CA2033328A1 - Process for preparation of a polymer having reactive terminal group - Google Patents
Process for preparation of a polymer having reactive terminal groupInfo
- Publication number
- CA2033328A1 CA2033328A1 CA002033328A CA2033328A CA2033328A1 CA 2033328 A1 CA2033328 A1 CA 2033328A1 CA 002033328 A CA002033328 A CA 002033328A CA 2033328 A CA2033328 A CA 2033328A CA 2033328 A1 CA2033328 A1 CA 2033328A1
- Authority
- CA
- Canada
- Prior art keywords
- polymer
- preparation
- terminal group
- reactive terminal
- isobutylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title abstract 2
- 229920000642 polymer Polymers 0.000 title abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- 150000002894 organic compounds Chemical class 0.000 abstract 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 abstract 1
- 239000002841 Lewis acid Substances 0.000 abstract 1
- 239000012986 chain transfer agent Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- 150000007517 lewis acids Chemical class 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/08—Butenes
- C08F10/10—Isobutene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Disclosed is a process for preparing an isobutylene-type allyl-terminated polymer, the process comprising mixing:
(A) a cationically polymerizable isobutylene-containing monomer;
(B) an organic compound serving as an initiator and concurrently as a chain transfer agent, the organic compound being represented by the formula (I) (C) at least one Lewis acid selected from the group consisting of (C2H5)2A~C~, (C2H5)A~C~2, SnC~4 and TiC~4; and (D) a compound serving as an end capping agent, the compound being represented by the formula (II)
(A) a cationically polymerizable isobutylene-containing monomer;
(B) an organic compound serving as an initiator and concurrently as a chain transfer agent, the organic compound being represented by the formula (I) (C) at least one Lewis acid selected from the group consisting of (C2H5)2A~C~, (C2H5)A~C~2, SnC~4 and TiC~4; and (D) a compound serving as an end capping agent, the compound being represented by the formula (II)
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP144634/1989 | 1989-06-06 | ||
| JP14463489 | 1989-06-06 | ||
| JP281331/1989 | 1989-10-27 | ||
| JP28133189 | 1989-10-27 | ||
| JP99067/1990 | 1990-04-13 | ||
| JP9906790 | 1990-04-13 | ||
| PCT/JP1990/000729 WO1990015081A1 (en) | 1989-06-06 | 1990-06-05 | Method of producing polymer terminated with reactive group |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2033328A1 true CA2033328A1 (en) | 1990-12-07 |
| CA2033328C CA2033328C (en) | 2002-04-02 |
Family
ID=27308852
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002033328A Expired - Fee Related CA2033328C (en) | 1989-06-06 | 1990-06-05 | Process for preparation of a polymer having reactive terminal group |
Country Status (2)
| Country | Link |
|---|---|
| CA (1) | CA2033328C (en) |
| WO (1) | WO1990015081A1 (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2969471B2 (en) | 1990-10-19 | 1999-11-02 | 鐘淵化学工業株式会社 | Method for producing isobutylene-based polymer having silyl group at terminal |
| US5350819A (en) * | 1993-02-19 | 1994-09-27 | Exxon Chemical Patents Inc. | Carbocationic catalysts and process for using said catalysts |
| US5506316A (en) * | 1993-02-19 | 1996-04-09 | Exxon Chemical Patents Inc. | Carbocationic catalysts and process for using said catalysts |
| US5478899A (en) | 1994-10-27 | 1995-12-26 | Shell Oil Company | Alkoxy silyl capping agents for making terminally functionalized polymers |
| US8344073B2 (en) * | 2009-01-16 | 2013-01-01 | The University Of Southern Mississippi | Functionalization of polyolefins with phenoxy derivatives |
| WO2019070037A1 (en) * | 2017-10-04 | 2019-04-11 | 株式会社カネカ | Allyl group-terminated styrene-isobutylene block copolymer, composition thereof, and methods for producing these |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3541408A1 (en) * | 1985-11-23 | 1987-05-27 | Bayer Ag | PRODUCTION OF POLYMERS BY CATIONIC POLYMERISATION |
| US4758631A (en) * | 1986-10-16 | 1988-07-19 | Dow Corning Corporation | Method of preparing allyl-terminated polyisobutylene |
-
1990
- 1990-06-05 CA CA002033328A patent/CA2033328C/en not_active Expired - Fee Related
- 1990-06-05 WO PCT/JP1990/000729 patent/WO1990015081A1/en active Application Filing
Also Published As
| Publication number | Publication date |
|---|---|
| WO1990015081A1 (en) | 1990-12-13 |
| CA2033328C (en) | 2002-04-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |