CA2143330A1 - Liquid or Gel Detergent Compositions Containing Calcium and Stabilizing Agent Thereof - Google Patents
Liquid or Gel Detergent Compositions Containing Calcium and Stabilizing Agent ThereofInfo
- Publication number
- CA2143330A1 CA2143330A1 CA 2143330 CA2143330A CA2143330A1 CA 2143330 A1 CA2143330 A1 CA 2143330A1 CA 2143330 CA2143330 CA 2143330 CA 2143330 A CA2143330 A CA 2143330A CA 2143330 A1 CA2143330 A1 CA 2143330A1
- Authority
- CA
- Canada
- Prior art keywords
- hydrocarbyl
- liquid
- detergent compositions
- gel detergent
- compositions containing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title abstract 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 title abstract 3
- 239000011575 calcium Substances 0.000 title abstract 3
- 229910052791 calcium Inorganic materials 0.000 title abstract 2
- 239000003599 detergent Substances 0.000 title abstract 2
- 239000007788 liquid Substances 0.000 title abstract 2
- 239000003381 stabilizer Substances 0.000 title 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 abstract 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 abstract 1
- -1 2-hydroxypropyl Chemical group 0.000 abstract 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 abstract 1
- 125000000129 anionic group Chemical group 0.000 abstract 1
- 229910001424 calcium ion Inorganic materials 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 abstract 1
- 239000011976 maleic acid Substances 0.000 abstract 1
- 239000001630 malic acid Substances 0.000 abstract 1
- 239000002736 nonionic surfactant Substances 0.000 abstract 1
- 229910001427 strontium ion Inorganic materials 0.000 abstract 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2082—Polycarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/06—Ether- or thioether carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/525—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/92—Sulfobetaines ; Sulfitobetaines
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Liquid or gel detergent compositions having improved physical stability comprise, by weight of the composition: (a) from about 3 percent to about 95 % of anionic sulfate or sulfonate surfactant; (b) from about 3 % to about 40 % nonionic surfactant, preferably polyhydroxy fatty acid amide having formula (I) wherein R1 is hydrogen, C1-C4 hydrocarbyl, 2-hydroxyethyl, 2-hydroxypropyl, or mixtures thereof; R7 is C5-C31 hydrocarbyl; and Z is a polyhydroxy-hydrocarbyl having a linear hydrocarbyl chain with at least three hydroxyl groups directly connected to the chain, or an alkoxylated derivative thereof; (c) from about 0.1% to about 3% of calcium or strontium ions; (d) from 0.05 to 10 % of malic, maleic or acetic acid, at a molar ratio with calcium of from 0.01:1 to 10:1.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP92870139 | 1992-09-01 | ||
EP92870139.0 | 1992-09-01 |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2143330A1 true CA2143330A1 (en) | 1994-03-17 |
CA2143330C CA2143330C (en) | 1999-02-23 |
Family
ID=8212268
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA 2143330 Expired - Fee Related CA2143330C (en) | 1992-09-01 | 1993-08-25 | Liquid or gel detergent compositions containing calcium and stabilizing agent thereof |
Country Status (9)
Country | Link |
---|---|
EP (1) | EP0658188A4 (en) |
JP (1) | JPH08500630A (en) |
CN (1) | CN1086842A (en) |
CA (1) | CA2143330C (en) |
CZ (1) | CZ53895A3 (en) |
MA (1) | MA22968A1 (en) |
MX (1) | MX9305316A (en) |
TR (1) | TR27708A (en) |
WO (1) | WO1994005758A1 (en) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BR9408132A (en) * | 1993-11-24 | 1997-08-05 | Unilever Nv | Viscous stable compositions for removing lime scale |
WO1995020027A1 (en) * | 1994-01-25 | 1995-07-27 | The Procter & Gamble Company | High sudsing light duty liquid or gel dishwashing detergent compositions containing long chain amine oxide |
WO1995020028A1 (en) * | 1994-01-25 | 1995-07-27 | The Procter & Gamble Company | Low to moderate sudsing detergent compositions containing long chain amine oxide |
US5500153A (en) * | 1994-07-05 | 1996-03-19 | The Procter & Gamble Company | Handwash laundry detergent composition having improved mildness and cleaning performance |
US5731276A (en) * | 1996-07-30 | 1998-03-24 | The Clorox Company | Thickened aqueous cleaning composition and methods of preparation thereof and cleaning therewith |
KR100525042B1 (en) * | 1996-07-30 | 2006-01-27 | 더 클로록스 캄파니 | Thickened aqueous cleaning composition |
BR9810747A (en) * | 1997-06-13 | 2000-09-19 | Procter & Gamble | Light-duty liquid dishwashing detergent compositions that have desirable low temperature stability characteristics and desirable grease and foaming removal characteristics |
EP1111031A1 (en) * | 1999-12-22 | 2001-06-27 | The Procter & Gamble Company | cleaning composition |
DE10120441C2 (en) | 2001-04-25 | 2003-09-04 | Henkel Kgaa | Detergent tablets with a viscoelastic phase |
JP4514436B2 (en) * | 2003-11-21 | 2010-07-28 | ライオン株式会社 | Liquid detergent composition |
CN106281750A (en) * | 2016-07-27 | 2017-01-04 | 得洁日化科技有限公司 | Gel heavy duty detergent fumes from cleaning agent |
CN112153958A (en) | 2018-06-04 | 2020-12-29 | 荷兰联合利华有限公司 | Preservative composition |
MX2020012640A (en) | 2018-06-04 | 2021-01-29 | Unilever Ip Holdings B V | Preservation compositions. |
EP3773921B1 (en) | 2018-06-04 | 2023-03-01 | Unilever IP Holdings B.V. | Preservation compositions |
WO2020109022A1 (en) * | 2018-11-30 | 2020-06-04 | Unilever N.V. | Preserved cleaning compositions |
EP4069810A1 (en) * | 2019-12-05 | 2022-10-12 | The Procter & Gamble Company | Cleaning composition |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4318818A (en) * | 1979-11-09 | 1982-03-09 | The Procter & Gamble Company | Stabilized aqueous enzyme composition |
US4529525A (en) * | 1982-08-30 | 1985-07-16 | Colgate-Palmolive Co. | Stabilized enzyme-containing detergent compositions |
FR2601960B1 (en) * | 1986-07-25 | 1989-05-26 | Lesieur Cotelle | DETERGENT, VISCOUS, DILUABLE COMPOSITION AND PROCESS FOR OBTAINING SAME |
SK25093A3 (en) * | 1990-09-28 | 1993-07-07 | Procter & Gamble | Detergent containing alkyl sulfate and polyhydroxy fatty acid amide surfactants |
GB9021217D0 (en) * | 1990-09-28 | 1990-11-14 | Procter & Gamble | Liquid detergent compositions |
DE69113057T2 (en) * | 1990-09-28 | 1996-05-30 | Procter & Gamble | ANIONTENSIDE, POLYHYDROXY FATTY ACID AMIDES AND MAGNESIUM CONTAINING DETERGENT COMPOSITIONS. |
JP3007151B2 (en) * | 1990-09-28 | 2000-02-07 | ザ、プロクター、エンド、ギャンブル、カンパニー | Detergent composition comprising polyhydroxy fatty acid amide and alkyl alkoxylated sulfate |
CZ87393A3 (en) * | 1990-11-16 | 1994-07-13 | Procter & Gamble | Light-type agents for dish washing, which contain alkyl-ethoxy-carboxylate surface-active agent and calcium or magnesium ions |
US5223179A (en) * | 1992-03-26 | 1993-06-29 | The Procter & Gamble Company | Cleaning compositions with glycerol amides |
-
1993
- 1993-08-25 CZ CZ95538A patent/CZ53895A3/en unknown
- 1993-08-25 EP EP93921186A patent/EP0658188A4/en not_active Withdrawn
- 1993-08-25 JP JP6507285A patent/JPH08500630A/en active Pending
- 1993-08-25 CA CA 2143330 patent/CA2143330C/en not_active Expired - Fee Related
- 1993-08-25 WO PCT/US1993/007994 patent/WO1994005758A1/en not_active Application Discontinuation
- 1993-08-31 TR TR00769/93A patent/TR27708A/en unknown
- 1993-08-31 MX MX9305316A patent/MX9305316A/en unknown
- 1993-09-01 CN CN 93118833 patent/CN1086842A/en active Pending
- 1993-09-02 MA MA23277A patent/MA22968A1/en unknown
Also Published As
Publication number | Publication date |
---|---|
WO1994005758A1 (en) | 1994-03-17 |
EP0658188A4 (en) | 1995-08-09 |
MA22968A1 (en) | 1994-04-01 |
EP0658188A1 (en) | 1995-06-21 |
TR27708A (en) | 1995-06-22 |
JPH08500630A (en) | 1996-01-23 |
CA2143330C (en) | 1999-02-23 |
CZ53895A3 (en) | 1995-11-15 |
CN1086842A (en) | 1994-05-18 |
MX9305316A (en) | 1995-01-31 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed |