CA2084570A1 - Manufacture of Ferric Sulphate Compounds - Google Patents
Manufacture of Ferric Sulphate CompoundsInfo
- Publication number
- CA2084570A1 CA2084570A1 CA2084570A CA2084570A CA2084570A1 CA 2084570 A1 CA2084570 A1 CA 2084570A1 CA 2084570 A CA2084570 A CA 2084570A CA 2084570 A CA2084570 A CA 2084570A CA 2084570 A1 CA2084570 A1 CA 2084570A1
- Authority
- CA
- Canada
- Prior art keywords
- closed vessel
- ferric
- liquid phase
- manufacture
- oxidation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G49/00—Compounds of iron
- C01G49/14—Sulfates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
A process is provided for the manufacture of ferric sulphate compounds from ferrous sulphate in a closed vessel containing a liquid phase and a vapour phase, the process comprising the oxidation of Fe++ to Fe+++ under pressure utilizing commercial oxygen in the closed vessel using NOx as a catalyst where x is a number between 1 and 2 inclusive of 1 and 2 and wherein the process comprises the following reactions:
1) (see fig. I) , and 2) (see fig. II) wherein n is any integer greater than or equal to two (2) and y is any integer which is equal to, or greater than zero (0) and less than 3n and wherein the oxidation of Fe++ is affected by spraying the liquid phase including a solution containing Fe++
introduced to the closed vessel, through a reacting cloud comprising NO, NO2 and O2 enclosed in the vapour space of the closed vessel and wherein substantially only Ferric ions is present in the liquid phase in the closed vessel relative to the amounts of Ferric and Ferrous ions prior to the addition of FeSO4.
1) (see fig. I) , and 2) (see fig. II) wherein n is any integer greater than or equal to two (2) and y is any integer which is equal to, or greater than zero (0) and less than 3n and wherein the oxidation of Fe++ is affected by spraying the liquid phase including a solution containing Fe++
introduced to the closed vessel, through a reacting cloud comprising NO, NO2 and O2 enclosed in the vapour space of the closed vessel and wherein substantially only Ferric ions is present in the liquid phase in the closed vessel relative to the amounts of Ferric and Ferrous ions prior to the addition of FeSO4.
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA000585382A CA1336856C (en) | 1988-12-08 | 1988-12-08 | Manufacture of hydroxylated ferric sulphate compounds |
US07/718,780 US5194241A (en) | 1988-12-08 | 1991-06-21 | Manufacture of hydroxylated ferric sulphate compound |
US07/765,498 US5194240A (en) | 1988-12-08 | 1991-09-26 | Manufacture of ferric sulphate |
CA002084570A CA2084570C (en) | 1991-06-21 | 1992-12-04 | Manufacture of ferric sulphate compounds |
US07/986,025 US5332565A (en) | 1988-12-08 | 1992-12-04 | Manufacture of ferric sulphate compounds |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/718,780 US5194241A (en) | 1988-12-08 | 1991-06-21 | Manufacture of hydroxylated ferric sulphate compound |
US07/765,498 US5194240A (en) | 1988-12-08 | 1991-09-26 | Manufacture of ferric sulphate |
CA002084570A CA2084570C (en) | 1991-06-21 | 1992-12-04 | Manufacture of ferric sulphate compounds |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2084570C CA2084570C (en) | 1994-06-05 |
CA2084570A1 true CA2084570A1 (en) | 1994-06-05 |
Family
ID=27169276
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002084570A Expired - Fee Related CA2084570C (en) | 1988-12-08 | 1992-12-04 | Manufacture of ferric sulphate compounds |
Country Status (1)
Country | Link |
---|---|
CA (1) | CA2084570C (en) |
-
1992
- 1992-12-04 CA CA002084570A patent/CA2084570C/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CA2084570C (en) | 1994-06-05 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed |