CA2093029C

CA2093029C - Lubricants, particularly lubricating grease compositions for constant velocity universal joints

Info

Publication number: CA2093029C
Application number: CA002093029A
Authority: CA
Inventors: Jon C. Root; Michael A. Wilson; Mark Baum
Original assignee: Exxon Research and Engineering Co
Current assignee: ExxonMobil Technology and Engineering Co
Priority date: 1992-04-14
Filing date: 1993-03-31
Publication date: 2003-07-29
Anticipated expiration: 2013-03-31
Also published as: JPH0617075A; CA2093029A1; EP0566326A1

Abstract

High performance lubricant compositions, particularly high performance lubricating grease for lubricating and reducing or eliminating shuddering in inboard constant velocity universal joints under high torque and high angle of articulation. In one preferred form, the lubricating grease comprises a base oil, a thickener and in intimate admixture therewith at least one organic molybdenum compound from the group consisting of molybdenum dithiophosphates and molybdenum dithiocarbamates and at least one ashless additive from the group consisting of ashless dithiophosphates and ashless dithiocarbamates.

Description

Cas~ 910226 LL1BI~IC~.NTS, PTdtTICOLARLY LTJBILIC~LTIPTG GREASE
COMPOSITIOIJS ~'OFt COP18TA3~TT ~IELOCIT3~ UI~TI~EItSAL JOINTS
JO~? C . gtOOT
MICHAEL A. ~PILSOF1 M~.RR B.~rUM
SPECTFTC~1TT01~T
BACKGROUND AND DESCRIRTION O~' THE INVENTION
This invention relates generally to lubricants and, more particularly, to lubricating greases which are particularly useful for lubricating and reducing or eliminating shuddering in constant velocity universal joints operating under high torque and high angle of articulation.
While the invention relates primarily to lubricating grease compositions, it also has utility in other lubricants such as lubricating oil.
Under high torque and high angle of articulation, inboard constant velocity universal joints give uneven torque to the wheels in automotive drives, pausing a shuddering sensation. The object of the invention, generally stated, is the provision of lubricants for such constant velocity universal joints which will reduce or eliminate such shuddering. Such lubricants or lubricating greases will have other applications wherein high performance low friction lubricants are required.
The procedures and equipment for producing lubricants, and particularly lubricating greases, are well known. Likewise, it is well known that a lubricating grease will comprise an oil and a thickening agent therefor as the base components and into which various low friction additives are intimately incorporated so as to result in a uniform intimate admixture of all components.
The present invention relates particularly to the combination of additives utilized, sometimes referred to as the "additive package". A lubricating grease formulated in accordance with the present invention will have the following general formula:
S~KN& FORMDL~A
Base Oil Thickening Agent Molybdenum Dithiocarbamate and/or Dithiophosphate Ashless Dithiophosphate and/or Dithiocarbamate Any suitable base oil may be utilized such as a mineral oil or a synthetic hydrocarbon oil having a viscosity of a lubricant. Various known thickening agents may be used the preferred ones being a urea type (monourea, diurea, triurea, tetraurea, and polyureaj.
The additives are commercially available from various sources under proprietary designations as follows:
Molybdenum dialkyl dithiocarbamate (MoDTC) and molybdenum dialkyl dithiophosphate (MoDTP) available from R.T. Vanderbilt Company, Inc. of Norwalk, Connecticut under the trademarks MOLYVAN A and MOLYVAN L, respectively. Molybdenum diaryl dithiophosphate available from ASAHI DENKA KOGYO K.K. SAKURA Lube 300. Ashless dithiophosphate and ashless dithiocarbamate available from R.T. Vanderbilt Company, Inc. under the trademarks VANLUBK
7611 and VANLUBE 732, respectively.
The following is a specific and preferred example of a lubricating gxease embodying the invention.
PR~FBRRED BKAMPLK
(Grease A) ~ By wei hq~t 600 SUS* Solvent Refined Paraffinic Oil 54.5 Polyurea Thickener 13.0 MolyVan L 1.0~
Vanlube 7611 1.5~
*600 Saybolt Universal Seconds Viscosity at 100°F.

~f~~:~%

The grease of the above preferred example was prepared in the following conventional manner.
Polyurea thickener was prepared in a kettle by adding: (a) about 30% by weight of a solvent extracted neutral base oil with a viscosity of 600 SUS at 100°F and (b) about 7.45% by weight of primary oleyl amine. The primary amine base oil was then mixed for 30-60 minutes at a maximum temperature of 120°F with about 5.4% by weight of an isocyanate, such as 143 L-MDT manufactured by Dow.
About 3% by weight water was then added and stirred for about 20 to 30 minutes before adding 40% base oil and heating to 320°F. The grease is then cooled to 180°F. At this time, 1% MolyVan L and 1.5% i7anlube 7611 are then added along with the remaining base oil. The resulting grease is then milled through a colloid type mill.
The grease of the above preferred example (Grease A) was subjected to the following standard physical tests with the results being tabulated as follows in comparison with:
(Grease B) Polyurea Base Grease (Grease C) 3% Moly Lithium (Grease D) Lithium Base Grease (Grease E) Lithium Base Grease w/Low Friction Additive Package (Grease F) Polyurea Base Grease w/3% Molybdenum disulfide 4 Ball Dropping Grease 60X* Wear** Point (A) 312 0.33 mm 412F

(B) 238 0.67 mm 412F

(C) 292 0.68 mm 401F

(D) 285 0.72 mm 408F

(E) 285 0.35 mm 417F

(F) 330 0.64 mm 423F

* 6~ Strakes in a standard grease worked as described in ~1STM Method D-217.
** ASTM Method D-2596-87.
The grease composition of the above-preferred example (Grease A) was subjected to Line Contact SRV friction and 1p load carrying test using the Optimol SRV Tester of Optimol Lubricants, Cartaret, New Jersey to demonstrate its ability to minimize or eliminate shuddering in a constant velocity universal joint. For purpose of comparison, the grease compositions of B-F above were also subjected to the same test. The comparative test results are tabulated as follows (Table 2).

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C

s G C4 Ci C W O
C

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N

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~

H C C C O C
H G O

H

s~

O W O G

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G G O C G C O G
G O G ~9 ~s C O C O

s ~ N ~ ~ ~ H H
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C O O O C ~ O C
C O ~ 9 ~ ~ H ~ ~ N
H ~ H

C~ C O C O O G G c?
C O ~ O

A I 1 I ~ I 9 1 I 1 J

The following examples are given to illustrate other uses in which the invention may be practiced:
Antifriction Bearings (Ball ~ Roller) Reciprocating F~ivots Automotive Steering Linkage Automotive Ball Joints From the foregoing preferred example, it will be apparent that the various components may be utilised in various ranges. In general, the useful range for the combined base, fillers, oils and thickeners is from 80 to 99.9 percent by weight of the grease compositions and the useful range for the additive package is from 0.1 to 20 percent by weight.

Claims

1. A lubricant composition comprising a base oil and a thickening agent comprising a mono urea compound, and in intimate admixture therewith additives comprising at least one organic molybdenum compound selected from the group consisting of molybdenum dithiocarbamates and molybdenum dithiophosphates and at least one ashless additive selected from the group consisting of ashless dithiophosphates and ashless dithiocarbamates.

2. A lubricating grease comprising a base oil and a thickening agent therefor comprising a mono urea compound and in intimate admixture therewith additives comprising at least one organic molybdenum compound selected from the group consisting of molybdenum dithiocarbamates and molybdenum dithiophosphates and at least one ashless additive selected from the group consisting of ashless dithiophosphates and ashless dithiocarbamates.

3. A lubricant composition comprising a base oil and a thickening agent comprising a mono urea compound, and in intimate admixture therewith additives comprising (1) at least one molybdenum compound selected from the group consisting of molybdenum dialkyl dithiophosphate, molybdenum dialkyl dithiocarbamate and molybdenum diaryl dithiophosphate and (2) an ashless additive selected from the group consisting of ashless dithiocarbamate and ashless dithiophosphate.

4. A lubricating grease comprising a base oil and a polyurea thickening agent therefor including at least a mono urea compound, and in intimate admixture therewith approximately 1.0% by weight of molybdenum dialkyl dithiophosphate and approximately 1.5% by weight of ashless dithiophosphate.