CA2039446C

CA2039446C - Powders of plant green juice and process for their production

Info

Publication number: CA2039446C
Application number: CA002039446A
Authority: CA
Inventors: Yoshihide Hagiwara; Hideaki Hagiwara
Original assignee: Japan Natural Food Co Ltd
Current assignee: Japan Pharmaceutical Development Co Ltd
Priority date: 1991-03-28
Filing date: 1991-03-28
Publication date: 1999-03-16
Anticipated expiration: 2011-03-28
Also published as: CA2039446A1

Abstract

Powders of plant green juice having an improved stability and tastiness which are storable for a long period of time, characterized in that said powders comprise:
(a) dry powders of the plant green juice obtained by squeezing fresh raw edible green plants and (b) a water-soluble alkaline naturally occurring mineral mixture dispersed uniformly in said dry powder, and the pH of a dispersion at the time of dispersing in water falls into a range of 6.2-9.5. The powders can be produced by adding a water-soluble alkaline naturally occurring mineral mixture to a plant green juice obtained by squeezing fresh raw edible green plants thereby to adjust the pH of said plant green juice to be a range of 6-9 and then spray-drying or lyophilizing the green juice,

Description

~03~6 POWDERS OF PLANT GREEN JUICE AND PROCESS FOR
THEIR PRODUCTION
.
Detailed explanation of the invention:
This invention relates to powders of plant green juice. More specifically, the invention relates to powders of plant green juice having an improved tastiness which are storable for long and a process for their production.
If drying green leaves of any plant usually, this involves such phenomenon that generally the leaves are discolored into yellow or turn brown, etc. Further, it is well known that even if the leaves keep their green color for a short period of time after the production of powders, its dried product loses a green color during storage and involves a change such as browning, degene-ration or a change in smell.
The Inventors have hitherto made research works on the powderization of a plant green juice obtained by squeezing any plant having green leaves, its stabiliza-tion, its long-term storage method, etc. Its outcomes are reported in a process for producing powders of plant green juice taste having an improved drinkability (Japanese Patent Publication No. 46-36177), a process for producing powders of green leaves of barley and wheat (Japanese Patent Publication No. 46-38548), a process for producing powders of plant green juice (Japanese Patent Publication No. 46-41177) and other numerous scientific literatures.
The green color of green leaves and green plants is chlorophyll. It is also known that chlorophyll is converted into colorless phaeophytin by suffering from an action of ultraviolet rays, an acid, an enzyme (chlo-rophyllase), etc., in consequence of which a brown color and a red color of xanthophyll, carotenoid, ~lavonoid pigment and the like become notable.

~394~

In the above Japanese Patent Publn. No. 46-' 38548, etc. the Inventors have proposed a process for producing powders of plant green juice which are free from any unpleasant smell and which may be stored stably for a long period of time by adjusting the pH of the plant green juice obtainable by mechanicallly squeezing green leaves of barley and wheat or green plants to form plant green juice, adjusting the pH of the green juice to be 6-9 with an alkaline substance such as carbonate, bicarbonate or hydroxide of an alkali metal or an alkaline earth metal like sodium carbonate, potassium carbonate, sodium bicarbonate, caustic potash, ammonium hydroxide or magnesium hydroxide and then ~pray drying or lyophilizing the obtained green juice.
The powders of the plant green juice produced ' by the above proposed processes can be stored for a relatively long period of time, usually one to two years without causing the green color of the raw green juice to discolor or fade. However, nobody could settle defects as foodstuffs that acid components (various organic acids and an amino acid) contained in the green juice were neutralized by adding the above alkaline substance, thereby to cause a change in the inherent flavor of the green juice in combination with the taste of said alkaline substance per se and to degrade the tastiness of powders of the green juice. Moreover, it has been clarified by subsequent long-term research works that at the time of adding the above alkaline substance the following phenomena are promoted thereby to darken a green color of the green juice and degrade the brightness of a fresh, vivid green color inherent to the juice, i.e.
alkali metal chlorination or alkaline earth metal chlo-rination of chlorophyll contained in the green juice, saponification of fatty acid ester, reddish browning of flavonoid type pigments, etc The Inventors made their ardent research works 203~

with a view to overcoming the above difficulties involved at the time of adjusting the pH of the plant green juice with the above alkaline substance. As a result, they discovered that if making the pH adjustment of the plant green juice with a water-soluble alkaline naturally occurring mineral mixture obtained from an ashed product of any animal, plant or seaweeds, unexpectedly not only the above defect could be solved but also there were obtainable stable and long-term storable powders of the plant green juice which flavor and taste were increasea notably and which were excellent in the tastiness. This discovery led to the completion of the present invention.
Thus, the present inven-tion is to provide powders of plant green juice having an improved stability and tastiness which are storable for a long period of time, characterized in that said powders comprise:
(a) dry powders of the plant green juice obtained by squeezing fresh raw green edible plants and (b) an alkaline naturally occurring mineral mixture dispersed uniformly in said dry powder, and the pH of the dispersion at the time of dispersing it in water falls into a range of 6 to 9.5.
Further, the invention is to provide a process for the production of powders of plant green juice having an improved stability and tastiness which are storable for a long period of time, characterized in that a water-soluble alkaline naturally occurring mineral mixture is added to the plant green juice obtainable by squeezing fresh raw green edible plants thereby to adjust the pH of said plant green juice to be a range of 6-9.5 and then spray-drying or lyophilizing the neutralized green juice.
In the following paragraph the present inven-tion will be explained in more detail.
The green edible plants which become an object ~39~

of treatment in the invention incluae not only grownedible plants having green leaves or stems (hereinafter referred to as "leaves and stems") but also edible wild herbs and medicinal plant having green leaves and stems;
plants such as fruit vegetables, edible roots, cereals or fruits having leaves and stems which are not usually eaten; green edible seaweeds; etc. Their specific examples may include green leaves of barley and wheat, spinach, lettuce, cabbage, Chinese cabbage, potherb musturd, cucumber, balsam pear, green pepper, green leaves of carrot, green leaves of raddish, parsley, celery, Angelica keiskei Koidz, confree leaves, green leaves of forage grass such as alfalfa, clove~ or kale, leaves of low striped bamboo, leaves of persim~ons, leaves of pine tree, spirulina, chlorella. These plants can be used singly or may be used in combination of two kinds or more. ~bove all, are suitable green leaves (green stems and leaves) of whea~ and barley, especially wheat and barley during or before the full head stage, preferably wheat and barley during or before the heading initiation stage, more preferably wheat and barley in the tillering stage to the head stage, such as green leaves of barley, wheat, naked barley, oat, Italian rye grass, etc.
Further, green leaves of the barley in the above stage are optimum.
These wheat and barley can be used ~ingly and can be also used in combination with the above-mentioned other green plants as required~
It is desired that these green plants should be treated while they are as fresh as possible. Further, where using stored leaves, it is desirable to employ those which should be subjected to discoloration and degeneration preventing means such as storage in inert gas, storage at low temperatures, storage after dehydra-tion at reduced pressure or storage after treatment withsulfurous acid gas or sulfite. The green leaves employed &

as raw material are thoroughly washed to remove any adhering -materials. If desired, they are sterilized with a germicide such as hypochlorous acid and ~urther washed fully with water. Further, the washed material is sliced to be any proper size. Where slicing the material, the resultant slices may be used by immersing them in a dilute (for example 0.1-2.0%) saline solution) and then removing water. Further, at any optional stage of this pre-treatment the following treatment may be made, i.e. a blanching treatment is conducted for 2-10 seconds or so at temperatures of 100~ to 140~ C at ordinary pressure (optionally at reduced or elevated pressure) and then a rapid cooling treatment. This treatment serves to inactivate enzymes (for example, chlorophylase, peroxidase, polyphenoloxidase, etc.) which may consti-tute one cause of the undesirable discoloration, degeneration of the green plant, etc.
The so pretreated green plant is squeezed after adding a suitable amount of water thereby to extract a juice. This juice extraction can be easily performed in the way already known per se by combining any mechanical pulverization means like mixer or juicer with any means for liquid-solid seperation such as centrifugal separa-tion or filtration, pulverizing any edible green plant and then separating coarse solid matters from the pulverized product. In the so obtained green juice of the edible green plant its liquid quality is adjusted to be a pH o~ 6-9.5, preferably a range of 6.5-8.5, more pre~erably a range of 6.5-7.S in accordance with the present invention by using a water-soluble alkaline natural mineral mixture.
The water-soluble alkaline natural mineral mixture used according to the present invention can be a water-soluble, alkaline extract containing a mineral mixture derived from the above starting material which is obtainable by heating naturally occurring mineral raw '- %~

materials contained in seaweeds, the bod~ of any plant or its leaf portion, a whole of any animal individual or its skelton at temperatures of about 300~ to 1000~ C, pre-ferably about 450~ to 700~ C to make them into an ash and extracting its ashed product with water or an aqueous acid solution. Especially, this is suitably a water-soluble alkaline extract obtained from an ashed product of the seaweeds.
Thus, examples of the seaweeds available may include various kelps (Laminaria), an edible seaweed (Eisenia blcyclis), wakameseaweed (Undaria pinnatifida), kajimeseaweed (Ecklonia cava), a sea lentil (Sargasum fulvellum), a kind of brown algae (Hijikia fusiforme), Eucheuma muricatum, giant kelp, etc. Ashes obtained by ashing these seaweeds are extracted with water or an aqueous acid solution. At the time of this extraction can be used a process which is already known per se or processes disclosed in the following official gazettes can be utilized, for instance, i.e. Japanese Laid-Open (kokai) Patent Publns. Nos. 48~870~63, 51-121562~ 51-121553, etc. Examples of the extracts from such seaweed ashes may include an extracted solution obtained by extracting an ashed product of red algae belongining to Cigartinales of Florideophycidae disclosed in Japanese Laid-Open (kokai) Patent Publn. No. 51-121563 with an aqueous extracting agent like water or an aqueous acid solution or its dried product; an extracted solution of the seaweed ash obtained by extracting an ashed product of any optional seaweeds covering the whole range of edible seaweeds such as green algae, brown algae or red algae other than the above examples with an aqueous acidsolution or its dried product as disclosed in Japanese Laid-Open (kokai) Patent Publn. No. 51-121562;
an extracted solution of the seaweed ash obtained by extracting an ashed product of any optional seaweeds covering the whole range of edible seaweeds such as yreen - 2~39~

algae, brown algae or red algae with an aqueous acid solution or its dried product; an extracted solution obtained by combining an alkaline extracted solution formed at the time of water-extracting a seaweed ash with an acidic extracted solution obtained by water-extracting a water-insoluble residue formed at the time of this water-extraction under acidic conditions of pH 5.0 or less after adjusting the pH of one of these extracted solutions or the pH of both of these solutions to be in a range of 5.0 to 9.0 and then dryiny the extract as required or its dried product as disclosed in Japanese Laid-Open (kokai) Patent Publn. No. 48-87046; etc. The above extracts of the seaweed ashes show a strong alkalinity usually of pH 9.0 or more, mostly a range of pH 10-12 and contain a variety of useful minerals contained in seaweeds comprehensively and collectively.
Moreover, the above extracts exhibit strong buffer properties at the time of their neutralization with an acid. Thus, they proved to be very suitable as a pH
controlling agent for the green juice in the present invention.
The above water-soluble alkaline naturally occurring mineral mixture is added to the raw green juice of the above plant for making the pH adjustment of said raw green juice. Where using the above extract of seaweed ashes, this may be added in the form of an extracted solution or in the form of its dried product.
Its amount added is such as adjusting the pH of the raw green juice to be within a range of pH 9.5 preferably p~
6.5-8.5, more preferably pH 6.5-7.5.
The raw green juice which pH was so adjusted may be subjected to the drying step directly. However, various auxiliary ingredients as stated below can be incorporated before subjecting the green juice to the drying step or optionally before making the pH adjustment according to the use of the resultant powders of green juice, etc. That is:
(1) A dried powder (including those obtained by age-treating coarse solid matters of fibrous material with dilute acids before-hand and then drying them) of plant fibrous material such as a residue of fibrous material formed after squeezing the above green plant, a residue formed at the time of extracting a fruit juice, a residue formed at the time of squeezing a sugar canel a residue formed at the time of squee~ing vegetables, or water-soluble polysaccharides or mucopolysaccharides obtainable by decomposing these plant ~ibrous materials with a decomposition enzyme like cellulase.
(2) Lignin sulfonate obtained by decomposing wood chips, a pulp, a saw dust, rice hulls, de-fatted embryo buds, etc. with sodium sulfite or an alkali agent (e.g.
caustic soda) to be water-soluble and salts thereof.
~3) A water-extracted product of the water-solubilized matters such as skeltons or cartilages of animals, fishes or the like, condroitin sulfuric acid, heparin, etc.
(4) A fatty-containing emulsion consisting mainly of protein, an emulsion such as co~
milk, soybean milk, ~ry milk or defatted milk and an emulsion consisting of a proper combination of these fats.
(5) Phosphoric acid salts or polyphosphoric acid salts such as ammonium phosphate, diammonium phosphate, potassium phosphate, dipotassium phosphate, tripotassium phosphate~ preferably sodium phosphate, ~03~4~

disodium phosphate, trisodium phosphate, sodium polyphosphate, sodium metaphosphate, sodium pyrophosphate, potassium polyphosphate, potassium meta-phosphate, potassium pyrophosphate, etc.
(6) Nutritive agents such as ascorbic acid, biotin, calcium pantothenate, carotene, chlorinated choline, magnesium oxide, niacin, chlorinated pyridoxine, ribo-flavin, sodium pantothenate, thiamine hydrochloride, tocopherol, vitamin A, vitamin B12, vitamin D2 and the like;
masking agents such as sodium metaphos-phate, sodium phosphate (primary, secondary and tertiary salts), sodium pyrophosphate, sodium tripolyphosphate and the like; thickeners such as gum arabic, tragacanth, sodium alginate, methyl cellulose, carboxylmethyl cellulose, calcium alginate and the like; solidi-fication inhibitors such as calcium aluminum silicate or calcium silcate; and preservatives such as sorbic calcium, benzoic acid, paraoxymethyl benzoate, sodium benzoate and the like.
(7) Others:, mannitol, sorbitol, lactose, soluble starch, amino acids, dextrose, fruit sugar, dextrin, cyclodextrin, polydextrose and the like.
3Q Further, in the plant green juice treated by the process of the present invention undesirable enzymes pertaining in the discoloration and degeneration can be decomposed or inactivated, and at the same time, the sterilization of bacteria having a possibility to get mixed can also be performed by instantaneously heat treating the green juice in any optional stage after the 2~3~

extraction of green juice but before the drying treat-ment. This treatment can be performed at normal, reduced or elevated pressures. For example, conditions such as treatment temperatures of 9~~ to 150~ C and treatment time of the order of 180 seconds to 2 seconds according to heating temperatures. After this treatment, it is desirable to cool the juice rapidly especially at a temperature not higher than 10~ C.
As above, the plant green juice which pH was adjusted according to the process of the present inven-tion is spray-dried or lyophilyzed as rapidly as possible. The spray drying or lyophylizing operation can be effected in the way already known per se.
For instance, at the time of spray-drying the juice can be spray dried by heating with a hot air at temperatures of the order of 120~ to 200~ C, preferably at temperatures of the order of 140~ to 170~ C or at room temperature using a dry air desicated by a suitable desiccant such as lithium chloride. Further, at the time of lyophylizing are usually employed conditions of a dry plate such as a temperature of 40~ to 50~ C and a vacumm of the order of l.0 to 0.01 mm Hg.
Moreover, the concentration of green juice to be subjected to a drying step is in a range of the order of 1.5 to 30~ and is desirably as high as possible.
Therefore, for concentrating the green juice continuous film concentrating devices, vacuum concentrating devices, etc. can be utilized. Further, at the time of working the process of the present invention, if desired, discoloration and degeneration of plant green juice like green juice extracted from green leaves of wheat and barley during transportation or storage can be prevented until it is subjected to a drying step, by the steps, used either alone or in combination, of replacing air with an inert gas such as nitrogen or argon, sealing an oxygen absorbent such as glucoseoxidase, maintaining it at cold temperatures and shutting off light.
In the above drying step there is some case where a low-boiling-point organic acid in the green juice or the like disappears and the pH at the time of dissolving the resultant powder in water usually somewhat increases depending on the drying conditions. Thus, said pH may usually fall into a range of 6.2 to 9.5.
In accordance with the above-mentioned process it is possible to produce powders of plant green juice 10 Comprising (a~ dry powders of the plant green juice obtained by squeezing fresh raw green edible plants, and tb) an alkaline naturally occurring mineral mixture dispersed uniformly in said dry powder, preferably water-extracted matters of seaweed ashes, and the pH of a dispersion at the time of dispersing in water being within a range of 6-9.5, preferably 6.5-8.5, especially preferably 6.5-7.5.
The green juice provided by the present inven-tion can aim at an increase in the flavor and taste of powders of the green juice obtained by using a water-soluble alkaline naturally occurrin~ mineral mixture, especially water-extracted matters of seaweed ashes as a pH controlling agent, said increase in the ~lavor and taste of powders being quite unattainable by the use of hitherto used chemical alkaline agents such as sodium carbonate or calcium hydro~ide. Thus, the green juice of 3~ the present invention is very rich in tastiness. ~ore-over, this green juice has a notably excellent stability~
compared with powders of green juice produced by the above conventional method. The green juice of the invention can maintain an inherent green color of the 3~ juice even if stored ~or a long period of time, e.g. 3 to 4 years. Thus, the green powders of the invention can be 2~3~4~

offered for drinking directly or after blending with water, war~ water, plain soda, cider, cow milk or other beverages. Further, the above green powders can be used by incorporating them in various foodstuffs as food additives. Moreover, they contain not only a wide variety of useful minerals abundantly to be introduced by an alkaline naturally occurring mineral mixture which is added in addition to vitamins and minerals derived from the starting plants but also an essential fatty acid and any other substance having a medicinal effect. They can be utilized effectively in the field of the drugs.
If desired, table salt, sugar, bee honey, glucose and other seasonings or spices can also be incorporated appropriately in the powders of the plant green juice of the invention. Examples of other additives incorporated may include vitamins, anti-oxidants such as d-isoascrobic acid, l-isoascrobic acid, propyl gallate, butyl hydroxy anisole or butyl hydroxy toluene, food antiseptics such as dehydroacetic acid and its sodium salt, or benzoic acid and its sodium salt, and emulsifiers such as sucrose fatty acid esters or sorbitan fatty acid esters. The plant green juice of the inven-tion can be formed into granules, pellets, coated tablets, capsules and other various forms.
The present invention will be explained more concretely by way of the following examples.

Fresh green leaves of barley were reaped and its 10 Kg was thoroughly washed. The above green leaves were washed well with a liquid of a commercially available cleaner for foods dissolved in a suitable amount of water, dehydrated and pulverized by means of a mixer. By squeezing the green leaves were produced nine liters of green juice (pH of 6.4, containing 410 g of a dried product of the extract). Separately, a dry kelp was made into an ash at 600~ C, watered and extracted aO3~ 4~6 thereby to prepare a water-extracted solution of the kelp ash. The resultant water-extracted solution was added to the above green juice thereby to neutralize the juice to a pH 7Ø Then its spray-drying was conducted at a blowing temperature of 170~ C to produce 405 g of an object green juice powder (yield of about 97%).

A total (10 kg) of two kilograms of fresh green leaves of barley, two kilograms of fresh green leaves of wheat, two kilograms of fresh green leaves of rye, two kilograms of spinach, one kilogram of Chinese cabbage and one kilogram of cabbage were washed well in water and squeezed with a juicer thereby to produce 9.5 liters of green juice (pH of 6.3, containing 450 g of a dried product of the extract). While, Eucheuma, one kind of red algae, was dried and made into an ash at 550~ C.
Water-souble components were extracted thereby to prepare an aqueous strongly alkaline naturally occurring mineral solution of pH 11.2. Using this aqueous solution 9.5 liters of the above green juice was neutralized to be a pH 7.2 and this was concentrated to be three liters by means of a continuous concentrating device. To the concentrate were added 400 g of dextrin and 400 g of lactose. Moreover, 400 g of a water-soluble fiber was added to the mixture, said water-soluble fiber being obtained by adding cellulase to a residue of fibrous material formed after squeezing an orange juice and decomposing it enzymatically. The resultant aqueous mixture was spray-dried thereby to produce 1,460 g of an object green juice powder.

A total (10 kg) of one kilogram of green pepper, one kilogram of cucumber, one kilogram of celery, one kilogram of leaves of carrot, two kilograms of spinach and four kilograms of green leaves of barley were washed well in water and extracted with a squeezer thereby to ~3~

produce 9.5 liters of green juice (pH of 6.1, containing 415 g of a dried ~roduct of the extract). Separately, a dry kelp was made into an ash at 600~ C, watered and extracted thereby to prepare an aqueous strongly alkaline naturally occurring mineral soultion. To the above green juice was added this aqueous alkaline soultion thereby to adjust the pH of the juice to be 6.9. Successively, 400 g of cyclodextrin, 200 g of lactose, 200 g of defatted milk, 100 g of gum arabic powder and ~00 g o~ powders of synthetic water-soluble fiber were added to the juice, followed by mixing them and solving the mixture. The resultant mixture was spray-dried thereby to produce 1,630 g of an object green juice powder.
EX~MPLE 4 As in the above Example 1 an aqueous strongly alkaline naturally occurring mineral solution (pH of 11.0) obtained by water extracting water-soluble compo-nents in rice hulls made into an ash at 500~ C was added to 4.6 liters of green juice (pH of 6.3, containing 210 g of a dried product Gf the extract) obtained from 5 kg of green leaves of barley thereby to adjust the pH of the green juice to be 7Ø Separately, 100 g of lignin sodium sulfonate obtained by decomposition solubilizing wood chips with sodium sulfite, 200 g of dextrin and 100 g of dry powders of Chinese cabbage were added to the juice and mixed. The resultant mixture was spray-dried thereby to produce 560 g of an object green juice powder.
EX~MPLE 5 Five kilograms of Chinese cabbage and five kilograms of spinach were washed well in water, pulver-ized with a mixer and squeezed to produce nine liters of green juice (pH of 6.3, containing 210 g of a dried product of the extract). To this were added 450 g of lactose and 450 g of cyclodextrin, followed by mixing them and solviny the mixture. To this mixture was added an aqueous alkaline naturally occurring mineral solution obtained by carbonizing an oak wood at 800~ C to produce 1.5 kg of a carbide and then eluting minerals in the carbide with five liters of wa~er thereby to adjust its pH to be 7Ø As in Example 1 the resultant mixture was spray-dried thereby to produce 1,250 g of an object vegetable green juice powder.
EX~PLE 6 Five kilograms of spinach and five kilograms of green pepper were extracted with a squeezer thereby to produce nine liters of green juice (pH of 6.1, containing 470 g of a dried product of the extract). To this green juice was added an aqueous alkaline naturally occurring mineral soultion having a pH of 11.2 obtained by carbon-izing a dry kelp at 700~ C and then adding water to elute minerals in the kelp and the p~ of the green juice was adjusted to be 7.2. Successively, lO0 g of glucose, 50 g of bee honey, 470 g of dextrin, 235 g of defatted milk and 200 g of water-soluble components (mainly water-soluble cellulose) obtainable by boil-sterilizing a mushroom, then adding cellulose to this at 35~ C for five hours and then decompositon solubilizng the mixture were mixed and solved. To the resultant mixture were added one gram of vitamin E and five grams of vitamin C. The green juice was further neutralized to be 7.0 with the above aqueous alkaline naturally occurring mineral soultion and was lyophylized thereby to produce l,380 g of an ohject vagetable powder.
[Storage stability testing of green juice powders]
As to the storage stability of green juice powders obtained by the above Examples 1-6 the content of chlorophill was determined in accordance with the following method.
Determination method of chlorophyll By weighing one gram of a sample 30 ml of 85%
acetone is added to the sample. After conducting a supersonic extraction the liquid is allowed to stand and ~394~6 the resultant supernatant is transferred to a beaker.
The same operation is repeated until the liquid would not get colored any longer. Whereby the supernatant is collected. The extracted solution is collected.
The extracted solution is transferred to a separatory funnel in which 50 ml of ethyl ether is put beforehand and 50 ml of 5% sodium sulfate is added to the funnel.
Then the funnel is shaked gently thereby to discharge an aqueous phase. ~n anhydrous sodium sulfate is added to the funnel and the mixture is dehydrated and filtered.
Then ethyl ether is added to the filtrate thereby to bring its total amount to 100 ml exactly. This is used as a sample solution. This sample solution is determined as to the absorbance at 660 nm and 642.5 nm. And the 1~ overall chlorophyll content is calculated in accordance with the following formula:
Overall chlorophyll (mg/l) =
7.12xA660+16 8xA6~2.5 The results obtained are shown in Table 1 below.

Table 1 Change in the overall chlorophyll pH at the time of dis-content in 100 g in the storage solving 2 g of the sample Overall chloro- testing (4~C) in 100 ml of distilled phyll content water after two years Example in 100 g After one year After two years from production l 1450 mg 1420 mg 1305 mg pH 7.2 2 290 mg 284 mg 275 mg pH 7.~
3 261 mg 253 mg 245 mg pH 7.3 4 478 mg 454 mg 445 mg pH 7.1 295 mg 282 mg 274 mg pH 7.1 6 246 mg 233 mg 231 mg pH 7.0 C~~

2~3~

[Tastiness testing of green juice powders]
Three grams of the green juice powder obtained by Example 3 was dissolved in 150 ml of water. And tastiness evaluation testing of the green juice powder was conducted by letting 25 women and 20 men drink the juice.
A comparison of the tastiness was made using a solution of 3 g of the green juice powder obtained by Example 3 dissolved in 150 ml of water and the green juice powder produced by adjusting the green juice to be neutral with Na2CO3 and NaOH instead ~f a naturally occurring mineral mixture in the process of Example 3.
The results obtained are shown in Table 2 below.

. .
Table 2 The green juice is The green juice The green juice fresh, slight and has a bad smell has a soap smell easy to drink and hard to drink and taste When adjusting the green juice to be neutral with a naturally 43 persons2 persons No person occurring mineral (45 persons) When adjusting the green juice to be neutral with Na2CO3 15 persons20 persons lQ persons (45 persons) When adjusting the green juice to be neutral with NaOH 7 persons25 persons 13 persons ~45 persons)

Claims

1. Powders of plant green juice having an improved stability and tastiness which are storable for a long period of time, characterized in that the powders comprise:
(a) dry powders of the plant green juice obtained by squeezing fresh raw edible green plants and (b) a water-soluble alkaline naturally occurring mineral mixture dispersed uniformly in the dry powder, and the pH of a dispersion at the time of dispersing in water falls into a range of 6-9.5.

2. The powders of plant green juice according to claim 1 wherein the edible green plants are one kind or two or more kinds selected from the group consisting of an edible grown plant, wild grasses and a medicinal plant having green leaves and stems; fruit vegetables, edible roots, cereals and a fruit plant having leaves and stems which are not usually eaten; and green edible seaweeds.

3. The powders of plant green juice according to claim 1 wherein the edible green plants comprise green leaves of barley and wheat.

4. The powders of plant green juice according to claim 3 wherein the barley and wheat are selected from the group consisting of barley, wheat, naked barley, oat and Italian rye grass.

5. The powders of plant green juice according to claim 1 wherein the alkaline naturally occurring mineral mixture is a water-soluble alkaline extract obtained from an ashed product of seaweeds.

6. The powders of plant green juice according to claim 5 wherein the alkaline naturally occurring mineral mixture is an alkaline extract obtained where a seaweed ash formed by ashing seaweeds at temperatures of about 300° to about 1,000° C is extracted with water or an aqueous acid solution.

7. The powders of plant green juice according to claim 5 wherein said extract exhibits an alkality of pH
10-12.

8. The powders of plant green juice according to claim 1 wherein the pH of said dispersion is within a range of 6.5-8.5.

9. A process for the production of powders of plant green juice having an improved stability and tastiness which are storable for a long period of time, characterized by adding a water-soluble alkaline naturally occurring mineral mixture to a plant green juice obtained by squeezing fresh raw edible green plants thereby to adjust the pH of said plant green juice to be a range of 6-9 and then spray-drying or lyophilizing the green juice.

10. The process according to claim 9 wherein said edible green plants are one kind or two or more kinds selected from the group consisting of an edible grown plant, wild grasses and a medicinal plant having green leaves and stems; fruit vegetables, edible roots, cereals and a fruit plant having leaves and stems which are not usually eaten; and green edible seaweeds.

11. The process according to claim 9 wherein said edible plants comprise green leaves of barley and wheat.

12. The process according to claim 11 wherein said barley and wheat are selected from the group consisting of barley, wheat, naked barley, oat and Italian rye grass.

13. The process according to claim 9 wherein the alkaline naturally occurring mineral mixture is a water-soluble alkaline extract obtained from an ashed product of seaweeds.

14. The process according to claim 13 wherein the alkaline naturally occurring mineral mixture is an alkaline extract obtained where a seaweed ash formed by ashing seaweeds at temperatures of about 300° to about 1,000° C is extracted with water or an aqueous acid solution.

15. The process according to claim 9 wherein the pH
of said dispersion is so adjusted as to fall into a range of 6.5-8.5.

16. The process according to claim 9 wherein said plant green juice is subjected to an instantaneous heating treatment before drying.

17. The process according to claim 16 wherein said plant green juice is treated at 90° to 150° C for 180 to 2 seconds.