CA2055397A1 - Bulk polymerization using specific metallocene catalysts for the preparation of cycloolefin polymers - Google Patents

Bulk polymerization using specific metallocene catalysts for the preparation of cycloolefin polymers

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Publication number
CA2055397A1
CA2055397A1 CA002055397A CA2055397A CA2055397A1 CA 2055397 A1 CA2055397 A1 CA 2055397A1 CA 002055397 A CA002055397 A CA 002055397A CA 2055397 A CA2055397 A CA 2055397A CA 2055397 A1 CA2055397 A1 CA 2055397A1
Authority
CA
Canada
Prior art keywords
bulk polymerization
preparation
metallocene catalysts
specific metallocene
cycloolefin polymers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002055397A
Other languages
French (fr)
Other versions
CA2055397C (en
Inventor
Michael-Joachim Brekner
Frank Osan
Juergen Rohrmann
Martin Antberg
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ticona GmbH
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2055397A1 publication Critical patent/CA2055397A1/en
Application granted granted Critical
Publication of CA2055397C publication Critical patent/CA2055397C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/602—Component covered by group C08F4/60 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F32/00—Homopolymers and copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
    • C08F32/08—Homopolymers and copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system having two condensed rings

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)

Abstract

Abstract of the disclosure Bulk polymerization using specific metallocene catalysts for the preparation of cycloolefin polymers Polymers of polycyclic olefins, such as, for example, norbornene or tetracyclododecene, or copolymers of polycyclic olefins with cycloolefins and/or 1-olefins are obtained without ring opening, in high space-time yield, with a high cycloolefin incorporation rate and at in-dustrially favorable polymerization temperatures, by bulk polymerization in which a catalyst is used which comprises an aluminoxane and a stereorigid chiral metal-locene compound of an element from groups IVb to VIb, where the hydrocarbon radicals forming the sandwich structure are different.
CA002055397A 1990-11-14 1991-11-13 Bulk polymerization using specific metallocene catalysts for the preparation of cycloolefin polymers Expired - Lifetime CA2055397C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4036264 1990-11-14
DE4036264.7 1990-11-14

Publications (2)

Publication Number Publication Date
CA2055397A1 true CA2055397A1 (en) 1992-05-15
CA2055397C CA2055397C (en) 2004-04-20

Family

ID=6418254

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002055397A Expired - Lifetime CA2055397C (en) 1990-11-14 1991-11-13 Bulk polymerization using specific metallocene catalysts for the preparation of cycloolefin polymers

Country Status (13)

Country Link
EP (1) EP0485893B1 (en)
JP (1) JP3247130B2 (en)
KR (1) KR100230915B1 (en)
AT (1) ATE165372T1 (en)
AU (1) AU641291B2 (en)
CA (1) CA2055397C (en)
CS (1) CS344291A3 (en)
DE (1) DE59108971D1 (en)
ES (1) ES2117632T3 (en)
HU (1) HUT59429A (en)
NO (1) NO914439L (en)
TW (1) TW227005B (en)
ZA (1) ZA918990B (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5602219A (en) * 1993-02-12 1997-02-11 Hoechst Aktiengesellschaft Process for preparing cycloolefin copolymers
US5637400A (en) * 1993-02-12 1997-06-10 Hoechst Aktiengesellschaft Cycloolefin copolymers having low melt viscosity and low optical attenuation
US5733991A (en) * 1993-02-12 1998-03-31 Hoechst Aktiengesellschaft Process for preparing cycloolefin polymer
US6214951B1 (en) 1993-02-12 2001-04-10 Hoechst Aktiengesellschaft Cycloolefin copolymers having high tear strength and low optical attenuation
US7205040B2 (en) 2003-11-10 2007-04-17 Mitsubishi Polyester Film Gmbh Peelable polyester film having improved oxygen barrier, process for its production and its use
US7829633B2 (en) 2002-09-13 2010-11-09 Ticona Gmbh Method for the production of a packaging made of thermoformable film having high thermal stability and a vapour barrier

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US5744664A (en) * 1990-07-05 1998-04-28 Hoechst Aktiengesellschaft Cycloolefin copolymers (COCS) as substrate material for liquid-crystal displays
DE59209568D1 (en) * 1991-02-27 1999-01-07 Ticona Gmbh Process for the preparation of cycloolefin (co) polymers with narrow molecular weight distribution
EP0594147A1 (en) * 1992-10-24 1994-04-27 Hoechst Aktiengesellschaft Cyclo-olefin copolymers as substrate material for liquid crystal displays
TW274100B (en) 1993-02-12 1996-04-11 Hoechst Ag
DE4304309A1 (en) * 1993-02-12 1994-08-18 Hoechst Ag Flexible cycloolefin copolymer film
EP0610850A1 (en) * 1993-02-12 1994-08-17 Hoechst Aktiengesellschaft Process for preparing cyclo-olefin polymers
DE4304308A1 (en) * 1993-02-12 1994-08-18 Hoechst Ag Rigid cycloolefin copolymer film
TW369545B (en) * 1993-02-12 1999-09-11 Hoechst Ag Process for preparing cycloolefin copolymers
DE4304285A1 (en) * 1993-02-12 1994-08-18 Hoechst Ag Cycloolefin copolymers with high tear resistance and low optical attenuation
DE4410559A1 (en) * 1994-03-26 1995-09-28 Hoechst Ag Oriented polyolefin film with amorphous polymer, process for its production and its use
DE4422157A1 (en) * 1994-06-24 1996-01-04 Hoechst Ag Process for the preparation of cycloolefin copolymers
DE4426185A1 (en) 1994-07-23 1996-01-25 Hoechst Ag Sealable oriented polyolefin multilayer film, process for its production and its use
DE4426184A1 (en) 1994-07-23 1996-01-25 Hoechst Ag Non-sealable oriented polyolefin multilayer film, process for its production and its use
DE19536043A1 (en) * 1995-09-28 1997-04-10 Hoechst Ag Polyolefin film with cycloolefin polymer, process for its production and its use
DE19539093A1 (en) 1995-10-20 1997-04-24 Hoechst Ag Metallized polyolefin film
DE19917790A1 (en) * 1999-04-20 2000-11-02 Hoechst Trespaphan Gmbh Biaxially oriented film for the production of ceramic capacitors
DE19929809A1 (en) 1999-06-30 2001-01-04 Ticona Gmbh Continuous process for the production of an amorphous polyolefin with a broad molar mass distribution and uniform glass temperature
DE10009646A1 (en) * 2000-03-01 2001-09-13 Ticona Gmbh Polymer mixture containing amorphous polyolefin, useful for preparing e.g. axially oriented films, has controllable relaxation and shrinkage properties
DE10012137A1 (en) 2000-03-13 2001-09-20 Mitsubishi Polyester Film Gmbh Biaxially oriented polyester film containing a cycloolefin copolymer, process for its production and its use
DE10022942A1 (en) 2000-05-11 2001-11-15 Mitsubishi Polyester Film Gmbh Mat white biaxially oriented polyester film, e.g. useful for food packaging, includes a cycloolefin copolymer
DE10026177A1 (en) 2000-05-26 2001-11-29 Mitsubishi Polyester Film Gmbh White, high-gloss polyester film containing cycloolefin copolymer (COC), process for its production and its use
DE10035328A1 (en) 2000-07-20 2002-01-31 Mitsubishi Polyester Film Gmbh Opaque polyester film containing cycloolefin copolymer (COC) with good surface adhesion, process for its production and its use
US6670423B2 (en) 2001-02-20 2003-12-30 E. I. Du Pont De Nemours And Company Polar ethylene-based polymer, cycloolefin polymer blends
US6696524B2 (en) 2001-02-20 2004-02-24 E. I. Du Pont De Nemours And Company Low Tg ethylene-based polymer, cycloolefin polymer blends
DE10137924B4 (en) 2001-08-07 2005-12-01 Ticona Gmbh Long fiber-reinforced polyolefin-plastic structure, process for its preparation and moldings produced therefrom
US6713582B2 (en) 2001-12-14 2004-03-30 Uniroyal Chemical Company, Inc. Process for the oligomerization of α-olefins having low unsaturation, the resulting polymers, and lubricants containing same
WO2003055678A1 (en) * 2001-12-21 2003-07-10 E.I. Du Pont De Nemours And Company Multilayer film
DE10223663A1 (en) 2002-05-28 2003-12-11 Mitsubishi Polyester Film Gmbh Transparent polyester film with improved water vapor barrier, process for its production and its use
DE10223662A1 (en) 2002-05-28 2003-12-11 Mitsubishi Polyester Film Gmbh Transparent polyester film with improved water vapor barrier, process for its production and its use
US7223459B2 (en) 2003-04-22 2007-05-29 Mitsubishi Polyester Film Gmbh Coextruded, hot-sealable and peelable polyester film, process for its production and its use
US7288312B2 (en) 2003-04-22 2007-10-30 Mitsubishi Polyester Film Gmbh Coextruded, hot-sealable and peelable polyester film having low peeling resistance, process for its production and its use
US7186452B2 (en) 2003-04-22 2007-03-06 Mitsubishi Polyester Film Gmbh Coextruded, hot-sealable and peelable polyester film having high peeling resistance, process for its production and its use
US7442427B2 (en) 2003-04-22 2008-10-28 Mitsubishi Polyester Film Gmbh Coextruded, hot-sealable and peelable polyester film, process for its production and its use
US7141293B2 (en) 2003-04-22 2006-11-28 Mitsubishi Polyester Film Gmbh Coextruded, hot-sealable and peelable polyester film having high peeling resistance, process for its production and its use
US7144615B2 (en) 2003-04-22 2006-12-05 Mitsubishi Polyester Film Gmbh Coextruded, hot-sealable and peelable polyester film, process for its production and its use
DE10352432A1 (en) 2003-11-10 2005-06-09 Mitsubishi Polyester Film Gmbh White, heat-sealable, peelable polyester film, process for its preparation and its use
DE10352431A1 (en) 2003-11-10 2005-06-09 Mitsubishi Polyester Film Gmbh Peelable polyester film with automatic venting, process for their preparation and their use
DE10352444A1 (en) 2003-11-10 2005-06-09 Mitsubishi Polyester Film Gmbh Adhesion-promoted, heat-sealable and peelable polyester film, process for its preparation and its use
US7288316B2 (en) 2003-11-21 2007-10-30 Topas Advanced Polymers, Inc. Cycloolefin copolymer heat sealable films
JP2004195246A (en) * 2004-02-13 2004-07-15 Mitsunobu Miyagi Laser probe
ES2397870T3 (en) 2006-10-05 2013-03-12 Treofan Germany Gmbh & Co. Kg Opaque film made of PLA simultaneously stretched
DE102007006825A1 (en) 2007-02-07 2008-08-14 Evonik Röhm Gmbh Plastic mold with anisotropic light scattering
DE102007055491A1 (en) 2007-11-21 2009-06-04 Mitsubishi Polyester Film Gmbh Low-density polyester film for polar substrates
KR101043657B1 (en) * 2008-09-23 2011-06-22 김명호 Wire Forming Equipment
WO2010096593A2 (en) 2009-02-18 2010-08-26 Northwestern University Beam pen lithography
US9452593B2 (en) 2010-04-15 2016-09-27 Topas Advanced Polymers, Inc. Melt blends of amorphous cycloolefin polymers and partially crystalline cycloolefin elastomers with improved toughness
DE102010030074A1 (en) 2010-06-15 2011-12-15 Evonik Degussa Gmbh Plastic photovoltaic module and method for its production
CN103025524A (en) 2010-07-27 2013-04-03 埃克森美孚石油公司 Film composition and method of making the same
WO2013036312A1 (en) 2011-08-19 2013-03-14 Avery Dennison Corporation Blends of ethylene copolymers and propylene based plastomers in multilayer films for low noise and rf welding
EP2918408A1 (en) 2011-12-22 2015-09-16 Avery Dennison Corporation Flexible Barrier Films Containing Cyclic Olefins
CN108189498B (en) 2012-01-31 2020-06-23 纳幕尔杜邦公司 Multilayer Film Containing Cyclic Olefin Copolymer
EP3452263B1 (en) 2016-03-11 2022-10-19 Polyplastics Usa, Inc. Injection stretch blow-molding (isbm) enhancement for semi-crystalline polyolefin containers utilizing alicyclic polyolefins
CN109071850B (en) 2016-05-12 2021-04-27 沙特基础工业全球技术有限公司 Capacitor film with high temperature resistance, its manufacturing method and its products
AR109065A1 (en) 2016-07-28 2018-10-24 Dow Global Technologies Llc MULTI-PAPER STRUCTURES, MULTI-PAPER FILMS AND FORMED CONTAINERS FROM THEM
US10951875B2 (en) 2018-07-03 2021-03-16 Raxium, Inc. Display processing circuitry
DE102018215422A1 (en) 2018-09-11 2020-03-12 Mitsubishi Polyester Film Gmbh Heat-sealable polyester film for the production of menu trays, processes for their production and their use
DE102019200365A1 (en) 2019-01-14 2020-07-16 Mitsubishi Polyester Film Gmbh Package made of polyester with a thermoformable bottom film and a sealable and peelable top film, process for their production and their use
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US11637219B2 (en) 2019-04-12 2023-04-25 Google Llc Monolithic integration of different light emitting structures on a same substrate
US11238782B2 (en) 2019-06-28 2022-02-01 Jasper Display Corp. Backplane for an array of emissive elements
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DE68911435T2 (en) * 1988-09-05 1994-04-28 Idemitsu Kosan Co Process for the production of a polymer.
DE3835044A1 (en) * 1988-10-14 1990-04-19 Hoechst Ag Process for the preparation of cycloolefin polymers
DE3922546A1 (en) * 1989-07-08 1991-01-17 Hoechst Ag METHOD FOR THE PRODUCTION OF CYCLOOLEFINPOLYMERS
DE3927257A1 (en) 1989-08-18 1991-02-21 Hoechst Ag METHOD FOR PRODUCING A POLYOLEFIN

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5602219A (en) * 1993-02-12 1997-02-11 Hoechst Aktiengesellschaft Process for preparing cycloolefin copolymers
US5637400A (en) * 1993-02-12 1997-06-10 Hoechst Aktiengesellschaft Cycloolefin copolymers having low melt viscosity and low optical attenuation
US5733991A (en) * 1993-02-12 1998-03-31 Hoechst Aktiengesellschaft Process for preparing cycloolefin polymer
US6214951B1 (en) 1993-02-12 2001-04-10 Hoechst Aktiengesellschaft Cycloolefin copolymers having high tear strength and low optical attenuation
US7829633B2 (en) 2002-09-13 2010-11-09 Ticona Gmbh Method for the production of a packaging made of thermoformable film having high thermal stability and a vapour barrier
US7205040B2 (en) 2003-11-10 2007-04-17 Mitsubishi Polyester Film Gmbh Peelable polyester film having improved oxygen barrier, process for its production and its use

Also Published As

Publication number Publication date
ZA918990B (en) 1992-07-29
HU913539D0 (en) 1992-01-28
JP3247130B2 (en) 2002-01-15
CS344291A3 (en) 1992-09-16
DE59108971D1 (en) 1998-05-28
TW227005B (en) 1994-07-21
ES2117632T3 (en) 1998-08-16
AU641291B2 (en) 1993-09-16
EP0485893A1 (en) 1992-05-20
JPH04268312A (en) 1992-09-24
HUT59429A (en) 1992-05-28
NO914439L (en) 1992-05-15
KR920009859A (en) 1992-06-25
EP0485893B1 (en) 1998-04-22
NO914439D0 (en) 1991-11-13
AU8777791A (en) 1992-05-21
CA2055397C (en) 2004-04-20
KR100230915B1 (en) 1999-11-15
ATE165372T1 (en) 1998-05-15

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