TW267948B - - Google Patents

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Publication number
TW267948B
TW267948B TW081104359A TW81104359A TW267948B TW 267948 B TW267948 B TW 267948B TW 081104359 A TW081104359 A TW 081104359A TW 81104359 A TW81104359 A TW 81104359A TW 267948 B TW267948 B TW 267948B
Authority
TW
Taiwan
Prior art keywords
compound
affinity
contact
ligand portion
ligand
Prior art date
Application number
TW081104359A
Other languages
Chinese (zh)
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Univ Brigham Young
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Univ Brigham Young filed Critical Univ Brigham Young
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Publication of TW267948B publication Critical patent/TW267948B/zh

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J45/00—Ion-exchange in which a complex or a chelate is formed; Use of material as complex or chelate forming ion-exchangers; Treatment of material for improving the complex or chelate forming ion-exchange properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • B01J20/262—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon to carbon unsaturated bonds, e.g. obtained by polycondensation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3092—Packing of a container, e.g. packing a cartridge or column
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
    • B01J20/3204—Inorganic carriers, supports or substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3214—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the method for obtaining this coating or impregnating
    • B01J20/3217—Resulting in a chemical bond between the coating or impregnating layer and the carrier, support or substrate, e.g. a covalent bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3214—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the method for obtaining this coating or impregnating
    • B01J20/3217—Resulting in a chemical bond between the coating or impregnating layer and the carrier, support or substrate, e.g. a covalent bond
    • B01J20/3219—Resulting in a chemical bond between the coating or impregnating layer and the carrier, support or substrate, e.g. a covalent bond involving a particular spacer or linking group, e.g. for attaching an active group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3244—Non-macromolecular compounds
    • B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
    • B01J20/3257—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one of the heteroatoms nitrogen, oxygen or sulfur together with at least one silicon atom, these atoms not being part of the carrier as such
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3244—Non-macromolecular compounds
    • B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
    • B01J20/3257—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one of the heteroatoms nitrogen, oxygen or sulfur together with at least one silicon atom, these atoms not being part of the carrier as such
    • B01J20/3259—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one of the heteroatoms nitrogen, oxygen or sulfur together with at least one silicon atom, these atoms not being part of the carrier as such comprising at least two different types of heteroatoms selected from nitrogen, oxygen or sulfur with at least one silicon atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3244—Non-macromolecular compounds
    • B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
    • B01J20/3257—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one of the heteroatoms nitrogen, oxygen or sulfur together with at least one silicon atom, these atoms not being part of the carrier as such
    • B01J20/3263—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one of the heteroatoms nitrogen, oxygen or sulfur together with at least one silicon atom, these atoms not being part of the carrier as such comprising a cyclic structure containing at least one of the heteroatoms nitrogen, oxygen or sulfur, e.g. an heterocyclic or heteroaromatic structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3268—Macromolecular compounds
    • B01J20/3272—Polymers obtained by reactions otherwise than involving only carbon to carbon unsaturated bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
    • B01J41/20—Anion exchangers for chromatographic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/50—Aspects relating to the use of sorbent or filter aid materials
    • B01J2220/58—Use in a single column

Abstract

A method for the removal, separation, and concentration of Rh, Ir, and/or Ru from a source solution which may contain larger concentrations of other ions including H+ comprises bringing the source solution into contact with a compound comprising a polyalkylene-polyamine-containing ligand covalently bonded through an organic spacer silicon grouping to a solid inorganic support. The ligand portion(s) of the compound has affinity for complexed anionic species of Rh, Ir, and/or Ru thereby removing them from the source solution. The Rh and/or Ru are first selectively removed from the compound through contact with a much smaller volume of a first receiving solution which changes the Rh and/or Ru speciation to have no affinity for the ligand portion of the compound. The Ir is then removed from the compound through contact with a much smaller volume of a second receiving solution having a greater affinity for the Ir than the ligand portion of the compound or having a greater affinity for the ligand portion of the compound than the Ir species. The concentrated ions thus removed may be further separated and recovered by known methods. The process is useful in the recovery and refining of the valuable Rh and Ir from a variety of sources. The invention is also drawn to the particular highly stable branched polyalkylene-polyamine-containing ligands covalently bonded through a spacer grouping to a hydrophilic inorganic solid support material.
TW081104359A 1991-06-03 1992-06-02 TW267948B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/709,378 US5120443A (en) 1991-06-03 1991-06-03 Processes for removing, separating and concentrating rhodium, iridium, and ruthenium from solutions using macrocyclic and nonmacrocyclic polyalkylene-polyamine-containing ligands bonded to inorganic supports

Publications (1)

Publication Number Publication Date
TW267948B true TW267948B (en) 1996-01-11

Family

ID=24849622

Family Applications (1)

Application Number Title Priority Date Filing Date
TW081104359A TW267948B (en) 1991-06-03 1992-06-02

Country Status (16)

Country Link
US (1) US5120443A (en)
EP (1) EP0588941B1 (en)
JP (1) JPH06508338A (en)
AT (1) ATE149860T1 (en)
BR (1) BR9206085A (en)
CA (1) CA2103144A1 (en)
DE (1) DE69218201T2 (en)
DK (1) DK0588941T3 (en)
ES (1) ES2101852T3 (en)
FI (1) FI935405A (en)
GR (1) GR3023454T3 (en)
NO (1) NO306701B1 (en)
RU (1) RU2095314C1 (en)
TW (1) TW267948B (en)
WO (1) WO1992021419A1 (en)
ZA (1) ZA924016B (en)

Families Citing this family (30)

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US5501767A (en) 1992-11-13 1996-03-26 Micron Technology, Inc. Method for gettering noble metals from mineral acid solution
US5441643A (en) * 1993-11-29 1995-08-15 The United States Of America As Represented By The Secretary Of The Interior Process for recovering metals from solution utilizing metalloprotein affinity chromatography
EP0748247B1 (en) * 1994-02-22 2012-06-20 The Curators Of The University Of Missouri Macrocyclic antibiotics as separation agents
US5547760A (en) * 1994-04-26 1996-08-20 Ibc Advanced Technologies, Inc. Compositions and processes for separating and concentrating certain ions from mixed ion solutions using ion-binding ligands bonded to membranes
AUPM632894A0 (en) * 1994-06-21 1994-07-14 Alldredge, Robert Louis Immobilised branched polyalkyleneimines
US5624881A (en) * 1994-09-27 1997-04-29 Syracuse University Chemically active ceramic compositions with a pyrogallol moiety
US5668079A (en) * 1994-09-27 1997-09-16 Syracuse University Chemically active ceramic compositions with an hydroxyquinoline moiety
US5616533A (en) * 1994-09-27 1997-04-01 Syracuse University Chemically active ceramic compositions with a thiol and/or amine moiety
US5612275A (en) * 1994-09-27 1997-03-18 Syracuse University Chemically active ceramic compositions with a phospho-acid moiety
FR2725382B1 (en) * 1994-10-05 1997-01-03 Commissariat Energie Atomique POLYAZACYCLOALCANES, TRI-, TETRA- OR PENTAAZAMACROCYCLIC COMPLEXES, PROCESS FOR MANUFACTURING SUCH SUBSTITUTED OR NON-SUBSTITUTED POLYAZACYCLOALCANES AND GRAFTS ON A SUPPORT AND USES OF POLYAZACYCLOALCANES
WO1996029146A1 (en) 1995-03-22 1996-09-26 Minnesota Mining And Manufacturing Company Solid phase extraction membrane
DE69732496T2 (en) * 1996-06-24 2006-05-04 IBC Advanced Technologies, Inc., American Fork POLY-N-CYCLIC AROMATIC LIGANDS BONDED TO SOLID CARRIERS FOR REMOVING AND CONCENTRATING IONES FROM SOLUTIONS
US6106723A (en) * 1997-02-10 2000-08-22 Grandics; Peter Method for removing pyrogens from dialysate
FR2774092B1 (en) * 1998-01-26 2000-02-18 Air Liquide PROCESS FOR THE PREPARATION OF GRAFT POLYAZACYCLOALCANES ON SILICA GEL AND USE OF THE GRAFT COMPOUNDS
FR2774093B1 (en) * 1998-01-26 2000-03-17 Air Liquide NOVEL SILICA GEL INCORPORATING POLYAZACYCLOALCANE PATTERNS, METHOD OF PREPARATION AND USE
US6339039B1 (en) 1998-06-12 2002-01-15 Jerker Porath Hydrogel product for adsorption purposes
SE512234C2 (en) * 1998-06-12 2000-02-14 Jerker Porath Hydrogel product for adsorption purposes consisting of a water-insoluble support matrix cross-linked with polymers
US6232265B1 (en) 1999-06-11 2001-05-15 Ibc Advanced Technologies, Inc. Particulate solid supports functionalized with polyhydroxypyridinone ligands
FR2796645B1 (en) * 1999-07-23 2001-09-14 Air Liquide NOVEL SILICA GEL INCORPORATING POLYAZACYCLOALCANE PATTERNS WITH MORE THAN SIX NITROGEN ATOMS, METHOD OF PREPARATION AND USE
GB0210099D0 (en) * 2002-05-02 2002-06-12 Anglo Platinum Ltd Separation of metals
JP4144311B2 (en) * 2002-10-08 2008-09-03 住友金属鉱山株式会社 Methods for separating and recovering platinum group elements
JP4691046B2 (en) * 2004-12-28 2011-06-01 日本曹達株式会社 Method for removing metal and method for producing polymer
EP1922422A4 (en) * 2005-04-13 2009-05-27 Metals Recovery Technology Inc Process for recovering platinum group metals, rhenium and gold
US7604784B2 (en) * 2005-06-24 2009-10-20 Metals Recovery Technology Inc. Process for the extraction of specific transition metals with gaseous HCL
US20140048741A1 (en) 2011-03-10 2014-02-20 3M Innovative Properties Company Filtration media
US9610576B2 (en) * 2012-09-27 2017-04-04 Agilent Technologies, Inc. Hydrolytically stable ion-exchange stationary phases and uses thereof
CN103554185A (en) * 2013-07-04 2014-02-05 上海工程技术大学 Macrocyclic polyamine polydentate ligands and synthesis method tehreof
DE102014012566A1 (en) * 2014-08-29 2016-03-03 Instraction Gmbh Sorbent for bonding metals and its production
RU2703011C1 (en) * 2019-04-30 2019-10-15 Публичное акционерное общество "Горно-металлургическая компания "Норильский никель" Method for selective extraction of platinum ions from chloride solutions
RU2742994C1 (en) * 2020-06-09 2021-02-12 Игорь Владимирович Федосеев Method for selective extraction of rhodium rh, ruthenium ru and iridium ir from hydrochloric acid solutions of chlorine complexes of platinum pt (iv), palladium pd (ii), gold au (iii), silver ag (i), rhodium rh (iii), ruthenium ru (iv) and iridium ir (iv)

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Also Published As

Publication number Publication date
BR9206085A (en) 1994-11-08
DK0588941T3 (en) 1997-09-22
NO934365D0 (en) 1993-12-01
ZA924016B (en) 1993-02-24
ATE149860T1 (en) 1997-03-15
EP0588941A4 (en) 1994-08-10
EP0588941B1 (en) 1997-03-12
US5120443A (en) 1992-06-09
FI935405A0 (en) 1993-12-02
ES2101852T3 (en) 1997-07-16
NO306701B1 (en) 1999-12-13
CA2103144A1 (en) 1992-12-04
NO934365L (en) 1994-02-01
RU2095314C1 (en) 1997-11-10
DE69218201T2 (en) 1997-06-26
GR3023454T3 (en) 1997-08-29
FI935405A (en) 1993-12-02
WO1992021419A1 (en) 1992-12-10
JPH06508338A (en) 1994-09-22
EP0588941A1 (en) 1994-03-30
DE69218201D1 (en) 1997-04-17

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