CA2077667A1 - Method of preparing aqueous dispersions of ethylene/.alpha.,.beta.-unsaturated carboxylic acid interpolymers - Google Patents

Method of preparing aqueous dispersions of ethylene/.alpha.,.beta.-unsaturated carboxylic acid interpolymers

Info

Publication number
CA2077667A1
CA2077667A1 CA 2077667 CA2077667A CA2077667A1 CA 2077667 A1 CA2077667 A1 CA 2077667A1 CA 2077667 CA2077667 CA 2077667 CA 2077667 A CA2077667 A CA 2077667A CA 2077667 A1 CA2077667 A1 CA 2077667A1
Authority
CA
Grant status
Application
Patent type
Prior art keywords
dispersions
ethylene
beta
unsaturated carboxylic
carboxylic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA 2077667
Other languages
French (fr)
Other versions
CA2077667C (en )
Inventor
Michael E. Rowland
Kenneth E. Springs
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Global Technologies LLC
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/44Preparation of metal salts or ammonium salts

Abstract

Aqueous dispersions of ethylene/~,.beta.-unsaturated carboxylic acid interpolymers (e.g., random ethylene/acrylic acid interpolymers) are formed using a mixture of bases at a concentration of at least 0.2 equivalents of base per mole of .alpha.,.beta.-unsaturated carboxylic acid. The dispersions have at least 10 weight percent dispersed solids and not more than 1 weight percent of the initial polymer in non-dispersed form. Preferred bases for use in forming the dispersions are ammonium hydroxide and/or alkali metal hydroxides. A mixture of ammonium hydroxide and potassium hydroxide is especially preferred for forming the dispersions with ethylene/acrylic acid interpolymers at an ammonium hydroxide: acrylic acid molar ratio of 1:1 and a potassium hydroxyde:
acrylic acid molar ratio in the range of 0.6-0.8:1. The dispersions are particularly useful in forming thin coatings of adhesive on substrates, such as paper and metal foil, using conventional techniques.
CA 2077667 1991-01-25 1992-01-24 Method of preparing aqueous dispersions of ethylene/.alpha.,.beta.-unsaturated carboxylic acid interpolymers Expired - Lifetime CA2077667C (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
US07646134 US5206279A (en) 1991-01-25 1991-01-25 Method of preparing aqueous dispersions of ethylene/α,β-unsaturated carboxylic acid interpolymers
US646,134 1991-01-25
PCT/US1992/000622 WO1992013012A1 (en) 1991-01-25 1992-01-24 METHOD OF PREPARING AQUEOUS DISPERSIONS OF ETHYLENE/α,β-UNSATURATED CARBOXYLIC ACID INTERPOLYMERS

Publications (2)

Publication Number Publication Date
CA2077667A1 true true CA2077667A1 (en) 1992-07-26
CA2077667C CA2077667C (en) 2004-05-04

Family

ID=24591907

Family Applications (1)

Application Number Title Priority Date Filing Date
CA 2077667 Expired - Lifetime CA2077667C (en) 1991-01-25 1992-01-24 Method of preparing aqueous dispersions of ethylene/.alpha.,.beta.-unsaturated carboxylic acid interpolymers

Country Status (8)

Country Link
US (2) US5206279A (en)
EP (1) EP0522146B1 (en)
JP (1) JP3146310B2 (en)
CA (1) CA2077667C (en)
DE (2) DE69231326D1 (en)
ES (1) ES2149171T3 (en)
FI (1) FI104087B1 (en)
WO (1) WO1992013012A1 (en)

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US7175904B2 (en) * 2003-08-28 2007-02-13 Congoleum Corporation Non-vinyl flooring and method for making same
JP4553624B2 (en) * 2004-04-16 2010-09-29 三井・デュポンポリケミカル株式会社 Aqueous dispersions and laminates
EP2374837B1 (en) * 2004-10-29 2016-07-20 E. I. du Pont de Nemours and Company Thermoplastic resin compositions suitable for use in transparent laminates
US7279513B2 (en) * 2004-11-19 2007-10-09 Nalco Company Preparation of neutralized ethylene-acrylic acid polymer dispersions and use in printing media for improvement of digital toner adhesion
US20070289693A1 (en) * 2006-06-15 2007-12-20 Anderson Jerrel C Thermoplastic resin compositions suitable for use in transparent laminates
US9765231B1 (en) * 2007-07-31 2017-09-19 Mad Dog Paint Products, Inc. Primer composition
US8129032B2 (en) 2008-02-01 2012-03-06 Exxonmobil Oil Corporation Coating compositions, coated substrates and hermetic seals made therefrom having improved low temperature sealing and hot tack properties
ES2410368T3 (en) 2008-07-16 2013-07-01 Trüb Emulsions Chemie Ag Process for producing thermoplastic solventless dispersions
EP2342239A4 (en) * 2008-10-31 2012-07-11 Du Pont High-clarity ionomer compositions and articles comprising the same
US20100166991A1 (en) 2008-12-30 2010-07-01 E.I. Du Pont De Nemours And Company High-clarity blended ionomer compositions and articles comprising the same
WO2010077428A8 (en) * 2008-12-31 2011-01-06 E. I. Du Pont De Nemours And Company Ionomer compositions with low haze and high moisture resistance and articles comprising the same
CN102686692B (en) 2009-09-25 2014-10-08 汉高股份有限及两合公司 For water-based adhesive polymer laminate to the metal substrate
JP5726597B2 (en) * 2011-03-30 2015-06-03 三井・デュポンポリケミカル株式会社 Aqueous dispersions and methods for producing the same, and laminate
US8907022B2 (en) 2011-09-01 2014-12-09 E I Du Pont De Nemours And Company Method to form an aqueous dispersion of an ionomer
KR20140090163A (en) * 2011-10-14 2014-07-16 미츠비시 폴리에스테르 필름 인코포레이티드 Laminate containing coated polyester film
US8841379B2 (en) 2011-11-07 2014-09-23 E I Du Pont De Nemours And Company Method to form an aqueous dispersion of an ionomer-polyolefin blend
US20130149930A1 (en) 2011-12-12 2013-06-13 E I Du Pont De Nemours And Company Methods to form an ionomer coating on a substrate
US9085123B2 (en) 2012-02-29 2015-07-21 E I Du Pont De Nemours And Company Ionomer-poly(vinylalcohol) coatings
JP2015516472A (en) 2012-02-29 2015-06-11 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーE.I.Du Pont De Nemours And Company Ionomer - poly (vinyl alcohol) blend and coating
US20130225021A1 (en) 2012-02-29 2013-08-29 E.I. Du Pont De Nemours And Company Highly viscous ionomer-poly(vinylalcohol) coatings
US10053597B2 (en) 2013-01-18 2018-08-21 Basf Se Acrylic dispersion-based coating compositions
RU2642423C2 (en) * 2013-03-15 2018-01-25 Акцо Нобель Коатингс Интернэшнл Б.В. Hybrid aqueous dispersions, composite latex emulsion of copolymer of (poly) ethylene and (meth) acrylic acid, hybrid organosilane composite latex emulsion of copolymer of (poly) ethylene and (meth) acrylic acid and coating compositions obtained therefrom
CN105102508A (en) * 2013-03-20 2015-11-25 李炳奭 Method for preparing environmentally friendly paper coating agent by using water dispersible resin of ethylene-(meth)acrylic acid polymer, and use thereof
US20150203615A1 (en) 2014-01-22 2015-07-23 E I Du Pont De Nemours And Company Alkali metal-zinc ionomer compositions
US20150203704A1 (en) 2014-01-22 2015-07-23 E I Du Pont De Nemours And Company Alkali metal-magnesium ionomer compositions
US9550930B2 (en) 2014-05-30 2017-01-24 Michelman, Inc. Thermal lamination adhesive coatings for use on substrates
US20170073540A1 (en) * 2015-09-15 2017-03-16 G3 Enterprises, Inc. Apparatus and Methods for Alternative Coatings Applicable to Metal
JP2018009272A (en) * 2016-07-12 2018-01-18 トゥーリンク スンディリアン ブルハドTwolink Sdn Bhd Accelerator free and high filler load nitrile glove

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US5206279A (en) * 1991-01-25 1993-04-27 The Dow Chemical Company Method of preparing aqueous dispersions of ethylene/α,β-unsaturated carboxylic acid interpolymers

Also Published As

Publication number Publication date Type
FI924254A0 (en) 1992-09-23 application
DE69231326T2 (en) 2000-12-28 grant
ES2149171T3 (en) 2000-11-01 grant
DE69231326D1 (en) 2000-09-14 grant
FI924254D0 (en) grant
JP3146310B2 (en) 2001-03-12 grant
WO1992013012A1 (en) 1992-08-06 application
FI104087B1 (en) 1999-11-15 grant
EP0522146B1 (en) 2000-08-09 grant
JPH05505644A (en) 1993-08-19 application
US5387635A (en) 1995-02-07 grant
FI924254A (en) 1992-09-23 application
CA2077667C (en) 2004-05-04 grant
EP0522146A1 (en) 1993-01-13 application
FI104087B (en) 1999-11-15 application
US5206279A (en) 1993-04-27 grant

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