CA2098684C - Composite porous carbonaceous membranes - Google Patents
Composite porous carbonaceous membranesInfo
- Publication number
- CA2098684C CA2098684C CA002098684A CA2098684A CA2098684C CA 2098684 C CA2098684 C CA 2098684C CA 002098684 A CA002098684 A CA 002098684A CA 2098684 A CA2098684 A CA 2098684A CA 2098684 C CA2098684 C CA 2098684C
- Authority
- CA
- Canada
- Prior art keywords
- temperature
- membrane
- porous substrate
- pores
- heating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000012528 membrane Substances 0.000 title claims abstract description 214
- 239000002131 composite material Substances 0.000 title claims abstract description 57
- 239000000203 mixture Substances 0.000 claims abstract description 80
- 239000011148 porous material Substances 0.000 claims abstract description 68
- 239000000463 material Substances 0.000 claims abstract description 66
- 239000000758 substrate Substances 0.000 claims abstract description 58
- 230000000274 adsorptive effect Effects 0.000 claims abstract description 56
- 238000000034 method Methods 0.000 claims abstract description 47
- 238000000926 separation method Methods 0.000 claims description 41
- 238000010438 heat treatment Methods 0.000 claims description 29
- 239000002243 precursor Substances 0.000 claims description 27
- 230000001590 oxidative effect Effects 0.000 claims description 24
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 22
- 238000001816 cooling Methods 0.000 claims description 22
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims description 22
- 229930195733 hydrocarbon Natural products 0.000 claims description 21
- 150000002430 hydrocarbons Chemical group 0.000 claims description 21
- 229920000642 polymer Polymers 0.000 claims description 19
- 239000012530 fluid Substances 0.000 claims description 18
- 229910052799 carbon Inorganic materials 0.000 claims description 15
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 10
- 229910052760 oxygen Inorganic materials 0.000 claims description 10
- 239000001301 oxygen Substances 0.000 claims description 10
- 239000004215 Carbon black (E152) Substances 0.000 claims description 8
- 229910002090 carbon oxide Inorganic materials 0.000 claims description 8
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 7
- 238000009826 distribution Methods 0.000 claims description 7
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 6
- 238000000576 coating method Methods 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- 229920001328 Polyvinylidene chloride Polymers 0.000 claims description 5
- 229920002239 polyacrylonitrile Polymers 0.000 claims description 5
- 239000005033 polyvinylidene chloride Substances 0.000 claims description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 4
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 4
- 239000000919 ceramic Substances 0.000 claims description 4
- 238000000151 deposition Methods 0.000 claims description 4
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 4
- 239000004800 polyvinyl chloride Substances 0.000 claims description 4
- 239000012808 vapor phase Substances 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims description 2
- FDPIMTJIUBPUKL-UHFFFAOYSA-N dimethylacetone Natural products CCC(=O)CC FDPIMTJIUBPUKL-UHFFFAOYSA-N 0.000 claims description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N o-dimethylbenzene Natural products CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 2
- 238000004227 thermal cracking Methods 0.000 claims description 2
- CHRJZRDFSQHIFI-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;styrene Chemical compound C=CC1=CC=CC=C1.C=CC1=CC=CC=C1C=C CHRJZRDFSQHIFI-UHFFFAOYSA-N 0.000 claims 1
- 150000001555 benzenes Chemical class 0.000 claims 1
- 230000003647 oxidation Effects 0.000 abstract description 45
- 238000007254 oxidation reaction Methods 0.000 abstract description 45
- 230000035699 permeability Effects 0.000 abstract description 41
- 239000012466 permeate Substances 0.000 abstract description 14
- 239000007789 gas Substances 0.000 description 43
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 22
- 239000001257 hydrogen Substances 0.000 description 22
- 229910052739 hydrogen Inorganic materials 0.000 description 22
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 18
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 17
- 239000000047 product Substances 0.000 description 16
- 238000009792 diffusion process Methods 0.000 description 15
- 230000007246 mechanism Effects 0.000 description 13
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 12
- 239000004816 latex Substances 0.000 description 10
- 229920000126 latex Polymers 0.000 description 10
- 229910052757 nitrogen Inorganic materials 0.000 description 10
- 239000012071 phase Substances 0.000 description 9
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 8
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 7
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 7
- 239000005977 Ethylene Substances 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- 230000001186 cumulative effect Effects 0.000 description 6
- 230000007423 decrease Effects 0.000 description 6
- 239000001294 propane Substances 0.000 description 6
- 229910002804 graphite Inorganic materials 0.000 description 5
- 238000012986 modification Methods 0.000 description 5
- 230000004048 modification Effects 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 239000000725 suspension Substances 0.000 description 5
- 239000001569 carbon dioxide Substances 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 4
- 238000003763 carbonization Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000010439 graphite Substances 0.000 description 4
- 239000001307 helium Substances 0.000 description 4
- 229910052734 helium Inorganic materials 0.000 description 4
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 4
- 229910002091 carbon monoxide Inorganic materials 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- 230000008901 benefit Effects 0.000 description 2
- 239000001273 butane Substances 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 230000007717 exclusion Effects 0.000 description 2
- 239000012510 hollow fiber Substances 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000007873 sieving Methods 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000005539 carbonized material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000004815 dispersion polymer Substances 0.000 description 1
- 238000007210 heterogeneous catalysis Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000012704 polymeric precursor Substances 0.000 description 1
- 229920000131 polyvinylidene Polymers 0.000 description 1
- NPSSWQJHYLDCNV-UHFFFAOYSA-N prop-2-enoic acid;hydrochloride Chemical compound Cl.OC(=O)C=C NPSSWQJHYLDCNV-UHFFFAOYSA-N 0.000 description 1
- 229920005573 silicon-containing polymer Polymers 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- -1 steam Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
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- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
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- C04B38/0022—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof obtained by a chemical conversion or reaction other than those relating to the setting or hardening of cement-like material or to the formation of a sol or a gel, e.g. by carbonising or pyrolysing preformed cellular materials based on polymers, organo-metallic or organo-silicon precursors
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00793—Uses not provided for elsewhere in C04B2111/00 as filters or diaphragms
- C04B2111/00801—Membranes; Diaphragms
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S264/00—Plastic and nonmetallic article shaping or treating: processes
- Y10S264/48—Processes of making filters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S55/00—Gas separation
- Y10S55/05—Methods of making filter
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Structural Engineering (AREA)
- Materials Engineering (AREA)
- Dispersion Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Manufacturing & Machinery (AREA)
- General Chemical & Material Sciences (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Nanotechnology (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Carbon And Carbon Compounds (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US90343092A | 1992-06-24 | 1992-06-24 | |
| US07/903430 | 1992-06-24 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2098684A1 CA2098684A1 (en) | 1993-12-25 |
| CA2098684C true CA2098684C (en) | 1997-12-16 |
Family
ID=25417495
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002098684A Expired - Fee Related CA2098684C (en) | 1992-06-24 | 1993-06-17 | Composite porous carbonaceous membranes |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP0575945B1 (en:Method) |
| KR (1) | KR960010383B1 (en:Method) |
| CA (1) | CA2098684C (en:Method) |
| DE (1) | DE69313734T2 (en:Method) |
| ES (1) | ES2105010T3 (en:Method) |
| SG (1) | SG86283A1 (en:Method) |
| TW (1) | TW242120B (en:Method) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5912048A (en) * | 1994-08-25 | 1999-06-15 | Air Products And Chemicals, Inc. | Passivation carbonaceous adsorptive membranes |
| US5998024A (en) * | 1995-02-02 | 1999-12-07 | Rainer H. Frey | Biocompatible material and method of manufacture and use thereof |
| US5681657A (en) * | 1995-02-02 | 1997-10-28 | Rainer H. Frey | Biocompatible porous hollow fiber and method of manufacture and use thereof |
| JP3361655B2 (ja) * | 1995-05-10 | 2003-01-07 | エヌオーケー株式会社 | 多孔質セラミックス複合中空糸膜およびその製造法 |
| US6471745B1 (en) * | 1996-06-28 | 2002-10-29 | University Of Delaware | Nanoporous carbon catalytic membranes and method for making the same |
| US5972079A (en) * | 1996-06-28 | 1999-10-26 | University Of Delaware | Supported carbogenic molecular sieve membrane and method of producing the same |
| US5897915A (en) * | 1996-10-28 | 1999-04-27 | Corning Incorporated | Coated substrates, method for producing same, and use therefor |
| US6062997A (en) * | 1998-02-06 | 2000-05-16 | Elenco Electronics, Inc. | Magnetic dart system |
| GB0106478D0 (en) | 2001-03-16 | 2001-05-02 | Univ Robert Gordon | Apparatus and method |
| KR101036274B1 (ko) * | 2010-01-05 | 2011-05-23 | (주)진명 | 슬라이드 탄성모듈 및 이를 이용한 휴대단말기용 힌지모듈 |
| US9527043B2 (en) | 2012-05-17 | 2016-12-27 | Samsung Electronics Co., Ltd. | Gas separation membrane and method of preparing the same |
| KR101920716B1 (ko) | 2012-05-17 | 2019-02-13 | 삼성전자주식회사 | 기체 분리막 및 그 제조방법 |
| CN106943888B (zh) * | 2017-03-31 | 2019-10-18 | 华南理工大学 | 一种阴离子掺杂的萤石型钨酸基混合导体透氢膜材料及其制备方法与应用 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2625690B1 (fr) * | 1988-01-11 | 1993-04-23 | Inst Francais Du Petrole | Procede de separation des constituants d'un melange en phase gazeuse au moyen d'une membrane composite |
| CA2029484C (en) * | 1989-11-14 | 1999-04-27 | Madhukar Bhaskara Rao | Gas separation by adsorbent membranes |
-
1992
- 1992-11-27 TW TW081108776A patent/TW242120B/zh active
-
1993
- 1993-06-17 CA CA002098684A patent/CA2098684C/en not_active Expired - Fee Related
- 1993-06-21 DE DE69313734T patent/DE69313734T2/de not_active Expired - Fee Related
- 1993-06-21 SG SG9501571A patent/SG86283A1/en unknown
- 1993-06-21 ES ES93109897T patent/ES2105010T3/es not_active Expired - Lifetime
- 1993-06-21 EP EP93109897A patent/EP0575945B1/en not_active Expired - Lifetime
- 1993-06-22 KR KR1019930011380A patent/KR960010383B1/ko not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| SG86283A1 (en) | 2002-02-19 |
| TW242120B (en:Method) | 1995-03-01 |
| ES2105010T3 (es) | 1997-10-16 |
| DE69313734T2 (de) | 1998-01-15 |
| DE69313734D1 (de) | 1997-10-16 |
| CA2098684A1 (en) | 1993-12-25 |
| EP0575945A2 (en) | 1993-12-29 |
| EP0575945B1 (en) | 1997-09-10 |
| KR960010383B1 (ko) | 1996-07-31 |
| KR940000137A (ko) | 1994-01-03 |
| EP0575945A3 (en) | 1994-01-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed | ||
| MKLA | Lapsed |
Effective date: 20080617 |