CA2045096A1 - Production of high viscosity index lubricants - Google Patents

Production of high viscosity index lubricants

Info

Publication number
CA2045096A1
CA2045096A1 CA2045096A CA2045096A CA2045096A1 CA 2045096 A1 CA2045096 A1 CA 2045096A1 CA 2045096 A CA2045096 A CA 2045096A CA 2045096 A CA2045096 A CA 2045096A CA 2045096 A1 CA2045096 A1 CA 2045096A1
Authority
CA
Canada
Prior art keywords
hydroisomerization
zeolite
feed
catalyst
typically
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA2045096A
Other languages
French (fr)
Other versions
CA2045096C (en
Inventor
Thomas F. Degnan
Dominick N. Mazzone
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mobil Oil AS
Original Assignee
Mobil Oil AS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil AS filed Critical Mobil Oil AS
Publication of CA2045096A1 publication Critical patent/CA2045096A1/en
Application granted granted Critical
Publication of CA2045096C publication Critical patent/CA2045096C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/64Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/10Lubricating oil

Landscapes

  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Lubricants (AREA)

Abstract

Petroleum waxes are converted to high viscosity index lubricants by a hydroisomerization process in which the wax feed is subjected to hydroisomerization over a low acidity zeolite isomerization catalyst which effects a preferential isomerization on the paraffin components in the feed to less waxy, high V.I. isoparaffins. The hydroisomerization is operated at high pressure, at least 1000 psig hydrogen partial pressure (reactor inlet) using a zeolite catalyst, preferably a noble metal containing zeolite beta catalyst which contains boron as a framework component of the zeolite to give a low alpha value, typically below 10. The hydroisomerization is carried out at a 650°F+ conversion in the range of 10 to 40 weight percent of the feed. A final dewaxing step to target pour point may be used with relatively low loss, typically no more than 15 weight percent, during this dewaxing. The final products typically have V.I. values in excess of 125 and usually in the range of 140 to 155 and are characterized by exceptional stability.
CA002045096A 1990-07-05 1991-06-20 Production of high viscosity index lubricants Expired - Lifetime CA2045096C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US54870190A 1990-07-05 1990-07-05
US548,701 1990-07-05

Publications (2)

Publication Number Publication Date
CA2045096A1 true CA2045096A1 (en) 1992-01-06
CA2045096C CA2045096C (en) 2000-08-29

Family

ID=24190035

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002045096A Expired - Lifetime CA2045096C (en) 1990-07-05 1991-06-20 Production of high viscosity index lubricants

Country Status (7)

Country Link
EP (1) EP0464546B1 (en)
JP (1) JP2954392B2 (en)
KR (1) KR0160780B1 (en)
AU (1) AU638336B2 (en)
CA (1) CA2045096C (en)
DE (1) DE69111315T2 (en)
ES (1) ES2077722T3 (en)

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EP0668342B1 (en) * 1994-02-08 1999-08-04 Shell Internationale Researchmaatschappij B.V. Lubricating base oil preparation process
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Also Published As

Publication number Publication date
EP0464546B1 (en) 1995-07-19
JPH04226593A (en) 1992-08-17
CA2045096C (en) 2000-08-29
EP0464546A1 (en) 1992-01-08
ES2077722T3 (en) 1995-12-01
AU7910991A (en) 1992-01-09
DE69111315T2 (en) 1996-01-11
AU638336B2 (en) 1993-06-24
KR0160780B1 (en) 1998-12-15
KR920002748A (en) 1992-02-28
DE69111315D1 (en) 1995-08-24
JP2954392B2 (en) 1999-09-27

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