CA2092715A1 - Catalyseurs a base de fer-zinc et conversion de gaz de synthese en alpha-olefines en presence de ces catalyseurs - Google Patents

Catalyseurs a base de fer-zinc et conversion de gaz de synthese en alpha-olefines en presence de ces catalyseurs

Info

Publication number
CA2092715A1
CA2092715A1 CA2092715A CA2092715A CA2092715A1 CA 2092715 A1 CA2092715 A1 CA 2092715A1 CA 2092715 A CA2092715 A CA 2092715A CA 2092715 A CA2092715 A CA 2092715A CA 2092715 A1 CA2092715 A1 CA 2092715A1
Authority
CA
Canada
Prior art keywords
catalysts
iron
olefins
alpha
conversion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA2092715A
Other languages
English (en)
Other versions
CA2092715C (fr
Inventor
Stuart Leon Soled
Sabato Miseo
Enrique Iglesia
Rocco Anthony Fiato
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2092715A1 publication Critical patent/CA2092715A1/fr
Application granted granted Critical
Publication of CA2092715C publication Critical patent/CA2092715C/fr
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • C07C1/044—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof containing iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/72—Copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with zinc, cadmium or mercury

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

Nouveaux catalyseurs à base de fer-zinc activé par du cuivre-potassium dans lesquels le rapport atomique fer:zinc est de 5:1 ou plus; ils présentent une activité, une sélectivité et une stabilité améliorées dans la synthèse d'alpha-oléfines à partir d'hydrogène et de monoxyde de carbone.
CA002092715A 1990-10-01 1991-09-13 Catalyseurs a base de fer-zinc et conversion de gaz de synthese en alpha-olefines en presence de ces catalyseurs Expired - Fee Related CA2092715C (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US591,304 1990-10-01
US07/591,304 US5100856A (en) 1990-10-01 1990-10-01 Iron-zinc based catalysts for the conversion of synthesis gas to alpha-olefins
PCT/US1991/006590 WO1992005869A1 (fr) 1990-10-01 1991-09-13 Catalyseurs a base de fer-zinc et conversion de gaz de synthese en alpha-olefines a l'aide des catalyseurs

Publications (2)

Publication Number Publication Date
CA2092715A1 true CA2092715A1 (fr) 1992-04-02
CA2092715C CA2092715C (fr) 1999-12-21

Family

ID=24365949

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002092715A Expired - Fee Related CA2092715C (fr) 1990-10-01 1991-09-13 Catalyseurs a base de fer-zinc et conversion de gaz de synthese en alpha-olefines en presence de ces catalyseurs

Country Status (6)

Country Link
US (1) US5100856A (fr)
EP (1) EP0553115B1 (fr)
CA (1) CA2092715C (fr)
DE (1) DE69128148T2 (fr)
NO (1) NO303272B1 (fr)
WO (1) WO1992005869A1 (fr)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6777452B2 (en) * 1999-09-21 2004-08-17 Hydrocarbon Technologies Promoted skeletal iron catalysts for Fischer-Tropsch synthesis processes
WO2003043734A1 (fr) * 2001-11-22 2003-05-30 Sasol Technology (Proprietary) Limited Catalyseurs fischer-tropsch contenant de la ferrihydrite et de l'aluminium
US6602922B1 (en) 2002-02-19 2003-08-05 Chevron U.S.A. Inc. Process for producing C19 minus Fischer-Tropsch products having high olefinicity
US20030158272A1 (en) 2002-02-19 2003-08-21 Davis Burtron H. Process for the production of highly branched Fischer-Tropsch products and potassium promoted iron catalyst
US6787576B2 (en) * 2002-12-27 2004-09-07 Exxonmobil Research And Engineering Company Linear alpha olefins from natural gas-derived synthesis gas over a nonshifting cobalt catalyst
US7393876B2 (en) * 2005-12-16 2008-07-01 Eltron Research, Inc. Fischer-tropsch catalysts
JP2008277696A (ja) * 2007-05-07 2008-11-13 Toshiba Corp 半導体装置の製造方法
US7879756B2 (en) * 2007-08-10 2011-02-01 Rentech, Inc. Precipitated iron catalyst for hydrogenation of carbon monoxide
KR100903439B1 (ko) 2007-10-15 2009-06-18 한국화학연구원 천연가스로부터 경질탄화수소의 직접 제조방법
WO2011054738A1 (fr) 2009-11-06 2011-05-12 Basf Se Catalyseur hétérogène contenant du fer et procédé de fabrication d'oléfines par réaction de monoxyde de carbone avec de l'hydrogène
WO2011054735A1 (fr) 2009-11-06 2011-05-12 Basf Se Catalyseur hétérogène contenant du fer et du cuivre et procédé de fabrication d'oléfines par réaction de monoxyde de carbone avec de l'hydrogène
EP2496348B1 (fr) * 2009-11-06 2016-01-06 Basf Se Catalyseur hétérogène contenant du fer et du manganèse et procédé de fabrication d'oléfines par réaction de monoxyde de carbone avec de l'hydrogène
CN107530679B (zh) 2015-04-28 2021-05-18 3M创新有限公司 用于呼吸防护的过滤器介质
CN109569623B (zh) * 2018-12-06 2021-03-16 清华大学 合成气直接制烯烃的催化剂、制备方法及使用方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4199523A (en) * 1975-04-29 1980-04-22 Ruhrchemie Aktiengesellschaft Process for the production of hydrocarbon mixtures
FR2370684A1 (fr) * 1976-11-10 1978-06-09 Shell France Procede pour la preparation d'un gaz riche en hydrogene
US4478955A (en) * 1981-12-21 1984-10-23 The Standard Oil Company Upgrading synthesis gas

Also Published As

Publication number Publication date
DE69128148D1 (de) 1997-12-11
EP0553115A4 (en) 1993-11-03
US5100856A (en) 1992-03-31
NO931231D0 (no) 1993-03-31
NO931231L (no) 1993-03-31
EP0553115B1 (fr) 1997-11-05
DE69128148T2 (de) 1998-03-12
WO1992005869A1 (fr) 1992-04-16
CA2092715C (fr) 1999-12-21
NO303272B1 (no) 1998-06-22
EP0553115A1 (fr) 1993-08-04

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