CA2010235A1 - Injecting gas into molten metal - Google Patents

Injecting gas into molten metal

Info

Publication number
CA2010235A1
CA2010235A1 CA002010235A CA2010235A CA2010235A1 CA 2010235 A1 CA2010235 A1 CA 2010235A1 CA 002010235 A CA002010235 A CA 002010235A CA 2010235 A CA2010235 A CA 2010235A CA 2010235 A1 CA2010235 A1 CA 2010235A1
Authority
CA
Canada
Prior art keywords
passageway
molten metal
gas
media disperser
openings
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002010235A
Other languages
French (fr)
Inventor
Ronald E. Gilbert
George S. Mordue
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unifrax I LLC
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2010235A1 publication Critical patent/CA2010235A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B9/00General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
    • C22B9/05Refining by treating with gases, e.g. gas flushing also refining by means of a material generating gas in situ
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/04Removing impurities by adding a treating agent
    • C21C7/072Treatment with gases

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Mold Materials And Core Materials (AREA)
  • Treatment Of Steel In Its Molten State (AREA)
  • Nozzles (AREA)
  • Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)

Abstract

INJECTING GAS INTO MOLTEN METAL

Abstract Gas is injected into molten metal by flowing the molten metal through a passageway (24), and by providing a plurality of openings about the periphery of the passageway (24). The gas is injected through the openings into the molten metal flowing through the passageway (24). Preferably, the openings are defined by a porous ceramic media disperser (32) that forms a portion of the passageway (24).

Description

2~

INJECTING GAS INTO MOLTEN METAL

Background of_the Invention 1. Field of the Invention The invention relates to techniques for injecting gas into molten metal and, more particularly, to a technique for uniformly injecting gas into molten metal being pumped through a passageway.

2. Description of the Prior Art In the course of processing molten metals, it sometimes is necessary to treat the metals with gas. For example, it is customary to in~ect gases such as nitrogen, chlorine, and argon into molten aluminum and molten aluminum alloys in order to remove undeslrable constituents such as hydrogen gas, non-metallic lncluslons, and alkali metal~. The gases added to the molten metal chemically react wlth the undesired constituents to convert them to a form (such as a precipitate, a dross, or an insoluble gas compound) that can be separated readily from the remainder of the molten metal.
As used herein, reference to "molten metal" will be understood to mean any metal such as aluminum, magnesium, copper, iron, and alloys thereof, which are amenable to gas purification.
Further, the term "gas" will be understood to mean any gas or combination of gases, including argon, nitrogen, chlorine, freon, sulfur hexafluoride, and the like, that have a purifying effect upon molten metals with which they are mixed.

. -~ 3 ~235 In the particular case of molten metal that has been melted in a reverberatory furnace, gas injection typically is accomplished by immersing a molten metal pump into the molten metal, and by injecting gas through a conduit into the outlet passageway of the pump. Suitable gas injection pumps of the type described are available commercially from Metaullics Systems, 31935 Aurora Road, Solon, Ohio 44139, under the model designation M30-CSD-Cl~ et al. In the referenced pumps, the gas is injected through a so-called flux tube, or injection tube having an inner diameter of approximately one-half inch. The flux tube is connected to the discharge passageway of the pump along the upper ~ide of the passageway.
Although the referenced pumps function well to in;ect purifying gas into the molten metal, certain problems have not been addressed. One of these problems relates to mixing the purifying gas as uniformly a~ possible with the molten metal being pumped.
Because the gas i8 injected through a relatively large tube at a single injection point, relatively large bubbles (incipient bubbles) of gas are discharged into the molten metal. It i5 only the high speed stream of molten metal which shears the incipient bubbles into a wide array of finely dispersed, smaller bubbles.
The speed of the molten metal, which is dependent upon the speed of rotation of the pump 1 8 impeller, thus ~ontrols the reaction rate, with smaller bubbles, of the gas with the metal.
Desirably, the gas would be injected uniformly into the molten metal in the form of very small incipient bubbles so that intimate mixing of the gas and molten metal would occur as quickly as po6sible. It also would be desirable to be able to inje~t small 2~3~

bubbles and dispexse the~ a~ rapidly as possible at all pump speeds, including very low speeds.

Summary of the Invention The present invention provides a new and improved S technique for injecting gas into molten metal that addresses the foregoing concerns. Apparatus according to the invention includes a passageway through which molten metal can be passed. A plurality of openings are disposed about the periphery of the passageway, and a means for injecting gas through the openings is provided.
In the preferred embodiment of the invention, the passageway constitute~ the outlet of a molten metal pump, and the op~nings are defined by a porous media disperser that is disposed within the passageway 80 as to form a portion of the inner wall of the pas~ageway. The media disperser preferably is made from bonded ceramic grain porous media, but it can be made from other material~, including graphite. The means for injecting gas includes a circumferential groove formed about the media disperser, the groove being in fluid communication with a source of compressed gas.
The invention also includes a method for injecting gas into molten metal that comprises the steps of passing the molten metal through a passageway having a predetermined cross-section, providing a plurality of openings in the passageway about the periphery of the passageway, and injecting gas into the molten metal through the openings of the passageway. In the preferred embodiment, the cross-section defines a circle, and the openings are defined by a porous ceramic media disperser.

.
.

2~ 5 By use of the present in~ention, the gas is injected into the molten metal uniformly about the periphery of the passageway. Moreover, because the gas is passed through a porous media disperser, exceedingly small bubbles of gas are discharged into the molten metal. By injecting very small bubbles and by in~ecting them uniformly about the periphery of the passageway, the gas is intimately mixed with the molten metal in a very short period of time. Excellent results are obtained at all pump speeds.
The foregoing and other features and advantages of the invention are illustrated in the accompanying drawings and are dQscribed in more detail in the specification and claims that ~ollow.

8rief Descri~tion of the Drawinas Figure 1 i8 a perspective view of a vessel containing molten metal into which a gas injection apparatus has been immersed;
Figure 2 is a cross-sectional view of the gas injection apparatus of Figure 1 with a gas injection conduit being shown out of position for purposes of clarity o~ illustration~
Figure 3 is a cross-sectional view of the apparatus of Figure 1, taken along a plane indicated by line 3-3 in Figure 2;
and Figure 4 is a view similar to Figure 3, showing an alternative embodiment of the invention.

2~23~

Description of the PreferredlE~odiment Referrinq to Figures 1-3, a gas injection apparatus according to the invention is indicated generally by the reference numeral 10. The apparatus 10 is in the for~ of a pump that is adapted to be immersed in molten metal contained within a vessel 14. The vessel 14 can be any container containing molten metal that i3 desired to be purified, although it is expected that the vessel 14 will be the external well of a reverberatory furnace.
It is to be understood that the pump can be any type of pump ~uitable for pumping molten metal. Generally speaking, however, and as particularly shown in Figures 2 and 3, the pump will have a base member 16 within which an impeller 18 is disposed.
The ba~e member 16 includes an outlet passageway 20. A fitting 22 is secured to the base member 16, the fitting including a ; 15 passageway 24 that 18 aliqned with the outlet passageway 20. A
sleeve 26 is secured to the fitting 22 hy means of a threaded ~;~ connection indicated at 28. A fluid-tight seal is effected by refractory cement indicated by the reference numeral 29. The sleeve 26 is hollow so as to define a longitudinally extending bore 30. The bore 30 is axially aligned with the passageway 24.
;~ Referring particularly to Figure 3, a porous ceramic media disperser 32 in the form of a ring is disposed within the ,~ fitting 22, and is held in place there by the sleeve 26. The media disperser 32 is compressed against a shoulder 34 formed within the fitting 22, the compression being accomplished by the end of the sleeve 26. A circumferential groove 36 is formed in the fitting 22 about the outer periphery of the media disperser 32. The fitting 22 includes a passageway 38 that is in fluid communication , :-'` , , ' .

2~ 5 , .

with the groove 36. Similarly, the base member 16 includes a passageway 40 that is in fluid communication with the passageway - 38. A gas in~ection conduit 42 i5 connected to the base member 16. The conduit 42 includes an internal passageway 44 that is in fluid communica~ion with the passageway 40 and with a source of compressed gas (not shown). The conduit 42 also functions as a support for the base member 16.
The media disperser 32 preferably is made from bonded ceramic grain porous media commercially available from Metaullics System~ of Solon, Ohio. A variety of materials can be used to make the media disperser 32. It has been found that glass frit-bonded aluminum oxide or glass frit-bonded silicon carbide works e~pecially well when in~ecting inert gase6 such as nitrogen, argon, or sul~ur hexafluoride into molten aluminum, magnesium, copper, or alloy~ thereof. Alternatively, a porous graphite media disperser or a ~intered oxide-based ceramic media disperser may be used when the gas being in~ected ig chlorine. The size and number of the openlngs in the media disperser 32 are important because they determine, in large measure, the size of the bubbles that are in~ected into the molten metal discharged by the pump 10.
Commercially available porous media dispersers that provide acceptable ga6 flow rates and small bubble size have pore diameters in the range of 10-100 microns. Gas flow rates and volumes are dependent upon the size of the media disperser and applied pres~ure. Those skilled in the art will be able to select appropriate media dispersers to suit their particular needs.
An alternative embodiment of the invention is illustrated in Figure 4. In this embodiment of the invention, the fitting 22 ,~
, ~

,:

Z~2~5 :

is replaced by a fitting 50. The fitting 50 i8 substantially similar to the fitting 22, and like elements are indicated by like re~erence numerals carried over from Figures 2 and 3. Instead of employing the pas~ageway 38, however, the embodiment shown in Figure 4 employs a passageway 52 which opens into a counterbored portion 54. A gas in;ection conduit 56 having an internal passageway 58 is secured within the counterbored portion 54 so that the pa~sageways 52, 58 are in fluid communication with each other. The embodiment of the invention illustrated in Figure 4 thus is usable with a molten metal pump of virtually any type, provided the fitting 50 can be secured to the outlet of the pump.
By use of the present invention, gas is injected into the molten metal uni~ormly about the periphery of the passageway 24.
: The bubbles that are injected are very small, and they become intimately mixed with the molten metal flowing through the pa~sageway 24 and the bore 30. The only significant limitation on the sleeve 26 is that it should be long enough to ensure complete mixing of the gas and the molten metal. Additionally, because the media disperser 32 is formed of a ceramic material, it withstands very well the corrosive and erosive action of the molten metal. Additionally, because the sleeve 26 is threaded into the fitting 22, the media disperser 32 can be replaced conveniently when necessary.
Although the invention has been described in its : 25 preferred form with a certain degree of particularity, it will be understood that the present disclosure of the preferred embodiment has been made only by way of example and that various changes may be resorted to without departing from the true spirit and scope of .

2C~ 5 the ~nvention as hereinafter claimed. It i8 intended that the patent shall cover, by suitable expression in the appended claims, whatever features of patentable novelty exist in the invention disclosed.

Claims (10)

1. A method of injecting gas into molten metal, comprising the steps of:
passing the molten metal through a passageway (24) having a predetermined cross-section;
providing a plurality of openings about the periphery of the passageway (24); and injecting gas through the openings into the metal in the passageway (24).
2. The method of claim 1, wherein the openings are defined by a porous media disperser (32).
3. The method of claim 2, wherein the media disperser (32) is in the form of a porous body of ceramic or graphite.
4. A method of injecting gas into molten metal, comprising the steps of:
providing a molten metal pump (10) having an outlet passageway (24) of a predetermined cross-section;

passing molten metal under pressure through the outlet passageway (24);
providing a plurality of openings about the periphery of the passageway (24); and injecting gas through the openings into molten metal flowing through the passageway (24).
5. The method of claim 4, wherein the openings are defined by a porous media disperser (32).
6. The method of claim 5, wherein the media disperser (32) is in the form of a porous body of ceramic or graphite.
7. The method of claim 4, wherein the openings are defined by a porous media disperser (32), and the inner diameter of the media disperser (32) defines the inner diameter of a portion of the passageway (24).
8. Apparatus for injecting gas into molten metal, comprising:
a passageway (24) through which the molten metal can flow;

a porous media disperser (32) disposed within the passageway (24) about the periphery of the passageway (24); and means for injecting gas through the porous media disperser (32) into the molten metal flowing through the passageway (24).
9. The apparatus of claim 8, wherein the passageway (24) is defined by a fitting (22) to which a sleeve (26) is secured, the sleeve (26) engaging the media disperser (32) and holding the media disperser (32) in place within the fitting (22).
10. The apparatus of claim 8, wherein the inner diameter of the media disperser (32) defines the inner diameter of a portion of the passageway (24).
CA002010235A 1989-02-17 1990-02-16 Injecting gas into molten metal Abandoned CA2010235A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US31289389A 1989-02-17 1989-02-17
US312,893 1989-02-17

Publications (1)

Publication Number Publication Date
CA2010235A1 true CA2010235A1 (en) 1990-08-17

Family

ID=23213482

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002010235A Abandoned CA2010235A1 (en) 1989-02-17 1990-02-16 Injecting gas into molten metal

Country Status (10)

Country Link
EP (1) EP0385617A1 (en)
JP (1) JPH02290930A (en)
KR (1) KR900013092A (en)
AU (1) AU4988890A (en)
BR (1) BR9000732A (en)
CA (1) CA2010235A1 (en)
HU (1) HUT57277A (en)
IL (1) IL93349A0 (en)
NO (1) NO900760L (en)
PT (1) PT93185A (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2652018B1 (en) * 1989-09-20 1994-03-25 Pechiney Rhenalu DEVICE FOR TREATING WITH GAS FROM A LARGE SURFACE ALUMINUM LIQUID BATH MAINTAINED IN A STATIONARY STATE IN AN OVEN.
FR2670839A1 (en) * 1990-12-21 1992-06-26 Cit Alcatel MACHINE, SUCH AS A VACUUM PUMP OR COMPRESSOR OF THE VOLUMETRIC OR DRIVE TYPE.
AUPN204895A0 (en) * 1995-03-29 1995-04-27 University Of Queensland, The Method of generation and dispersion of fine bubbles and apparatus therefor
CN108396109B (en) * 2017-02-05 2019-08-27 鞍钢股份有限公司 Method for generating dispersed bubbles in molten steel in steel ladle

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2101000B1 (en) * 1970-08-04 1977-01-14 Activite Atom Avance
US4052199A (en) * 1975-07-21 1977-10-04 The Carborundum Company Gas injection method
CH641839A5 (en) * 1979-07-10 1984-03-15 Alusuisse DEVICE FOR INITIATING GASES IN METAL MELT.
US4351514A (en) * 1980-07-18 1982-09-28 Koch Fenton C Apparatus for purifying molten metal
IT1176428B (en) * 1984-07-18 1987-08-18 Radex Italiana Spa OUTLET SLEEVE IN A DEVICE TO CONTROL THE STEEL FLOW MELTED FROM A LADLE OR A BASKET

Also Published As

Publication number Publication date
PT93185A (en) 1991-10-15
HU900835D0 (en) 1990-05-28
JPH02290930A (en) 1990-11-30
NO900760L (en) 1990-08-20
HUT57277A (en) 1991-11-28
KR900013092A (en) 1990-09-03
AU4988890A (en) 1990-08-23
IL93349A0 (en) 1990-11-29
NO900760D0 (en) 1990-02-16
BR9000732A (en) 1991-01-22
EP0385617A1 (en) 1990-09-05

Similar Documents

Publication Publication Date Title
US12031550B2 (en) Tensioned support post and other molten metal devices
US11098719B2 (en) Tensioned support shaft and other molten metal devices
US3982913A (en) Method and apparatus for degassing metallic melts
CA2176475C (en) System and device for removing impurities from molten metal
US4351514A (en) Apparatus for purifying molten metal
US9617617B2 (en) Ultrasonic degassing of molten metals
US6887425B2 (en) Shaft and post assemblies for molten metal apparatus
CA2931124C (en) Ultrasonic probes with gas outlets for degassing of molten metals
US20080213111A1 (en) System for releasing gas into molten metal
US4295883A (en) Device and method for introducing gases into molten metal
CA2010235A1 (en) Injecting gas into molten metal
KR860007980A (en) Metallurgy exhaust sleeve
US3380727A (en) Devices for introducing gas into a metal melt
KR850004031A (en) Method and apparatus for preventing eddy of bottom injection container
FR2367560A1 (en) DEVELOPMENT AT INSTA
EP0317187A3 (en) Metallurgical tuyere and method of calibrating same
SE452989B (en) Nozzle for injecting gases into metal smelts
GR890300190T1 (en) Apparatus for removing gaseous and solid impurities from a molten product contained in a vessel
US4148468A (en) Lance for the flush gas treatment of non-ferrous molten metals
SU589261A1 (en) Method of degassing liquid metal
RU1803860C (en) Liquid chromatography column
FR2592393A1 (en) INJECTION LANCE FOR METALLURGICAL CONTAINER AND METHOD FOR MANUFACTURING SAME.
SU1380793A2 (en) Air-atomizing burner
RU1786098C (en) Immersible tuyere
RU2240893C1 (en) Metal stream gas protection apparatus

Legal Events

Date Code Title Description
FZDE Discontinued