CA2139496A1

CA2139496A1 - Hair treatment preparations

Info

Publication number: CA2139496A1
Application number: CA002139496A
Authority: CA
Inventors: Kurt Seidel; Reinhard Mueller; Detlef Hollenberg; Christian Priebe
Original assignee: Individual
Current assignee: Henkel AG and Co KGaA
Priority date: 1992-07-03
Filing date: 1993-06-24
Publication date: 1994-01-20
Also published as: DE59307950D1; ATE161709T1; WO1994001077A1; ES2111752T3; GR3026138T3; EP0648104B1; EP0648104A1

Abstract

The use of water-based hair treatment prepara-tions containing a combination of cationic polymers bearing imidazolinium groups with amophteric or zwitter-ionic polymers leads to a considerable improvement in wet combability and to a shift in dry combability into an optimal range for style retention.

Description

21~9496 Zg9 PC~ ~ 12.10.1992 ~ir tro~tmont pr-paratio~

This invent~on relates to hair ~r~a~ment prepara-~ion~ containing a special combination of poly~e~s.
The uashing and carQ of hair iQ an important part of personal hygiene. Both the wa~hing of hair ~ith shampoos and the decoratiYe finishing of hair ~tyles, for e~ample by coloring or permanent waving, ar~ meas-ures which affect the natural structure and properties of hair. For examp}e, th~ wet and dry combability of hair, its hold and its ~ody cAn be adversely affoct~3d or the number of spl it ends can be increased by 5UC~I
measures .
Accordingly, it has long becn st~ndard practice to subject the hair to a special aftertreatment. To this end, the hair is treated, normally by rinsing, vith ~peci~l active ~ubstanc~s, for example quaternary am~onium salts or special polymers. Com~ability, hold and body are improved and the number of split ends are reduced by this treatment, depending on the formulation of the prepara~ion used.
Additions of cationic polymer~ to ~air treatment preparations generally lead to an improvement in we~ and dry combability. Additions of ampho~eric polymers produce significant improvements in wet combability bu~
generally have little effect on dry combability.
Qther po5itiYe effects can often be obtained ~y combining several active substances from different classes. Thus, it is known ~rom DE-Al-30 ~ 738, for example, ~at hair treat~ent preparations can be pro-vided with a mixture of amphoteric and cationic po~y-mers.
Whereas the improvement in ~et combability, i.e.
a reduction in vet combing ~ork, is desi~able in every ~139~96 ~ 299 PCT 2 case, the circumstances regarding dry combabil~ty ~re more complicated. Lo~ combing work values character~ze an improvement in comba~ility. However, if combing ~ork is overly reduced, ~he hair loses body and hold fiO that, in ex~reme cases, certain styles can no longer be created. Accordingly, a certain increas~ in dry co~bing work may be en~irely desirable, above all ~n the case of relatively intricate ~tyles, in order to ~mprove style retention.
It has now surpr~singly been found that prepara-tions containing a combination of amphoteric or zwitter-ionic polymers and certain cationic polymers produce a desirable improvement in ~et combabil~ty wh~le increas-ing dry com~ing work to an optlmsl level for style lS retention. Accordingly, it is possible to achieve both a distinct improvement in wet styla~ility and an in-crease in dry style retention. In addition, the treatcd hair shows good curl retention and bounce.
Arcordingly, the present invention relates to aqueous ~air treatment preparations containing a com-bination of cationic and a~photeric or zwi~erionic polymers in addi~ion to typical cosmetic constituents, characterized in that the cationic poly~ers contain imidazol inium groups .
'rhe cationic polymers, suitable for use in accord-ance with the invention sre synt~esized from comp~unds which contain a~ least one polymerizable group in addi-tion to at least one cationic group and which are free fronl anionic ~roups.
The polymerizab}e group is preferably a vinyl group. However, cationic polymer~ in which the polymer main chain is made up for example of glycosides may also be used.

Typica~ cationic groups are groups containing quaternary n~trogen or phosphorus atoms. Groups con-21~9~91~

29g PCT 3 talning q~ater~.ary nitrogen atoms ar2 preferr~d. The quaternary nitrogen atoms ~ay carry four different substituents or partly ths same sub~tituents and may also be part of a ring syste~. So rar as the present invention is concerned, it is c Ncial that at least some of the cationic groups contain quaternary nitrogen a~oms forming par~ of an imidazollnlu~ ring. According to the invention, polymer~ in which at least 50~ of the cation-ic groups contain i~idazoliniu~ r~ngs are preferred polymers. Polymers in w~ich the lmidazolinium systems are the only cationic groups are particul~rly preferred.
The imidazolinium syste~s are preferably quater-ni2ed imidazoles w~ich contain only the polymerizable group as substituent. However, i~idazoles containing }5 other subs~ituents, particularly c,., alkyl groups, may a}so be used. Quaternization may be carried o~t ~ith any known quaternizing agents, for example di~ethyl sulfate, dietnyl sulfate and methyl chloride.
According to the invsntion, ca~ionic polymer~
containing at least one nonionic monomer in addition to the ca~io~ic monomers are also preferred. Suitable nonionic mon~mers are, for example, vinyl pyrrolidone, vinyl acetate, acrylamide, methacryla~ide, ~ethyl acrylate, ethyl acrylate, methyl methacrylate and ethyl methacrylate. Vinyl pyrrolidone i5 a particularly pre~erred nonionic ~onomer.
Viny~ imidazolinium methoc~loride/viny~ pyrroli-.
done copolymers are commercially available, for exa~ple, under the name of Luviquat (BASF).
30 ! Among ~e copolymers of oat~onic and nonionic mono~ers, those in ~hich ~he ratio o~ ca~ionic to nonionic mono~e~s is from 1.5:1 to 1:1.5 are preferred f~r the purposes of the invention. Copolymers in which t~e ra~io of cat}onic and nonionic monomers is approxi-mate~y 1:1 haYe proved to ~e partic~larly suita~le ~or ~139196 the purposes of t~e invention.
"A~photer{c polymers" in t~e con~ext ~f the invention ars understood to be polymers which contain both free amino qroups and free -COOH or -SO,H groups in the mol~cule and which are capable of for~ing inner salts. "2witterionic polymers" are poly~ers ~hich conta~n quaternary ammonium groups and -COO~ or -S03-groups in the molecule.
One example of an amp~oteric polymer suitable for lo use ~n accordance wit~ the invention is ~he acrylic resin commercially obtainabl~ as Amphomer~ vhich is a copolymer of tert.butylaminoethyl ~ethacryla~e, N-(1,1,3,3-tetramethylbutyl)-acrylamide and tYo or mor~
monomers from the group consisting of acrylic acid, methacrylic acid and simple esters thereof.
O~her amphoteric or zwitterionic polymers 3uit-able f~r use in accordance ~t~ the invention are the compounds mentioned in G~-A-2,104,091, in EP-A 4~ 71~, in EP-A-21~ 27~, in EP-~-283 81~ and in DE-A-28 ~7 369.
Zwitterionic polymers consisting essentially of the following monomers are particularly preferred:

(~ monomers containing quaternary ammonium groups corresponding to general formula Rl-~H=cR2-Co-x-(cnH~n)-N~)R3R~Rs A~' (I) in w~ich R~ and ~ independently of one anot~er represent hydrogen or a methyl group and R3, R~
and R5 independently of ~ne another represent C1, alkyl groups, X is an NH group or an oxygen atom, n is an integer o~ 2 to 5 and A~-) is the anion of an organic or inorganic acid and 35 ~B) mono~eric carboxylic acids corresponding to 21~9496 general formula (II):

R~-CH=CR~-COOH (II) in which R6 and R' independen~ly of one another are hydrogen or methyl groups.

According to the invention, these compounds ~ay be used both directly and also in salt form, i . e . after neutralization of the polymers, for example vith an alkali metal hydroxide. Particulars of the production of ~hese polymers can be found in D~-A-39 29 973.
Polymers based on monomers (~), in w~ich R3, R
and Rs are methyl groups, X is an NH group and A~-' is a halide, methoxysulfate or ethoxysulfate ion, are most particularly preferred. ~crylamidopropyl trimethyl ammonium chloride is a particularly preferred monomer (~). Acrylic acid or an alkali ~etal sa~t of acrylic acid, ~ore particularly the sodium salt, is preferab~y

2~ used as the monomer (~) for the polymers ment~oned above.
Other preferred zwit~erionic polymers are those in which the number of monomers (a) is greater than the nu~ber of monomers (B~. Ratios of the (~) to (B) monomers of greater than 1.5 are par~icularly preferred.
Both cationic and amphoteric and zwitterionic polymers are preferably present in quantities of 0.01 to 10% by weigh~, based on th~ preparation.as a whole Quantities of o.o1 to 5S by weight are particularly

3~ prefe~red~ .
Preparations containing the cationic poly~ers and amphoteric or zwitterionic polymers in quantity ratios of 10:1 to 2:1 have proved to be particularly effectiVe.
It has also been found that particularly good results are obtained in accordance with the inven~ion if the prepara~ions according to the inYention also contai~
a surfactant. The surfactant may be an anionic, cation-ic, ampholytic, z~it~erionic or nonionic surfactant.
Fxamples of ca~ionic ~urfactants suitable for use lr. the ~lair treatment preparations according to the ~nvention are, in particular, quaternary ammonium compounds, preferably ammonium halides, especially chloride and bromides, such as al~yl ~rimethyl ammoniu~
chlorides, dialkyl di~ethyl ammonium chlorides and trialky} methyl ammonium chlorides, for example cetyl tri~ethyl amm~nium chloride, stearyl trimethyl ammonium chloride, distea~yl dimethyl ammonium chloride, lauryl dimethyl ammonium chlo~ide, lauryl dimet~y} benzyl ammonium chloride and tricetyl methyl ammonium chloride.
Other cationic surfactants suita~le for use in accord-a~ce with t~e invention are quaternized protein hydroly-zates.
Also suitable for the purposes of the invention are silicone oils, such as for example the commercially available produc~s Q2-7224 (a sta~ilized trimethyl silyl amodimethicone; a product of Dow Corning~, Dow Corning 929 Emulsion (containing a hydroxylamino-modified silicone which is also ~no~n as amodimethicone), SM-2059 (General Electric), SLM-55067 (Wacker) and Ab~1-Quat 3270 and 3272 ~Th. Goldschmid~; diquaternary polydimeth-yl siloxanes, Quate~nium-80).
Apart from a favourable conditioning effert, alky.l amidoamines, particularly fatty acid amidoaminesJ
such as the stearyl amidopropyl di~ethyl amine commer-~ially available as Te~o Amid~ s 18, are distinguished in particular by their ready biodegradability.
So-called esterquat~, ~uch as the dialkyl ammoni-um methosulfates and methyl ~ydroxyalkyl dialkoyloxy-al~yl ammonium methosulfates mar~eted under the name Stepantex~, are also readily biodegradable.

213949~
- H 299 P~T 7 one example of a quaternary sug~r d~rivative suitable for use as a cationic surfac~ant is ~he com~er-c~al product Gluc~uat100 of which the ClFA na~ is ~d~r Methyl Gll~cet~-10 ~y~roxy~ropyl ~imonium Chloride.
Particularly preferred cationic surfactants are ~ alkylamidoamines, quaternary ester compc~nds and quater-nary sugar derivatives.
Anionic surfactants suitable for the preparat~ons according to the invention are any of ~he anionic sur-factan~s which are suitable for use on ~he ~uman body.
They are characterized by a water-solubilizing anionic group, fol example a carboxylate, sulfate, sulfonate or phosphate group, and a lipophilic alkyl qroup containing approximately 10 to Z2 carbon atoms. Glycol or polygly-col ether groups, ester, ether and ami~e groups and al~o hydroxyl groups may also be present in the molecule.
The following are examples o~ suitable anionic surfac-tants in the form of the sodium, potassium and ammoniu~
salts and also the mono-, di- and trialkanolam~oniu~
salts containing 2 or 3 carbon atoms in the alkanol group: -- linear fatty acids con~aining 10 to 22 car~on atoms (soaps), - ether carboxylic acids correspondin~ to the formula R-0-(CH2-CH~0)~-CH2-COOH, in which R ~s a linear alkyl group conta}ning 10 to 22 carbon - atoms and x = 0 or 1 ~o 16, - acyl sarcosides containing 10 to 18 carbon atoms - - . 30 . in the acyl g~oup,-- acyl ~aurides containing 10 to 18 car~on atoms in the acyl group, - acyl isethionates containing 10 to 18 carbon atoms in the acyl group, - sulfosuccinic acid mono- and dialkyl esters con-213!~496 H 299 PC~ 8 taining 8 ~o 18 carbon atoms in the alkyl group and sulfosuccinic acid monoalkyl polyoxyet~yl esters containing 8 to 18 carbon ato~s in t~e alkyl group and ~ to 6 oxyet~yl g~oups, - linear alkane sulfonates containing 12 to 18 carbon atoms, - linear alp~a-olefin sulfona~es contain~ng 12 to 18 c~rbon atoms, - alpha-sulfofatty acid methyl esters of fatty acids containing 12 to 18 carbon atoms, - al~yl sulfates and alkyl polyglycol et~er su}-fates corresponding to the for~ula R-O(CH2-C~20)~-OSO3H, in which R is a preferably line~r alkyl group containing 10 to 18 carbon ato~s and x = O
1~ or 1 to 12, - mixtures of surface-active hydroxysulfonates according to DE-A-37 25 030, - sulfated hydroxyalkyl polyethylene and~or hy-droxyalkyl propylene glycol ethers according to DE^~-37 23 354, - sulfonates of unsaturated.fatty acids containing 12 to z4 carbon atoms an~ 1 to 6 dou~le bonds according to DE-A-39 26 34~, - esters of ~artaric acid and citric acid with alcohols which are adducts of approximately 2 to 15 molecules ethylene oxide and/or propylene oxide wit~ fa~ty alcohols containing 8 to 22 carbon atoms.
Preferred anionic su~factants are alkyl sulfates, 30 alkil polyglycol et~er sulfates and ethe~ carboxylic acids containing 10 to 18 carbon atoms in the alkyl group and up to 12 ~lycol et~er groups in the molecule and also sulfosuccinic acid mono- and dia}kyl esters containing 8 to 18 car~on ato~s in the a~kyl group and sulfosuccinic acid ~onoalkyl polyoxye~hyl esters con-taining 8 to 18 carbon atoms in the alkyl group and ~ ~o6 oxyethyl groups.
~ wi~terionic surfac~ants are sur~ace-active co~pounds which contain at least one qua~ernary ammonium group and at leas~ one -CoOt~ or -503~ ) group in the molecule. Particularly suitable zwitterionic surfac-tants are ~he so-called betaines, such as t~e N-alky}-N,~-dimethyl ammonium glycinates, for example cocoal~yl dimethyl ammonium glycinate, N-acy}aminopropyl-N,N-dimethyl ammonium glycinates, for example cocoacylaminopropyl dimethyl ammoniu~ glycinate, and 2-~lkyl-3-carboxymethyl-3-hydroxyethyl imidazol~nes containing 8 to 18 carbon ato~s in the alkyl or acyl gro~p and coco-acyl aminoethyl hydroxyethyl carboxymethyl glycinate.
15 A preferred zwitterionic surfactant is the f atty acid amide derivative known by ~e CTFA name of Cocamidopro-py 1 Bet a i ne .
Ampholytic surf actants are surface-active com-~ pounds whic~, in addition to a C~ 1B alkyl or acyl group20 in the ~olecule, contain at leas~ one free amino group and at leas~ one -COOH or -SO3H group and ~hich are capable of forming inner salts. Examples of suitable ampholytic surfactants are ~-alkyl glycines, N-alkyl propionic acids, N-alkyl aminobu~y~ic acids, ~-alkyl iminodipropionic acids, N-hydroxyethyl-N-alkyl amidopro-pyl glyc ines, N-alkyl taurines, N-alkyl ~;arcosines, 2-alkyl aminopropionic acids and alkyl amlnoace~ic acids all containing approximately 8 to 18 carbon atoms in the alkyl group. Par~icularly preferred ampholytic surfac-tants are ~-cocoalkyl amin~propionat~, cocoacyl amino-e~hyl aminopropionate and Clz,~ acyl sarcosine.
~ onionic surfactants contain, for example, a polyol group, a polyalkylene glyc~l e~her group or a combination of polyol and polyglycol ether groups as t~e hydrophilic group. Examples of compounds such a~ ~hese ~39~96 are - adducts of 2 ~o 30 mol ethylene oxide and/or 0 to 5 ~ol propylene oxide with linear ~atty alcohols s containing 8 to 22 carbon ato~s, ~th fatty acids - containing 12 to 22 carbon atoms and with alkyl-p~enols containing 8 to 15 carbon atoms in the alkyl group, - Cl~22 fatty acid monoesters and dieste~s of adducts of 1 to 30 mol ethylene oxide ~ith glycerol, - C~22 alkyl mono- and oligoglycosides and et~oxy-lated analogs t~ereof and - adducts of S to 60 mol ethylene oxide with castor oil and hydrogena~e~ castor oil.

The compounds containing alkyl groups used as surfactants may be individua~ substances. Hovever, it is generally preferred to produce the compounds in question from native vegetable or animal ra~ ma~erials so ~hat mixtures of compounds differing in their chain lengt~ according to the particular raw material used are obtained.
~he surfac~ants ~hich are adducts of ethyle~e and~or propylene oxide ~ith fatty alcohols or deriva-tives of such adducts may be bo~h products having a "nor~al-~ange~ ~omolog distribution and also pro~ucts - ~aving a "narrow-range" ~omolog d~str~bution. "Ncrmal-range" products are mix~ures of homologs which are 30 obtained in the reaction of fatty alcohol and alkylene oxide using alkali metals, alkali metal hydroxides or alkali metal alco~olates as catalysts. By contrast, narrow-range products are ob~ained ~hen, for example, hydrotalcites, alXaline earth metal sal~s of ether carboxylic acids, alkaline ear~h metal oxides, hydrox-2139~96 ides or alcoholates are used as catalysts. I~ may b~e preferable to use narrow-range products.
The quantity of surfac~ants w~ich may be present in the preparations according to the invention is dependent upon the par~icular type of surfactant and the purpose for which t~e preparation i~ intended.
Hair aftertreatmen~ preparations preferably con-~ain cationic and/or nonionic surfactants, more particu-larly in quantities of 0.1 to 10% by weight, based on the preparation as ~ whole. Quantities of 0.1 to 3~ by weight are particularly preferred, Hair tonics also preferably contain cationic and~or nonionic surfactants, more particularly in quan-tities of 0.1 ~o 10% ~y weight, based on the preparat~on as a whol~. Quantities of 0.1 to 5% by weight are partic~larly preferred.
Shampoos preferably contain anionic surfactants, if desired in combination with ampholytic and/or non-ionic surfactants, more particularly in quantities of 1 to 50~ by weight, based on t~e preparation as a ~hole.
Quantities of 3 to 20% by weight are particularly preferre~.
The preparations according to the invention pref-erably ~ave pH values of 2.5 to 7 and, more particular-ly, in the range from 3 tD 6 .
Sh ampoos, ha ir aftertreatment preparations ana - hair tonics are preferred preparations according to the invention. Nevert~eless, the preparations may also be permanent waYe preparations, dyes, b~ow-wave prepara-tions and other typical hair treatment preparations.
The preparations may be formulated as aqueous oraqueous/alcoholic solutions! creams, lotions, yels, emu~sions and other typical cosmetic preparation~.
T~e preparations may contain any other known ~5 constituents according to the type of hair treatment ~ 1 3 9 Li 9 6 H 2g9 PCT 12 pr~paration and the particular formulation.
The constituents in question are:

- nonion~c polymers such as, for example, vinyl pyrrolidone/vinyl acrylate copolymers, polyvinyl pyrrolidone and vinyl pyrrolidone/vinyl acetate copolymers and polysiloxanes, - anionic polymers such as, for example, polyacry-lic acids, crosclinked polyacrylic acids, viny}
acetate~crotonic acid copoly~ers, vinyl pyr~oli-d~ne,~vinyl acrylate copolymers, ~inyl acetate/
butyl maleate/isobornyl acrylate copolymers, methyl vinyl e~her/maleic anhydride copolymers, acrylic acid/ethyl acrylate~N-tert butyl acryl-amide terpolymers, - other cationic polymers such a~, for example, quaterni2ed cellulose ethers, polysiloxanes containing quate~nary groups, a~ylamide/dimet~yl diallyl a~monium chloride copolyme~s and dimethyl aminomethacrylate/vinyl pyrrolidon~ copolymers quaternized with diethyl sulfate, - t~ickeners, such as agar agar, guar gum, algin-ates and xantham gum, - structurants, suc~ as glucose and maleic acid, - hai~-conditioning compounds, such as phospho-lipids, for example soya lecithin, egg lecithin, cephalins, and also sili~one oils - - protein hydrolyzates, more particularly elastin, collagen, keratin, miik p~otein, soya protein and wheat protein hydrolyza~es, condensa~ion products thereof with ~atty acids and quaternized protein hydrolyzates, - perfume oils, dimethyl isosorbide and cyclodex-t~ins, - solubilizers, such as e~hanol, isopropanol, ~139~96 H 299 P~T 13 ethylene glycol, propylene glycol, glycerol and diethylene glycol, - dyes, - antidandruff agents, such as Piroctone Olamine and Zinc Omadine, - - other subs~ances for pH adjus~ment, - active substances, suc~ as pant~enol, allantoin, pyrrolidone carboxylic acids and their salts, plant extracts ~nd vitamir,s, - light stabilizers, - consistency regulators, such a~ sugar esters, polyol esters or polyol alkyl ethers, - fats and waxes, such as spermaceti, beeswax, mon~an ~ax, paraffins and fatty alcohols, - fat~y acid alkanolamides, - complexing agents, such as EDrA, ~TA and phos-phonic acids, - swelling and penetra~ion agents, suc~ as ~lycer-ol, propylene glycol monoethyl ether, carbonates, hydrogen carbonates, guanidines, ureas and primary, secondary and tertiary phosphates, - opacifiers, such as latex, - pearlescers, such as ethylene glycol monostearate and distearate, - propellents, suc~ as propaneJ~utane m~xtures, NzO, dimethyl ether, Co2 and air and - antioxidants, - substantive dyes, - .
- so-called coupler and deve~oper .componen~s as . oxidation dye precursors, - reducing agen~c such as, for example, ~hioglycol-ic acid and derivatives thereof, thiolactic acid, cysteamine, thiomal ic acid and ~-mercaptoethan~-sulfonic acid, - oxidizing agents, such as hydrogen peroxide, !

po~assium bromate and sodium bromate.

The presene in~ention als~ relates to a process ~or treating hair using a preparation according to the invention.
In a preferred embod~ment of t~e process accord-ing to ~he inven~ion, prepara~ions containing the combination o~ ac~ive ingredients according to the invention are applied to the hair and, ate~ a cQrta~n contact time, generally between a few seconds and about 20 ~inutes, are rinsed off from the hair either ~ith water or with a preparation large~y containing water.
The follo~ing Examples are intended to illustrate the inven~ion.
E x ~ m P 1 e ~

~. Determinati~n of vct and dry ~o~ability Test methods The combability tes~s were carried out by t~e method according to J. soc~ Cosm. Chem. 19~3 t2~] 782.
Combing work was studied on bro~n ~air (Alkinco #6634, tress lengt~ 12 cm, tress weight 1 g). The hair used was }ightly preda~aged (cold-waved or ~leached~
hair which the average consumer would be expec~ed have.
After the zero measurement, the tresses were soaked with loo ~l-of the formulati~n to be tested. After a con~act time ~f S minutes, the tresses were rinsed out for 1 minu~e in running wa~er (1 l/min., 38 C). To determine wet combing wor~, the ~resses ~ere then remeasured. To determine dry comblng work, the tresses were first dried for 12 hours at 30 c~2~% relative air humidity and then remeasured.

~139~96 Resul~s The composition of the mixtures tested ~nd the results of the com~ing work measurements are set out in Table 1. The combing work values are each based on the value of t~e zero measurement. T~ey ~ad a statistical certa inty of 9g . 99 % .

T~blo 1 ~quantit~es in parts by v~ig~t}

Component / mixture Cl C2 C3 I1 C4 C5 Steno~16181 3 0 3.0 3.03.0 3.0 3.0 CutinaG~S2 0.5 0.5 0.50.5 0.5 0.5 Eumulgin~B 1~ 0.4 0.4 0.40.4 0.4 0.4 Eumulgin-B 2 0.8 0.8 0.80.8 0.8 0.8 Eutanol~Gs l.o 1.0 1.01.0 l.o 1.0 Acrylamidopropyl trimethyl anumonium chloride~acryl lC
acid copolymer, neutral-ized with sodium hydroxide (poly~er Pl acc. to DE 39 29 973) - 0.2 - 0.2 - 0.2 LuviquatFC 5506 - - 4.04.0 Gafquat755-~7 ~ 8.0 8.0 Water <-------- ad 100 ---------->
Wet combing wo~k [~]
- cold-~aved hair - 85 47 76 69 7~ 70 Dry combing wor~ [~]
- cold-waved hair - ~52 85 210266 152 165 wet combinq work [%]
- bleached hair - 8~ 70 Dry combing ~ork ~%) - bleached hair - 95 . 236 1 C~6/C~8 fatty alcohol (HENKEL) 2 Glycerol ~onostearate (CTFA name: Glyceryl Steara~e) (HEN~EL) 3 Cetostearyl alcohol containing approx. 12 mol EO
(CT~A name: Ceteareth-12) (HENKEL) ~ 139~96 Cetostearyl alco~ol con~aining 2pprox. 20 ~ol EO
(CTFA nam~: Ceteareth-20) (HE~KE~) 5 Condensati~n product of saturated liquid f~tty alcohols, primarily decyl alcohol, prepared ~y thc Guer~et reaction (CT~A name: Octyldodecanol) (HENKFL) 6 Vinyl imidazolinium methochloride~vinyl pyrroli-done copolymer ~50:50) (sverage ~olecular weight:
approx. 80,000 D~lton: 40% active substance: CTFA
name: Polyquaterniu~-16~ (BASF) Vinyl pyrrolidone/dimet~ylaminoethyl methacrylate copolymer quaternized with diethyl sulfate (19%
active substance in water) (GAF) The results show that application of the mixture~
according to the invention leads to ~he required i~-provement in wet combing work (the target range is at a value of around ?0 or lower) accompanied by an increase in dry combing work to the optimal value for style retention of approxi~a~ely 230 to z70.

lI. Application Examples The quantities in the following Examples ~re %
by weight.
) ~air ri~se Stenol01618 1.8 TegoamidS 18~ 1.6 1,2-Propylene glycol 1.0 ~0 . C~tric acid - 0.6 LuviquatFC 550 1 0 Polymer Pl acc. to DE 39 29 973 0.2 Perfume oil, wa'cer ad 100 ~ ~,N-dimethyl-N'-stearoyl-1,3-diaminopropane (CTFA

~13949~
H 299 PC~ 17 name: Stearamidopropyl Dimet~ylamine)(GOLDSCHMIDT) 2) ~air rlnse S~enol1618 1.8 StepantexVS 909 1 . 8 1,2-Propylene glycol 0.7 Ci~ric acid 0.2 LuYiquat-HM 5526' 2.5 Polymer Pl acc. to DE 39 29 973 0.4 Perfume oil, dye, water ad 100 9 N-methyl-~-(2-hydroxyethyl)-N,N-d~-(tallowacyloxy-ethyl~-ammonium methosulfate ~90% active su~stance in isopropanol) (STEPA~) ~ Vinyl imida201inium methochlo~ide/vinyl pyrroli-done copolymer (50:50) (average molecular vei~ht:
approx. 800,~00 Dalton; Z0% active substance; CTFA
name: Polyquaternium 16) (BASF) 3) Hair rinse Stenol~1618 2.5 Eumulgin~B 1 1.0 EumulginB 2 1.0 C~tinaCPl~ ~ 0 Eutano~G 0.5 Pola~ax~GP 200~1 0.~5 AbilQuat 3270l2 0.5 Dow Corning929-Emulsion~3 . 2.6 LuviquatFC 370~ 0.8 Amp~ome~ i5 0 . 8 `
Citric acid 0.02 Water ad 100 10 Ester of saturated long-chain fatty alcoh~ls and 35fat~y acids, primarily palmitic acid ce~yl ester ~139~9~

(CTFA name: Ce~yl Palmltate)-(ff~NKE~) Stearyl alco~ol~polyethylene glycol stearate mix-ture (CTFA name: Stearyl ~lcohol (and) PEG
S~earate) (CRODA) lZ Diquaternary polymethyl siloxane (CTFA name: Qua-ternium 80) (GOLDSCHMIDr) Aminofunctional polydimethyl siloxane (35% active su~stance) ~DOW COMING~
~ Vinyl imidazolinium methochlor~de~vinyl pyrroli-done copolymer (30:~0) (40% active substance, CTFA
name: Polyquaternium-16~ (BASF) Methyl methacrylate/tert.butyl aminoethyl met~-ac~ylate~2-hydroxypropyl methacrylate/~-(1,1,3,3-tetramethyl butyl)-acrylamide copolymer (D~LFT
NATIONAL) ~) Hair rinse Rewoquat-W 75001~ 1.1 Lane~te00l7 3,0 EumulginB } 0.8 EumulginB 2 1.6 CutinaGMS 0.5 EutanolG 1.0 LuviquatHM 552 1.2 Polymer Pl acc. to DE 39 29 973 0.4 Water ad 100 16 1-Met~yl-2-nortallowalkyl-3-tallow fatty acid amidoethyl imidazolinium methosulfate (approx. 75 active substance) tREWO)- -17 Mixture of higher saturate~ fatty alcohols, pri-marily cetyl and ~tearyl alcohol (C~FA name:
Cetearyl Alcohol (HENKEL) ~13949~

5) ~ampoo Texapon~ ~5'g 43 Dehyton~Kl~ 10. 0 Plantaren~-1200Z 4.0 Euperlan6P~ 300021 1.6 Arquad-3l622 LuviquatFC ~50 1.2 Polymer Pl acc. to ~E 39 29 g73 0.2 GlucamateDOE 12023 0.5 Sodium chloride 0.2 water ad 100 Sodium lauryl ether sulfate (app~ox. 28~ active subs~ance; C~A name: Sodium Lauret~ Sulfate) (HENKEL) atty acid amide deriYati~e, betaine structure, corresponding to t~e formula R-CONH(C~2~ 3~ (C~) 2-CH2COO (approx. 30% active substance; CTFA name:
Cocoamidopropyl Betaine~ ~HEN~EL) 20C12-C16 alkyl glucoside, degree of oligo~erization 1.4 (approx. 50~ active substance; CT~A name:
Lauryl Polyglycoside~ ~HE~KE~) 21 Liquid dispersion of pearlescing su~stances and amphosurfactant (approx. 62~ active substa~ce;
CTFA name: Glycol Distearate (and) Glycerin (and) La~reth-4 (and) Cocoamidopropyl Betaine) (HENKEL) 22 Tri-C16-alkyl methyl ammonium chloride ~AKZO) 23 Ethoxylated ~et~yl glucoside dioleate (CTFA-name:
PEG-120 Methyl Glucose Dioleate) (AMERCHOL]-6~ Shampoo Texapon~N 702' .21. 0 Plantaren-1200 8 . 0 C;enamin~DsAc25 1. 2 Cutina~EGMS2D 0 . 6 t ~139~96 - ~ 2g9 PCT 20 Luviqua~FC 370 2.0 PolyTner Pl acc. ~o DE 39 29 973 0. 3 Anti l~ 141 l iquid27 1. 3 Sodium chloride 0 . 2 Water ad 100 2- Sodium lauryl ether sulfate tapprox. ~2% active su~stance) (HE~KEL) 25 Dimethyl distearyl ammonium chloride (HOECHST) o 25 Ethylene glycol monostearate (approx. 25-35% ~ono-ester, 60-70% diester; CTFA name: Glycol Stearate) tH~:NKEL) ~' Polyoxyethy~ene p~opylene glycol dioleate (40 active substance; CTFA Name: Propylene Glycol (and) PEG-55 Propylene ~lycol Oleate) (GOL~SCHM}DT) 7) Sha~po Texapon~ 14 S2~ 50.0 ~e~yton~K 10.0 AkypoRLH 100 NV29 4.5 Cutin~AGS30 2.0 D-Pan~henol 0.5 Glucose 1.0 Salicylic acid 0.4 Sodium chloride 0.5 Polymer Pl acc. to DE 3g 29 973 0.6 Luviquat~ 552 . 1.0 Water ad 100 .
2~ Sodium lauryl myristyl ether sulfate (approx. 23 active substance; CTFA name: Sodium Myreth Sul-f ate ) ( HENKEL) C12-14 fatty alcoholtl0 ethylene oxide ac~tic acid 3~ sodium sal~c (22% active substance; CTFA name:

~1394~S

Sodium Laureth-ll Car~oxylate) (CHEM-Y) 30 Ethylene glycol stearate (approx. 5-15~ monoes~er, 85-g5~ diester; CTFA name: Glycol Disteara~e) (HENKEL) 8) 8~ampoo ~exapon~ S 25.0 Texapon~sB 321 7.5 Eucarol~TA~2 12.0 Akypo8RLM 100 N~ 9.O
Dehyton~AB 3033 8 . 3 Elfacos~GT Z82S3~ 0.5 Sodium chloride 0.5 Polymer Pl acc. to DE 39 Z9 973 0.6 LuviquatFC 550 4.0 water ad 100 31 Sulfosuccinic acid semiester ~ased on an alkyl polyglycol et~er, di-Na salt (approx. 40% active substance; CTFA name: Disodiu3 Lauret~ Sul~osuc-cinate~ (~ENXEL) 32 Lauryl alcohol+7 ethylene oxide tartrate sodium salt ~approx. 25% ac~ive su~ctance: CTFA na~e:
Sodium Laureth-~ Tar~rate) (AUSICHE~) 3- Fatty amine deriYative, betaine s~ructure (approx.
30% active substance; cT~A name: Coco-Betaine) ( HEI~KEL) - Tallow alcohol+60 ethylene oxide myristyl ether (CT~A name: Tallowet~-60 Myr-styl Glycol) (AKZ0) 9~ ~onic pack ~remoYable by rin~i~g) Stenol1~18 3.0 Eumulgin~ 1 0-5 Eumu~gin~B 2 0 5 Cutina~CP 1.0 2~9496 Eutanol~G 1.5 Car~opol o~o3~ 0-004 Do~ CorningD929 Emulsion 2.9 ~olymer Pl acc. to DE 39 29 973 0.3 Luviquat-FC 550 4.0 ~riethanolamine . 0.09 Water ad 100 Polyacrylic acid (GOODRICH) 10) ~onic pack ~re~a~ning on the ~r) CelquatL 200~6 0.6 L~Yiskol~K303' Z
D-Panthenol 5 ~ehyquart~SP3~ 1.0 NutrilanI39 1.0 Na~rosol~250 HR'C 1.1 LuYiquat~FC 370 0.7 Polymer Pl acc. to D~ 39 29 973 0.5 Water ad 100 ~6 ~uaternized cellulose derivative (g5% active ~ub-stance: CTFA name: Polyqua~ernium-4) (DELFT
NATIGNAL)5 ~ Polyvinyl pyrrolidone (95~ active substance; CTFA
name: P~P~ (BASF) 3g Aqueous solution of oxyethyl al~ylammonium phosphate (approx. 50% ac~ve su~stance; C~FA
name: Quaternium-52) (HENKEL~
~9 Collagen hydrolyzate (approx. 39~ ~ctive subs-~ance; CT~A name: ~ydrolyzed Collagen) (~ENKEL~
Hydroxyet~yl cellulose (AQU~L~) 11) Dyeing cr~am Cl2l~ Fatty alco~ol 1.2 ~139496 Lanette 0 4.0 Eumul~in~B 2 0.8 Cutina~ K~ 16~ 2.0 Sodium sulfite 0.5 L(+) Ascor~ic acid 0.5 Ammonium sulfate 0.5 1,2-Propylene glycol 1.2 Poly~er JR 4 oo'2 o . 3 p-Aminophenol o. 3s p-Tolylene diamine 0.85 2-Methyl resorcinol . 0.14 6-Methyl-m-aminophenol 0.42 Polymer P1 acc. to DE 39 29 973 0.7 Luvi~ua~DFC 550 4.0 Ammonia 1.5 Water ad 100 '1 Fatty acid monoJdiglyceride emulsifier mixture (CTFA name: Tallow Glycerides (and) Glyceryl Stearate (and) Potassium Stearate) (HENKEL) 2 Quaternized hydroxyethyl cellulose (U~ION CARBIDE) 12 ~ DeVeloper disper~ion for dyeing cream 11) Texapon~N 25 2.1 Hydrogen peroxide (50%) 12.0 Turpinal~SL'3 1.7 Latekoll~D" 12.0 Polymer Pl acc. to DE 39 29 973 0.1 L~viquat~FC 550 0 9 ~ater ad 100 3 l-Hydroxye~hane-l,l-diphosphonic acid (60~ active substance; CTFA n~me: Etidronic Acid) (HENKEL) '~ Acrylate~methacrylic acid copolymer (25~ active 3~ substance) (BASF) ~139496 H 29g PCT 2~

The dyeing cream had a p~ value of 10 . û . It gave t2~ ha ~ r a strong red t int .

13) $~nting shampoo Texapon~N 70 14 . 0 Dehyton~K 10 . 0 A~ypoR~M 45 ~Y 5 1~.7 Plantaren--1200 q, o Cremophor~RH 40~6 0 . 8 Dye C . I . 1~ 719 0 . 02 Dye C. I . 1 2 251 0 . 02 Dye C. I . 12 250 0. û~
Dye C. 1. 56 05g o. 03 PHB ester 0 . 25 Luviquat~FC 370 1. 6 Polymer Pl acc . to DE 39 29 . 973` 0 . 2 Perfume oil q. s.
water ad 100 20 5 ~au~yl alcohol+4 . 5 ethylene oxide acetic acid sodium salt (20.4% active substance) (C~EH-Y) 6 Castor oil, hydrogenated 1 45 e~hylene oxide (CTFA
na~Te: PEG-40 Hydrogenated Castor Oil) (BASF) When the }~air was washed ~ith this tinting shampoo, it was left bright 1 ight blond in cclor .

4) Permanent wa~e cream wave cream Plantaren-800" 5.0 Thioglycolic acid 8.0 Turpinal~SL 0-5 Am~onia (25%~ 7.3 Ammonium carbonate 3.0 Cetostearyl alcohol 5.

2139~96 Guerbe~ a~cohol 4.0 Luviquat~HM 552 1.5 Polymer Pl acc. to DE 39 29 973 0.1 Perfume oil q.S
Water ad 100 " C~-C10 alkyl glucoside, degree of oligomerization 1.6 ~appr~x. 60% active subs~ance) (HENKEL) Fixing solution Plan~aren-800 5.0 Hydrogenated castor oil 2.0 Potassium bromate 3.5 Nitrilotriacetic acid 0.3 Citric acid 0.2 Polymer Pl acc. to DE 39 2g 973 0.2 Luviqua~6FC 550 1.0 Perfume oil q.s Water ad 100

Claims

New Claims

1. A water-based hair treatment preparation containing a combination of cationic and amphoteric or zwitterionic polymers in addition to typical cosmeticconstituents, characterized in that the cationic polymers contain imidazolinium groups and the zwitterionic polymers consist essentially of (.alpha.) monomers containing quaternary ammonium groups corresponding to general formula (1):

R1-CH-CR3-CO-Z-(CnH2n)-N(+)R3R4R5 A(-) (I) in which R1 and R2 independently of one another represent hydrogen or a methyl group and R3, R4 and R5 independently of one another represent C1-4 alkyl groups, Z is an NH group or an oxygen atom, n is an integer of 2 to 5 and A(-) is the anion of an organic or inorganic acid and (.beta.) monomeric carboxylic acids corresponding to general formula (II):

R6-CH = CR7-COOH (II) in which R5 and R7 independently of one another are hydrogen or methyl groups, or alkali metal, alkaline earth metal, aluminium or ammonium salts of these acids.

2. A preparation as claimed in claim 1, characterized in that the cationic polymer contains at least one nonionic monomer.

3. A preparation as claimed in claim 2, characterized in that the nonionic monomer is vinyl pyrrolidone.

4. A preparation as claimed in any of claims 1 to 3, characterized in that it contains a zwitterionic polymer.

5. A preparation as claimed in claim 4, characterized in that the monomer (.alpha.) is acrylamidopropyl trimethyl ammonium chloride while the monomer (.beta.) is acrylic acid or an alkali metal salt, more particularly the sodium salt, or acrylic acid.

6. A preparation as claimed in claim 4 or 5, characterized in that the number of monomers (.alpha.) in the zwitterionic polymer is greater than the number of monomers (.beta.).

7. A preparation as claimed in any of claims 1 to 6, characterized in that it contains 0.01 to 10% by weight and more particularly 0.01 to 5% by weight of amphoteric or zwitterionic polymers and 0.01 to 10% by weight and more particularly 0.01 to 5% by weight of cationic polymers, based on the preparation as a whole.

8. A preparation as claimed in any of claims 1 to 7, characterized in that it also contains a surfactant.

9. A preparation as claimed in claim 8, characterized in that the surfactant is a cationic or nonionic surfactant.

10. A preparation as claimed in any of claims 1 to 9, characterized in that the preparation has a pH value of 2.5 to 7 and, more particularly, in the range from3.0 to 6.0

11. A process for treating hair, characterized in that a preparation as claimed in any of claims 1 to 10 is applied to the hair.

12. A process as claimed in claim 11, characterized in that the hair is subsequently rinsed with water or with a preparation largely containing water.