CA2030596A1 - Process of removing and concentrating desired molecules from solutions - Google Patents
Process of removing and concentrating desired molecules from solutionsInfo
- Publication number
- CA2030596A1 CA2030596A1 CA002030596A CA2030596A CA2030596A1 CA 2030596 A1 CA2030596 A1 CA 2030596A1 CA 002030596 A CA002030596 A CA 002030596A CA 2030596 A CA2030596 A CA 2030596A CA 2030596 A1 CA2030596 A1 CA 2030596A1
- Authority
- CA
- Canada
- Prior art keywords
- molecules
- cation
- ligand
- solid
- desired molecules
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title abstract 5
- 150000001768 cations Chemical class 0.000 abstract 4
- 239000007787 solid Substances 0.000 abstract 4
- 150000002500 ions Chemical class 0.000 abstract 3
- 239000011159 matrix material Substances 0.000 abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- 150000001413 amino acids Chemical class 0.000 abstract 2
- 150000001450 anions Chemical class 0.000 abstract 2
- 239000007789 gas Substances 0.000 abstract 2
- 239000003446 ligand Substances 0.000 abstract 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000011780 sodium chloride Substances 0.000 abstract 1
- 125000006850 spacer group Chemical group 0.000 abstract 1
- 231100000331 toxic Toxicity 0.000 abstract 1
- 230000002588 toxic effect Effects 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Landscapes
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
A method is disclosed for the quantitative removal and concentration of desired molecules or ions, such as gases, anions and amino acids, from a source solution which may contain larger concentrations of other molecules. The method comprises bringing the source solution into contact with a solid cation-ligand-matrix consisting of a cation complexed to a ligand molecule covalently bonded to a matrix consisting of an organic spacer bonded to a solid inorganic support through a silicon atom. The cation has an affinity for the desired molecules to form a complex between the desired molecules and the cation portion of the solid cation-ligand-matrix at binding sites initially held by H2O or other weakly coordinated ligands or via ion pairing. The desired molecule complex is broken releasing either the desired molecules or desired molecules complexed with the cation by contacting the solid cation-ligand-matrix-desired molecule complex with a much smaller volume of a receiving solution in which said desired molecules are soluble. The concentrated ions or molecules thus removed may be analyzed and/or recovered by known methods. The process is useful in measuring the concentrations of molecules originally present at parts per billion levels; in the removal of low levels of toxic molecules such as ammonia or anions such as chromate from potable and saline water; in the preparation of ultrapure salts and gases; and in the recovery of valuable molecules present in low concentrations as in the separation of amino acids, etc.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA002030596A CA2030596C (en) | 1990-11-23 | 1990-11-23 | Process of removing and concentrating desired molecules from solutions |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA002030596A CA2030596C (en) | 1990-11-23 | 1990-11-23 | Process of removing and concentrating desired molecules from solutions |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2030596A1 true CA2030596A1 (en) | 1992-05-24 |
CA2030596C CA2030596C (en) | 2003-08-12 |
Family
ID=4146501
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002030596A Expired - Fee Related CA2030596C (en) | 1990-11-23 | 1990-11-23 | Process of removing and concentrating desired molecules from solutions |
Country Status (1)
Country | Link |
---|---|
CA (1) | CA2030596C (en) |
-
1990
- 1990-11-23 CA CA002030596A patent/CA2030596C/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CA2030596C (en) | 2003-08-12 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed |