CA2030931A1 - Metallic water borne base coat of improved stability and appearance - Google Patents
Metallic water borne base coat of improved stability and appearanceInfo
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- CA2030931A1 CA2030931A1 CA 2030931 CA2030931A CA2030931A1 CA 2030931 A1 CA2030931 A1 CA 2030931A1 CA 2030931 CA2030931 CA 2030931 CA 2030931 A CA2030931 A CA 2030931A CA 2030931 A1 CA2030931 A1 CA 2030931A1
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Abstract
Abstract There is disclosed a metallic waterborne base coat composition exhibiting excellent appearance and a method for long term stability and the introduction of aluminum flake pigments into a waterborne coating. The coating vehicle is based on acrylic latex exhibiting excellent drying and film properties. The coating compositions disclosed are also in compliance with current and proposed volatile organic compound regulations.
Description
.
3 3.
The present invention is concerned with a waterborne coating composition designed for the coating of transportation vehicles. The invention is related to coating compositions primarily for a base coat of a multi-coat system which includes primers and transparent clear coats, particularly with base coats containing metallic pigments, based on acrylic latex polymers.
It is customary in the painting of an automobile that a series of coatings, be applied to the substrate. The first coat being the primer followed by the base coat and ~inally the clear coat. The base coat provides the good decorative quality to the final finish via organic and inorganic pigments. In many automobile finishes, a metallic finish is desired. To obtain this metallic effect, metallic pigments are present in the base coat typically aluminum flakes.
In the current market place, automobile coatings, especially base coats, contain a high level of organic solvent. With increasing concern about the volatile organic emissions into the atmosphere, an intensive effort in research and development in coatings containing mainly water as the solvent with a small level of organic solvent is under way. An example of such an effort is US patent No. 4 730 020 which discloses a water-dilutable coating composition comprising specifically selected acrylic copolymers, solvent blends, coloring and/or optical effect pigments and polymer dispersions. To obtain the desired optical effect of the metallic flakes, the correct combination of acrylic copolymer and solvent blend must be achieved.
An aqueous thermosetting acrylic resin described by US
patent 3 862 071 controls the metallic pigment orientation by the addition of a water insoluble copolymer. Microgel technology as described by GB-PS No.
3 3.
The present invention is concerned with a waterborne coating composition designed for the coating of transportation vehicles. The invention is related to coating compositions primarily for a base coat of a multi-coat system which includes primers and transparent clear coats, particularly with base coats containing metallic pigments, based on acrylic latex polymers.
It is customary in the painting of an automobile that a series of coatings, be applied to the substrate. The first coat being the primer followed by the base coat and ~inally the clear coat. The base coat provides the good decorative quality to the final finish via organic and inorganic pigments. In many automobile finishes, a metallic finish is desired. To obtain this metallic effect, metallic pigments are present in the base coat typically aluminum flakes.
In the current market place, automobile coatings, especially base coats, contain a high level of organic solvent. With increasing concern about the volatile organic emissions into the atmosphere, an intensive effort in research and development in coatings containing mainly water as the solvent with a small level of organic solvent is under way. An example of such an effort is US patent No. 4 730 020 which discloses a water-dilutable coating composition comprising specifically selected acrylic copolymers, solvent blends, coloring and/or optical effect pigments and polymer dispersions. To obtain the desired optical effect of the metallic flakes, the correct combination of acrylic copolymer and solvent blend must be achieved.
An aqueous thermosetting acrylic resin described by US
patent 3 862 071 controls the metallic pigment orientation by the addition of a water insoluble copolymer. Microgel technology as described by GB-PS No.
2 073 609 also results in the proper metal orientation.
Also disclosed in DE No. 3 210 051 is an attempt to : :: :: :
control metallic pigment orientation using polyurethane dispersions. Cellulosic esters have also been used to control metal fixation as disclosed in DE No. 3 216 549.
In general, the metal fixation in base coats is achieved by a rheology modifiers such as inorganic and organic thickeners. All previous rheology modifiers or rheology control agents for water borne coatings have poor shelve stability, poor weathering characteristics and are cumbersome to use. The particular rheology control agent used in this invention results in a non-mottled, high head-on-brightness, outstanding flop, and high quality finish, even in the case of a silver metallic base coat and does not suffer from the problems cited earlier.
Typically, coating compositions used in the automotive market, especially in the automotive after market, are produced by mixing various bases to give the desired color. These coating compositions are then applied in about 1-5 days after preparation. A major problem is the introduction of aluminum flakes which react with water to generate hydrogen gas. Therefore, the aluminum flake must be segregated from the rest of the waterborne components to minimize this hazard. This invention also describes a method for the storage of aluminum flake in an organic medium with introduction of the flakes into the aqueous ervironment just prior to application of the coating system.
This invention relates to waterborne compositions for use in metallic and nonmet~llic base coats in a multicoat system for the automotive market.
More specially, the present invention is concerned with an acrylic latex coating composition for use in an automotive paint base coat composition. The invention also relates to base coats containing pigments, me-tallic pigments, organic solvents, and conventional paint additives. The outstanding metal control exhibited by this coating composition is attrib~ted to the rheology control agent and the film shrinkage of the latex vehicle while drying. The use of acrylic latex results in a very fast dry time. This coating composition provides a base coat that satisfies current and proposed volatile organic compound regulations. Even with conventional non~metallic pigments, the coating exhibits excellent appearance.
This invention describes a method for the storage of aluminum flake in an organic medium with introduction of the flakes into the aqueous environment just prior to application of the coating system. This method minimizes the potential hazard of the aluminum flake reacting with water to form hydrogen gas during storage. This method can also be used for the storage of other water sensitive pigments such as copper and brass.
Other pigments such as plastic films, mica and coated metallic foils can be stored using this method.
The automotive base coat pain~ comprises five components; A) aluminum base, B) neutralization base, C) clear resin base, D) pigmented base, and E) surfactant base~ Component A, the aluminum base, is composed of metallic flakes slurred into a solvent borne resin and water miscible solvents. The resin used in this component may be a water reducible acrylic, water reducible polyester, or water reducible alkyd. Commonly used metallic pigments, used singularly or as a mixture are copper, copper alloys, aluminum, steel, mica, plastic films, and coated metallic foils, preferably aluminum at a lavel of 10-30 % by weight, preferably 20-30 ~ by weight. The aluminum hase contains 5-40~, preferably 20-30~ by weight of the solvent borne water reducible resin. The organic solvent for this base must be water miscible. Examplss of solvents are methanol, ethanol, propanol, butanol, N-methylpyrrolidone, glycols, glycol esters, glycol acetates, diethylene ~ .:
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glycol ethers, diethylene glycol acetates, propylene glycol esters, propylene glycol acetates, dipropylene glycol, dipropylene glycol acetates, specially preferred are ethylena glycol propyl ether, ethylene glycol butyl ether, ethylene glycol hexyl ether, propylene methyl ether, propylene ethyl ether, propylene propyl ether, propylene butyl ether, propylene hexyl ether, dipropylene methyl ether, dipropylene ethyl ether, dipropylene propyl ether, and dipropylene butyl ether.
Component B, neutralization base, is composed of a solvent borne water reducible resin, neutralized with an amine, preferably ammonia dispersed in water to a level of 10-25 %, preferably 10-20 ~ by weight. Excess amine, preferably ammonia, is added at a level of 1-10 ~, preferably 5-10 %, by weight.
Component C, clear resin base, contains; 1) acrylic latex polymer at a level of 10-50 ~, preferably 25-35 %, 2) 0-15 ~ water miscible solvent, preferably 5-12 %, 3) 0.5-5.0 % hydrophilic silica, prefe.rably 1.5-2.5 %. The hydrophilic silica can be dispersed into the acrylic late~ polymer by normal dispersing techniques.
Component D, pigment base, contains acrylic latex grinding polymer at a level of 5-50 ~, preferably 15-30 ~. This level depends on the pigment in the component. The level of pigment in component D is 0.5-35 % by weight, this level depends on the pigment characteristics also. Typically, a pigment to binder weight ratio of about 10/100 to 300/100 is acceptable.
The pigments are typically ground using conventional dispersion equipment such as sand mills, pearl mills, ball mills, horizontal mills, and vertical mills.
Optional wetting agents, surfactants, and dispersing aids can be employed.
Component E, surfactant base, contains a polymer fluorocarbon surfactant at a level of 0.1-4.0 ~, preferably 2.0-3.0 % in water.
2~3~3 ~
This invention is directed to a coating composition for a water borne base coat especially designed for the automotive market. This invention describes a method for the introduction of m~tallic flakes into a waterborne coating resulting in a highly superior base coat. The proper metal fixation is accomplished by the use of a novel rheology control agent which employs hydrophilic silica and a polymeric nonionic fluorocarbon surfactant. The novel rheology 10 control agent described and claimed in copending related US application and filed and incorporated herein by re~erence. The basecoat is broken down into five bases that are combined just prior to application of the base coat.
The invention describes a method for the storage of aluminum flake in an organic medium with introduction of the flakes into the aqueous environment just prior to application of the coating system. This method minimizes the potential hazard of the aluminum 20 flake reacting with water to form hydrogen gas during storage.
Component A, aluminum base, is an aluminum slurry in an organic environnient containing either a low to moderate acid number acrylic or polyester or alkyd.
25 The acid number of these polymers based on solids should be about 15 to 65. The preferred polymer is a water reducible solvent borne acrylic modified with glycidyl esters. The acrylic polymer is prepared via normal solution polymerization techniques. The acrylic polymer 30 is composed of; 1) 3-5 ~ by weight of an ethylenically unsaturated carboxylic acid such as methacrylic acid and acrylic acid, preferably methacrylic acid, 23 15-30 % by weight methylmethacylate, 3) 5-20 ~ by weight 2-ethylhydroxymethacrylate, 4) 1-10 % by weight isobornyl methacrylate, and 5) optionally 5 20 % by weight of a glycidyl ester of a tertiary C10 fatty acid. The acrylic ; , .- . : : : :~ :
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polymer is prepared in organic solvents that are water miscible, such as methyl ethyl ketone, acetone, ethanol, methanol, propanol, butanol, N-methylpyrrolidone, glycols, glycol ethers, glycol acetates, diethylene glycol ethers, diethylene glycol acetates, propylene glycol ethers, propylene glycol acetates, dipropylene glycol ethers, dipropylene glycol acetates, specially preferred are ethylene glycol propyl ether, ethylene glycol butyl ether, ethylene glycol hexyl ether, propylene methyl ether, propylene ethyl ether, propylene propyl ether, propylene butyl ether, propylene hexyl ether, dipropylene methyl ether, dipropylene ethyl ether, dipropylene propyl ether, methyl ethyl ketone and dipropylene butyl ether. Optionally, surfactants can also be present during the polymerization at a level of 0.1-2O0 ~ by weight. The viscosity of the final polymer is 16000 to 18000 cps with a solids content of 50-75 ~
by weight, preferably 55-65 ~ by weight. The acid number of the polymer based on solids should be 10-70, preferably 15-65.
Any commercial aluminum paste available for solvent borne or waterborne applications can be used in the preparation of component A. The amount of aluminum flake in the component is 4-30 ~ by welght, preferably 23-30 ~ by weight.
Other nonmetallic and metallic pigments that can be incorporated lnto this base include copper, copper alloys, mica, coated metallic foils, plastic flakes and steel. However, this is not a conclusive list.
Additional organic solvent may be needed to reduce the viscosity of the acrylic resin. Acceptable solvents must be water miscible such as methyl ethyl ketone, acetone, ethanol, methanol, propanol, butanol, N-methylpyrrolidone, glycols, glycol ethers, glycol acetates, diethylene glycol ethers, diethylene glycol 2 ~ ~3~J`~ l acetates, propylene glycol ethers, propylene glycol acetates, dipropylene glycol ethers, dipropylene glycol acetates, specially preferred are ethylene glycol propyl ether, ethylene glycol butyl ether, e~hylene glycol hexyl ether, propylene methyl ether, propylene ethyl ether, propylene propyl ether, propylene butyl ether, propylene hexyl ether, dipropylene methyl ether, dipropylene ethyl ether, dipropylene propyl ether, and dipropylene butyl ether. Component A has a to~al solids of 25 ~ to 50 ~ by weight, 5 % to 35 % binder by weight, and 35 ~ to 50 ~ organic solvent by weight. Additional wetting, anti-settling additives common to the paint industry may be added.
The preparation of component A, the aluminum base, is critical for the proper appearance of the aluminum flake in the final coating. The proper amount of the acrylic resin solution is dissolved into the proper amount of water miscible organic solvent, such as methyl ethyl ketone, acetone, ethanol, methanol, propanol, butanol, N-methylpyrrolidone, glycols, glycol ethers, glycol acetates, diethylene glycol ethers, diethylene glycol acetates, propylene glycol ethers, propylene glycol acetates, dipropylene glycol ethers, dipropylene glycol acetates, specially preferred are ethylene glycol propyl ether, ethylene glycol butyl ether, ethylene glycol hexyl ether, propylene methyl ether, propylene ethyl ether, propylene propyl ethex, propylene butyl ether, propylene hexyl ether, dipropylene methyl ether, dipropylene ethyl ether, dipropylene propyl ether, and dipropylene butyl ether.
The proper amount of the aluminum paste is slurred into the above described resin solutionO The aluminum slurry must be stirred until the bas~ is smooth and uniform.
Component B, neutralization base, is an aqueous solution containing dispersed acrylic resin and ammonia. The acrylic described above is used in the ' ;~' ' `~ -- , . : . , :
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component. Other water reducible resins such as polyester and alkyds may be used. An aqueous solution containing O.l-15.0 ~, preferably 0.1-8.0 ~ ammonia by weight is prepared. The correct amount of the acrylic resin, usually 5-25 ~ by weight, preferably 10-20 % by weight, is added to the basic aqueous solution and stirred~ The resulting solution should be clear to slightly turbid and have a pH range of 7.5 10.0, preferably 8.0 to 10Ø The r4sulting solution should have a nonvolatile range of 5-25 ~ by weight,preferably 10-20 ~.
Component C, clear resin base, of the coatlng composition contains an acrylic latex. Typical properties of this acrylic latex are as follows:
Solids content, % 20-60 pH 7 -to 10 Weight per gallon, lbs 8.0 to 9.0 Minimum film formation temperature, C O to 70 Sward hardness 25 to 110 Mechanical stability OK
Glass transitition temperature, C 10 to 50 Average molecular weight 150,000 to 300,000 Number average molecular weight 30,000 to 60,000 Acid number on solids 5 to 35 Volatile organic solvents, ~ O to 20 Particle size, nm 50 to 150 Specially preferred acrylic latics are Neocryl A-622, Neocryl A-640, Neocryl A-6037 sold by ICI
resins, Joncryl J-537, Joncryl J-538 sold by Johnson Wax, Arolon 860-W-45 sold by NL Industries. The amount of this acrylic latex in this component is 15 45 % by weight, preferably 25-35 ~ by weight. The level of organic solvent in this component is 5.0-30 % by weight, preferably 5-15 ~ by weight, and the solvent must be water miscible. Examples of water miscible solvents are methyl ethyl ketone, acetone, ethanol, methanol, 2 ~
propanol, butanol, N-methylpyrrolidone, gly~ols, glycol ethers, glycol acetates, diethylene glycol ethers, diethylene glycol acetates, propylene glycol ethers, propylene glycol acetates, dipropylene glycol ethers, diprcpylene glycol acetates, specially preferred are ethylene glycol propyl ether, ethylene glycol butyl ether,~ ethylene glycol hexyl ether, propylene methyl ether, propylene ethyl ether, propylene propyl ether, propylene butyl ether, propylene hexyl ether, dipropylene methyl ether, dipropylene ethyl ether, dipropylene propyl ether, and dipropylene butyl ether.
This component may also contain other conventional paint additives such as thickening agents, extenders, plasticizers, stabilizers,light stabilizers, wetting agents, waxes, antifoams, defoamers and catalysts, singly or a multitude of them at the conventional levels.
Hydrophilic colloidal silica is also present in this component at a level o~ 1.0-8.0 % by weight, preferably 2.0-3.0 % by weight. The particle size of the hydrophilic colloidal silica is about 1.0 10,000 millimicron and a surface area of about 50-1200 square meters per gram. The silica is about 99.8 ~ silicon dioxide by weight and exist in three dimensional branched chain aggregates and has a surface that is hydrophilic and capable of hydrogen bonding. The silica is dispersed into the above resin solution using conventional techniques, such as ball mills, pebble mills, horizontal mills vertical mills and ~earl mills.
The total nonvolatile range o~ this component is 20-50 %, preferably 25-35 ~ by weight.
Component D, pigmented base, imparts the coloring effect upon the coating composition. The resin used for the dispersing of the pigments is an acrylic latex. Typical properties of this acrylic latex are as follows:
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la Solids content, ~ 20-60 pH 7 to 10 Weight per gallon, lbs 8.0 to 9.0 Minimum film formation tamperature, C 0 to 70 Sward hardness 25 to 110 Mechanical stability OK
Glass transitition temperature, C 10 to 50 Average molecular weight 150,000 to 300,000 Number average molecular weight 30,000 to 60,000 Acid number on solids 5 to 35 Volatile or~anic solvents, ~ 0 to 20 Particle size, nm 50 to 150 Specially preferrad acrylic latics are Neocryl A-622, Neocryl A-640, Neocryl A-6037 sold by ICI
resins, Joncryl J-537, Joncryl J-538 sold by Johnson Wax, Arolon 860-W-45 sold by NL Industries. The level of this resin in component D is 15-60 ~ by weight, preferably 20 40 % by weigh-t. The organic, inorganic pigments and/or dyestuffs are ground with this resin employin~ standard techniques. Examples of dispersing equipment are ball mills, pebble mills, pearl mills, horizontal mills, and vertical mills. Examples of pigments and dyestuffs but not limited to are -titanium dioxide, graphite, carbon black, zinc oxide, cadminum sulfide, chromium oxide, zinc sulfide, zinc chromate, strontium chromate, barium chromate, lead chromate lead cyanamide, lead silico chromate, chromium oxide, zinc sulfide, yellow nickel titanium, yellow chromium titanium, red iron oxide, transparent red oxide, 3Q transparent yellow oxide, black iron oxide, ultramarine blue, phthalocyanine complexes, amaranth, quinacridones, and halogenated thioindigo pigments. The level of pigment/dyestuff in Component D is 0.1 to 35.0 % by weight, typically 5-25 %. This component may also contain other conventional paint additives such as dispersing aids, anti-settling aids, we~ting aids, ~(~3~J`~
thickening agents, extenders, plasticizers, stabilizers, light stabilizers, waxes, antifoams, defoamers and catalysts singly or a multitude of them at the conventional levels. Also present in this component is a water miscible solvent such as methyl ethyl ketone, acetone, ethanol, methanol, propanol, butanol, N-methylpyrrolidone, glycols, glycol ethers, glycol acetates, diethylene glycol ethers, diethylene glycol acetates, propylene glycol ethers, propylene glycol acetates, dipropylene glycol ethers, dipropylene glycol acetates, specially preferred are ethylene glycol propyl ether, ethylene glycol butyl ether, ethylene glycol hexyl ether, propylene methyl ether, propylene ethyl ether, propylene propyl ether, propylene butyl ether, propylene hexyl ether, dipropylene methyl ether, dipropylene ethyl ether, dipropylene propyl ether, and dipropylene butyl ether at a level of 0 to 25 ~ by weight, preferably 0-12 % by weight.
Component E, surfactant base, contains a polymeric nonionic fluorocarbon surfactant at a level of 0.1 to 5 % by weight, preferably 2.0 to 3.0 ~ by weight, in water. The polymeric nonionic fluorocarbon surfactant contains ethylene oxide linkages, has a weight average molecular weight of about 5,000 to 50,000 and contains 2-25 ~ of fluorine by weight of the surfactant. One preferred nonionic fluorocarbon polymer contains about 30-70 ~ by weight ethylene oxide linkages, 10-20 % by weight of fluorine and has a weight average molecular weight of about 10,~00-30,000.
The final coating composition is produced by mixing Components A through E together in order and at appropriate levels to give the desired color and metallic effect. Typically, the solids of the final coating is 5 to 30 % by weight, organic levels 5 to L5 %
by weight. The rheology of the coating is defined by the amount of colloidal silica and polymeric nonionic , fluorocarbon surfactant present in the coating. The level of colloidal silica is 0.5 to 5.0 ~ and 0.05 to 1.0 % of polymeric nonionic fluorocarbon surfactant by weight of water used in the final base coat formulation.
The water content ranges between 30 to 90 ~ by weight of the final base coat composition.
Other water reducible resin may be added to the coating to improve certain film properties such as aqueous one component aliphatic polyurethane dispersions, polyesters, and alkyds.
Additional anionic and nonionic surfactants can be added to the paint composition to increase wetting of the substrate by the coating such as FC-120, FC-430 sold by 3M, Surfonyl 104, Surfonyl 440 sold by Air Products, Triton X100 sold by Rohm and Haas, Troysol LAC sold by Troy Chemical Company, Aerosol OT's sold by American Cyanamid including the salts of dialkyl sulfosuccinates and Igepal's sold by GAF including the ethoxylated alkyl phenols.
The viscosity of the final base coat is about 10 Pas at a shear rate of 0.001 1/s and 0.05 at a shear rate of 1,000 1/s. This base coat exhibits a very high viscosity at low shear rate while having a low viscosity at high shear rates. This phenomenon results in the outstanding metal effect this coating composition possesses. The efflux time of the coating through a ~4 Ford cup is 15 to 30 seconds at 23 C.
The coating composition can be applied using conventional spray equipment or high volume low pressure spray equipment resulting in a high quality finishO
After a flash off time of 15 to 45 minutes, a transparent top coat can be applied over this basecoat.
Example of transparent top coats are two component, based on acrylic and/or polyester resins cured with polyisocyanates, silanes, and acid cured epo~y coatings, however, this is not an inclusive list. The preferred , 2 ~
transparent top coat is a two component acrylic polyisocyanate coating.
The following examples illustrate the invention without limiting the scope thereof.
Example 1; Base Coat Preparation Preparation of an Acrylic Polymer modified with A Glycidyl Ester of Tertiary C10 Fatty Acid.
A five liter three neck round bottomed flask was fitted with an agitator, thermometer, condenser, nitrogen inlet and monomer inlet ~nd charged with 680 g of methoxypropanol, 20 g of methyl ethyl ketone. The mixture was brought to reflux and the temperature adjusted to 140-141 C by adding 5.0 ~ of methyl ethyl ketone. A monomer solution was prepared containing 333 g of propenoic acid, 847 g of methyl-2-methyl-2-propionate, 450 g of 2~ethylhexyl~2-methylpropionate, 180 g of isobornyl-2-methyl-2-propionate and 27 g of Surfynol 440. An initiator solution was also prepared containing 36 g of t-butyl peroxybenzoate and 76 g of methoxypropanol. The above monomer solution and initiator solutions were added to the reaction flask at a uniform rate over two hours. After completion of the additions, the monomer line was flushed with 35.0 g of methoxypropanol and a solution containing 15 g of t-butylperoxybenzoate and 40 g of methoxypropanol was then added over 10 minutes. The reaction was then refluxed for an additional 135 minutes. After refluxing, 475 ~ of a glycidyl ester of a tertiary C10 fatty acid was added to the flask, heated to reflux and reacted to constant acid value. The reaction was allowed to cool, then 43 g of methoxypropanol and 588 g of ethanol were added to the resin to reduce the viscosity. The properties of the resin are: viscosity Z5-Z6, solids 60-61 %, and acid number of 53 to 56 based on solids.
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Preparation of Component A - Aluminum Base The acrylic resin described above, 44.0 g, was added to 19.0 g o butoxyethanol. This mixture was stirred until a homogeneous solution was produced. A
commercial solvent borne aluminum paste, 38.0 g was added to the resin solution. The resulting slurry was then stirred until a smooth, uniform slurry was produced. This aluminum base contains 49.8 % by weight of volatile organic solvents, 38.4 % by weight of solids, and 24.3 ~ by weight of aluminum flake.
Preparation of Component B - Neutralization Base To 300 g of deionized water, 8.0 g of 30 aqueous ammonia was added. the solution was stirred well before adding 100.0 g of the acrylic resin described above. The resulting mixture was stirred until the solution was clear to slightly turbid. The nonvolatile level of this base was 14.8 % by weight, water level 74.9 ~ by weight, volatile organic solvent 9.8 % by weight. The final pH of this dispersion was 9.2.
Preparation of Component C - Clear Resin Latex Premixed were 48.0 g of hydrophilic colloidal silica, 10.0 g of a defoamer and 1865 g of Neocryl A-622. This mixture was then ground on a horizontal mill until a particle size of less than 8 microns was achieved. Deionized water, 260 g, was then added to the above slurry under agitation to yield a uniform latex solution. The level of silica was 2.2 ~ by weight. Volatile organic level was 8.9 % by weight and solids level was 28.3 % by weight.
Preparation of Component D - Pigmented Bases The ollowing pigment slurry was prepared, 80 g Neocryl A-6037, 2.1 g of 30 ~ aqueous ammonia, 23.9 g of transparent red oxide, and 0.2 g of a defoamer. The above components were mixed together and predispersed - : ,, , :
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using a Cowles blade. The mixture was then ground on a horizontal mill until the desired particle size was achieved. A let down solution containing 70.0 g of Neocryl A-6037 and 2.0 g of 30 % aqueous ammonia was added to the grind portion. The resulting pigment paste was reduced under agita~ion with a solution containing 5.75 g of deioni~ed water, 19.2 g o* butoxyethanol. The resulting pigmented base had a pH of 9.2, a solids level of 48 % by weight, a volatile organic level of 9.4 % by weight, a binder level of 36.2 ~ by weight, a pigment level of 11.8 ~ by weight and a water level of 42.0 % by weight.
Preparation of Component E - Surfactant Base To 48 g of deionized water, 2.0 g of a polymeric nonionic fluorocarbon surfactant was added.
The mixture was stirred to give a slightly turbid solution.
Example 2 - Preparation of a Waterborne Red Metallic Base Coat Component Parts by Weight Component B 4.0 Neutralization Base Component A 2.0 Aluminum Base Component C 72.0 Clear Resin Base Component D 13.0 Pigmented Base Component E 9.0 Surfactant 8ase The above formula was used to prepare a red metallic base coat. The order of addition is that listed. After each introduction of a component, the entire solution was stirred. The base coat was sprayed on panels primed with an epoxy primer. The base coat was sprayed on the substrate using conventional spray ; : , : . .
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equipment until hiding was achieved. The basecoat was allowed to flash for 30 minutes and ~h~n clear coated with a transparent coating based on isocyanate technology. The final properties of the base coat after coating with a conventional polyurethane clear coat are listed below, including appearance ratings.
Properties of the Red Metallic Base Coat and Base Coat/Clear Coat System Property Value Water 68.9 %
Volatile Organic 9.1 %
Pigment 2.1 ~
Nonvolatile 28.1 %
Binder 24.0 %
Weight per Gallon (lbs/gal)8.3 VOC tlbs/gal) 2.2 Gloss, 20 deg 82 Adhesion good Film Thickness (mil) 1.0 Humidity good Water Spray excell.
Metal Control excell.
Example 3 - Preparation of a Waterborne SilveI Metallic Component B 18.0 Neutralization Base Component A 9.1 Aluminum Base Component C 63.6 Clear Base Component D 9.1 Surfactant Base _ __ _ ., ' ~., "
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The above formula was used to prepare a silver metallic base coat. The order of addition is that listed. After each introduction of a component, the entire solution was stirred. The base coat was sprayed on panels primed with an epoxy primer. The base coat was sprayed on the substrate using conventional spray equipment until hiding was achieved. The base coat was allowed to flash for 30 minutes and then clear coated with a transparent coating based on isocyanate technology. The final properties of the base coat after coating with a conventional polyurethane clear coat are listed below, including appearance ratings.
Properties of the Silver Metallic Base Coat and Base Coa~/Clear Coat system Property Value Water 67.9 %
Volatile Organic 12.2 %
Pigment 2.5 %
Nonvolatile 24.4 %
Binder 22.8 %
Weight per Gallon (lbs/gal) 8.3 VOC (lbs/gal) 3.0 Gloss, 20 83 Adhesion good Film Thickness (mil) 0.8 Humidity good Water Spray excell.
Metal Control excell.
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Also disclosed in DE No. 3 210 051 is an attempt to : :: :: :
control metallic pigment orientation using polyurethane dispersions. Cellulosic esters have also been used to control metal fixation as disclosed in DE No. 3 216 549.
In general, the metal fixation in base coats is achieved by a rheology modifiers such as inorganic and organic thickeners. All previous rheology modifiers or rheology control agents for water borne coatings have poor shelve stability, poor weathering characteristics and are cumbersome to use. The particular rheology control agent used in this invention results in a non-mottled, high head-on-brightness, outstanding flop, and high quality finish, even in the case of a silver metallic base coat and does not suffer from the problems cited earlier.
Typically, coating compositions used in the automotive market, especially in the automotive after market, are produced by mixing various bases to give the desired color. These coating compositions are then applied in about 1-5 days after preparation. A major problem is the introduction of aluminum flakes which react with water to generate hydrogen gas. Therefore, the aluminum flake must be segregated from the rest of the waterborne components to minimize this hazard. This invention also describes a method for the storage of aluminum flake in an organic medium with introduction of the flakes into the aqueous ervironment just prior to application of the coating system.
This invention relates to waterborne compositions for use in metallic and nonmet~llic base coats in a multicoat system for the automotive market.
More specially, the present invention is concerned with an acrylic latex coating composition for use in an automotive paint base coat composition. The invention also relates to base coats containing pigments, me-tallic pigments, organic solvents, and conventional paint additives. The outstanding metal control exhibited by this coating composition is attrib~ted to the rheology control agent and the film shrinkage of the latex vehicle while drying. The use of acrylic latex results in a very fast dry time. This coating composition provides a base coat that satisfies current and proposed volatile organic compound regulations. Even with conventional non~metallic pigments, the coating exhibits excellent appearance.
This invention describes a method for the storage of aluminum flake in an organic medium with introduction of the flakes into the aqueous environment just prior to application of the coating system. This method minimizes the potential hazard of the aluminum flake reacting with water to form hydrogen gas during storage. This method can also be used for the storage of other water sensitive pigments such as copper and brass.
Other pigments such as plastic films, mica and coated metallic foils can be stored using this method.
The automotive base coat pain~ comprises five components; A) aluminum base, B) neutralization base, C) clear resin base, D) pigmented base, and E) surfactant base~ Component A, the aluminum base, is composed of metallic flakes slurred into a solvent borne resin and water miscible solvents. The resin used in this component may be a water reducible acrylic, water reducible polyester, or water reducible alkyd. Commonly used metallic pigments, used singularly or as a mixture are copper, copper alloys, aluminum, steel, mica, plastic films, and coated metallic foils, preferably aluminum at a lavel of 10-30 % by weight, preferably 20-30 ~ by weight. The aluminum hase contains 5-40~, preferably 20-30~ by weight of the solvent borne water reducible resin. The organic solvent for this base must be water miscible. Examplss of solvents are methanol, ethanol, propanol, butanol, N-methylpyrrolidone, glycols, glycol esters, glycol acetates, diethylene ~ .:
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glycol ethers, diethylene glycol acetates, propylene glycol esters, propylene glycol acetates, dipropylene glycol, dipropylene glycol acetates, specially preferred are ethylena glycol propyl ether, ethylene glycol butyl ether, ethylene glycol hexyl ether, propylene methyl ether, propylene ethyl ether, propylene propyl ether, propylene butyl ether, propylene hexyl ether, dipropylene methyl ether, dipropylene ethyl ether, dipropylene propyl ether, and dipropylene butyl ether.
Component B, neutralization base, is composed of a solvent borne water reducible resin, neutralized with an amine, preferably ammonia dispersed in water to a level of 10-25 %, preferably 10-20 ~ by weight. Excess amine, preferably ammonia, is added at a level of 1-10 ~, preferably 5-10 %, by weight.
Component C, clear resin base, contains; 1) acrylic latex polymer at a level of 10-50 ~, preferably 25-35 %, 2) 0-15 ~ water miscible solvent, preferably 5-12 %, 3) 0.5-5.0 % hydrophilic silica, prefe.rably 1.5-2.5 %. The hydrophilic silica can be dispersed into the acrylic late~ polymer by normal dispersing techniques.
Component D, pigment base, contains acrylic latex grinding polymer at a level of 5-50 ~, preferably 15-30 ~. This level depends on the pigment in the component. The level of pigment in component D is 0.5-35 % by weight, this level depends on the pigment characteristics also. Typically, a pigment to binder weight ratio of about 10/100 to 300/100 is acceptable.
The pigments are typically ground using conventional dispersion equipment such as sand mills, pearl mills, ball mills, horizontal mills, and vertical mills.
Optional wetting agents, surfactants, and dispersing aids can be employed.
Component E, surfactant base, contains a polymer fluorocarbon surfactant at a level of 0.1-4.0 ~, preferably 2.0-3.0 % in water.
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This invention is directed to a coating composition for a water borne base coat especially designed for the automotive market. This invention describes a method for the introduction of m~tallic flakes into a waterborne coating resulting in a highly superior base coat. The proper metal fixation is accomplished by the use of a novel rheology control agent which employs hydrophilic silica and a polymeric nonionic fluorocarbon surfactant. The novel rheology 10 control agent described and claimed in copending related US application and filed and incorporated herein by re~erence. The basecoat is broken down into five bases that are combined just prior to application of the base coat.
The invention describes a method for the storage of aluminum flake in an organic medium with introduction of the flakes into the aqueous environment just prior to application of the coating system. This method minimizes the potential hazard of the aluminum 20 flake reacting with water to form hydrogen gas during storage.
Component A, aluminum base, is an aluminum slurry in an organic environnient containing either a low to moderate acid number acrylic or polyester or alkyd.
25 The acid number of these polymers based on solids should be about 15 to 65. The preferred polymer is a water reducible solvent borne acrylic modified with glycidyl esters. The acrylic polymer is prepared via normal solution polymerization techniques. The acrylic polymer 30 is composed of; 1) 3-5 ~ by weight of an ethylenically unsaturated carboxylic acid such as methacrylic acid and acrylic acid, preferably methacrylic acid, 23 15-30 % by weight methylmethacylate, 3) 5-20 ~ by weight 2-ethylhydroxymethacrylate, 4) 1-10 % by weight isobornyl methacrylate, and 5) optionally 5 20 % by weight of a glycidyl ester of a tertiary C10 fatty acid. The acrylic ; , .- . : : : :~ :
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polymer is prepared in organic solvents that are water miscible, such as methyl ethyl ketone, acetone, ethanol, methanol, propanol, butanol, N-methylpyrrolidone, glycols, glycol ethers, glycol acetates, diethylene glycol ethers, diethylene glycol acetates, propylene glycol ethers, propylene glycol acetates, dipropylene glycol ethers, dipropylene glycol acetates, specially preferred are ethylene glycol propyl ether, ethylene glycol butyl ether, ethylene glycol hexyl ether, propylene methyl ether, propylene ethyl ether, propylene propyl ether, propylene butyl ether, propylene hexyl ether, dipropylene methyl ether, dipropylene ethyl ether, dipropylene propyl ether, methyl ethyl ketone and dipropylene butyl ether. Optionally, surfactants can also be present during the polymerization at a level of 0.1-2O0 ~ by weight. The viscosity of the final polymer is 16000 to 18000 cps with a solids content of 50-75 ~
by weight, preferably 55-65 ~ by weight. The acid number of the polymer based on solids should be 10-70, preferably 15-65.
Any commercial aluminum paste available for solvent borne or waterborne applications can be used in the preparation of component A. The amount of aluminum flake in the component is 4-30 ~ by welght, preferably 23-30 ~ by weight.
Other nonmetallic and metallic pigments that can be incorporated lnto this base include copper, copper alloys, mica, coated metallic foils, plastic flakes and steel. However, this is not a conclusive list.
Additional organic solvent may be needed to reduce the viscosity of the acrylic resin. Acceptable solvents must be water miscible such as methyl ethyl ketone, acetone, ethanol, methanol, propanol, butanol, N-methylpyrrolidone, glycols, glycol ethers, glycol acetates, diethylene glycol ethers, diethylene glycol 2 ~ ~3~J`~ l acetates, propylene glycol ethers, propylene glycol acetates, dipropylene glycol ethers, dipropylene glycol acetates, specially preferred are ethylene glycol propyl ether, ethylene glycol butyl ether, e~hylene glycol hexyl ether, propylene methyl ether, propylene ethyl ether, propylene propyl ether, propylene butyl ether, propylene hexyl ether, dipropylene methyl ether, dipropylene ethyl ether, dipropylene propyl ether, and dipropylene butyl ether. Component A has a to~al solids of 25 ~ to 50 ~ by weight, 5 % to 35 % binder by weight, and 35 ~ to 50 ~ organic solvent by weight. Additional wetting, anti-settling additives common to the paint industry may be added.
The preparation of component A, the aluminum base, is critical for the proper appearance of the aluminum flake in the final coating. The proper amount of the acrylic resin solution is dissolved into the proper amount of water miscible organic solvent, such as methyl ethyl ketone, acetone, ethanol, methanol, propanol, butanol, N-methylpyrrolidone, glycols, glycol ethers, glycol acetates, diethylene glycol ethers, diethylene glycol acetates, propylene glycol ethers, propylene glycol acetates, dipropylene glycol ethers, dipropylene glycol acetates, specially preferred are ethylene glycol propyl ether, ethylene glycol butyl ether, ethylene glycol hexyl ether, propylene methyl ether, propylene ethyl ether, propylene propyl ethex, propylene butyl ether, propylene hexyl ether, dipropylene methyl ether, dipropylene ethyl ether, dipropylene propyl ether, and dipropylene butyl ether.
The proper amount of the aluminum paste is slurred into the above described resin solutionO The aluminum slurry must be stirred until the bas~ is smooth and uniform.
Component B, neutralization base, is an aqueous solution containing dispersed acrylic resin and ammonia. The acrylic described above is used in the ' ;~' ' `~ -- , . : . , :
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component. Other water reducible resins such as polyester and alkyds may be used. An aqueous solution containing O.l-15.0 ~, preferably 0.1-8.0 ~ ammonia by weight is prepared. The correct amount of the acrylic resin, usually 5-25 ~ by weight, preferably 10-20 % by weight, is added to the basic aqueous solution and stirred~ The resulting solution should be clear to slightly turbid and have a pH range of 7.5 10.0, preferably 8.0 to 10Ø The r4sulting solution should have a nonvolatile range of 5-25 ~ by weight,preferably 10-20 ~.
Component C, clear resin base, of the coatlng composition contains an acrylic latex. Typical properties of this acrylic latex are as follows:
Solids content, % 20-60 pH 7 -to 10 Weight per gallon, lbs 8.0 to 9.0 Minimum film formation temperature, C O to 70 Sward hardness 25 to 110 Mechanical stability OK
Glass transitition temperature, C 10 to 50 Average molecular weight 150,000 to 300,000 Number average molecular weight 30,000 to 60,000 Acid number on solids 5 to 35 Volatile organic solvents, ~ O to 20 Particle size, nm 50 to 150 Specially preferred acrylic latics are Neocryl A-622, Neocryl A-640, Neocryl A-6037 sold by ICI
resins, Joncryl J-537, Joncryl J-538 sold by Johnson Wax, Arolon 860-W-45 sold by NL Industries. The amount of this acrylic latex in this component is 15 45 % by weight, preferably 25-35 ~ by weight. The level of organic solvent in this component is 5.0-30 % by weight, preferably 5-15 ~ by weight, and the solvent must be water miscible. Examples of water miscible solvents are methyl ethyl ketone, acetone, ethanol, methanol, 2 ~
propanol, butanol, N-methylpyrrolidone, gly~ols, glycol ethers, glycol acetates, diethylene glycol ethers, diethylene glycol acetates, propylene glycol ethers, propylene glycol acetates, dipropylene glycol ethers, diprcpylene glycol acetates, specially preferred are ethylene glycol propyl ether, ethylene glycol butyl ether,~ ethylene glycol hexyl ether, propylene methyl ether, propylene ethyl ether, propylene propyl ether, propylene butyl ether, propylene hexyl ether, dipropylene methyl ether, dipropylene ethyl ether, dipropylene propyl ether, and dipropylene butyl ether.
This component may also contain other conventional paint additives such as thickening agents, extenders, plasticizers, stabilizers,light stabilizers, wetting agents, waxes, antifoams, defoamers and catalysts, singly or a multitude of them at the conventional levels.
Hydrophilic colloidal silica is also present in this component at a level o~ 1.0-8.0 % by weight, preferably 2.0-3.0 % by weight. The particle size of the hydrophilic colloidal silica is about 1.0 10,000 millimicron and a surface area of about 50-1200 square meters per gram. The silica is about 99.8 ~ silicon dioxide by weight and exist in three dimensional branched chain aggregates and has a surface that is hydrophilic and capable of hydrogen bonding. The silica is dispersed into the above resin solution using conventional techniques, such as ball mills, pebble mills, horizontal mills vertical mills and ~earl mills.
The total nonvolatile range o~ this component is 20-50 %, preferably 25-35 ~ by weight.
Component D, pigmented base, imparts the coloring effect upon the coating composition. The resin used for the dispersing of the pigments is an acrylic latex. Typical properties of this acrylic latex are as follows:
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la Solids content, ~ 20-60 pH 7 to 10 Weight per gallon, lbs 8.0 to 9.0 Minimum film formation tamperature, C 0 to 70 Sward hardness 25 to 110 Mechanical stability OK
Glass transitition temperature, C 10 to 50 Average molecular weight 150,000 to 300,000 Number average molecular weight 30,000 to 60,000 Acid number on solids 5 to 35 Volatile or~anic solvents, ~ 0 to 20 Particle size, nm 50 to 150 Specially preferrad acrylic latics are Neocryl A-622, Neocryl A-640, Neocryl A-6037 sold by ICI
resins, Joncryl J-537, Joncryl J-538 sold by Johnson Wax, Arolon 860-W-45 sold by NL Industries. The level of this resin in component D is 15-60 ~ by weight, preferably 20 40 % by weigh-t. The organic, inorganic pigments and/or dyestuffs are ground with this resin employin~ standard techniques. Examples of dispersing equipment are ball mills, pebble mills, pearl mills, horizontal mills, and vertical mills. Examples of pigments and dyestuffs but not limited to are -titanium dioxide, graphite, carbon black, zinc oxide, cadminum sulfide, chromium oxide, zinc sulfide, zinc chromate, strontium chromate, barium chromate, lead chromate lead cyanamide, lead silico chromate, chromium oxide, zinc sulfide, yellow nickel titanium, yellow chromium titanium, red iron oxide, transparent red oxide, 3Q transparent yellow oxide, black iron oxide, ultramarine blue, phthalocyanine complexes, amaranth, quinacridones, and halogenated thioindigo pigments. The level of pigment/dyestuff in Component D is 0.1 to 35.0 % by weight, typically 5-25 %. This component may also contain other conventional paint additives such as dispersing aids, anti-settling aids, we~ting aids, ~(~3~J`~
thickening agents, extenders, plasticizers, stabilizers, light stabilizers, waxes, antifoams, defoamers and catalysts singly or a multitude of them at the conventional levels. Also present in this component is a water miscible solvent such as methyl ethyl ketone, acetone, ethanol, methanol, propanol, butanol, N-methylpyrrolidone, glycols, glycol ethers, glycol acetates, diethylene glycol ethers, diethylene glycol acetates, propylene glycol ethers, propylene glycol acetates, dipropylene glycol ethers, dipropylene glycol acetates, specially preferred are ethylene glycol propyl ether, ethylene glycol butyl ether, ethylene glycol hexyl ether, propylene methyl ether, propylene ethyl ether, propylene propyl ether, propylene butyl ether, propylene hexyl ether, dipropylene methyl ether, dipropylene ethyl ether, dipropylene propyl ether, and dipropylene butyl ether at a level of 0 to 25 ~ by weight, preferably 0-12 % by weight.
Component E, surfactant base, contains a polymeric nonionic fluorocarbon surfactant at a level of 0.1 to 5 % by weight, preferably 2.0 to 3.0 ~ by weight, in water. The polymeric nonionic fluorocarbon surfactant contains ethylene oxide linkages, has a weight average molecular weight of about 5,000 to 50,000 and contains 2-25 ~ of fluorine by weight of the surfactant. One preferred nonionic fluorocarbon polymer contains about 30-70 ~ by weight ethylene oxide linkages, 10-20 % by weight of fluorine and has a weight average molecular weight of about 10,~00-30,000.
The final coating composition is produced by mixing Components A through E together in order and at appropriate levels to give the desired color and metallic effect. Typically, the solids of the final coating is 5 to 30 % by weight, organic levels 5 to L5 %
by weight. The rheology of the coating is defined by the amount of colloidal silica and polymeric nonionic , fluorocarbon surfactant present in the coating. The level of colloidal silica is 0.5 to 5.0 ~ and 0.05 to 1.0 % of polymeric nonionic fluorocarbon surfactant by weight of water used in the final base coat formulation.
The water content ranges between 30 to 90 ~ by weight of the final base coat composition.
Other water reducible resin may be added to the coating to improve certain film properties such as aqueous one component aliphatic polyurethane dispersions, polyesters, and alkyds.
Additional anionic and nonionic surfactants can be added to the paint composition to increase wetting of the substrate by the coating such as FC-120, FC-430 sold by 3M, Surfonyl 104, Surfonyl 440 sold by Air Products, Triton X100 sold by Rohm and Haas, Troysol LAC sold by Troy Chemical Company, Aerosol OT's sold by American Cyanamid including the salts of dialkyl sulfosuccinates and Igepal's sold by GAF including the ethoxylated alkyl phenols.
The viscosity of the final base coat is about 10 Pas at a shear rate of 0.001 1/s and 0.05 at a shear rate of 1,000 1/s. This base coat exhibits a very high viscosity at low shear rate while having a low viscosity at high shear rates. This phenomenon results in the outstanding metal effect this coating composition possesses. The efflux time of the coating through a ~4 Ford cup is 15 to 30 seconds at 23 C.
The coating composition can be applied using conventional spray equipment or high volume low pressure spray equipment resulting in a high quality finishO
After a flash off time of 15 to 45 minutes, a transparent top coat can be applied over this basecoat.
Example of transparent top coats are two component, based on acrylic and/or polyester resins cured with polyisocyanates, silanes, and acid cured epo~y coatings, however, this is not an inclusive list. The preferred , 2 ~
transparent top coat is a two component acrylic polyisocyanate coating.
The following examples illustrate the invention without limiting the scope thereof.
Example 1; Base Coat Preparation Preparation of an Acrylic Polymer modified with A Glycidyl Ester of Tertiary C10 Fatty Acid.
A five liter three neck round bottomed flask was fitted with an agitator, thermometer, condenser, nitrogen inlet and monomer inlet ~nd charged with 680 g of methoxypropanol, 20 g of methyl ethyl ketone. The mixture was brought to reflux and the temperature adjusted to 140-141 C by adding 5.0 ~ of methyl ethyl ketone. A monomer solution was prepared containing 333 g of propenoic acid, 847 g of methyl-2-methyl-2-propionate, 450 g of 2~ethylhexyl~2-methylpropionate, 180 g of isobornyl-2-methyl-2-propionate and 27 g of Surfynol 440. An initiator solution was also prepared containing 36 g of t-butyl peroxybenzoate and 76 g of methoxypropanol. The above monomer solution and initiator solutions were added to the reaction flask at a uniform rate over two hours. After completion of the additions, the monomer line was flushed with 35.0 g of methoxypropanol and a solution containing 15 g of t-butylperoxybenzoate and 40 g of methoxypropanol was then added over 10 minutes. The reaction was then refluxed for an additional 135 minutes. After refluxing, 475 ~ of a glycidyl ester of a tertiary C10 fatty acid was added to the flask, heated to reflux and reacted to constant acid value. The reaction was allowed to cool, then 43 g of methoxypropanol and 588 g of ethanol were added to the resin to reduce the viscosity. The properties of the resin are: viscosity Z5-Z6, solids 60-61 %, and acid number of 53 to 56 based on solids.
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Preparation of Component A - Aluminum Base The acrylic resin described above, 44.0 g, was added to 19.0 g o butoxyethanol. This mixture was stirred until a homogeneous solution was produced. A
commercial solvent borne aluminum paste, 38.0 g was added to the resin solution. The resulting slurry was then stirred until a smooth, uniform slurry was produced. This aluminum base contains 49.8 % by weight of volatile organic solvents, 38.4 % by weight of solids, and 24.3 ~ by weight of aluminum flake.
Preparation of Component B - Neutralization Base To 300 g of deionized water, 8.0 g of 30 aqueous ammonia was added. the solution was stirred well before adding 100.0 g of the acrylic resin described above. The resulting mixture was stirred until the solution was clear to slightly turbid. The nonvolatile level of this base was 14.8 % by weight, water level 74.9 ~ by weight, volatile organic solvent 9.8 % by weight. The final pH of this dispersion was 9.2.
Preparation of Component C - Clear Resin Latex Premixed were 48.0 g of hydrophilic colloidal silica, 10.0 g of a defoamer and 1865 g of Neocryl A-622. This mixture was then ground on a horizontal mill until a particle size of less than 8 microns was achieved. Deionized water, 260 g, was then added to the above slurry under agitation to yield a uniform latex solution. The level of silica was 2.2 ~ by weight. Volatile organic level was 8.9 % by weight and solids level was 28.3 % by weight.
Preparation of Component D - Pigmented Bases The ollowing pigment slurry was prepared, 80 g Neocryl A-6037, 2.1 g of 30 ~ aqueous ammonia, 23.9 g of transparent red oxide, and 0.2 g of a defoamer. The above components were mixed together and predispersed - : ,, , :
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using a Cowles blade. The mixture was then ground on a horizontal mill until the desired particle size was achieved. A let down solution containing 70.0 g of Neocryl A-6037 and 2.0 g of 30 % aqueous ammonia was added to the grind portion. The resulting pigment paste was reduced under agita~ion with a solution containing 5.75 g of deioni~ed water, 19.2 g o* butoxyethanol. The resulting pigmented base had a pH of 9.2, a solids level of 48 % by weight, a volatile organic level of 9.4 % by weight, a binder level of 36.2 ~ by weight, a pigment level of 11.8 ~ by weight and a water level of 42.0 % by weight.
Preparation of Component E - Surfactant Base To 48 g of deionized water, 2.0 g of a polymeric nonionic fluorocarbon surfactant was added.
The mixture was stirred to give a slightly turbid solution.
Example 2 - Preparation of a Waterborne Red Metallic Base Coat Component Parts by Weight Component B 4.0 Neutralization Base Component A 2.0 Aluminum Base Component C 72.0 Clear Resin Base Component D 13.0 Pigmented Base Component E 9.0 Surfactant 8ase The above formula was used to prepare a red metallic base coat. The order of addition is that listed. After each introduction of a component, the entire solution was stirred. The base coat was sprayed on panels primed with an epoxy primer. The base coat was sprayed on the substrate using conventional spray ; : , : . .
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equipment until hiding was achieved. The basecoat was allowed to flash for 30 minutes and ~h~n clear coated with a transparent coating based on isocyanate technology. The final properties of the base coat after coating with a conventional polyurethane clear coat are listed below, including appearance ratings.
Properties of the Red Metallic Base Coat and Base Coat/Clear Coat System Property Value Water 68.9 %
Volatile Organic 9.1 %
Pigment 2.1 ~
Nonvolatile 28.1 %
Binder 24.0 %
Weight per Gallon (lbs/gal)8.3 VOC tlbs/gal) 2.2 Gloss, 20 deg 82 Adhesion good Film Thickness (mil) 1.0 Humidity good Water Spray excell.
Metal Control excell.
Example 3 - Preparation of a Waterborne SilveI Metallic Component B 18.0 Neutralization Base Component A 9.1 Aluminum Base Component C 63.6 Clear Base Component D 9.1 Surfactant Base _ __ _ ., ' ~., "
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The above formula was used to prepare a silver metallic base coat. The order of addition is that listed. After each introduction of a component, the entire solution was stirred. The base coat was sprayed on panels primed with an epoxy primer. The base coat was sprayed on the substrate using conventional spray equipment until hiding was achieved. The base coat was allowed to flash for 30 minutes and then clear coated with a transparent coating based on isocyanate technology. The final properties of the base coat after coating with a conventional polyurethane clear coat are listed below, including appearance ratings.
Properties of the Silver Metallic Base Coat and Base Coa~/Clear Coat system Property Value Water 67.9 %
Volatile Organic 12.2 %
Pigment 2.5 %
Nonvolatile 24.4 %
Binder 22.8 %
Weight per Gallon (lbs/gal) 8.3 VOC (lbs/gal) 3.0 Gloss, 20 83 Adhesion good Film Thickness (mil) 0.8 Humidity good Water Spray excell.
Metal Control excell.
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Claims (44)
1. An automotive paint base coat characterized by that composition consisting of:
a) an aluminum base b) neutralization base c) clear resin base d) pigmented base and e) surfactant base
a) an aluminum base b) neutralization base c) clear resin base d) pigmented base and e) surfactant base
2. The base coat composition of claim 1 wherein the aluminum base consists of:
1) a water reducible solvent borne acrylic resin having an acid number of 15-65 based on solids and a solid content of 50-75 %
by weight, 2) a metallic pigment at a level of 4-30 %
by weight,
1) a water reducible solvent borne acrylic resin having an acid number of 15-65 based on solids and a solid content of 50-75 %
by weight, 2) a metallic pigment at a level of 4-30 %
by weight,
3) 25-55 % total solids by weight,
4) 35-50 % total water miscible organic solvent by weight,
5) 5-35 % total binder by weight.
3. The base coat composition of claim 1 wherein the aluminum base consists of:
1) a water reducible solvent borne acrylic resin having an acid number of 15-65 based on solids and a solid content of 50-75 %
by weight, 2) a solvent borne aluminum flake at a level of 4-30 % by weight, 3) 25-55 % total solids by weight, 4) 35-50 % total water miscible organic solvent by weight, 5) 5-35 % total binder by weight.
4. The base coat composition of claim 1 wherein the aluminum base consists of:
1) a water reducible solvent borne acrylic resin having an acid number of 15-65 based on solids and a solid content of 50-75 %
by weight, 2) an aluminum flake treated for water stability at a level of 4-30 % by weight, 3) 25-55 % total solids by weight, 4) 35-50 % total water miscible organic solvent by weight, 5) 5-35 % total binder by weight.
5. The base coat composition of claim 1 wherein the aluminum base consists of:
1) a water reducible solvent borne acrylic resin having an acid number of 15-65 based on solids and a solid content of 50-75 %
by weight, 2) a mica flake at a level of 4-30 % by weight, 3) 25-55 % total solids by weight, 4) 35-50 % total water miscible organic solvent by weight, 5) 5-35 % total binder by weight.
3. The base coat composition of claim 1 wherein the aluminum base consists of:
1) a water reducible solvent borne acrylic resin having an acid number of 15-65 based on solids and a solid content of 50-75 %
by weight, 2) a solvent borne aluminum flake at a level of 4-30 % by weight, 3) 25-55 % total solids by weight, 4) 35-50 % total water miscible organic solvent by weight, 5) 5-35 % total binder by weight.
4. The base coat composition of claim 1 wherein the aluminum base consists of:
1) a water reducible solvent borne acrylic resin having an acid number of 15-65 based on solids and a solid content of 50-75 %
by weight, 2) an aluminum flake treated for water stability at a level of 4-30 % by weight, 3) 25-55 % total solids by weight, 4) 35-50 % total water miscible organic solvent by weight, 5) 5-35 % total binder by weight.
5. The base coat composition of claim 1 wherein the aluminum base consists of:
1) a water reducible solvent borne acrylic resin having an acid number of 15-65 based on solids and a solid content of 50-75 %
by weight, 2) a mica flake at a level of 4-30 % by weight, 3) 25-55 % total solids by weight, 4) 35-50 % total water miscible organic solvent by weight, 5) 5-35 % total binder by weight.
6. The base coat composition of claim 1 wherein the neutralization base consists of:
1) 0.1-15 % by weight ammonia, 2) 5-25 % by weight of the acrylic described in claim 2, 3) a pH in the range of 7.5-10.0 4) 5-25 % by weight solids.
1) 0.1-15 % by weight ammonia, 2) 5-25 % by weight of the acrylic described in claim 2, 3) a pH in the range of 7.5-10.0 4) 5-25 % by weight solids.
7. The base coat composition of claim 1 wherein the aluminum base consists of:
1) a water reducible solvent borne polyester resin having an acid number of 15-65 based on solids and a solid content of 50-75 by weight, 2) a metallic pigment at a level of 4-30 by weight, 3) 25-55 % total solids by weight, 4) 35-50 % total water miscible organic solvent by weight, 5) 5-35 % total binder by weight.
1) a water reducible solvent borne polyester resin having an acid number of 15-65 based on solids and a solid content of 50-75 by weight, 2) a metallic pigment at a level of 4-30 by weight, 3) 25-55 % total solids by weight, 4) 35-50 % total water miscible organic solvent by weight, 5) 5-35 % total binder by weight.
8. The base coat composition of claim 1 wherein the aluminum base consists of:
1) a water reducible solvent borne polyester resin having an acid number of 15-65 based on solids and a solid content of 50-75 %
by weight, 2) a solvent borne aluminum flake at a level of 4-30 % by weight, 3) 25-55 % total solids by weight, 4) 35-50 % total water miscible organic solvent by weight, 5) 5-35 % total binder by weight.
1) a water reducible solvent borne polyester resin having an acid number of 15-65 based on solids and a solid content of 50-75 %
by weight, 2) a solvent borne aluminum flake at a level of 4-30 % by weight, 3) 25-55 % total solids by weight, 4) 35-50 % total water miscible organic solvent by weight, 5) 5-35 % total binder by weight.
9. The base coat composition of claim 1 wherein the aluminum base consists of:
1) a water reducible solvent borne polyester resin having an acid number of 15-65 based on solids and a solid content of 50-75 %
by weight, 2) an aluminum treated for water stability at a level of 4-30 % by weight, 3) 25-55 % total solids by weight, 4) 35-50 % total water miscible organic solvent by weight, 5) 5-35 % total binder by weight.
1) a water reducible solvent borne polyester resin having an acid number of 15-65 based on solids and a solid content of 50-75 %
by weight, 2) an aluminum treated for water stability at a level of 4-30 % by weight, 3) 25-55 % total solids by weight, 4) 35-50 % total water miscible organic solvent by weight, 5) 5-35 % total binder by weight.
10. The base coat composition of claim 1 wherein the aluminum base consists of:
1) a water reducible solvent borne polyester resin having an acid number of 15-65 based on solids and a solid content of 50-75 by weight, 2) a mica flake at a level of 4-30 % by weight, 3) 25-55 % total solids by weight, 4) 35-50 % total water miscible organic solvent by weight, 5) 5-35 % total binder by weight.
1) a water reducible solvent borne polyester resin having an acid number of 15-65 based on solids and a solid content of 50-75 by weight, 2) a mica flake at a level of 4-30 % by weight, 3) 25-55 % total solids by weight, 4) 35-50 % total water miscible organic solvent by weight, 5) 5-35 % total binder by weight.
11. The base coat composition of claim 1 wherein the neutralization base consists of:
l) 0.1-15 % by weight ammonia, 2) 5-25 % by weight of the polyester described in claim 7, 3) a pH in the range of 7.5-10.0, 4) 5-25 % by weight solids.
l) 0.1-15 % by weight ammonia, 2) 5-25 % by weight of the polyester described in claim 7, 3) a pH in the range of 7.5-10.0, 4) 5-25 % by weight solids.
12. The base coat composition of claim 1 wherein the aluminum base consists of:
1) a water reducible solvent borne alkyd resin having an acid number of 15-65 based on solids and a solid content of 50-75 by weight, 2) a metallic pigment at a level of 4-30 %
by weight, 3) 25-55 % total solids by weight, 4) 35-50 % total water miscible organic solvent by weight, 5) 5-35 % total binder by weight.
1) a water reducible solvent borne alkyd resin having an acid number of 15-65 based on solids and a solid content of 50-75 by weight, 2) a metallic pigment at a level of 4-30 %
by weight, 3) 25-55 % total solids by weight, 4) 35-50 % total water miscible organic solvent by weight, 5) 5-35 % total binder by weight.
13. The base coat composition of claim 1 wherein the aluminum base consists of:
1) a water reducible solvent borne alkyd resin having an acid number of 15-65 based on solids and a solid content of 50-75 %
by weight, 2) a solvent borne aluminum flake at a level of 4-30 % by weight, 3) 25-55 % total solids by weight, 4) 35-50 % total water miscible organic solvent by weight, 5) 5-35 % total binder by weight.
1) a water reducible solvent borne alkyd resin having an acid number of 15-65 based on solids and a solid content of 50-75 %
by weight, 2) a solvent borne aluminum flake at a level of 4-30 % by weight, 3) 25-55 % total solids by weight, 4) 35-50 % total water miscible organic solvent by weight, 5) 5-35 % total binder by weight.
14. The base coat composition of claim l wherein the aluminum base consists of:
1) a water reducible solvent borne alkyd resin having an acid number of 15-65 based on solids and a solid content of 50-75 %
by weight, 2) an aluminum flake treated for water stability at a level of 4-30 % by weight, 3) 25-55 % total solids by weight, 4) 35-50 % total water miscible organic solvent by weight, 5) 5-35 % total binder by weight.
1) a water reducible solvent borne alkyd resin having an acid number of 15-65 based on solids and a solid content of 50-75 %
by weight, 2) an aluminum flake treated for water stability at a level of 4-30 % by weight, 3) 25-55 % total solids by weight, 4) 35-50 % total water miscible organic solvent by weight, 5) 5-35 % total binder by weight.
15. The base coat composition of claim 1 wherein the aluminum base consists of:
1) a water reducible solvent borne alkyd resin having an acid number of 15-65 based on solids and a solid content of 50-75 %
by weight, 2) a mica flake at a level of 4-30 % by weight, 3) 25-55 % total solids by weight, 4) 35-50 % total water miscible organic solvent by weight, 5) 5-35 % total binder by weight.
1) a water reducible solvent borne alkyd resin having an acid number of 15-65 based on solids and a solid content of 50-75 %
by weight, 2) a mica flake at a level of 4-30 % by weight, 3) 25-55 % total solids by weight, 4) 35-50 % total water miscible organic solvent by weight, 5) 5-35 % total binder by weight.
16. The base coat composition of claim 1 wherein the neutralization base consists of:
1) 0.1-15 % by weight ammonia, 2) 5-25 % by weight of the alkyd described in claim 12, 3) a pH in the range of 7.5-10.0, 4) 5-25 % by weight solids.
1) 0.1-15 % by weight ammonia, 2) 5-25 % by weight of the alkyd described in claim 12, 3) a pH in the range of 7.5-10.0, 4) 5-25 % by weight solids.
17. The base coat composition of claim 1 wherein the clear resin base consists of:
1) an acrylic latex having a solids level of 20-60 % by weight and a glass transition temperature of 10-50 °C, 2) water miscible solvent at a level of 1.0 -12.0 % by weight, 3) hydrophilic colloidal silica at a level of 1.0-8.0 % by weight, 4) total solids of 20-60 % by weight.
1) an acrylic latex having a solids level of 20-60 % by weight and a glass transition temperature of 10-50 °C, 2) water miscible solvent at a level of 1.0 -12.0 % by weight, 3) hydrophilic colloidal silica at a level of 1.0-8.0 % by weight, 4) total solids of 20-60 % by weight.
18. The base coat composition of claim 1 wherein the clear resin base consists of:
1) an acrylic latex having a solids level of 20-60 % by weight and a glass transition temperature of 10-50 °C, 2) water miscible solvent at a level of 1.0 -12.0 % by weight, 3) hydrophilic colloidal silica having a particle size of l.0-10,000 millimicrons at a level of 1.0-8.0 % by weight, 4) total solids of 20-60 % by weight.
1) an acrylic latex having a solids level of 20-60 % by weight and a glass transition temperature of 10-50 °C, 2) water miscible solvent at a level of 1.0 -12.0 % by weight, 3) hydrophilic colloidal silica having a particle size of l.0-10,000 millimicrons at a level of 1.0-8.0 % by weight, 4) total solids of 20-60 % by weight.
19. The base coat composition of claim 1 wherein the pigmented base consists of:
1) an acrylic latex having a solids level of
1) an acrylic latex having a solids level of
20-60 % by weight and a glass transition temperature of 10-50 °C, 2) water miscible solvent at a level of 0-25 % by weight, 3) inorganic/organic pigments at a level of 0.1-45.0 % by weight, 4) total solids of 5-60 % by weight.
20. The base coat composition of claim 1 wherein the pigmented base consists of:
1) an acrylic latex having a solids level of 20-60 % by weight and a glass transition temperature of 10-50 °C, 2) water miscible solvent at a level of 0-25 % by weight, 3) inorganic/organic dyestuffs at a level of 0.1-45.0 % by weight, 4) total solids of 5-60 % by weight.
20. The base coat composition of claim 1 wherein the pigmented base consists of:
1) an acrylic latex having a solids level of 20-60 % by weight and a glass transition temperature of 10-50 °C, 2) water miscible solvent at a level of 0-25 % by weight, 3) inorganic/organic dyestuffs at a level of 0.1-45.0 % by weight, 4) total solids of 5-60 % by weight.
21. The base coat composition of claim 1 wherein the surfactant in the surfactant base, used at a level of 0.1-5.0 % by weight in water, is selected from the group consisting of:
a) a polymeric nonionic fluorocarbon surfactant containing 2-25 % fluorine by weight of the surfactant, b) a polymeric nonionic fluorocarbon surfactant having an average molecular weight of 5,000 to 50,000, c) a polymeric nonionic fluorocarbon surfactant having 30-70 % ethylene oxide linkages by weight of the surfactant.
a) a polymeric nonionic fluorocarbon surfactant containing 2-25 % fluorine by weight of the surfactant, b) a polymeric nonionic fluorocarbon surfactant having an average molecular weight of 5,000 to 50,000, c) a polymeric nonionic fluorocarbon surfactant having 30-70 % ethylene oxide linkages by weight of the surfactant.
22. The base coat composition of claim 1 that is further overcoated with a clear coat composition.
23. The base coat composition of claim 1 that is further overcoated with a polyurethane clear coat composition.
24. A method of forming a basecoat composition consisting of mixing:
a) an aluminum base with a, b) neutralization base, and then the further addition of c) clear resin base, d) pigmented base and, e) surfactant base.
a) an aluminum base with a, b) neutralization base, and then the further addition of c) clear resin base, d) pigmented base and, e) surfactant base.
25. A method according to claim 24 wherein the aluminum base consists of:
a) a water reducible solvent borne acrylic resin having an acid number of 15-65 based on solids and a solid content of 50-75 %
by weight, b) a metallic pigment at a level of 4-30 %
by weight, c) 25-55 % by weight total solids, d) 35-50 % by weight total water miscible organic solvent, e) 5-35 % by weight total binder.
a) a water reducible solvent borne acrylic resin having an acid number of 15-65 based on solids and a solid content of 50-75 %
by weight, b) a metallic pigment at a level of 4-30 %
by weight, c) 25-55 % by weight total solids, d) 35-50 % by weight total water miscible organic solvent, e) 5-35 % by weight total binder.
26. A method according to claim 24 wherein the aluminum base consists of:
a) a water reducible solvent borne acrylic resin having an acid number of 15-65 based on solids and solids content of 50-75 by weight, b) a solvent borne aluminum flake at a level of 4-30 % by weight, c) 25-55 % by weight total solids, d) 35-50 % by weight total water miscible organic solvent, e) 5-35 % by weight total binder.
a) a water reducible solvent borne acrylic resin having an acid number of 15-65 based on solids and solids content of 50-75 by weight, b) a solvent borne aluminum flake at a level of 4-30 % by weight, c) 25-55 % by weight total solids, d) 35-50 % by weight total water miscible organic solvent, e) 5-35 % by weight total binder.
27. A method according to claim 24 wherein the aluminum base consists of:
a) a water reducible solvent borne acrylic resin having an acid number of 15-65 based on solids and solids content of 50-75 by weight, b) an aluminum flake treated for water stability, at a level of 4-30 % by weight, c) 25-55 % by weight total solids, d) 35-50 % by weight total water miscible organic solvent, e) 5-35 % by weight total binder.
a) a water reducible solvent borne acrylic resin having an acid number of 15-65 based on solids and solids content of 50-75 by weight, b) an aluminum flake treated for water stability, at a level of 4-30 % by weight, c) 25-55 % by weight total solids, d) 35-50 % by weight total water miscible organic solvent, e) 5-35 % by weight total binder.
28. A method according to claim 24 wherein the aluminum base consists of:
a) a water reducible solvent borne acrylic resin having an acid number of 15-65 based on solids and solids content of 50-75 by weight, b) a mica flake at a level of 4-30 % by weight, c) 25-55 % by weight total solids, d) 35-50 % by weight total water miscible organic solvent, e) 5-35 % by weight total binder.
a) a water reducible solvent borne acrylic resin having an acid number of 15-65 based on solids and solids content of 50-75 by weight, b) a mica flake at a level of 4-30 % by weight, c) 25-55 % by weight total solids, d) 35-50 % by weight total water miscible organic solvent, e) 5-35 % by weight total binder.
29. A method according to claim 24 wherein the neutralization base consists of:
a) 0.1-15 % by weight ammonia, b) 5-25 % by weight of the acrylic described in claim 25, c) a pH in the range of 7.5-10.0, d) 5-25 % by weight total solids.
a) 0.1-15 % by weight ammonia, b) 5-25 % by weight of the acrylic described in claim 25, c) a pH in the range of 7.5-10.0, d) 5-25 % by weight total solids.
30. A method according to claim 24 wherein the aluminum base consists of:
a) a water reducible solvent borne polyester resin having an acid number of 15-65 based on solids and solids content of 50-75 %
by weight, b) a metallic pigment at a level of 4-30 %
by weight, c) 25-55 % total solids by weight, d) 35-50 % total water miscible organic solvent by weight, e) 5-35 % total binder by weight.
a) a water reducible solvent borne polyester resin having an acid number of 15-65 based on solids and solids content of 50-75 %
by weight, b) a metallic pigment at a level of 4-30 %
by weight, c) 25-55 % total solids by weight, d) 35-50 % total water miscible organic solvent by weight, e) 5-35 % total binder by weight.
31. A method according to claim 24 wherein the aluminum base consists of:
a) a water reducible solvent borne polyester resin having an acid number of 15-65 based on solids and solids content of 50-75 %
by weight, b) a solvent borne aluminum flake at a level of 4-30 % by weight, c) 25-55 % total solids by weight, d) 35-50 % total water miscible organic solvent by weight, e) 5-35 % total binder by weight.
a) a water reducible solvent borne polyester resin having an acid number of 15-65 based on solids and solids content of 50-75 %
by weight, b) a solvent borne aluminum flake at a level of 4-30 % by weight, c) 25-55 % total solids by weight, d) 35-50 % total water miscible organic solvent by weight, e) 5-35 % total binder by weight.
32. A method according to claim 24 wherein the aluminum base consists of:
a) a water reducible solvent borne polyester resin having an acid number of 15-65 based on solids and solids content of 50-75 %
by weight, b) an aluminum flake treated for water stability at a level of 4-30 % by weight, c) 25-55 % total solids by weight, d) 35-50 % total water miscible organic solvent by weight, e) 5-35 % total binder by weight.
a) a water reducible solvent borne polyester resin having an acid number of 15-65 based on solids and solids content of 50-75 %
by weight, b) an aluminum flake treated for water stability at a level of 4-30 % by weight, c) 25-55 % total solids by weight, d) 35-50 % total water miscible organic solvent by weight, e) 5-35 % total binder by weight.
33. A method according to claim 24 wherein the aluminum base consists of:
a) a water reducible solvent borne polyester resin having an acid number of 15-65 based on solids and solids content of 50-75 %
by weight, b) a mica flake at a level of 4-30 % by weight, c) 25-55 % total solids by weight, d) 35-50 % total water miscible organic solvent by weight, e) 5-35 % total binder by weight.
a) a water reducible solvent borne polyester resin having an acid number of 15-65 based on solids and solids content of 50-75 %
by weight, b) a mica flake at a level of 4-30 % by weight, c) 25-55 % total solids by weight, d) 35-50 % total water miscible organic solvent by weight, e) 5-35 % total binder by weight.
34. A method according to claim 24 wherein the neutralization base consists of:
a) 0.1-15 % by weight ammonia, b) 5-25 % by weight of the polyester described in claim 30, c) a pH in the range of 7.5-10.0, d) 5-25 % by weight solids.
a) 0.1-15 % by weight ammonia, b) 5-25 % by weight of the polyester described in claim 30, c) a pH in the range of 7.5-10.0, d) 5-25 % by weight solids.
35. A method according to claim 24 wherein the aluminum base consists of:
a) a water reducible solvent borne alkyd resin having an acid number of 15-65 based on solids and solids content of 50-75 %
by weight, b) a metallic pigment at a level of 4-30 %
by weight, c) 25-55 % total solids by weight, d) 35-50 % total water miscible organic solvent by weight, e) 5-35 % total binder by weight.
a) a water reducible solvent borne alkyd resin having an acid number of 15-65 based on solids and solids content of 50-75 %
by weight, b) a metallic pigment at a level of 4-30 %
by weight, c) 25-55 % total solids by weight, d) 35-50 % total water miscible organic solvent by weight, e) 5-35 % total binder by weight.
36. A method according to claim 24 wherein the aluminum base consists of:
a) a water reducible solvent borne alkyd resin having an acid number of 15-65 based on solids and solids content of 50-75 %
by weight, b) a solvent borne aluminum flake at a level of 4-30 % by weight, c) 25-55 % total solids by weight, d) 35-50 % total water miscible organic solvent by weight, e) 5-35 % total binder by weight.
a) a water reducible solvent borne alkyd resin having an acid number of 15-65 based on solids and solids content of 50-75 %
by weight, b) a solvent borne aluminum flake at a level of 4-30 % by weight, c) 25-55 % total solids by weight, d) 35-50 % total water miscible organic solvent by weight, e) 5-35 % total binder by weight.
37. A method according to claim 24 wherein the aluminum base consists of:
a) a water reducible solvent borne alkyd resin having an acid number of 15-65 based on solids and solids content of 50-75 %
by weight, b) an aluminum flake treated for water stability at a level of 4-30 % by weight, c) 25-55 % total solids by weight, d) 35-50 % total water miscible organic solvent by weight, e) 5-35 % total binder by weight.
a) a water reducible solvent borne alkyd resin having an acid number of 15-65 based on solids and solids content of 50-75 %
by weight, b) an aluminum flake treated for water stability at a level of 4-30 % by weight, c) 25-55 % total solids by weight, d) 35-50 % total water miscible organic solvent by weight, e) 5-35 % total binder by weight.
38. A method according to claim 24 wherein the aluminum base consists of:
a) a water reducible solvent borne alkyd resin having an acid number of 15-65 based on solids and solids content of 50-75 by weight, b) a mica flake at a level of 4-30 % by weight, c) 25-55 % total solids by weight, d) 35-50 % total water miscible organic solvent by weight, e) 5-35 % total binder by weight.
a) a water reducible solvent borne alkyd resin having an acid number of 15-65 based on solids and solids content of 50-75 by weight, b) a mica flake at a level of 4-30 % by weight, c) 25-55 % total solids by weight, d) 35-50 % total water miscible organic solvent by weight, e) 5-35 % total binder by weight.
39. A method according to claim 24 wherein the neutralization base consists of:
a) 0.1-15 % by weight ammonia, b) 5-25 % by weight of the alkyd described in claim 35, c) a pH in the range of 7.5-10.0, d) 5-25 % by weight solids.
a) 0.1-15 % by weight ammonia, b) 5-25 % by weight of the alkyd described in claim 35, c) a pH in the range of 7.5-10.0, d) 5-25 % by weight solids.
40. A method according to claim 24 wherein the clear resin base consists of:
a) an acrylic latex having a solids level of 20-60 % by weight and a glass transition temperature of 10-50 C, b) water miscible solvent at a level of 1.0 -12.0 % by weight, c) hydrophilic colloidal silica at a level of 1.0-8.0 % by weight, d) total solids of 20-60 % by weight.
a) an acrylic latex having a solids level of 20-60 % by weight and a glass transition temperature of 10-50 C, b) water miscible solvent at a level of 1.0 -12.0 % by weight, c) hydrophilic colloidal silica at a level of 1.0-8.0 % by weight, d) total solids of 20-60 % by weight.
41. A method according to claim 24 wherein the clear resin base consists of:
a) an acrylic latex having a solids level of 20-60 % by weight and a glass transition temperature of 10-50 C, b) water miscible solvent at a level of 1.0 -12.0 % by weight, c) hydrophilic colloidal silica having a particle size of 1.0-10,000 millimicrons at a level of 1.0-8.0 % by weight, d) total solids of 20-60 % by weight.
a) an acrylic latex having a solids level of 20-60 % by weight and a glass transition temperature of 10-50 C, b) water miscible solvent at a level of 1.0 -12.0 % by weight, c) hydrophilic colloidal silica having a particle size of 1.0-10,000 millimicrons at a level of 1.0-8.0 % by weight, d) total solids of 20-60 % by weight.
42. A method according to claim 24 wherein the pigmented base consists of:
a) an acrylic latex having a solids level of 20-60 % by weight and a glass transition temperature of 10-50 C, b) water miscible solvent at a level of 0 25 % by weight, c) inorganic/organic pigments at a level of 0.1-45.0 % by weight, d) total solids of 5-60 % by weight.
a) an acrylic latex having a solids level of 20-60 % by weight and a glass transition temperature of 10-50 C, b) water miscible solvent at a level of 0 25 % by weight, c) inorganic/organic pigments at a level of 0.1-45.0 % by weight, d) total solids of 5-60 % by weight.
43. A method according to claim 24 wherein the pigmented base consists of:
a) an acrylic latex having a solids level of 20-60 % by weight and a glass transition temperature of 10-50 C, b) water miscible solvent at a level of 0-25 % by weight, c) inorganic/organic dyestuffs at a level of 0.1-45.0 % by weight, d) total solids of 5-60 % by weight.
a) an acrylic latex having a solids level of 20-60 % by weight and a glass transition temperature of 10-50 C, b) water miscible solvent at a level of 0-25 % by weight, c) inorganic/organic dyestuffs at a level of 0.1-45.0 % by weight, d) total solids of 5-60 % by weight.
44. A method according to claim 24 wherein the surfactant in the surfactant base, used at a level of 0.1-5.0 % by weight in water, is selected from the group consisting of:
a) a polymeric nonionic fluorocarbon surfactant containing 2-25 % fluorine by weight of the surfactant, b) a polymeric nonionic fluorocarbon surfactant having an average molecular weight of 5,000 to 50,000, c) a polymeric nonionic fluorocarbon surfactant having 30-70 % ethylene oxide linkages by weight of the surfactant.
a) a polymeric nonionic fluorocarbon surfactant containing 2-25 % fluorine by weight of the surfactant, b) a polymeric nonionic fluorocarbon surfactant having an average molecular weight of 5,000 to 50,000, c) a polymeric nonionic fluorocarbon surfactant having 30-70 % ethylene oxide linkages by weight of the surfactant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA 2030931 CA2030931A1 (en) | 1990-11-27 | 1990-11-27 | Metallic water borne base coat of improved stability and appearance |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA 2030931 CA2030931A1 (en) | 1990-11-27 | 1990-11-27 | Metallic water borne base coat of improved stability and appearance |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2030931A1 true CA2030931A1 (en) | 1992-05-28 |
Family
ID=4146536
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA 2030931 Abandoned CA2030931A1 (en) | 1990-11-27 | 1990-11-27 | Metallic water borne base coat of improved stability and appearance |
Country Status (1)
| Country | Link |
|---|---|
| CA (1) | CA2030931A1 (en) |
-
1990
- 1990-11-27 CA CA 2030931 patent/CA2030931A1/en not_active Abandoned
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