CA2079264A1 - Preceramic polymers incorporating boron - Google Patents

Preceramic polymers incorporating boron

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Publication number
CA2079264A1
CA2079264A1 CA002079264A CA2079264A CA2079264A1 CA 2079264 A1 CA2079264 A1 CA 2079264A1 CA 002079264 A CA002079264 A CA 002079264A CA 2079264 A CA2079264 A CA 2079264A CA 2079264 A1 CA2079264 A1 CA 2079264A1
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CA
Canada
Prior art keywords
boron
polysilazane
polymers incorporating
preceramic polymers
incorporating boron
Prior art date
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Granted
Application number
CA002079264A
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French (fr)
Other versions
CA2079264C (en
Inventor
Roger L. K. Matsumoto
Joanne M. Schwark
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Kion Corp
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Individual
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Publication of CA2079264A1 publication Critical patent/CA2079264A1/en
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Publication of CA2079264C publication Critical patent/CA2079264C/en
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Expired - Fee Related legal-status Critical Current

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    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/16Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers in which all the silicon atoms are connected by linkages other than oxygen atoms
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    • C04B35/515Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
    • C04B35/56Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides
    • C04B35/565Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on silicon carbide
    • C04B35/571Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on silicon carbide obtained from Si-containing polymer precursors or organosilicon monomers
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    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605Treating the starting powders individually or as mixtures
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    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/60Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which all the silicon atoms are connected by linkages other than oxygen atoms
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    • C08G79/00Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
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  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
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Abstract

A boron-substituted polysilazane in which the boron is derived from a borane and is bound to the polysilazane through boron-carbon bonds is disclosed. The polysilazane is prepared by reacting a silazane ammonolysis product containing at least one 2-6 carbon alkenyl or alkenyl group with a borane containing at least one B-H group per molecule. The boron-substituted polysilazane can be used to prepare silicon carbide-containing ceramic articles.
CA002079264A 1991-10-07 1992-09-28 Preceramic polymers incorporating boron Expired - Fee Related CA2079264C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/772,524 US5206327A (en) 1991-10-07 1991-10-07 Preceramic polymers incorporating boron and their application in the sintering of carbide ceramics
US772,524 1991-10-07

Publications (2)

Publication Number Publication Date
CA2079264A1 true CA2079264A1 (en) 1993-04-08
CA2079264C CA2079264C (en) 2003-12-30

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Application Number Title Priority Date Filing Date
CA002079264A Expired - Fee Related CA2079264C (en) 1991-10-07 1992-09-28 Preceramic polymers incorporating boron

Country Status (5)

Country Link
US (2) US5206327A (en)
EP (1) EP0536698B1 (en)
JP (1) JPH07207033A (en)
CA (1) CA2079264C (en)
DE (1) DE69211801T2 (en)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5635250A (en) * 1985-04-26 1997-06-03 Sri International Hydridosiloxanes as precursors to ceramic products
US5736477A (en) * 1989-05-22 1998-04-07 Hercules Incorporated Inorganic oxide resins for internal oxidation inhibition of carbon-carbon composites
US5558908A (en) * 1994-11-07 1996-09-24 Lanxide Technology Company, Lp Protective compositions and methods of making same
DE19735271C2 (en) * 1997-08-14 2000-05-04 Bosch Gmbh Robert Soft magnetic, mouldable composite material and process for its production
DE19741460A1 (en) * 1997-09-19 1999-03-25 Max Planck Gesellschaft Polymeric ceramic precursor preparation
DE19741458A1 (en) * 1997-09-19 1999-03-25 Max Planck Gesellschaft New boron-containing polysilazanes used as precursor compounds e.g., in production of ceramic bodies
DE19815978B4 (en) * 1998-04-09 2004-01-08 Forschungszentrum Karlsruhe Gmbh Process for the production of small and micro parts from ceramic
US6426127B1 (en) * 1999-12-28 2002-07-30 Electron Vision Corporation Electron beam modification of perhydrosilazane spin-on glass
DE60126736T2 (en) * 2000-08-31 2007-11-15 Az Electronic Materials Usa Corp. RADIATION SENSITIVE POLYSILAZAN COMPOSITION, PATTERN PRODUCED THEREOF, AND A METHOD OF SURFACING A CORRESPONDING COATING FILM
US7198747B2 (en) * 2000-09-18 2007-04-03 President And Fellows Of Harvard College Fabrication of ceramic microstructures
WO2004065316A2 (en) * 2002-08-20 2004-08-05 The Regents Of The University Of Colorado Polymer derived ceramic materials
US7326514B2 (en) * 2003-03-12 2008-02-05 Cornell Research Foundation, Inc. Organoelement resists for EUV lithography and methods of making the same
US7077991B2 (en) * 2004-02-06 2006-07-18 The Regents Of The University Of California Nanocomposites of silicon nitride, silicon carbide, and boron nitride
US7794557B2 (en) * 2004-06-15 2010-09-14 Inframat Corporation Tape casting method and tape cast materials
US20060141237A1 (en) * 2004-12-23 2006-06-29 Katherine Leighton Metal-ceramic materials
US8329830B2 (en) 2009-06-30 2012-12-11 3M Innovative Properties Company Surface treatment process and treated article
JP5813006B2 (en) 2009-12-22 2015-11-17 スリーエム イノベイティブ プロパティズ カンパニー Process for preparing storage stable curable polysilazane and polysilazane prepared thereby
CN102115539A (en) * 2010-12-31 2011-07-06 厦门大学 Preparation method for liquid polyborosilazane
US9701591B2 (en) * 2011-10-12 2017-07-11 United Technologies Corporation Method for fabricating a ceramic material
CA2880812C (en) * 2012-08-01 2020-10-27 Allied Mineral Products, Inc. Reinforced refractory containers
US9359479B2 (en) 2013-05-30 2016-06-07 General Electric Company Methods of using boron-containing additives as silicon carbide crosslinking agents
WO2015057394A1 (en) * 2013-10-15 2015-04-23 United Technologies Corporation Preceramic polymer for ceramic including metal boride
CN112573928B (en) * 2019-09-27 2023-01-13 郑州大学 Preparation method of boron-containing polymer precursor ceramic
CN114015059B (en) * 2021-11-10 2022-09-13 中国科学院宁波材料技术与工程研究所 High boron content carborane polymer and synthetic method thereof

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4108929A (en) * 1974-09-03 1978-08-22 General Electric Company Hot pressed silicon carbide
US4041117A (en) * 1975-06-30 1977-08-09 General Electric Company Silicon carbide sintered body
US4220600A (en) * 1977-10-26 1980-09-02 The Foundation: The Research Institute For Special Inorganic Materials Polycarbosilane, process for its production, and its use as material for producing silicon carbide fibers
US4482689A (en) * 1984-03-12 1984-11-13 Dow Corning Corporation Process for the preparation of polymetallo(disily)silazane polymers and the polymers therefrom
US4668642A (en) * 1984-09-11 1987-05-26 Dow Corning Corporation Ceramic materials from silazane polymers
FR2581391B1 (en) * 1985-05-06 1987-06-05 Rhone Poulenc Rech ORGANO-POLYSILAZANE COMPOSITION COMPRISING FREE RADICAL GENERATORS AND CROSSLINKABLE BY ENERGY SUPPLY
US4767728A (en) * 1986-07-30 1988-08-30 The United States Of America As Represented By The United States National Aeronautics And Space Administration Boron-containing organosilane polymers and ceramic materials thereof
US4851491A (en) * 1986-07-30 1989-07-25 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Boron-containing organosilane polymers and ceramic materials thereof
US4906763A (en) * 1987-02-13 1990-03-06 Paciorek Kazimiera J L Boron nitride preceramic polymers
US5045399A (en) * 1988-01-22 1991-09-03 Ethyl Corporation Organoborosilazane polymers
US4921925A (en) * 1988-06-30 1990-05-01 Ethyl Corporation Organoborosilazane polymers
US4962069A (en) * 1988-11-07 1990-10-09 Dow Corning Corporation Highly densified bodies from preceramic polysilazanes filled with silicon carbide powders
US4910173A (en) * 1989-04-14 1990-03-20 Ethyl Corporation Preceramic compositions and ceramic products
US4987201A (en) * 1989-06-05 1991-01-22 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Boron-carbon-silicon polymers and the ceramic thereof
US5171736A (en) * 1989-10-16 1992-12-15 Massachusetts Institute Of Technology Preceramic organosilicon-boron polymers
US5169908A (en) * 1991-12-20 1992-12-08 Dow Corning Corporation Curable boron modified hydropolysilazane polymers

Also Published As

Publication number Publication date
JPH07207033A (en) 1995-08-08
DE69211801D1 (en) 1996-08-01
DE69211801T2 (en) 1996-10-31
US5206327A (en) 1993-04-27
CA2079264C (en) 2003-12-30
US5386006A (en) 1995-01-31
EP0536698B1 (en) 1996-06-26
EP0536698A1 (en) 1993-04-14

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