CA2092049A1 - Process for the Recovery of Rhodium from Residues of Carbonylation Reactions - Google Patents

Process for the Recovery of Rhodium from Residues of Carbonylation Reactions

Info

Publication number
CA2092049A1
CA2092049A1 CA2092049A CA2092049A CA2092049A1 CA 2092049 A1 CA2092049 A1 CA 2092049A1 CA 2092049 A CA2092049 A CA 2092049A CA 2092049 A CA2092049 A CA 2092049A CA 2092049 A1 CA2092049 A1 CA 2092049A1
Authority
CA
Canada
Prior art keywords
rhodium
recovery
residues
carbonylation reactions
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA2092049A
Other languages
French (fr)
Other versions
CA2092049C (en
Inventor
Peter Lappe
Helmut Springer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Celanese GmbH
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Publication of CA2092049A1 publication Critical patent/CA2092049A1/en
Application granted granted Critical
Publication of CA2092049C publication Critical patent/CA2092049C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G55/00—Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/54—Preparation of carboxylic acid anhydrides
    • C07C51/573—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B11/00—Obtaining noble metals
    • C22B11/04—Obtaining noble metals by wet processes
    • C22B11/042—Recovery of noble metals from waste materials
    • C22B11/048—Recovery of noble metals from waste materials from spent catalysts
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/009—General processes for recovering metals or metallic compounds from spent catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Metallurgy (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

The present invention relates to a process for the recovery of rhodium from acetic anhydride-containing residues, which are produced in the carbonylation of methanol and/or methyl acetate and/or dimethyl ether. A
carboxylic acid having 2 to 5 carbon atoms is added to the residue, the mixture is heated, 1 to 10 mol of methanol per mol of acetic anhydride are added, the constituents boiling more readily than the carboxylic acid are distilled off, the mixture is cooled and the rhodium-containing residue is separated.
CA 2092049 1992-03-27 1993-03-19 Process for the recovery of rhodium from residues of carbonylation reactions Expired - Fee Related CA2092049C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP4210027.5 1992-03-27
DE19924210027 DE4210027A1 (en) 1992-03-27 1992-03-27 Process for the recovery of rhodium from carbonylation reaction residues

Publications (2)

Publication Number Publication Date
CA2092049A1 true CA2092049A1 (en) 1993-09-28
CA2092049C CA2092049C (en) 2000-10-31

Family

ID=6455190

Family Applications (1)

Application Number Title Priority Date Filing Date
CA 2092049 Expired - Fee Related CA2092049C (en) 1992-03-27 1993-03-19 Process for the recovery of rhodium from residues of carbonylation reactions

Country Status (11)

Country Link
EP (1) EP0564862A1 (en)
JP (1) JPH0784629B2 (en)
KR (1) KR100251252B1 (en)
CN (1) CN1077908A (en)
AU (1) AU656844B2 (en)
BR (1) BR9301283A (en)
CA (1) CA2092049C (en)
DE (1) DE4210027A1 (en)
MX (1) MX9301572A (en)
TW (1) TW212144B (en)
ZA (1) ZA931987B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7196227B2 (en) 2002-12-23 2007-03-27 Eastman Chemical Company Process for the recovery of phosphorus and iodine containing catalyst components

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE1030095B1 (en) * 2021-12-24 2023-07-26 Indaver Nv METHOD FOR PROCESSING LIQUID PHARMACOCHEMICAL AND/OR FINE CHEMICAL WASTE MATERIALS CONTAINING ORGANIC SOLVENTS AND PRECIOUS METALS
BE1030097B1 (en) * 2021-12-24 2023-07-25 Indaver Nv Method for optimizing liquid pharmacochemical and/or fine chemical wastes comprising organic solvents and precious metals

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE591195C (en) * 1931-04-25 1934-01-18 Consortium Elektrochem Ind Process for separating liquid mixtures of acetic anhydride, acetic acid and water
DE1290535C2 (en) * 1968-01-31 1975-11-20 Ruhrchemie Ag, 4200 Oberhausen PROCESS FOR SEPARATION AND RECOVERY OF RHODIUM FROM HYDROFORMYLATION PRODUCTS
US4340569A (en) * 1981-03-06 1982-07-20 The Halcon Sd Group, Inc. Treatment of carbonylation residues
US4434241A (en) * 1982-09-27 1984-02-28 Eastman Kodak Company Catalyst recovery process from tar from carbonylation reactions
US4578368A (en) * 1985-05-06 1986-03-25 Eastman Kodak Company Catalyst recovery process
US4659682A (en) * 1985-07-08 1987-04-21 The Halcon Sd Group, Inc. Recovery of noble metal values from carbonylation residues
US4605541A (en) * 1985-08-26 1986-08-12 The Halcon Sd Group, Inc. Recovery of noble metal values from carbonylation residues using immiscible liquids
DE3610603A1 (en) * 1986-03-29 1987-10-01 Hoechst Ag METHOD FOR CLEANING AND RECOVERY OF THE POLLUTED CATALYST SOLUTION RESULTING FROM CARBONYLATING METHYL ACETATE AND / OR DIMETHYL ETHER
GB8618710D0 (en) * 1986-07-31 1986-09-10 Bp Chem Int Ltd Recovering metals
US4950629A (en) * 1988-12-27 1990-08-21 Eli Lilly And Company Process for catalyst recovery
DE3903909A1 (en) * 1989-02-10 1990-08-16 Hoechst Ag METHOD FOR REMOVING METALLIC CORROSION PRODUCTS FROM A POLLUTED CATALYST SOLUTION RESULTING FROM CARBONYLATING METHANOL AND / OR METHYL ACETATE AND / OR DIMETHYL ETHER

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7196227B2 (en) 2002-12-23 2007-03-27 Eastman Chemical Company Process for the recovery of phosphorus and iodine containing catalyst components

Also Published As

Publication number Publication date
KR100251252B1 (en) 2000-04-15
CA2092049C (en) 2000-10-31
JPH0784629B2 (en) 1995-09-13
KR930019557A (en) 1993-10-18
JPH0641653A (en) 1994-02-15
TW212144B (en) 1993-09-01
DE4210027A1 (en) 1993-09-30
ZA931987B (en) 1993-10-19
AU3545193A (en) 1993-09-30
AU656844B2 (en) 1995-02-16
MX9301572A (en) 1993-11-01
CN1077908A (en) 1993-11-03
BR9301283A (en) 1993-10-05
EP0564862A1 (en) 1993-10-13

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