CA2079264A1 - Preceramic polymers incorporating boron - Google Patents
Preceramic polymers incorporating boronInfo
- Publication number
- CA2079264A1 CA2079264A1 CA002079264A CA2079264A CA2079264A1 CA 2079264 A1 CA2079264 A1 CA 2079264A1 CA 002079264 A CA002079264 A CA 002079264A CA 2079264 A CA2079264 A CA 2079264A CA 2079264 A1 CA2079264 A1 CA 2079264A1
- Authority
- CA
- Canada
- Prior art keywords
- boron
- polysilazane
- polymers incorporating
- preceramic polymers
- incorporating boron
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 title abstract 2
- 229910052796 boron Inorganic materials 0.000 title abstract 2
- 229920000642 polymer Polymers 0.000 title 1
- UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical compound B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 abstract 4
- 229920001709 polysilazane Polymers 0.000 abstract 4
- 229910000085 borane Inorganic materials 0.000 abstract 2
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 238000005915 ammonolysis reaction Methods 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 239000000919 ceramic Substances 0.000 abstract 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 abstract 1
- 229910010271 silicon carbide Inorganic materials 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/16—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers in which all the silicon atoms are connected by linkages other than oxygen atoms
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
- C04B35/56—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides
- C04B35/565—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on silicon carbide
- C04B35/571—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on silicon carbide obtained from Si-containing polymer precursors or organosilicon monomers
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/62605—Treating the starting powders individually or as mixtures
- C04B35/6269—Curing of mixtures
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/60—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which all the silicon atoms are connected by linkages other than oxygen atoms
- C08G77/62—Nitrogen atoms
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
- C08G79/08—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing boron
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
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- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
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- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3224—Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
- C04B2235/3225—Yttrium oxide or oxide-forming salts thereof
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- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3244—Zirconium oxides, zirconates, hafnium oxides, hafnates, or oxide-forming salts thereof
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- C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
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- C04B2235/38—Non-oxide ceramic constituents or additives
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- C04B2235/3821—Boron carbides
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- C04B2235/383—Alpha silicon carbide
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- C04B2235/3873—Silicon nitrides, e.g. silicon carbonitride, silicon oxynitride
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- C04B2235/3886—Refractory metal nitrides, e.g. vanadium nitride, tungsten nitride
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- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/42—Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
- C04B2235/428—Silicon
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Ceramic Products (AREA)
- Silicon Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A boron-substituted polysilazane in which the boron is derived from a borane and is bound to the polysilazane through boron-carbon bonds is disclosed. The polysilazane is prepared by reacting a silazane ammonolysis product containing at least one 2-6 carbon alkenyl or alkenyl group with a borane containing at least one B-H group per molecule. The boron-substituted polysilazane can be used to prepare silicon carbide-containing ceramic articles.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/772,524 US5206327A (en) | 1991-10-07 | 1991-10-07 | Preceramic polymers incorporating boron and their application in the sintering of carbide ceramics |
US772,524 | 1991-10-07 |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2079264A1 true CA2079264A1 (en) | 1993-04-08 |
CA2079264C CA2079264C (en) | 2003-12-30 |
Family
ID=25095362
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002079264A Expired - Fee Related CA2079264C (en) | 1991-10-07 | 1992-09-28 | Preceramic polymers incorporating boron |
Country Status (5)
Country | Link |
---|---|
US (2) | US5206327A (en) |
EP (1) | EP0536698B1 (en) |
JP (1) | JPH07207033A (en) |
CA (1) | CA2079264C (en) |
DE (1) | DE69211801T2 (en) |
Families Citing this family (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5635250A (en) * | 1985-04-26 | 1997-06-03 | Sri International | Hydridosiloxanes as precursors to ceramic products |
US5736477A (en) * | 1989-05-22 | 1998-04-07 | Hercules Incorporated | Inorganic oxide resins for internal oxidation inhibition of carbon-carbon composites |
US5558908A (en) * | 1994-11-07 | 1996-09-24 | Lanxide Technology Company, Lp | Protective compositions and methods of making same |
DE19735271C2 (en) * | 1997-08-14 | 2000-05-04 | Bosch Gmbh Robert | Soft magnetic, mouldable composite material and process for its production |
DE19741460A1 (en) * | 1997-09-19 | 1999-03-25 | Max Planck Gesellschaft | Polymeric ceramic precursor preparation |
DE19741458A1 (en) * | 1997-09-19 | 1999-03-25 | Max Planck Gesellschaft | New boron-containing polysilazanes used as precursor compounds e.g., in production of ceramic bodies |
DE19815978B4 (en) * | 1998-04-09 | 2004-01-08 | Forschungszentrum Karlsruhe Gmbh | Process for the production of small and micro parts from ceramic |
US6426127B1 (en) * | 1999-12-28 | 2002-07-30 | Electron Vision Corporation | Electron beam modification of perhydrosilazane spin-on glass |
DE60126736T2 (en) * | 2000-08-31 | 2007-11-15 | Az Electronic Materials Usa Corp. | RADIATION SENSITIVE POLYSILAZAN COMPOSITION, PATTERN PRODUCED THEREOF, AND A METHOD OF SURFACING A CORRESPONDING COATING FILM |
US7198747B2 (en) * | 2000-09-18 | 2007-04-03 | President And Fellows Of Harvard College | Fabrication of ceramic microstructures |
WO2004065316A2 (en) * | 2002-08-20 | 2004-08-05 | The Regents Of The University Of Colorado | Polymer derived ceramic materials |
US7326514B2 (en) * | 2003-03-12 | 2008-02-05 | Cornell Research Foundation, Inc. | Organoelement resists for EUV lithography and methods of making the same |
US7077991B2 (en) * | 2004-02-06 | 2006-07-18 | The Regents Of The University Of California | Nanocomposites of silicon nitride, silicon carbide, and boron nitride |
US7794557B2 (en) * | 2004-06-15 | 2010-09-14 | Inframat Corporation | Tape casting method and tape cast materials |
US20060141237A1 (en) * | 2004-12-23 | 2006-06-29 | Katherine Leighton | Metal-ceramic materials |
US8329830B2 (en) | 2009-06-30 | 2012-12-11 | 3M Innovative Properties Company | Surface treatment process and treated article |
JP5813006B2 (en) | 2009-12-22 | 2015-11-17 | スリーエム イノベイティブ プロパティズ カンパニー | Process for preparing storage stable curable polysilazane and polysilazane prepared thereby |
CN102115539A (en) * | 2010-12-31 | 2011-07-06 | 厦门大学 | Preparation method for liquid polyborosilazane |
US9701591B2 (en) * | 2011-10-12 | 2017-07-11 | United Technologies Corporation | Method for fabricating a ceramic material |
CA2880812C (en) * | 2012-08-01 | 2020-10-27 | Allied Mineral Products, Inc. | Reinforced refractory containers |
US9359479B2 (en) | 2013-05-30 | 2016-06-07 | General Electric Company | Methods of using boron-containing additives as silicon carbide crosslinking agents |
WO2015057394A1 (en) * | 2013-10-15 | 2015-04-23 | United Technologies Corporation | Preceramic polymer for ceramic including metal boride |
CN112573928B (en) * | 2019-09-27 | 2023-01-13 | 郑州大学 | Preparation method of boron-containing polymer precursor ceramic |
CN114015059B (en) * | 2021-11-10 | 2022-09-13 | 中国科学院宁波材料技术与工程研究所 | High boron content carborane polymer and synthetic method thereof |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4108929A (en) * | 1974-09-03 | 1978-08-22 | General Electric Company | Hot pressed silicon carbide |
US4041117A (en) * | 1975-06-30 | 1977-08-09 | General Electric Company | Silicon carbide sintered body |
US4220600A (en) * | 1977-10-26 | 1980-09-02 | The Foundation: The Research Institute For Special Inorganic Materials | Polycarbosilane, process for its production, and its use as material for producing silicon carbide fibers |
US4482689A (en) * | 1984-03-12 | 1984-11-13 | Dow Corning Corporation | Process for the preparation of polymetallo(disily)silazane polymers and the polymers therefrom |
US4668642A (en) * | 1984-09-11 | 1987-05-26 | Dow Corning Corporation | Ceramic materials from silazane polymers |
FR2581391B1 (en) * | 1985-05-06 | 1987-06-05 | Rhone Poulenc Rech | ORGANO-POLYSILAZANE COMPOSITION COMPRISING FREE RADICAL GENERATORS AND CROSSLINKABLE BY ENERGY SUPPLY |
US4767728A (en) * | 1986-07-30 | 1988-08-30 | The United States Of America As Represented By The United States National Aeronautics And Space Administration | Boron-containing organosilane polymers and ceramic materials thereof |
US4851491A (en) * | 1986-07-30 | 1989-07-25 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Boron-containing organosilane polymers and ceramic materials thereof |
US4906763A (en) * | 1987-02-13 | 1990-03-06 | Paciorek Kazimiera J L | Boron nitride preceramic polymers |
US5045399A (en) * | 1988-01-22 | 1991-09-03 | Ethyl Corporation | Organoborosilazane polymers |
US4921925A (en) * | 1988-06-30 | 1990-05-01 | Ethyl Corporation | Organoborosilazane polymers |
US4962069A (en) * | 1988-11-07 | 1990-10-09 | Dow Corning Corporation | Highly densified bodies from preceramic polysilazanes filled with silicon carbide powders |
US4910173A (en) * | 1989-04-14 | 1990-03-20 | Ethyl Corporation | Preceramic compositions and ceramic products |
US4987201A (en) * | 1989-06-05 | 1991-01-22 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Boron-carbon-silicon polymers and the ceramic thereof |
US5171736A (en) * | 1989-10-16 | 1992-12-15 | Massachusetts Institute Of Technology | Preceramic organosilicon-boron polymers |
US5169908A (en) * | 1991-12-20 | 1992-12-08 | Dow Corning Corporation | Curable boron modified hydropolysilazane polymers |
-
1991
- 1991-10-07 US US07/772,524 patent/US5206327A/en not_active Expired - Lifetime
-
1992
- 1992-09-28 CA CA002079264A patent/CA2079264C/en not_active Expired - Fee Related
- 1992-10-06 DE DE69211801T patent/DE69211801T2/en not_active Expired - Fee Related
- 1992-10-06 EP EP92117039A patent/EP0536698B1/en not_active Expired - Lifetime
- 1992-10-07 JP JP4268564A patent/JPH07207033A/en active Pending
-
1993
- 1993-04-26 US US08/053,890 patent/US5386006A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JPH07207033A (en) | 1995-08-08 |
DE69211801D1 (en) | 1996-08-01 |
DE69211801T2 (en) | 1996-10-31 |
US5206327A (en) | 1993-04-27 |
CA2079264C (en) | 2003-12-30 |
US5386006A (en) | 1995-01-31 |
EP0536698B1 (en) | 1996-06-26 |
EP0536698A1 (en) | 1993-04-14 |
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