CA2079264A1 - Preceramic polymers incorporating boron - Google Patents

Preceramic polymers incorporating boron

Info

Publication number
CA2079264A1
CA2079264A1 CA002079264A CA2079264A CA2079264A1 CA 2079264 A1 CA2079264 A1 CA 2079264A1 CA 002079264 A CA002079264 A CA 002079264A CA 2079264 A CA2079264 A CA 2079264A CA 2079264 A1 CA2079264 A1 CA 2079264A1
Authority
CA
Canada
Prior art keywords
boron
polysilazane
polymers incorporating
preceramic polymers
incorporating boron
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002079264A
Other languages
French (fr)
Other versions
CA2079264C (en
Inventor
Roger L. K. Matsumoto
Joanne M. Schwark
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kion Corp
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2079264A1 publication Critical patent/CA2079264A1/en
Application granted granted Critical
Publication of CA2079264C publication Critical patent/CA2079264C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/16Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers in which all the silicon atoms are connected by linkages other than oxygen atoms
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/515Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
    • C04B35/56Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides
    • C04B35/565Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on silicon carbide
    • C04B35/571Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on silicon carbide obtained from Si-containing polymer precursors or organosilicon monomers
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605Treating the starting powders individually or as mixtures
    • C04B35/6269Curing of mixtures
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/60Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which all the silicon atoms are connected by linkages other than oxygen atoms
    • C08G77/62Nitrogen atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G79/00Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
    • C08G79/08Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing boron
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3224Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
    • C04B2235/3225Yttrium oxide or oxide-forming salts thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3244Zirconium oxides, zirconates, hafnium oxides, hafnates, or oxide-forming salts thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418Silicon oxide, silicic acids or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38Non-oxide ceramic constituents or additives
    • C04B2235/3817Carbides
    • C04B2235/3821Boron carbides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38Non-oxide ceramic constituents or additives
    • C04B2235/3817Carbides
    • C04B2235/3826Silicon carbides
    • C04B2235/383Alpha silicon carbide
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38Non-oxide ceramic constituents or additives
    • C04B2235/3817Carbides
    • C04B2235/3826Silicon carbides
    • C04B2235/3834Beta silicon carbide
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38Non-oxide ceramic constituents or additives
    • C04B2235/3817Carbides
    • C04B2235/3839Refractory metal carbides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38Non-oxide ceramic constituents or additives
    • C04B2235/3817Carbides
    • C04B2235/3839Refractory metal carbides
    • C04B2235/3843Titanium carbides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38Non-oxide ceramic constituents or additives
    • C04B2235/3852Nitrides, e.g. oxynitrides, carbonitrides, oxycarbonitrides, lithium nitride, magnesium nitride
    • C04B2235/386Boron nitrides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38Non-oxide ceramic constituents or additives
    • C04B2235/3852Nitrides, e.g. oxynitrides, carbonitrides, oxycarbonitrides, lithium nitride, magnesium nitride
    • C04B2235/3865Aluminium nitrides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38Non-oxide ceramic constituents or additives
    • C04B2235/3852Nitrides, e.g. oxynitrides, carbonitrides, oxycarbonitrides, lithium nitride, magnesium nitride
    • C04B2235/3873Silicon nitrides, e.g. silicon carbonitride, silicon oxynitride
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38Non-oxide ceramic constituents or additives
    • C04B2235/3852Nitrides, e.g. oxynitrides, carbonitrides, oxycarbonitrides, lithium nitride, magnesium nitride
    • C04B2235/3886Refractory metal nitrides, e.g. vanadium nitride, tungsten nitride
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/40Metallic constituents or additives not added as binding phase
    • C04B2235/404Refractory metals
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/42Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
    • C04B2235/428Silicon

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Ceramic Products (AREA)
  • Silicon Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A boron-substituted polysilazane in which the boron is derived from a borane and is bound to the polysilazane through boron-carbon bonds is disclosed. The polysilazane is prepared by reacting a silazane ammonolysis product containing at least one 2-6 carbon alkenyl or alkenyl group with a borane containing at least one B-H group per molecule. The boron-substituted polysilazane can be used to prepare silicon carbide-containing ceramic articles.
CA002079264A 1991-10-07 1992-09-28 Preceramic polymers incorporating boron Expired - Fee Related CA2079264C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/772,524 US5206327A (en) 1991-10-07 1991-10-07 Preceramic polymers incorporating boron and their application in the sintering of carbide ceramics
US772,524 1991-10-07

Publications (2)

Publication Number Publication Date
CA2079264A1 true CA2079264A1 (en) 1993-04-08
CA2079264C CA2079264C (en) 2003-12-30

Family

ID=25095362

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002079264A Expired - Fee Related CA2079264C (en) 1991-10-07 1992-09-28 Preceramic polymers incorporating boron

Country Status (5)

Country Link
US (2) US5206327A (en)
EP (1) EP0536698B1 (en)
JP (1) JPH07207033A (en)
CA (1) CA2079264C (en)
DE (1) DE69211801T2 (en)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5635250A (en) * 1985-04-26 1997-06-03 Sri International Hydridosiloxanes as precursors to ceramic products
US5736477A (en) * 1989-05-22 1998-04-07 Hercules Incorporated Inorganic oxide resins for internal oxidation inhibition of carbon-carbon composites
US5558908A (en) * 1994-11-07 1996-09-24 Lanxide Technology Company, Lp Protective compositions and methods of making same
DE19735271C2 (en) * 1997-08-14 2000-05-04 Bosch Gmbh Robert Soft magnetic, mouldable composite material and process for its production
DE19741460A1 (en) * 1997-09-19 1999-03-25 Max Planck Gesellschaft Polymeric ceramic precursor preparation
DE19741458A1 (en) * 1997-09-19 1999-03-25 Max Planck Gesellschaft New boron-containing polysilazanes used as precursor compounds e.g., in production of ceramic bodies
DE19815978B4 (en) * 1998-04-09 2004-01-08 Forschungszentrum Karlsruhe Gmbh Process for the production of small and micro parts from ceramic
US6426127B1 (en) * 1999-12-28 2002-07-30 Electron Vision Corporation Electron beam modification of perhydrosilazane spin-on glass
KR100804444B1 (en) * 2000-08-31 2008-02-20 에이제토 엘렉토로닉 마티리알즈 가부시키가이샤 Forming method of patterned polysilazane film and firing method of photosensitive polysilazane coating film
US7198747B2 (en) 2000-09-18 2007-04-03 President And Fellows Of Harvard College Fabrication of ceramic microstructures
US20060069176A1 (en) * 2002-08-20 2006-03-30 Bowman Christopher N Polymer derived ceramic materials
US7326514B2 (en) * 2003-03-12 2008-02-05 Cornell Research Foundation, Inc. Organoelement resists for EUV lithography and methods of making the same
US7077991B2 (en) * 2004-02-06 2006-07-18 The Regents Of The University Of California Nanocomposites of silicon nitride, silicon carbide, and boron nitride
US7794557B2 (en) * 2004-06-15 2010-09-14 Inframat Corporation Tape casting method and tape cast materials
US20060141237A1 (en) * 2004-12-23 2006-06-29 Katherine Leighton Metal-ceramic materials
US8324324B2 (en) * 2009-06-30 2012-12-04 3M Innovative Properties Company Composition and process for preparing curable organofluorine-modified polysilazanes, and polysilazanes prepared thereby
JP5813006B2 (en) 2009-12-22 2015-11-17 スリーエム イノベイティブ プロパティズ カンパニー Process for preparing storage stable curable polysilazane and polysilazane prepared thereby
CN102115539A (en) * 2010-12-31 2011-07-06 厦门大学 Preparation method for liquid polyborosilazane
US9701591B2 (en) * 2011-10-12 2017-07-11 United Technologies Corporation Method for fabricating a ceramic material
WO2014022725A2 (en) * 2012-08-01 2014-02-06 Allied Mineral Products, Inc. Reinforced refractory containers
US9359479B2 (en) 2013-05-30 2016-06-07 General Electric Company Methods of using boron-containing additives as silicon carbide crosslinking agents
EP3057925B1 (en) * 2013-10-15 2019-11-27 United Technologies Corporation Manufacturing process of a preceramic polymer for ceramic including metal boride
CN112573928B (en) * 2019-09-27 2023-01-13 郑州大学 Preparation method of boron-containing polymer precursor ceramic
CN114015059B (en) * 2021-11-10 2022-09-13 中国科学院宁波材料技术与工程研究所 High boron content carborane polymer and synthetic method thereof
CN118580735B (en) * 2024-08-05 2024-11-22 长沙民德消防工程涂料有限公司 A fire-proof and stain-resistant nano-silicon anion coating and a preparation method thereof

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4108929A (en) * 1974-09-03 1978-08-22 General Electric Company Hot pressed silicon carbide
US4041117A (en) * 1975-06-30 1977-08-09 General Electric Company Silicon carbide sintered body
GB2009196B (en) * 1977-10-26 1982-04-15 Res Inst For Special Inorganic Polycarbosilane process for its prudiction and its use as material for producing silicon carbide
US4482689A (en) * 1984-03-12 1984-11-13 Dow Corning Corporation Process for the preparation of polymetallo(disily)silazane polymers and the polymers therefrom
US4668642A (en) * 1984-09-11 1987-05-26 Dow Corning Corporation Ceramic materials from silazane polymers
FR2581391B1 (en) * 1985-05-06 1987-06-05 Rhone Poulenc Rech ORGANO-POLYSILAZANE COMPOSITION COMPRISING FREE RADICAL GENERATORS AND CROSSLINKABLE BY ENERGY SUPPLY
US4767728A (en) * 1986-07-30 1988-08-30 The United States Of America As Represented By The United States National Aeronautics And Space Administration Boron-containing organosilane polymers and ceramic materials thereof
US4851491A (en) * 1986-07-30 1989-07-25 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Boron-containing organosilane polymers and ceramic materials thereof
US4906763A (en) * 1987-02-13 1990-03-06 Paciorek Kazimiera J L Boron nitride preceramic polymers
US5045399A (en) * 1988-01-22 1991-09-03 Ethyl Corporation Organoborosilazane polymers
US4921925A (en) * 1988-06-30 1990-05-01 Ethyl Corporation Organoborosilazane polymers
US4962069A (en) * 1988-11-07 1990-10-09 Dow Corning Corporation Highly densified bodies from preceramic polysilazanes filled with silicon carbide powders
US4910173A (en) * 1989-04-14 1990-03-20 Ethyl Corporation Preceramic compositions and ceramic products
US4987201A (en) * 1989-06-05 1991-01-22 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Boron-carbon-silicon polymers and the ceramic thereof
US5171736A (en) * 1989-10-16 1992-12-15 Massachusetts Institute Of Technology Preceramic organosilicon-boron polymers
US5169908A (en) * 1991-12-20 1992-12-08 Dow Corning Corporation Curable boron modified hydropolysilazane polymers

Also Published As

Publication number Publication date
US5386006A (en) 1995-01-31
EP0536698A1 (en) 1993-04-14
EP0536698B1 (en) 1996-06-26
US5206327A (en) 1993-04-27
CA2079264C (en) 2003-12-30
DE69211801D1 (en) 1996-08-01
DE69211801T2 (en) 1996-10-31
JPH07207033A (en) 1995-08-08

Similar Documents

Publication Publication Date Title
CA2079264A1 (en) Preceramic polymers incorporating boron
GB1392685A (en) Production of shaped articles of silicon carbide and silicon ni tride
EP0389084A3 (en) Process for producing a polyborosilazane
CA2062218A1 (en) Silicon boron nitride ceramic and precursor compounds, a process for their preparation and their use
EP0490401A3 (en) Self-curing ceramicizable polysiloxanes
CA2004406A1 (en) Ceramic/fiber composite and process for its production
CA2025469A1 (en) Organic amide-modified polysilazane ceramic precursors
IL99189A0 (en) Self-reinforced silicon nitride ceramic body and a method of preparing the same
EP0278734A3 (en) Boron nitride preceramic polymers
WO1992001732A3 (en) Preceramic polysilazane compositions
GB1434136A (en) Sintered refractory material
KR940014258A (en) High Temperature Resistant Silicon Nitride Ceramic and Manufacturing Method Thereof
EP0497171A3 (en) Polycarbosilanes containing heteroatoms
EP0396146A3 (en) Ceramic preforms having high mechanical strength, a process for their preparation and metal matrix composites obtained therefrom
IL86690A (en) Copolymers containing si-n and si-si bonds,polycarbosilazanes obtained by pyrolysis of the said copolymers,and use of the said polycarbosilazanes for the preparation of silicon carbonitride
Seyferth et al. Polymeric aluminasilazane precursors for aluminosilicon nitride
JPS63117966A (en) Manufacture of boron nitride base sintered body
Atchekzai et al. Preparation of Borazine-Derived Monomers for the Fabrication of NB-Type Ceramic Materials
GB1469768A (en) Ceramic materials
Seyferth Organosilicon Polymers as Precursors for Silicon-Containing Ceramics. Technical Report
Tani et al. Method of Manufacturing Silicon Carbide-Based Materials and a Composition of Raw Materials Therefore
Laine et al. Organometallic Polymers as Precursors to Ceramic Materials: Silicon Nitride and Silicon Oxynitride.
JPS6337074B2 (en)
Sajgalik et al. Preparation and properties of fine Si sub 3 N sub 4 ceramics
Allor et al. Silicon nitride based ceramic composites

Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed