CA2035219A1 - No-till liquid herbicide and fertilizer suspension - Google Patents

Abstract

1826 Burdick Case 8 No-Till Liquid Herbicide and Fertilizer Suspension Abstract of the Disclosure A liquid fertilizer composition suitable for no-till farming contains a stabilizing amount of an admixture of calcium chloride and ammonium polyphosphate. As an improvement over clay suspensions, this liquid fertilizer can be used for one pass planting and herbicide application.
Higher amounts of potash can be incorporated in the liquid fertilizer along with sulphur and nitrogen nutrients.

Description

;~03S2~
This invention relates to liquid applications of fertilizer and herbicides for agriculture. In particular, the invention relates to the use of calcium chloride as a liquid suspension agent.
The high levels of productivity achieved in modern agriculture have been largely the result of quite recent knowledge gained on effective means of applying sprays of fertilizers and herbicides. No-till farming is a new area in which soil is preserved and fertilizer requirements lowered by killing residual plants with a topical herbicide and using a seed drill to insert seed and spray nozzles to apply liquid fertilizer. But even this method of farming is limited by the requirement for separate applications of herbicide and fertilizer due to the incompatibility of the herbicide with the fertilizer suspending agent. As a result, two passes are required over the field instead of one which would be possible if a new suspending agent were available, which was not incompatible with herbicide. U.S.
Patent 4,874,854 discloses comparative examples of polymers which are incompatible with the herbicide paraquat.
U.S. Patents 3,526,495, 3,679,390 and 4,315,763 teach that a wide variety of calcium salts cause gelling and thickening of fertilizers, similar to iron salts as described in U.S. Patents 4,056,381 and 4,336,053. The first three references teach the equivalency of calcium chloride with other calcium salts, while a combination of all five references would suggest to a person of ordinary skill in the art that both calcium and iron salts can perform the same functions as fertilizer suspending agents.
U.S. Patent 4,118,218 discloses a process for preparing granular herbicidal compositions using an inert sodium or calcium chloride carrier.
U.S. 3,526,495 and U.S. 3,679,390 further illustrate that the present invention represents a long sought after 203s~.g result on which considerable time and effort has been expended. Whereas all prior art practitioners had the same goals and all materials were readily available, their disclosures all teach away from the discovery contained herein.
When clay is used as a suspending agent for fertilizer, the suspension produced has limited stability and tends to settle in about 24 hours. Thus, when trucks are not able to go into fields to spray the liquid fertilizer because of rain, it is necessary to unload the trucks and remix the liquid fertilizer. Therefore, it would be an advance in the state-of-the-art to have a liquid fertilizer composition which would not settle even if weather or mechanical delays put off field application.
A separate problem with clay suspensions is that they are difficult to prepare. While clay is readily available and low cost material, preparation of the clay suspension is both time consuming and labor intensive. Thus it would be a further advance to be able to use a low cost and readily available suspension agent which could avoid the shortcomings of clay.
Clay is known to be a useful absorbent. However, this property is detrimental when clay removes effective amounts of herbicide from a suspension. Thus a new type of suspension in which both fertilizer and herbicide could be applied from one composition would be a monumental advance for agriculture.
A further disadvantage of prior art clay suspensions of liquid fertilizers is the inability to incorporate desirable quantities of potash (potassium chloride) without encountering precipitation problems. As a practical limit it is difficult to prepare a clay suspension containing more than 10% by weight potash. Thus, the availability of a suspending agent which would allow incorporation of more than 10~ by weight potash IA ~he liquid ~ertilizer would be , 20352~ ~
a significant advance. It would not have been apparent to employ calcium chloride for such a purpose in view of literature reports that precipitation rather than suspension would occur.
It is known that individual calcium salts are capable of performing unique functions; wherein other calcium salts are ineffective. U.S. Patent 4,859,208 discloses and claims calcium citrate in a print paste composition.
The invention provides a liquid fertilizer composition which can additionally contain an herbicide in which a suspending agent is produced by mixing ammonium polyphosphate with calcium chloride prior to the addition of potash.
The process of the invention involves the steps:
(1) mixing calcium chloride with ammonium polyphosphate for a time sufficient to prepare a solution; and (2) adding potash (potassium chloride) to the solution to prepare a storage stable liquid fertilizer suspension.
Water may be added as a separate addition in step (2).
The composition and process of the invention have further utility when additions of other nitrogen and sulphur sources and/or herbicide are incorporated in a storage stable liquid which can be used to increase agricultural production and/or lower costs and labor associated with modern productivity.
The unique liquid fertilizer composition and process of its production is a novel property of calcium chloride in distinction to other water soluble calcium salts. This was completely unexpected in view of numerous references which instructed a person of ordinary skills in the art that equivalent results could be achieved according to literature ~035~ 9 references which allow selection of any one af the following calcium salts: nitrate, citrate, tartrate, sulphur, phosphate, chloride, acetate, bromide, carbonate, etc.
In fact, it was only after more than sixty different metal salts were evaluated as suspending agents that it was discovered that calcium chloride provided a new and useful composition of matter. It was surprising to find that calcium nitrate, calcium citrate, calcium acetate, calcium formate and calcium sulfate simply did not give similar results. Typically one to two minutes are required to mix aqueous calcium chloride with ammonium polyphosphate in comparison to the many hours required to swell and mix clay in preparing prior art sllspensions.
While it is not known with certainty, it is believed that a complex is formed when calcium chloride and ammonium polyphosphate are mixed in practicing the present invention. This complex would correspond to the original formula Ca(NH4)2 P2 7 having some degree of hydration.
U.S. 3,526,495 makes disclosure of reacting calcium slag at a temperature between 140F and 130F. The unexpected nature of the present invention is clearly indicated in this reference where it is stated that calcium chloride is suitable for forming a thixotropic gel precipitate in a manner similar to calcium oxide or calcium nitrate.
Unexpectedly it has been discovered that calcium chloridé
does not react in this manner, and instead produces a new and useful product via a new process.
In addition to the discovery that calcium chloride was an inexpensive and readily available suspending agent, it was an even greater discovery to find that the present invention opened~up an entirely new field of no-till agriculture. Elimination of clay as a fertilizer suspending agent by the substitution of calcium chloride now allows a combination seed drill and spray application to kill, plant ~0352~ 9 and fertilize in one pass over the field. The need to first kill the vegetation in a first pass and then later to drill in seeds and fertilize in a second pass is eliminated. It was known that topical herbicides such as the ICI Gramoxone~
herbicide and the Chevron Paraquat~ herbicide are absorbed by the clay suspending agent in conventional fluid fertilizers.
In detail the process of the invention involves the addition of a very soluble calcium salt (calcium chloride) to form a solution instead of a precipitate and thereafter using such a solution as a suspending agent for potash and additional fertilizer and herbicide ingredients. One of the points of novelty of this process is that an initial cloudiness is observed when a concentrated calcium chloride solution is added to the "10-34-0" ammonium polyphosphate which disappears within a minute or so as the ingredients are stirred. This observation is similar to the addition of ammonia to silver nitrate solution wherein initial cloudiness is observed until an excess of ammonia is present to form the complex and produce a clear solution. In any event it is possible to speculate that prior art inves,tigators may have stopped their efforts at the first sign of precipitation and concluded that calcium chloride was equivalent to all other calcium salts.
After the formation of the suspending solution which is step (1) of this process, step (2) involves adding potash (potassium chloride) and water as required. Thus, step (2) requires that the potash be added as a solid to obtain beneficial suspension action. While it is not known with certainty, it is believed that some type of encapsulation of potash particles may occur in step (2).
When steps (1) and (2) of the process are complete, a new and useful fluid fertilizer composition results which is storage stable and can incorporate higher levels of potash :' Z0~5~.9 along with other fertilizer and herbicide ingredients. The advantages of this clay free composition have been previously described.
The following Preparations and Examples illustrate the practice of the invention which has industrial applicability in the field of agriculture and horticulture.
All amounts are given in parts by weight unless otherwise indicated.
PreParation A
A stock solution was prepared of 50% by weight CaC12.2H20 in tap water. A 3 part portion of the calcium chloride solution was placed in a tank and stirred while a 28.8 part portion of ammonium polyphosphate (Agway "10-34-0") as added along with 5.2 parts of water. After two minutes of stirring a clear solution was produced. No indication of settling or precipitation was observed from a sample removed from the tank.
With continued stirring, 47.4 parts of potash and 15.6 parts water were added. Stirring continued for one minute to prepare a liquid fertilizer suspension.
A fluid pourable suspension of the potassium chloride particles (potash) was observed.
It was thus shown that use of calcium chloride, corresponding to a dosage of 30 pounds CaC12.2H2O pe,r ton of finished suspension, was an effective stabilizer for a fluid suspension of potassium chloride in ammonium polyphosphate fertilizer solution.
S~mples of the above suspension containing calcium chloride were poured into glass sample jars and subjected to agitation employing a Burrell Wrist Action Shaker at a setting of "1" for 4 hours. No settling of the suspending KCl particles was observed in these samples.
Several samples of the above fluid fertilizer suspension containing calcium chloride were stored for 20352~.9 prolonged periods to observe the stability af this suspension over time. It was found that these fluid fertilizer suspension samples remained fluid and pourable yet showed no perceptible potassium chloride settling after 10 days of static storage.
Comparison Pre~aration B
Prior Art Clay Sus~ension A liquid fertilizer was prepared containing active ingredients as in Preparation A except that clay was used as the suspending agent instead of calcium chloride.
Attapulgite clay (Min-U-Gel 200 from Floridin Company) can be preslurried and allowed to swell for several hours before being used. A total time of 12 hours would be required to disperse the ingredients to prepare a formulation of nutrient value equivalent to formulation A which was prepared in less than 1 hour. The comparison formulation began to settle in 2-3 hours but did not form a firm settling and could be remixed by transfer to the preparation tank. The comparison Preparation B contained 28.8 parts ammonium polyphosphate, 22.3 parts water, 47.4 parts potash and 1.5 parts attapulgite clay.
A fluid suspension of the potassium chloride particles was observed. This experiment corresponded to current industry practice for preparing attapulgite-stabilized suspensions of potassium chloride in ammonium polyphosphate fertilizer. The active dosage of attapulgite in this case was 30 pounds per ton of finished fluid fertilizer suspension.
Samples of the above prepared fluid fertilizer suspension were placed in glass jars and agitated with a Burrell Wrist Action Shaker on a setting of "1" for 4 hours. After this period it was observed that the attapulgite-stabilized fertilizer suspension samples showed significant settling of the potassium chloride particles.

203~2~ 9 This example thus showed that attapulgite was a less effective stabilizing agent for preparing fluid fertilizer suspensions stable to vibration compared to calcium chloride stabilized of Preparation A.
Vpon static storage the attapulgite suspension from above was observed to shcw significant settling of potassium chloride particles after only 16 hours which was much less effective than the Preparation A.
Pre~aration C
Liquid Fertilizer and Herbicide Calcium Chloride Suspension Herbicide is added to Preparation A in an amount effective for topical application.
Comparison PreParation D
Liquid Fertilizer and Herbicide Cla~ Sus~ension Herbicide is added to Preparation ~ in an amount effective for topical application.
ExamDle 1 Preparation C is applied to a field by a tractor drawn seed drill~fertilizer applicator. The ground cover is killed without adverse effect on the seeds deposited by the seed drill. A crop can be produced without soil erosion with a yield at least equivalent to conventional farming methods. Com~arison 1 Comparison preparation D could not be used for a one pass treatment of a field as in Example 1 because the clay used for suspension absorbed the Paraquat~ herbicide. A
first application of herbicide and a second application with a seed drill and clay fertilizer suspension were required to obtain results similar to Example 1.
Exam~le 2 Both Preparation A and Comparison Preparation B were applied to fields by a tractor drawn fertilizer sprayer.
Except for the case of preparation and storage stability of Preparation A, the results obtained were equivalent.

2035;~.9 Example 3 Other storage stable fluid fertilizer compositions were prepared and tested as in Example 2 and Preparation A
except that other nutrients such as ammonium sulfate and sulphur compounds were added. Equivalent results were obtained in storage tests and field application.
This example illustrates the wide utility of the invention to not only prepare "3-10-30" blends but "4-10-22-2.5" blends as well.

Claims (24)

1. A liquid fertilizer composition comprising an admixture of calcium chloride or an equivalent salt and ammonium polyphosphate as a suspending agent.

2. The composition of claim 1 further comprising more than 10% by weight potash.

3. The composition of claim 2 further comprising more than 5% by weight available nitrogen.

4. The composition of claim 1 further comprising an herbicide.

5. The composition of claim 4 where the herbicide is Paraquat? or Gramoxone? topical herbicide or equivalent.

6. The composition of claim 5 used for no-till farming.

7. The composition of claim 1 comprising a 3-10-30 fertilizer composition.

8. The composition of claim 1 further comprising a sulphur agent.

9. The composition of claim 8 wherein the fertilizer-sulphur composition is "4-10-22-2.5".

10. A liquid fertilizer composition containing a stabilizing amount of calcium chloride.

11. The composition of claim 10 further comprising more than 10% by weight potash.

12. The composition of claim 11 further comprising more than 5% by weight available nitrogen.

13. The composition of claim 10 further comprising a herbicide.

14. The composition of claim 13 where the herbicide is Paraquat? or Gramoxone? topical herbicide or equivalent.

15. The composition of claim 14 used for no-till farming.

16. The composition of claim 10 comprising a 3-10-30 fertilizer composition.

17. The composition of claim 10 further comprising a sulphur agent.

18. The composition of claim 17 where the fertilizer-sulphur composition is "4-10-22-2.5".

19. A process for preparing a storage stable liquid fertilizer composition comprises the steps:
(1) mixing calcium chloride with ammonium polyphosphate for a time sufficient to prepare a solution; and (2) adding potassium chloride to the solution to prepare a storage stable liquid fertilizer suspension.

20. The process of claim 19 where an herbicide is added in step (2).

21. The process of claim 19 in which Ca(NH4)2 P2O7 is produced in step (1).

22. The process of claim 21, characterized in that the steps are preformed at ambient temperature.

23. The process of claim 19 where water is added in step (2).

24. The process of claim 19 where a sulphur compound is added in step (2).