein said means for providing liquid under pressure to said capture zone comprise liquid carrying passages communicating between said hollow shaft and said liquid supply chamber.
9. The centrifugal concentrator of claim 8 wherein said means for providing liquid under pressure to said liquid supply chamber comprises a rotating union adapted to provided liquid communication between a liquid supply means and said hollow shaft.
10. The centrifugal concentrator of claim 4 wherein said liquid supply means comprises a first supply line which is adapted to be selectively closed or opened and a secondary supply line which is adapted to supply liquid to said rotating union when said first supply line is closed.
11. A method of separating particulate material of higher specific gravity from a liquid slurry comprising a liquid and particulate material of different specific gravities, said method comprising:
a) providing a concentrator comprising:
(i) a hollow drum having an open end, a substan-tially closed end and an inner surface, mounted co-axially on a hollow shaft;
(ii) means for rotatably supporting said hollow shaft on an axis;
(iii) drive means for rotating said drum and hollow shaft about said axis;
(iv) material supply means to deliver said liquid slurry into the end of said drum spaced from said open end;
wherein said inner surface of said hollow drum comprises an outwardly inclined migration surface and a capture zone above said migration surface, wherein said capture zone comprises a generally vertical annular wall located radially outwardly of said migration zone and a flow-obstructing element extending perpendicularly from said vertical wall, and said capture zone is adapted to be fluidized from a source of liquid under pressure located radially outwardly of said capture zone, and said hollow drum further comprises a discharge outlet adjacent said closed end; and v) means for providing liquid under pressure to said capture zone;
b) rotating said hollow drum;

c) feeding said slurry through said material supply means;
d) providing liquid under pressure to provide radially inwardly directed fluidizing liquid in said capture zone to agitate said slurry in said capture zone;
e) stopping the supply of said slurry to said hollow bowl;
f) reducing the speed of said rotation of said bowl and substantially simultaneously providing a reduced volume of fluidizing liquid under pressure to said capture zone; and g) washing captured particles out of said capture zone through said discharge outlet.
CA 2149978 1995-05-23 1995-05-23 Centrifugal concentrator Expired - Lifetime CA2149978C (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
CA 2149978 CA2149978C (en) 1995-05-23 1995-05-23 Centrifugal concentrator
PCT/CA1996/000338 WO1996037307A1 (en) 1995-05-23 1996-05-22 Centrifugal concentrator
NZ308040A NZ308040A (en) 1995-05-23 1996-05-22 Centrifugal concentrator
CN96194104A CN1083737C (en) 1995-05-23 1996-05-22 Centrifugal concentrator
AU57567/96A AU707961B2 (en) 1995-05-23 1996-05-22 Centrifugal concentrator

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CA 2149978 CA2149978C (en) 1995-05-23 1995-05-23 Centrifugal concentrator

Publications (2)

Publication Number Publication Date
CA2149978A1 CA2149978A1 (en) 1996-11-24
CA2149978C true CA2149978C (en) 1999-12-07

Family

ID=4155890

Family Applications (1)

Application Number Title Priority Date Filing Date
CA 2149978 Expired - Lifetime CA2149978C (en) 1995-05-23 1995-05-23 Centrifugal concentrator

Country Status (5)

Country Link
CN (1) CN1083737C (en)
AU (1) AU707961B2 (en)
CA (1) CA2149978C (en)
NZ (1) NZ308040A (en)
WO (1) WO1996037307A1 (en)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2271958C (en) * 1996-12-09 2000-02-08 Benjamin V. Knelson Centrifugal separator with injection of fluidizing liquid between non-fluidized recesses
US5895345A (en) * 1996-12-09 1999-04-20 Knelson; Benjamin Centrifugal separator with a reduced number of fluidized recesses
US6095965A (en) * 1997-08-06 2000-08-01 Sortech Separation Technologies Ltd. Centrifugal separator for dry components
CA2446383C (en) 2002-12-03 2004-10-12 Knelson Patents Inc. Centrifugal separation bowl with material accelerator
WO2008049212A1 (en) * 2006-10-23 2008-05-02 Mcalister Steven A Centrifugal concentrator
CA2770039C (en) * 2009-07-29 2014-12-02 Flsmidth A/S Centrifugal bowl with liner material molded on a frame
CN103203291B (en) * 2013-04-23 2014-03-26 丹东大迪矿山科技有限公司 Continuous ore discharge centrifugal separator
CN104815765B (en) * 2015-04-14 2017-09-12 昆明理工大学 A kind of micro-size fraction material centrifugal classification equipment
CN105396702A (en) * 2015-12-10 2016-03-16 中国矿业大学 Fine coal centrifugal separation equipment capable of discharging materials continuously
US20190060914A1 (en) * 2016-02-25 2019-02-28 Sepro Mineral Systems Corp. Method and apparatus for centrifugal concentration using vibratory surfaces and rotor bowl for use therein
US10695774B2 (en) * 2017-11-21 2020-06-30 Richard F Corbus Centrifuge separator for gold mining and recovery
CN108940612A (en) * 2018-05-30 2018-12-07 嘉善永金金属制品有限公司 A kind of cleaning machine for metal material separation
CN109354369B (en) * 2018-10-22 2023-12-05 长沙理工大学 Control method of slurry treatment system
CN111375496A (en) * 2019-12-31 2020-07-07 浙江三联环保科技股份有限公司 Drum type separator
MX2022007183A (en) 2020-04-21 2022-07-19 Sepro Mineral Systems Corp Particle separation by density.

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4286748A (en) * 1980-05-19 1981-09-01 Bailey Albert C Centrifugal concentrator
US4515689A (en) * 1982-12-03 1985-05-07 Clasicon (Proprietary) Limited Classifying means
US4824431A (en) * 1987-01-13 1989-04-25 Mcalister Steven A Centrifugal concentrator

Also Published As

Publication number Publication date
CN1185122A (en) 1998-06-17
CN1083737C (en) 2002-05-01
AU707961B2 (en) 1999-07-22
CA2149978A1 (en) 1996-11-24
NZ308040A (en) 1998-12-23
WO1996037307A1 (en) 1996-11-28
AU5756796A (en) 1996-12-11

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