CA2115344A1 - Attracting and ingestion-stimulating agent for cockroach - Google Patents

Attracting and ingestion-stimulating agent for cockroach

Info

Publication number
CA2115344A1
CA2115344A1 CA002115344A CA2115344A CA2115344A1 CA 2115344 A1 CA2115344 A1 CA 2115344A1 CA 002115344 A CA002115344 A CA 002115344A CA 2115344 A CA2115344 A CA 2115344A CA 2115344 A1 CA2115344 A1 CA 2115344A1
Authority
CA
Canada
Prior art keywords
cockroach
ingestion
attracting
parts
tetrahydro
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002115344A
Other languages
French (fr)
Inventor
Kazumasa Ogino
Haruo Shimamura
Kazuyuki Tomisawa
Fumio Urushizaki
Masami Nemoto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Taisho Pharmaceutical Co Ltd
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2115344A1 publication Critical patent/CA2115344A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02—Amines; Quaternary ammonium compounds
    • A01N33/04—Nitrogen directly attached to aliphatic or cycloaliphatic carbon atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/002—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits
    • A01N25/006—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits insecticidal
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02—Amines; Quaternary ammonium compounds
    • A01N33/06—Nitrogen directly attached to an aromatic ring system

Abstract

There are provided attracting and ingestion-stimulating agents for cockroach comprising as the active ingredient: (a) one or more compounds selected from the group of 1-amino-5,6,7,8-tetrahydronaphthalene, 2-amino-5,6,7,8-tetrahydronaphthalene, 2-aminomethyl-5,6,7,8-tetrahydronaphthalene and a salt thereof; and (b) one or more compounds selected from the group of p-n-butylphenol, p-n-amylphenol, 5,6,7,8-tetrahydro-1-naphthol and 5,6,7,8-tetrahydro-2-naphthol. The attracting and ingestion-stimulating agents for cockroach exhibit the very potent attracting and ingestion-stimulating activities in the known species of house cockroach, both male and female.

Description

DESCRIPT~ON
Attracting and ingestion-stimulating agent for cockroach TECHNICAL FIELD
The presen~ invention relates to attracting and ingestion-stimulating agents for coc~roaches.

BACKGROUN~ ART
Cockroach is one of the sanitarily harmful insects most widely known throughout th,e world.
In Japan, as the ~ouse cockroach are known Periplaneta fuliginosa S., P.jsponica K., P.americana L., Blattells germanic L., etc.
In general, it is important for extermination of cockroach to possess both an attracting activity and an ingestion-stimulating acti~ity.
, We have already provided several cockroa~h attracting and inges~ion-stimulating ~gents which stimulataneously possess the activities both (USP 4,627,981; USP 4,911,907).
Te~ralol, naphthol and phenol compounds and 3,7-dimethyl-10-isopropyl-2,6-cyclodecadien-1-ol, which are active ingredients of these cockroach attracting and inges~ion-stimulating agents, are suiciently active without any additives. Howe~er, they ~re oten actiYe against male P.americana L. only, and thus when applie~ to colonies of other species of cockroach or WO ~3/02554 2 ~ ~ 3 ~ PCI~/JP92/00795 -- 2 ~-- .

colonies of female cockroach only, they sometim~s produce lower effects.

DISCLOSURE OF INVENTION
In order ~o provide more effectively attracting and ingestion-stim~lating agen~s for cockro~ch than the prior art agents, we have investigated a composition comprising;
(a)one or more compounds selected from ~he group of l-amino-5,6,7,8-te~rahydronaphthalene, 2-amino-5,6,7,8-tetrahydronaphthalene, 2-aminomethyl-5,6,7,8-~etrahydro-naphthalene and a salt thereof ; and (b)one or more compounds selected from the group of p-n-butylphenol, p-n-amylphenol, 5,6,7,8-tetrahydro-1-naphtyhol and 5,6,7,8-tetrahydro-2-naphthol show a hight attrac~an~ and ingestion-stimulating activity for cockroach.
A more preferred agent for cockroach of the invention is concerned with a attracting and ingestion-s~imulating agent for cockroach comprising as active ingredien~s a co~pound selected from the group consis~ing of 1-amino-5,6,7,8-tetrahydronaphthalene, 2-amino-5,6,7,8-tetrahydronsphthalene, 2-aminomethyl-5,6,7,8-~etrahydronaphth~lene a~d a salt ~hereof, and a compound selected from the group consisting of p-n-~mylphenol, p-n-butylphenol, 5,6,7,8-tetrshydro-1-nap~thol and 5,6,7,8-tetrahydro-2-n~phthol.

w093/û25s4 2 1 1 ~ 3 ~ ~ PCT/JP92/007g5 _ 3 _ ~..t, . ~ . .
All of the com~ound are known compounds.
l-Amino-5,6,7,8-tetrahydronaphthalene, 2-amino-5,6,7,8-tetrahydronaphthalene and 2-aminomethyl-5,6,7,8-tetrahydro-naphthalene are disclosed, for example, in the litera~ure cited below.
V.S. Misara et al., J.Indian Chem. Soc., 1985, 36, 803 S.W. Fenton et al., J.Am.Chem. Soc., 1955, 77, 979 V.Grinsteins et al., Lav.RSR Zinat.Akad.Ve~tis,Kim.~er., lg67, 7, 12 As the salt of the compo~nds, there can be mentioned, for example, hydrochloric acid salt, oxalic acid salt, citric acid salt, acetic acid salt, phosphoric acid salt, malonic acid salt, sulfric acid salt~ tartaric acid salt, maleic acid salt, lactic acid salt and pyrophosphoric acid salt.
2-Aminomethyl-5,6,7,8-tetrahydronaphthalene is allow to stand in air to give a salt.
The salt comp~und has a chemical structure as shown ~elo~;

C H2 NH 3~) ~ C H 2 N H C 0 Howe~er, none of l-~mino-5,6,7,8-tetr~hydronaphthslene 2-amino-5,6,7,8-tetrahydronaphthalene ~nd 2-aminomethyl-21153'1~

5,6,7,8-tetrahydronaphthalene are known for their cockroach attracting and ingestion-stimulating activities. p-n-Amyl-phenol, p-n-butylphenol, 5,6,7,8-t~trahydro-1-naphthol and 5,6,7,8-tetrahydro-2-naphthol are known for their cockroach attracting and ingestion-stimul~ting activities as describ~d in USP 4,911,907 and USP 4,627,981.
Attracting and ingestion-stimulating agents for cockroach according to the invention can be prepared, for example, by dissolving these compounds in an appropriate solvent ~for example, a hydrophilic organic solvent such as acetone, methanol, ethanol, tetrahydrofuran, ethylene glycol, diethylene glycol or N,N-dimethyl- formamide or lipophilic organic solvent such as benzene, chloroform, ether, methylene chloride or n-hexane) then impergnating ~n appropriate carrier (or pap~r, cardboad, non-woven cloth, or flannel) with the `~
solution and drying off the solvent to give ~ttracting tapes or the like. The acti~e-ingredient compounds according to the invention can also be used in such a ~orm as granule, pill or tablet prepared by a conventional method using binder, excipient, lubricant, st~bilizer and others as usually ;
employed to give a bait.
The bait form o the active-ingredient compounds according to the invention can be formulated together with an insecticidal ingredient As the typical examples of the SUB~;TITUTE SHEiE~T

211~344 insecticidal ingredient, there can be mentioned, organophosphorous insecticides such as 0,0-dimethyl 0-4-nitro-m-toIyl phosphorothioate, 0,0-diethyl 0-(2,3-dihydro-3-oxo-2-phenylpyridazin-6-yl)phosphorothioate, 0-3,5,6-trichloro-2-pyridyl 0,0-dimethyl phosphorothioate, pyrethroids such as ~RS)-3-allyl-2-methyl-4-oxocyclopent-2-enyl(lRS)cis,trans-2,2-dimethyl-3-~2-me~hylprop-l-enyl)cyclopropanecarboxylate, (S)-a-cyano-3-phenoxy-benzyl(lR,3R)-3-~2,2-dibromovinyl)-2,2-dimethylcyclopropane-carboxylate, 3-phenoxybenzyl(lRs)cis~trans-2~2-dimethyl-3-(2 methylprop-l-enyl)cycloprop~necarboxylate, 5-benzyl-3-furylmethyl-(lRS)cis,trans-2,2-dimethyl 3-~2-methyprop-1-enyl)cyclopropane- :
carboxylate, a -cyano-3-phenoxybenzyl(lRS,3SR)-(lRS,3RS)-2,~- :
dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylate, 3-phenoxybenzyl(lRS)cis,trans-3-(2,2-dichlorovinyl)-2,2-dimethyl-cyclopropanecarboxylate, 2-~4-ethoxyphenyl)-2-methylpropyl ~-phenoxybenzyl ether, (RS)-~-cyano-3-phenoxybenzyl(RS)- a - ;:
isopropyl-4-chlorophenylacetate, (RS)-2-methyl-4-oxo-3-prop-2-ynylcyclopent-2-enyl(IRS,3SR)-(lRS,3SR)-2,2-dimethyl-3-(2-methylpro-I-enyl)cyclopropanecarboxylate, carbamates such as l-naphtyl methylcarbamate, 2-isopropoxyphenyl methylcarb~mate, dodec~dienote oxime-ether benzoylphenyl urea, insect growth regulator compounds such as dode~adienoa~e compounds, oxime-ether compounds, pyriyl compounds, benzoylphenyl compounds urea and other insecticides suc~ as ~etrahydro-5~5-dimethyl-2(1H)- --SlJ~;TlTlJTE SHE~T
.. .. . . . . . .. .. .... . . .. . .

` 21153~
5~ -pyrimidinone-~3-(4-triflyuoromethyl)phenyl]~ 2-[4-(~rifluoro-methyl)phenyl]ethyl~-2-propenylidene hydrazone, boric acid etc.
If desired, the cockroach bait may contain one or more conventional adjuvants. Examples of conventional adjuvants include pulverized grain, biscuit powder, sweetening, water, sugar, maltose excipient, excipients, stabirizer, surfactant, plant oil, dextrin and micro~ristallin cellulose.
The active ingredient according to the invention show an attracting and ingestion-stimulating activity in a very small amount so that no particular care should be taken for amount to be used.
It is preferable, for example, that a bait would contain the ingredient in a concentration of 0.01 % by weight or more of whole amount.
The attracting and ingestion-stimulating action of the ~gents according to the invention will be described below in T I ~T ~ C ~ FFT

wr~93/Q2554 211~3~ P~/JP~2/007~

detail with reference to t~st examples.

Tes~ ex~mple 1 (Test material) A test material was prepared by ~he similar method in example 5.
The test material ~ont~ined 0.05 % by weight of the compound in Table 1.

~.

w0 93~û~54 2 1 1 S 3 ~ 4 Table 1 Test m~terial Tes~ ~ompound's nalne ::
1-amiDo-5. 6. 7. 8 tetr~hyc~ona~tha1ene b 2-~ino-5. 6. 7. 8~tetrshydr~naphth~1ene . . _ ~-aminomethyl-5. 6. 7. 8~ahydronaphchalelle d p n-amylpherlol . _ .
p n butylph~nol 5. 6. 7. 8tetrah~o-l~aphtl~ol 5. 6. 7. 8 tet~ahy~-2~phthol .
h ~-aminomethyl-5. 6. 7. 8~etrshydr~n~phthaler~e 5. ~. 7, 8~et~shydro-2~p~1 i l-ami~v-5.6.7.8-tetrahydrQnapbtha1ene 5.~.7.8-tetrahydrD-~-n2ph~hol _ 2-aminomethyl-5.6.7.8-tetr~hydronaphthalene p-n-amylphe~ol _ k 2-~mino-5.6.7.8-tetr~hydrDnaphthale~
p ~-butylphenol . without cDmpound (as the co~tr~l) (Test insect) Groups of Periplaneata fuliginosa S., P.japonica K., P.
aus~rAlasiae L., P.americana L., Blattell~ germanic L., Blat~a orientalis L. each consisting of 100 ~dult male and ~emale . . . :
(1:1) cockroaches were prepared per one test ma~eri~ls.
(Test methods) W~ 93/025~ à ~ 4 ~ PCI`/J~92/007~5 A group of the test inse~ts was placed individually in a c~ge. After three days, the bait of the test material was examined f~r the degree of ingestion. The degree of ingestion ;
of test material~a) - (k) were compared with test material ~1). The experiment was repeated three times, and the average number of degree of ingestion ~as taken.

(Tes~ results) Results are shown in T~ble 2.

W~ 93/02~S4 2 i l i ~ 1 4 PCr/JP92/Q~79~

--U ~ ~ o =) o~ _ C- _ C~ o~
~ _ ._ ~ ~ _. c~ c~ ~ ~ r~

~ _ _ __ _ _ _ E
.` . ~ ~ 0 o ~ ~ C~ ~ ~ ~ ~ o nJ _ _ ~ _ _ _ _ N N ~ N

, ~ ~o ~ _ _ _ _. ~
',~ 0 C`~ ~ ~ 0 .* ~ O .~. ~ ~ ~
O _ _ _ _ _ _ _ N ._ C`~ _. a~
Cd _ _ _ _ ~ ~
~ U~ ~ CO U~ ~ CL ~ ~ 0 'O ~ ~ _~
~ ~ ~ o ~ c~ c~ ~ c~ u~ o -o _ _. c~ _ _ _ _ ~t~ c~ ~ ~ 3 _ ~ _ _ ~ ~

a; . E
o o ~ o ~ o C~ o Ul ~ ~ ~
~ tr~ ~ C~l c~ _ _ ~ O t`~ 00 Il) U~ :
oo _ _ C~ _ _ _ _ ~i C'~ ~ C~ ~ ':

. l~lt t H~
U~ _ U~ In ~ CO Ul 0 C`~ ~O a 0 ~ U~ U~ ~ C~ ~ _ ~ o CO

L E D ,. _ _ ~ _ -- _ _ .~: E--I

W0 93/025~i4 ` 2 1 i a `~ PCI`/JP92~00795 -- 10 -- .

Test example 2 ~Test m~terials) Th~ same test procedure as in Test example 1 were employed except ~hat two parts of hydromethylnone was formNlated as an insec~icide to give a test material ~A) - (L).

(Test insects) As tes~ insects were employed 12 groups of Periplaneata fuliginosa L., P.americana L., Blattella germanic L., Blatta orien~alis L. consisting of 30 adult cockroar~es and 30 larvae cockroaches per one test material.

(Test method) 48 rooms~ approximately 6 ma~s in size~ were used. ~ne week before initiation of the test each room was stocked with a group of different species of the corkroacb, which was given food and water.
The test material baits were set at five positions in each 'room.
Effect of the attractants was evaluated on the basis of the number ~f dead cockroach.

(Test results) The results are shown in Table 3.

WO 93/02!;S4 h ~ ~ PCItJP92/00795 _ _. __ _ _ ..
i ~x o r~ ~ o r~ o o ~ o I~ o ~
~ tn ~ o ~ 0 ui ~ O Ln ~ u~ ~ o 0 'c ~ ~n u~ u~ u~ u~ u~ u~ r~ ~ 0 co c~
0 ~ _ _ :`

~ o- ~ ~ 0 ~ U~ ~ U~ ~ ~ o C~ Ul C`~
_~ 0 r~ r~ r~ r~ 0 r~ ~ u~ ~ ~ _ ~, _ _ _ _ _ i ~ ~ o o ~ C~) o ~ ~ I~ ~ o ~
~ U~- ~ ~ ~ C`l C~ ~ 00 ~? ~ ~ u~ _ ~D ~r3 . _ o o,~ _ o 0 _ _ _ __ C~ o -u~
~ _~ 0 ~ u~ 1~ ~ O ~ 0 O` ~ 0 ~
~ -~_ _ . _ _ . _ ~.

c~ 0 ~ ~ 1~ ~ o o ~ o r~
O U~ - ~ ~ ~ ~ C~ ~0 ~ 'D u~ ~O u'~
~ ~ ~ ~ ' ~ _ _ _ _ . ~ :
C~ ~ ~ C~ ~ o o 0 0 0 C~ ~ O- 0 ~ ~:
E~ ~ ~ ~ c~ ~ In U~ C'~ r~ 0 ~ ~ ~ o ~ ~ _~ _ _ _ _ _ _ C~l ~ `' ~ _ _ _ _ O
,j 4~~ ~ o co o c~ o c~ o ~ r~ o ~ .
~1 U~ -- to ~`1 ~) C~ _ N _ ~0 ~f) ~ ~0 O .:
~o ::
~ - - - - - - - -CL ~ ~ 0 U~ ~ ~? O ~ C`l ~ C~) CO r~ ' .
f~ ~ ~ ~ ~3 N C~ ~ 'O O _ O _ O
~ _ _ _ __ ~ ' L G ~ C~) a k3 ~. ~ _ _ _, ~ _~ O
~ ~ . _ w093~0~ ~ 2 1~ a 3 ~ ~ ~CT~JPg2/007~

BEST MODE FOR CARRYING OUT THE INVENTION
Some examples of this invention will be explained as the following examples.
However, this inYention is not limited to these examples.
Unless otherwise indicated, all par~s are by weight.

E~ample 1 A mixture of 75 parts powdery fish ~eal, 5 parts of ~altose, 5 par s of L-arabinose, 5 p8rts of oleic acid, 10 parts of rice brain oil~ 0.06 part of permethrin, 0.05 part of p-n-butylphenol and O.03 part of 2-amino-5,6,7,8-tetrahydro- ;
naphthalene w~s kneaded together with some water, and the mixture was formed into a small granular bait of the invention weighing about 0 7 g per gr~nule.

Example 2 150 parts of water-soluble starch, 150 parts of potato starch, 100 parts of boric acid 0.6 part of sodium benzoa~e, 0.2 part of dib11~ylhydroxytoluene, 0.03 part of 2-amino-5,6>7,8-tetrahydro- naphthalene, O.1 part of 5,6,7,8-te~rahydro-l-naphthol and 599.5 parts of water were blended ~nd formed into ~ cockroach bait o~ the invention weighing abou~ 10 g per piece.

Ex~mple 3 100 par~s of wheat powders, 35 parts of water-soluble WO 93/025~ ) 3 ~ ~ PCl`~JP92/00795 starch~ 35 parts of starch, one part of methoprene, 0.06 part of sodium benzoate, 0.02 par~ of dibutylhydroxytoluPne, 0.05 p~rt of 5,6,7,8-tetrahydro-2-naphthol and 0.03 part of 2-amino-5,6,7,8- tetrahydron~phthalene hydrocarbo~ate were blended ~ogether ~ith an appropriate amount of water and formed in~o a cockroach bait of the in~ention weighing about 5 g per piece.

Example 4 lOO parts of corn syrup, 30 par~s of sorbitol, 14 parts of gelatin, 48 parts of water, 2 p~rts of pyriproxyfen, 0.06 part of sodium benzoate~ 0.02 part of dibutylhydroxytoluene, p-n-butylphenol and 0.1 parts of 2-aminomethyl-5,6~7,8-tetr~ydronaphthalene were blended and formed into a co~kroach bAit of ~he invention weighing about 10 g per piece.

Example 5 40 par~s of ~hick malt syr~p, 45 parts of oats powder, 11 'p~rts of macrogol, 0.5 part of cyphenot~rin, onP part of diflu~enæurone, 0.06 part of sodium benzoate, 0.02 part of dibutylhydroxy~oluene, 0.05 part of p-n-amylphenol and 2-amino-5,6,7,8-tetr~hydro- naphthalene were blended ~nd formed into a csckroach bait of the invention weighing about 10 g per piece.

Example 6 WO 93/Q~554 2 ~ ~ ~ 3 4 ~ PC~/JP92/00795 -- ~4 --20 p~rts of brown sugar, 2 parts of corn oil, 2 parts of chryslis powder, 20 parts of biscuit powder, 50 parts dextrin, 0.06 part of sodium benzoate, 0.02 part of dibutylhydroxytoluene, 2 parts of hydramethylnone, 0.02 part of p-n-amylphenol and 0.03 part of 2-amino-5,6,7,8-tetrahydro-naphthalene were blended and formed }nto a cockroach bait of the invention weighing about 5 g per piece.

Example 7 20 parts of powdery sugar, lO parts of corn oil~ 30 par~s of sweet corn oii, 60 parts of crystalline cellulose, 2 parts of e~hofenprox, 0.06 parts sodium benzoate, 0.02 part of dibutylhydroxytoluene, 0.02 part of p-n-amylphenol ~nd 0. 03 p2rt of 2-amino-5,6,7,8-tetrahydronaphthalene were blended and formed into a cockroach bait of the invention ~eighing about 5 g per piece.

Example 8 15 parts of miner~l oil, 2 parts of ammonium hydroxide, 2 par~s vf polyoxyethylene nonylphenyl ether, 0.5 p~rt of carboxymethyl cellulose, 3.5 parts of potato starch, one part of propox~r, 0.5 part of fenoxycarb, 0.06 part o~ sodium be~ozate, 0.02 part of dibutyl~ydroxytoluene, 0.05 part of 5,6,7,8-tetrahydro-2-naphthol and 0.03 part of 2-amino-5,6~7,8-tetrahydronapbthal~ne were blended and ormed into a WC~ 93/02~ 3 3 1 ~ PCl`/JP92/00795 .' . - 15 -.; . , `; :
cockroach bait of the invention weighing about 5 g per piece.
Example 9 15 parts of white mineral oil, 1.5 par~s of polyoxyethylene glycol dioleate, 2 parts of polyoxyethyle~e nonylphenyl ether, one part of hydroxyethyl cellulose, 0.5 part of xanthane gum, 5 parts of corn starch, 2 part5 of chloropyrifosmethyl, 0.06 part of sodium benzoate, 0.02 part of 5,6,7,8-tetrahydro-2-n~pbthol and 0.0~ part of 2-amino-5,6,7,8-tetrahydro-naph~halene were blended and formed into a cockroach bait of the invention weighing about 5 g per piece.

INDUSTRIAL APPLICABILITY
The attracting and ingestion-stimulating agents o the invention not only exhibit a potent attracting and ingestion-stimulating activity on various species of cockroach but also are highly effective in cockrosch extermination even ~hen m~le and female cockroaches li~e toge~her.
This brings about low productio~ ost and mini~ize the size vf the preparation for easiness on use.
The attracting and ingestion-stimulating component of the invention can also provide each of the cockroach controlling agents with fast acting effect.

Claims (2)

1. An attracting and ingestion-stimulating agent for cockroach comprising as the active ingredient;
(a) one or more compounds selected from the group of 1-amino-5,6, 7,8-tetrahydronaphthalene, 2-amino-5,6,7,8-tetrahydronaphthalene, 2-aminomethyl-5,6,7,8-tetrahydro-naphthalene and a salt thereof ; and (b) one or more compounds selected from the group of p-n-butylphenol, p-n-amylphenol, 5,6,7,8-tetrahydro-1-naphthol and 5,6,7, 8-tetrahydro-2-naphthol.
2. An attracting and ingestion-stimulating agent for cockroach comprising as the active ingredient one compound selected from the group consisting of 2-aminomethyl-5,6,7,8-tetrahydronaphthalene, 1-amino-5,6,7,8-tetrahydronaphthalene, 2-amino-5,6,7,8-tetrahydro-naphthalene and a salt thereof, and one compound selected from the group consisting of p-n-amylphenol, p-n-butylphenol, 5,6,7,8-tetrahydro-1-naphthol and 5,6,7,8-tetrahydro-2-naphthol.
CA002115344A 1991-08-09 1992-06-22 Attracting and ingestion-stimulating agent for cockroach Abandoned CA2115344A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP20082291 1991-08-09
JP200822/1991 1991-08-09

Publications (1)

Publication Number Publication Date
CA2115344A1 true CA2115344A1 (en) 1993-02-18

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Family Applications (1)

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Country Status (5)

Country Link
EP (1) EP0598122A1 (en)
AU (1) AU660473B2 (en)
BR (1) BR9206343A (en)
CA (1) CA2115344A1 (en)
WO (1) WO1993002554A1 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994014323A1 (en) * 1991-07-09 1994-07-07 Taisho Pharmaceutical Co., Ltd. Attracting and ingestion-stimulating agent for cockroach
PT802727E (en) * 1995-01-09 2002-01-30 Johnson & Son Inc S C INSECT LIQUID (CHAMARIZ)
AUPR709901A0 (en) * 2001-08-17 2001-09-06 Grotech Australia Pty Ltd Edible pesticidal formulations
US8404260B2 (en) 2008-04-02 2013-03-26 Bayer Cropscience Lp Synergistic pesticide compositions
WO2017079684A1 (en) * 2015-11-06 2017-05-11 Gries Gerhard J Baits for cockroaches

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4627981A (en) * 1984-09-14 1986-12-09 Taisho Pharmaceutical Co., Ltd. Attractant-ingestion stimulant preparations for Periplaneta americana L
JPH0610122B2 (en) * 1986-10-14 1994-02-09 大正製薬株式会社 Cockroach feeding stimulant
US5484588A (en) * 1990-08-09 1996-01-16 Taisho Pharmaceutical Co., Ltd. Attracting and ingestion-stimulating agent for cockroach
JP3125445B2 (en) * 1991-07-09 2001-01-15 大正製薬株式会社 Cockroach Attraction, Feeding Stimulant

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EP0598122A1 (en) 1994-05-25
WO1993002554A1 (en) 1993-02-18
AU660473B2 (en) 1995-06-29

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