CA1262979A - Polyolefin blends containing reactive agents - Google Patents

Abstract

ABSTRACT OF THE DISCLOSURE
A polyolefin blend comprising, in physical admixture, a major portion of particles of a first polyethylene and a minor portion of particles of a composition of a second polyethylene, is disclosed. The first polyethylene is selected from the group consisting of homopolymers of ethylene and copolymers of ethylene and at least one C4 - C10 higher alpha-olefin, and the second polyethylene is a copolymer of ethylene and at least one C4 - C10 higher alpha-olefin having a density of at least 0.890 g/cm3, especially at least 0.910 g/cm3, and a melt index of at least 40 dg/min. The density of the second polyethylene is at least about 0.005 g/cm3 lower than that of the first polyethylene and the melt index of the second polyethylene is at least 10 dg/min. higher than that of the first polyethylene. The composition of the second polyethylene contains an agent that is capable of reacting with polyolefins that are in a molten state. Such agents are selected from the group consisting of cross-linking agents and modifying agents, and mixtures thereof. In an alternative embodiment, the second polyethylene has a shear viscosity that is not more than 50% of that of the first polyethylene at 200°C and a shear rate of 400 sec-1; in this regard, the first and second polyethylene may be more broadly defined as being homopolymers and copolymers of hydrocarbon alpha-olefins having 2-10 carbon atoms. The blends may be used in a wide variety of processes, including blow-moulding processes, film and pipe extrusion processes, sheet thermoforming processes and rotational moulding processes.

Description

7~

POLYOLEFIN BLENDS CONTAININ~ REACT~V~ AGENTS
The present invention relates to polyolefin blends and in particular to a physical admixture of a maJor portion of particles of an ekhylene polymer with a minor portion o~ particles of a composition oE an ethylene polymer and an agent that ls capable of reacting with polyoleEins in the molten state, such reactive agent being a cross-linking agent and/or a modifying agent and being further defined hereinbelow.
Polymers oE ethylene, for example, homopolymers o ethylene and copolymers of ethylene and higher alpha-olefins, are used in large volumes for a variety of end-uses, for example, in the form of film, fi~res, moulded or thermoformed articles, pipe, coatings and the like.
Polyolefin compositions as offered for sale and/or used in such end-uses often contain reactive and/or non-reactive agents to modify or stabilize the polymer during processing or during use of articles fabricated from the compositions. Typical reactive agents include cross-linking agents and certain unsaturated compounds.
Typical non-reactive agents include antioxidants and other stabilizers, nucleation agents and additives that affect the slip or blocking characteristics of products or the release of products from moulds used in fabrication processes. It is important that the incorporation of agents into polyolefin compositions be carried out so that the resultant composition has uniEorm properties.
Polymers having properties that are commercially-acceptable in a variety of end-uses are known.
In addition, improvements in some polymer properties could lead to improved products and/or use of the polymers in additional end-uses. For instance, one method of improving the end-use characteristics of an article rotationaIly moulded from polymers of ethylene is to incorporate a cross-linking agent, for example, an organic peroxide, into the polymer composition. In the rotational moulding of a composition containing an organic peroxide, the polymer flows to coat the inside of the mould and then the cross-linking agent causes crosslinking of the polymer so as to increase the molecular welght of the polymer, thereby improving end-use properties of the resultant article.
Cross-linkable compositions especially adapted for rotational moulding end-uses are disclosed in European Patent Publication No. 0 0~7 210 of G. White, published 1983 August 31.
Cross-linkable compositions may also be used in other end-uses to obtain improvements in product properties;
the cross-linking of the polymer will tend to affect melt characteristics of the polymer under low shear rate processing conditions. One example of the use of partial cross-linking to obtain an improvement in film properties is disclosed in Canadian Patent No. 1 123 560 of D.A. Harbourne, which issued 1982 May 18.
Techniques for the incorporation of agents into polyolefins are well known in the art. Non-reactive agents, especially stabilizing agents, are frequently incorporated into molten polymer during the process for the manufactura of the polymer. Reactive and non-reactive ayents may also be incorporated into polymers by melt blending techniques in which the agent is metered into or otherwise added to molten polymer during extrusion of the polymer into pellets or a fabricated article.
It is important in the addition of agen-ts that the agent be uniformly distributed throughout the polymerO
With non-reactive agents, however, the uniormity of the distribution of the agent is normally less critical than with reactive agents. F'or example, the re~uirements for a slip agent or a stabilizer may be less critical than for a cross-linking agent~ The cross-linking of a polymer increases the molecular weight of the polymer. Thus, in order to obtain a product of uniform properties, especially ~z~

properties clependent on molecular weight, it is important that the cross-linking of the polymer be carried out in a uniform manner. I~ the cross-linking is not uniform, the resultant product may, Eor example, have areas of weakness due to either insufficient or excessive cross~linking of the polymer or have gel particles resulting from excessive cross-linking of the polymer, such gel particles resulting in unacceptable visual appearance and/or areas of weakness in the product. Some fabrication processes, for example blow moulding of bottles and the manufac-ture of sheet and film, may be more sensitive to non-uniform product properties than other processes. In order to obtain uniform product properties, it has been necessary to use expensive and/or complex processes to incorporate reactive agents into polymers, including special handling facilities and special extruder screw designs.
The blending of organic peroxide with molten polyethylene is disclosed in U.S. Patent 3 182 033 of R~S.
Gregorian, which issued 1965 May 04, and in Canadlan Patent 20 957 473 of H.J. Cook, which issued 1974 November 12. DoA.
Alia disclosed in U.S. Patent 4 197 381, which ~ssued 1980 April 0~, that the blending of crystalline polymers and amorphous elastomeric polymers aided in the product;on of cross-linkable polymers having a homogeneous composition.
The blending of reactive agents into polyethylene by means of a physical blend of polyethylene with a different polymer containing the reactive agent is disclosed in Canadian application No. 485 651 of D.W. Boivin and R.A. Zelonka filed 1986 June 27.
A blend of polyolefins capable of being used to incorporate reactive agents into polyolefins in a uniform and more economical manner has now been found.
Accordingly, the present invention provides a polyolefin blend comprising, in physical admixture, a major portion of particles of a first polyethylene and a minor portion of particles of a composition of a second ,~:

polyethylene, in ~h;ch the Eirst polyethylene is selected Erom the group consisting of homopolymers of ethylene and copolymers oE e-thylene and at least one C4 - C1o higher alpha-olefin, said second polyethylene being a copolymer of ethylene and at least one C4 - Clo higher alpha-oleEin having a density of at least 0.~90 g/cm3 and a melt index in the range of 40-200 dg/min., the density of the second polyethylene being at least about 0.005 g/cm3 lower than that oE the first polyethylene and the melt index of the second polyethylene being at least 10 dg/min. higher than that of the first polyethylene, said composition being a composition of the second polyethylene and a reactive agent selected from the group consisting of cross-linking agents and modifying agents, and mixtures thereof, said reactive agent being capable of reacting with said polyethylene in a molten state.
In a preEerred embodiment of the blends of the presen-t invention, the reactive agent is a cross-linking agent which is an organic peroxide.
In a further embodiment, the reac-tive agent is a modifying agent.
In another embodiment, the melt index oE the second polyethylene is 40-60 dg/min. higher than that of the first polyethvlene.
The present invent;on also provides a polyolefin blend comprising, in physical admixture, a major portion of particles of a first polyethylene and a minor portion of particles of a composition of a normally solid second polyethylene, in which the first polyethylene is selected from the group consisting of homopolymers of ethylene and copolymers of ethylene and at least one C4 - Cl0 higher alpha-ole~in, said second polyethylene being a copolymer of ethylene and at least one C4 - Clo higher alpha-olefin having a density of at least 0,890 g/cm3 and a melt index oE
at least 40 dg/min., said second polyethylene having a shear viscosity that i5 not more than 50% of that of said Eirst polyethylene when measured at 200C and a shear rate of 400 sec~l, said composition being a composition of the second polyethylene and a reactive agent selected fro~ the group consisting of cross-linking agents and modifying agents, and mixtures thereof, said reactive agent being capable of reacting with polyethylenes in a molten state.
In a preEerred embodiment, the shear viscosity of the second polyethylene is not more than about 30 ~ of that of the first polyethylene.
The present invention further provides a polyolefin blend comprising, in physical admixture, a major portion of particles of a first polyolefin and a minor portion of particles o a composition of a normally solid second polyolefin, said polyolefins being selected from the group consisting of homopolymers and copolymers of hydrocarbon alpha-olefins having 2-lO carbon atoms, said second polyolefin having a shear viscosi-ty that is not more than 50% of that of said first polyolefin when measured at 200C and a shear rate o~ 400 sec~l, said composition being a composition of the second polyolefin and a reactive agent selected from the group consisting of cross-linking agents and modifying agents, and mixtures thereof, said reactive agent being capahle of reacting with said polyolefins in a molten state.
In addition, the present invention provides a process or the manufacture of articles from a polyolefin and a reactive agent capable of reacting with the polyolefin in a molten state, comprising feeding to melt processing apparatus a polyolefin blend comprising, in physical admixture, a major portion of particles of a first polyolefin and a minor portion of particles of a composition of a normally solid second polyolefin, said polyolefins being selected from the group consisting of homopolymers and copolymers of hydrocarbon alpha-olefins having 2-lO carbon 7~

atoms, sai~ second polyolefin having a shear viscosity that i.5 not more than 50% of that of said first polyolefin ~7hen measured at 200C and a shear rate of 400 sec-l, said composition being a composition of the second polyolefin and a reactive agent selected Erom the group consisting o-E
cross-linking agents and modlfying agents, and mixtures thereof, melting and admixing said blend and forming an article from the resultant blend. The invention also provides processes for the manufacture of articles from the other blends described herein.
The polyolefin of the blends oE the present invention is particularly described herein with reference to such polyolefins being a homopolymer of ethylene and/or a copolymer of ethylene and a minor amount of at least one C4 - Clo higher alpha-olefin, for example a copolymer of ethylene and a minor amount of butene-l, hexene-l and/or octene--l. It is to be understood, however, that the polyolefins may be broadly defined as being homopolymers or copolymers of hydrocarbon alpha-olefins having 2-10 carbon atoms. Techni~ues for the manufacture of such polymers are ~nown in the art.
As noted above, the invention is particularly defined with reference to the polyolefins being homopolymers and copolymers of ethylene.
The characteristics of the first polyethylene, for example, the density and melt index of the polymer, will depend to a large extent on the intended end-use of the resultant products but, in embodiments, the density may range from about 0.890 g/cm3 to about 0.970 g/cm3 and the melt index, as measured by the method of ASTM D-1238 (condition E), may range up to about 100 dg/min. For example, polymers intended for film and shee-t end-uses tend to have melt indices of less than about 10 dg/min whereas polymers intended for moulding end-uses tend to have higher values of melt index. The ranges of density and melt index -- 7 ~
of polyoleEins that are useful for various types oE products are known in the trade.
The characteristics of -the second polyethylene differ from those described above for the Eirst poly-ethylene. In one embodiment, the density of the secondpolyethylene is lower than that of the first polyethylene, being at least 0.890 g/cm3, especially at least 0.910 g/cm3, but with the proviso that it is at least about 0.005, especially 0.008 g/cm3 lower than the density of the first polyethylene. Secondly, the melt index of the second polyethylene is hi~her than that of the first polyethylene, being in the range of 40-200, especially 60-150 d~/min., but with the proviso that it is at leas-t 10 d~/min., preferably at least 20 dg/min., hi~her than the melt index of the Eirst polyethylene.
In an alternate embodiment, the second poly-ethylene ha~s a density of at least 0.890 ~/cm3, especially at least 0.910 g/cm3, a melt index of at least 40 dg/min.
and has a lower shear viscosity than the first polyethylene;
in particular the she~r viscosity is not more than 50% of that of the first polyethylene. Pre~ferably, the shear viscosity oE the second polyethylene is not more than about 30% of the shear viscosity of the first polyethylene. As used herein, shear viscosity is determined at 200C at a shear rate of ~00 sec~l.
In the broader aspects of the invention, the shear viscosity of the second polyolefin is not more than 50~ of that of the first polyolefin, and especially 5-15% of that of the first polyolefin.
The second polyolefin is a normally solid polymer and may include materials frequently referred to as solid waxes but does not include materials that are liquids at ambient temperatures and pressures; the blends of the invention are physical admixtures and are therefore capable of physical separation into the respective components at amblent temperatures.
The second polyethylene contains a reactive agent selected from the group conslsting of cross-linking agents and modifying agents, and mixtures thereof. As used herein, the expression '!reactive agent" refers to an agent that undergoes a chemical reaction at temperatures at which polyethylene is in a molten state. It is to be understood, however, that the rate of chemical reaction may not be significant until the temperature of the molten polyethylene is substantially above the melting point of the polyethylene. For example, it is known that cross-linking agents for polyethylene are usually selected so that the cross-linking reaction occurs above the melting point of the polymer e.g. at or near normal melt processing temperatures. It is preferred that the reaction temperature be such that adequate mixing of polymer and reactive agent may be achieved prior to extensive reaction between polymer and reactive agent; the half-life of a cross-linking agent is usually known over a range of temperatures and may be used to assist in selection of a cross-linking agent suitable for an intended end-use. It is to be understood that the reactive agent may be more than one chemical compound or species and, in that event, part of the composition of the second polyethylene may contain one reactive agent and another part of the composition of the second polyethylene may contain a second reactive agent. It is to be further understood that if the reactive agent is more than one chemical compound or species, then each such reactive agent may be capable of reacting with polyethylene that is in a molten state and/or one such reactive agent may be capable of reacting with another such reactive agent.
In the event that the reactive agent is a cross-linking agent e.g. an organic peroxide, the firs~
polyethylene may, but normally will not, contain organic peroxide. However, it may under sorne circumstances be desirable to incorporate portions of the cross-linking ~6~3 ~ ~

formulation into the first polye-thylene. For example, if the cross-linkable composition is to be comprised of both an organic peroxide and a co-curing agent, as is disclosed in the aforementioned publication of G. White, it might be advantageous to admix the co-curing agent with the Eirst polyethylene and to admix the organic peroxide with the second polyethylene. Such an incorporation of the co-curing agent into the first polyethylene may aid in the fabrication oE a uniform product. In any event, the first polyethylene will often contain non-reactive agents known to be incorporated into polyethylene including antioxidan-ts and other stabilizers, pigments and the like, it being under-stood that some so-called non-reactive agents useful in polyethylene may have detrimental ef~ects on cross-llnking or other reactive agents useful with polyethylene and as such will likely not be used in combination with such cross~linking or other reactive agents.
For blends containing cross-linking agents, the preferred cross-linking agent is an organic peroxide, especially a bis(tert. allcyl peroxy alkyl) benzene, dicumyl peroxide or acetylenic diperoxy compound. Other organic peroxides are known to those skilled in the art, including t-butyl hydroperoxide and di-t-butyl peroxide.

2,5-Dimethyl-2,5 bis(-tert~ butyl peroxyisoprop~l)benzene is the preferred organic peroxide and is available commercially under the trade mark Vulcup from Hercules Incorporated. ~s an alternative, the cross-linking agent may be 2,5-dimethyl-2,5-di(t-butylperoxy)hexyne-3 which is available commercial-ly under the trade mark Lupersol 130 from Lucidol Division of Pennwalt Corporation. In an embodiment, the composition of the second polyethylene may be similar to compositions disclosed in the aforementloned publication of G. White except that the polyethylene would be selected so as to meet the requirements of the present invention. While the amount of cross-linking agen-t in the second polyethylene may be varied over a wide ran~e it may be preferable not to have a ~6~:~'79 high concentration oE cross-linklng agent in the second polyethylene and to then admix only a small amount o~ the second polythylene with the first polye-thylene. In that e~ent, problems may be experienced in mixing the rela-ti~ely high concentration of cross-linking agent in the second polyethylene in a uniform manner into the first polyethylene. If the cross-linking agen-t is an organic peroxide, it is preferred that less than ~% by weight oE
peroxide be present in the second polyethylene and preferably 0.05-1.0% by weight of peroxide.
As noted above, a co-curing agent may be incorporated into the first or second polyethylene i.e.
either separately from or admixed with cross-linking agent.
Examples of co-curing agents include triallyl cyanurate, triallyl isocyanurate and 1,2-polybutadiene.
The reactive agent may be a modifying agent, which may be used ei-ther alone or, usually, in combination with an initiator. Examples of modifying agents include unsaturated organic acids, and derivatives thereof, e.g.
acrylic acid, methacrylic acid, maleic acid, fumaric acid, itaconic acid, crotonic acid, maleic anhydrlde, cross-linkable silane compounds e.g. vinyltrimethoxysilane, vinyltriethoxysilane, vinyltris(2-methoxyethoxy) silane and vinylmethyldimethoxysilane, and other compounds capable of being reacted with molten polyethylene. The use of sulphur trioxide-trimethylamine complex, as the modifying agent is described and claimed in the copending patent application of J.R. Boocock Eiled concurrently herewith. The modifying agents will usually be used in combination with an initiator especially a cross-linking agent e.g. an organic peroxide.
With some modifying agents, other initiators are known e.g.
styrene acts as an initiator for maleic anhydride. The modifying agent and initiator rnay be separately admixed with the second polyethylene as compositions thereof. Under some processing conditions, modifying agents may react with ~2~;2~7~

polyethylene in the sub.stantial absence of an added initiator. For example, it is known to thermally react maleic anhydride with polyethylene at temperatures of at least about 375C~
The polyethylenes of the blend may contain a stabilizing agent e.g. an antioxidant or an ultra violet stabilizer. Examples of antioxidants are hindered phenolic antioxidants e.g. octadecyl-3,5-di-tert.butyl-4-hydroxy cinnamate and tetrakis-methylene-3-(3',5'ditert.butyl-4 hydroxyphenyl) propiona~e methane. Hindered phenolic antioxidants may be used in combination with a phosphite antioxidant e.g. di(stearyl)-pentaerythritol diphosphite, tris di-tert.-butyl phenyl phosphite, dilauryl thiodi-propionate and bis(2,4-tert.-butylphenyl) pentaerythritol diphosphite. Examples of ultra violet stabilizers are 2-hydroxy-4-n-octoxybenzophenone, 2-(3'-tert butyl-2'-hydroxy-5'-methylphenyl)-5-chlorobenzotriazole and bis-(2,2,6,6,-tetramethyl 4-piperidyl)sebacate. Moreover, the polyethylenes of the blend may contain sli~ agents, anti-blocking agents, anti-static agents, mould release agents, pigments, nucleating or other processing aids or the like. Examples of slip agents are erucamide and stearamide, of anti-static agen-ts are bis(hydroxyethyl) tallow amine and glycerol monooleate, of anti-blocking agents are silica and mica and of mould release agents are calcium stearate and zinc stearate. Examples oE nucleating agents or other processing aids are talc, silica, polyethylene glycol, fluorinated elastomers and polyolefin waxes, or the like.
As noted above, stabili~ing or other so-called non-reactive agents may have detrimen~al effects on cross-linking or other reactive agents and for that reason it may be preferable not to use certain combinations of agents, as will be understood by those skilled in the art~
The ratio oE the first polyethylene to the second polyethylene may be varied over a wide range, particularly from about 5:1 to about 400:1 and especially about 50:1 to about 100:1. The ratio selected will depend on a variety of ~6~7~
- 12 ~
factors, includinq the amount oE reactive agent (or o additiona] reactive agent) to be lncorporated into the blend, the type(s) of reactive agent, the need for a uniform product, the type oE processing that the resultant blend is to be subjected to and the mixing capabilities of apparatus used therein and the like. With regard to the mixing capabilities of the apparatus, twin-screw extruders may be more effective than single screw extruders.
The amount of reactive agent in the blend of the present invention will depend, in particular, on the type of reactive a~ent and the intended end-use of the blend. Thus, the amount could vary, depending on such other factors, from a few parts per million ~ppm) in the blend to in excess of one per cent, by weigh-t. ~Such amounts will be understood by those skilled in the art.
In the event that the reactive agent is a cross-linking agent, the first and second polyethylenes may be selected and admixed so that the amount oE cross-linking agent in the blend is in the range of about 25 ppm to about 1000 ppm by weight of the blend. The amount of cross-linking agent in the blend will depend primarily on t~le intended end-use for the blend. Blends intended for the fabrication of highly cross-linked products will have relatively high levels of cross-linking agents. On the other hand, a small amount oE cross-linking agent may be present in the blend so as to effect only a partial crosslinking of the resultant product.
The particles of the first and second polyethylenes may be any convenient shape and size and may for example be granules, powder, pellets or the like. Such forms are commercially available forms of polyethylene and/or may be obtained by known techniques e,g. grinding, melt pelletization and the like. However, it is preferred that the particles of the first polyethylene be of substantially the same size as the particles of the composition of the second polyethylene. As the diEference ~26~
- :L3 -in size b~atween the particles increases, so does the possibillty that the two types of particles wlll become separated ~rom one another during storage, transportation or other handling of the blend; such differences may be less cri-tical iE the blend is fed to an extruder shortly after preparation thereof.
The composition o the second polyethylene may be produced by techniques known in the art for incorporating agents into polyethylene. Such methods include melt blend-ing, coating and extrusion, and injection of the agent intomolten polyethylene. If the reactive agent is a modifying agent or especially a cross-linking agent, the reactive agent should be incorporated into the polyethylene ln a manner that does not result in premature reaction with the polyethylene, as in known in the art.
The blends of the present invention may be used for the incorporation of reactive agents into polyethylene, especially in a versatile and economic manner. The result-ant blends may be used in a wide variety oE end-uses, as is known for polyethylene. Such uses include blow-moulding processes, film and pipe extrusion processes, sheet thermo-forming processes and rotational moulding processes.
Apparatus used in such processes is referred to herein as melt processing apparatus. In particularly preferred embodiments, the blends are used in the manuEacture of film in a blown film process. As is illustrated hereinafter, such a use of the blends can result in substantial increases in the rate of produc-tion of film of acceptable ~uality.
However, for any particular combination of apparatus, polymer composition and processing conditions, there may be an optimum level of cross-linking a~ent above which increas-es in the rate of film production, if any, may be at the detriment of film quality.
The present invention is illustrated by the following examples:

37~

A composi~ion of an ethylene/butene~l copol~mer, with 0.55% by weight of Vulcup R organic peroxide and 0 55%
by weight of triallyl isocyanurate, was prepared by a melt-blending technique. The copolymer had a density of 0.950 g/cm3 and a melt index of 50 dg/min~
The composition was admixed with S~LAIR* 58~polyethylene, a copolymer oE ethylene and butene 1 having a density of 0.955 g/cm3, a melt index of 0.43 dg/min. and a shear viscosity of 3580 poise, in a ratio of polyethylene:-composition of 100:1, to give a blend of the present invention. The resultant blend was fed to a blow moulding machine equipped with a mould for the fabrication of one gallon bottles, The bottles obtained were of good quality, being free of gel particles. Further details are given below, as Run 1.
As a comparison, the corresponding composition having an ethylene homopolymer, with a density of 0~960 g/cm3, a melt index of 21 dg/min. and a shear viscosity of 1700 poise, and the organic peroxide and triallyl isocyanu-rate was preparedO A blend of this composition and SCLAIR58A polyethylene (1:100) was prepared and fed to the blow moulding machine. It was found that the polymer contained pellet-sized particles of gel. In addition the polymer melt failed to fill the bottle cavity and the bottles obtained were incomplete and full of holes. Further details are given below as Run 2.
Further details are as follows:
Run No. _ 1 2 _ 3**
30 Diameter swell, %142.3 43.6 ~~
Weight swell, %2 474 394 493 Parison melt strength98 47.6 20.9 sec/lOOg3 1. Defined as (width of parison/0.5 x circumference of die orifice~-l, expressed as a percentage. Measured at a shear rate of 9000 sec~l in a blow moulding process (1.8 litre bottles).
* denotes trade mark ~ ~ ' 9~

2. Defined as (actual weight of parison/theoretical weight of parison~-l, expressed as a percentage. Measured at a shear rate of 9000 sec~1 as in (1) above. The theoretical weight of the parison is the weight in the absence of swell and drawdown.

3. The time in seconds that a parison weighing lOOg will hang freely from the die of a blow moulding apparatus.
** Comparative data for SCLAIR 5~A polyethylene that does not contain organic peroxide and triallyl isocyanurate.
Example II
A composition of an ethylene/butene-l copolymer with 0.25~ by weight of Vulcup R organic peroxlde and 0.25 by weight of triallyl isocyanurate was prepared by a melt-blending technique. The copolymer had a density oE
0.924 g/cm3, a melt index of 53 dg/min. and a shear viscosity of 620 poise.
The composition was admixed with SCLAIR 13J4 polyethylene, an ethylene/octene-l copolymer having a density of 0.926 g/cm3, a melt index of 1.0 dg/min. and a shear viscosity of 5~40 poise, in a ratio of polyethylene :
composition of 50:1, to give a blend of the present invention.
The resultant blend was fed to apparatus for the manufacture of film by a blown film technique. The film had a thickness of 25 ~m. It was found that a gel-free film could be produced and that the film has a higher melt strength than film produced from SCLAIR 13J4 polyethylene that did not contain the composition of organic peroxidel The higher mel~ strength permitted an increase in the rate of production of film of 40%.
Subsequent testing showed that the impact strength and tensile strength of the film were not adversely affected by the use of the composition of organic peroxide and/or the higher production rate.
Example III
Dynamic rheological properties of the ethylene/-butene-l and ethylene/octene-l copolymers of Example II were i ,,,~ ~

~6~3'7~
- 16 ~
measured using a Rheometrics* On-Line rheometerO That rheometer measures the relationship between complex viscosity and angular frequency which, according to the Mer~-Cox rule, is equivalent under conditions o~ linear viscoelas-ticity to the relationship between shear viscosity and shear ra-te.
The dynamic rheological properties were determin-ed a~ 200C under conditions that were equivalent to a shear rate of 400 sec~l. It was found that tne shear viscosities of the ethylene/butene-l and ethylene/octene-l copolymers were 980 and 8000 poise respectively.
~ s noted in Example II, film of acceptable properties could be made according to the present invention using the above polymers.
Example IV
A granular linear low density polyethylene identified as ESSO* LL10~1-49, which has a density of 0~918 g/cm3, a melt index of 1.0 dg/min. and a shear viscosity of 6250 poise, was extruded into film using a blown Eilm process. The film produced had a thickness of 50 ~m/ It was Eound that the maximum production rate obtainable with the apparatus and processing conditions being used was 38.
kg/hr. The production rate was limited by, in particular/
s-tability of the bubble in the blown film process and melt fracture of the polymer at the die lips.
A pelletized composition of a melt-processing aid and 1000 ppm of Lupersol 130 organic peroxide in an ethylene/
butene-l copolymer having a density of 0.920 g/cm3, a mel-t index of 1.40 dg/min. and a shear viscosity of 5250 poise, was blended into the above linear low density polymer so as to provide 5~ of the composition in the polymer. When film was produced using the method described above, the polymer did not exhibit melt fracture. However, the level of gel in the film was too high to permit an evaluation of any increased stability of the bubble.
The above composition was replaced, at a 2%
level, with a pelletized composition of 2500 ppm of Lupersol * denotes trade mark 3~
~ 17 -l30 organic peroxide in an ethylene/butene-l copolymer having a density of 0.92~ g/cm3, a melt index of 53 dy/min. and a shear viscosity of 620 poise. On extrusion of the blend into film, it was found that the film obtained was essentially free of gel and that it was possible to increase the production rate by 47~, to 56.7 kg/hr.; melt fracture was not experienced during the trial.
Example V
In a series of runs, ethylene/alpha-olefin copolymer pellets containing Lupersol 130 organic peroxide were blended with SCLAIR 13J4 polyethylene, an ethylene/-octene-l copolymer having a density of 0.925 g/cm3, a melt index of 1.0 dg/min. and a shear viscosity of 5~0 poise.
The resultant blends were extruded into Eilm in a blown film process, the apparatus used being equipped with an efficient mixing screw. Further details of the ethylene/alpha-olefin copolymer and the results obtained are shown in Table I.
Table I
Shear Run Copolymer Melt Viscosity Viscosity Film No,* Comonomer Density Index ~poise)** ~pois0) Quality 1 octene-l 0.9261.0 9000 5440 poor 2 butene-l 0.9245.1 470G 2810 fair 3 butene-l 0.92420.0 1800 1330 good

4 octene-l 0.92~1.0 9000 5440 poor butene-l 0.9245.1 4700 2~10 poor 6 bu~ene-l 0.92~20.0 1800 1330 good * In Runs 1 to 3, 1.0% by weight of pellets containing 5000 ppm oE peroxide were used; in the remaining runs, 2~ by weight of peilets containing 5000 ppm of peroxide were used.
** Dynamic viscosity measured at 200C, 400 radians/sec.
The results show that when the polymer containing the peroxide has a melt viscosity that is about the same as that of major component, film of good quality was not obtained~ When the melt viscosity of the polymer containing peroxide was reduced to 50~ of the major polymer component, as in Runs 2 and 5, film quality was marginal, being , ~,, , ~.J, 1~ -dependent on the amount oE peroxide used. However, when the melt viscosity of the polymer containing peroxide was only 20% of that of the major polymer component, good quality ~ilm was obtained~
In a related series of runs, attempts were made to extrude film from a number of blends using apparatus equipped with a very inefficient mixing screw. It was Eound that even when the melt viscosity of the polymer containing peroxide was reduced to 5% of that of the major component, the peroxide concentration had to be less than 2500 ppm in order to obtain film of good ~uality. Thus the present invention will permit the manufacture of film using apparatus having a very ineEficient mixing screwl although more efficient mixing screws are preferred.
Example VI
About 1500g of SCLAIR 2114 polyethylene, an ethylene/butene-l copolymer having a density of 0.924 g/cm3, a melt index of 53 dg/min. and a shear viscosity of 620 poise, were ground in an Abbe* cut-ter equipped with a 0.48 cm mesh screen. About 45g of sulphur trioxide-trimethyl-amine complex was dissolved in 600 ml of dis-tilled water at 50C and, with minimal delay, was distributed on the particles of polyethylene in a Henschel* mixer maintained at 90C. Nitrogen was continuously passed through the mixer for a period of 20 minutes to remove water vapour. The resultant coated particles, which were still moist, were dried overnight in a vacuum oven at 95C.
A masterbatch was prepared by extruding the thus dried mixture from a lo 90 cm single screw Brabender*
extruder, equipped with a mixing screw, at a melt temperature of 182C. The extrudate was cooled in a water bath, cut in a strand cutter and dried overnight under vacuum. The calculated amount of sulphur trioxide-tri-methylamine complex in the masterbatch was 2.9% by weight.
A physical admixture of 23g of the masterbatch and 660g of SCLAIR 13-llE polyethylene, an ethylene/butene-1 * denotes trade mark ,. . . .
~'f~
~,;.. .,~

~2~297~

copolymer having a density of 0.920 g/cm3, a melt index of 1.40 dg/min. and a shear viscosity of 5250 poise, was prepared. The admixture was extruded from the Brabender extruder, now equipped with a venting screw and a breaker plate, at a melt temperature of 256C, to form cast film having a width of 13O5 cm and a thickness of 50 ~m. The hold-up time in the extruder was estimated to be 2.5-5 minutes.
The ~ilm thus obtained was dyeable with basic dyes, whereas film from either SCLAIR 2114 or SCLAIR 13-llE
polyethylene is not dyeable. In addition, the film did not show evidence of significant amounts of black specks, which are produced if a powder of the complex is reacted with polyethylene.
The sulphonation of polyethylene using sulphur trioxide-triethylamine complex is the subject of a copending patent application of J.R.B. Boocock filed concurrently herewith.
Example VII
In a series of runs, pellets of a polymer were coated with 2500 ppm of Lupersol 130 organic peroxide cross-linking agent. The resultant coated pellets were physically admixed, at a 2% level, with SCLAI~ 13J4 polyethylene, an ethylene/octene-l copolymer having a density of 0.926 g/cm3, a melt index of 1.0 dg/min. and a shear viscosity of 5440 poise, to give blends of the present invention. The resultant blends were fed to -the extruder of a blown film process; the extruder was equipped with the most efficient mixing screw that was available.
The film obtained was inspected for quality. The results obtained are shown in Table II.

i 3 ~2~ 7~

Table II
Run Film NoO Polymer Quality Comments _ l ethylene/butene/- good good melt stren~th octene 2 HPPE good good melt strength 3 polyethylene wax good good melt strength, reduoed power consumption 4 polypropylene good good melt strength white concen~rate good good melt strength 6 black concentra-te good good melt strength l. (i) ethylene/butene/octene terpolymer, density 0.910 g/cm3, melt index 1.7 dg/min.
(ii) HPPE = high pressure polyethylene, density 0.918 g/cm3, melt index 7.0 dg/min (iii) polyethylene wax = N-34 Epolene~ polymer, density 0.910 g/cm3, Brookfield viscosity 450 centipoise at 125C.
(v) polyprop~lene = Shell* 6300, density 0.905 g/cm3, melt flow index 20.0 dg/min.
~vi) white concentrate = TiO2 in a high pressure polyethylene.
(vii) black concentrate = carbon black in a linear low density polyethylene.
Example VIII
~ physical admixture of an ethylene/bu-tene-l copolymer having a density of 0.920 g/cm3, a melt index of 1.4 dg/min. and a shear viscosity of 5250 poise, a concen-trate of an organic peroxide cross-linking agent and maleic anhydride was prepared in a Henschel* mixer such that the admixture contained 50 ppm of cross-linking agent and 1% by weight of maleic anhydride. The concentrate of the cross-linking agent was in the form of pellets of an ethylene/-butene-l copolymer having a density of 0.924 g/cm3, a melt index of 53 dg/min. and a shear viscosity of 620 poise, 5i~ * denotes trade mark !s ~

9~9 containing Lupersol 130 organic peroxide. The maleic anhydride was in the Eorm of powder7 The mixture was blended in the Henschel mixer for five minutes at a maximum temperature of about 70C and then extruded through a corotating twin screw extruder, the first two zones of which were at a temperature of 18aC and -the remaining zones at a temperature of 200C.
A maleic anhydride-grafted polymer containing 0.56~ by weight of maleic anhydride was obtained; the melt index of the polymer was 0.53.
Films of the grafted polymer were pressed onto aluminum foil, nylon film and ethylene/vinyl alcohol copolymer ~ilm at a temperature of about 180C. Good adhesion of the gra~ted polymer to the foil or film substrate was observed in each instance.
This example illustrates the use of the present invention with a modifying agent. The reaction of maleic anhydride with ethylene/butene~l copolymers is discussed further in the copending application of C.S. Wong and R.A. Zelonka filed concurrently herewith.
Example IX
~n e-thylene/butene-l copolymer having a density of 0.959 g/cm3, a melt index of 85 dg/min. and a shear viscosity of 3~0 poise, was blended with 2500 ppm of t-butylhydroperoxide. The resulting blend was physically admixed with pellets of an ethylene/butene-l copolymer copolymer having a density of 0.920 g/cm3, a melt index of

5.5 dg/min. and a shear viscosity of 2630 poise, in ratios of from 3:97 to 6:94.
The admixtures thus obtained were fed to a process for the extrusion coating of paper. The extruded admixture had higher melt strength such that the line speed of the extrusion coating line could be increased from 26 m/minute, in the absence of the peroxide blend, to 46 m/minute.

. . ?

~ 22 ~
Example X
An ethylene/butene-l copolymer having a density of 0.924 g/cm3, a melt index of 53 dg/min. and a shear viscosity of 620 poise, was blended with 2500 ppm of Lupersol 130 organic peroxide. The resulting blend was physically admixed, at a 4~ and at a 6% level, ~ith SCLAIR
58A ethylene/butene-l copolymer which has a density of 0.955 ~/cm3, a melt index of 0.43 dg/min. and a shear viscosity of 3580 poise. The resulting blends were extruded into sheet having a thickness of 5 mm.
The sheets thus obtained were free of gel, had higher melt strength than the corresponding sheets formed from SCLAIR 58A polyethylene and gave improved performance in the thermoforming process.
Example X_I
Physical admixtures of SCLAIR 13-llE ethylene/-butene-l copolymer, which has a density of 0~920 g/cm3, a melt index of 1.4 dg/min. and a shear viscosity of 5250 poise, organic peroxide and maleic anhydride were prepared.
The organic peroxide (Peroxide Concentrate) was in the form of pellets of a composition of Sclair 2114 polyethylener an ethylene/butene-l copolymer having a density of 0.924 g/cm3, a melt index of 53 d~/min. and a shear viscosity of 620 poise, with 4000 ppm of Lupersol 130 or~anic peroxide and 4000 ppm of triallyl isocyanurate. The maleic anhydride was either in the form of a powder or a blend in polyethylene, as shown below.
The physical admixture was fed to a 1.9 cm Brabender single screw extruder and extruded into a strand using a melt temperature of 225C.
Adhesion tests were conducted by pressing the ~hopped strand into film between sheets of aluminum at a temperature of 180C for about 5 seconds.

,' ~26~7~;9 Further details and -the results obtained are as follows:
Sample A B C
5 SCLAIR 13-llE copolymer (g) 1473 1331 1331 Peroxide Concentrate (g) ].B.75 18.75 18.75 Maleic anhydride*
Powder (g) 7-5 concentra-te #l (g) - 150 concentrate #2 (g) - - 150 Results _ _ .
Graft (as anhydride plus 0.35 0.31 0.24 acid) (%) Melt Index (dg/min.) 0.44 0.64 0.72 15 Adhesion** 3 2 * In Sample A, the maleic anhydride was in the Eorm of a powder; In Sample B, the maleic anhydride was in the form of maleic anhydride deposited on ground Sclair 2114 polyethylene from -the melt in a rotary evaporator (Concentrate ~1, which contained about 5%
by we.ight of maleic anhydri.de);
In Sample C, the maleic anhydride was in the form of maleic anhydride deposited onto ground SCLAIR 2114 polyethylene by evaporation of a solution at 60-65C
in a rotary evaporator followed by application of a vacuum and cooling to ambient temperature (Concentrate ~2, which contained about 5~ by weight of maleic anhydride).
** Estimated order of strength of adhesion (1 = bestj.
The adhesion obtained with Sample A was very poor.

SUPPLEMENTAR~ DISCLOSURE

In a preferred embodiment of the process of the present invention, the blends are used in the manufacture of film. Such a process for the manufacture of film would normally be operated so as to produce produc-ts that are cross-linked to an extent that gel is not formed or that the shear viscosity of the first polyolefin is increased to not more than five times its original value. In the manu~acture of film, it is further preferred that at least -the polymer of the first polyolefin be at least 70~ by weight of so-called linear low density polyethylene. In particular, the polymer should be a copolymer of ethylene and at least one C4-Clo higher alpha-olefin e.g.
butene-l, hexene-l and/or octene-l, and have a density in 15 the range of 0.910 - 0.930 g/cm3.
It has been disclosed hereinbefore that the polyethylenes of the blend may contain nucleating agents or other processing aids, examples of the latter being fluorina-ted elastomers. Such processing aids are 20 particularly useful in the manufacture of film, especiaily from linear low density polyethylene, and tend to reduce any likelihood for melt fracture to occur, as is disclosed in U~S. Patent 3 125 547 of P.S. Blatz, issued 1964 March 17.
Melt fracture is a phenomenon that may occur during extrusion of molten polyethylene through a die. At low rates of extrusion, the extrudate may be smooth but at some higher rate the extrudate will become rough; the transition from smooth extrudate to rough extrudate may 30 occur as the result of a relatively small increase in the rate of extrusion. The phenomenon is well known, being discussed by for instance J.P. Tordella in SPE Journal, p 36-40, February 1956. Copolymers of ethylene and C4-Clo higher alpha-olefins, and especially such - ~ .

S2~7~

po]ymers of relatively low density, which are now freguently referred to as linear low density polyethylene, tend to be particularly susceptible to the occurrence of melt fracture.
It has been found to be advantageous to incorporate fluorinated elastomer processing aids into the blends of the present invention~ especially as part of the composition of the second polyolefin. Such use of a fluorinated elastomer is illustrated by the following example:
Example XII
A linear low density polyethylene, which was an ethylene/butene-l copolymer having a density of 0.920 g/cm3, a melt index of loO dg/min. and a shear viscosity of 6000 poise, and containing no additives other than antioxidant, was extruded through a 6.25 cm extruder equipped with an annular die havin~ a diameter of 10 cm.
The die gap was 0.75 mm and the melt temperature oE the polyethylene was 200C. The film blow-up ratio was 2.5:1 and the resultant film had a thickness of 0 1 mm.
Melt fracture was observed in the ex-trusion of the polyethylene at an extrusion rate of as low as about 7 kg/hour. However, film could still be manufactured at extrusion rates of up to about 58 kg/hour, at which rate the film bubble in the blown film extrusion process became unstable as a result of insufficient melt strength of the polyethylene.
While continuing to operate the process at the same extrusion rate, 1.5~ by weight of a concentrate was fed to the extruder along with the polyethylene. The concentrate was a linear low density polyethylene, an ethylene/butene-l copolymer having a density of 0.926 g/cm3~ a melt index of 73 dg/min and a shear viscosity of 7~4 210 poise, and containing 3000 ppm of Lupersol 130 peroxide and 2.6~ of a fluorinated elastomer processing aid of tAe type disclosed in the aEorementioned U.S. 3 125 547. After 20 minutes, melt Eracture was no longer observed at the extrusion rate of 58 kg/hour. Furthermore, the extrusion rate could be increased by 20% to 71 kg/hour before the film bubble became unstable. Melt fracture was not observed at this higher extrusion rate.
The haze and gloss of film produced using the linear low density polyethylene containing the concentrate was superior to film produced using the polyethylene without concentrate, because of the absence of melt fracture.

.p ~

Claims (84)

The embodiments of the invention in which an exclusive property or privilege is claimed are defined as follows:

1. A polyolefin blend comprising, in physical admixture, a major portion of particles of a first polyolefin and a minor portion of particles of a composition of a normally solid second polyolefin, said polyolefins being selected from the group consisting of homopolymers and copolymers of hydrocarbon alpha-olefins having 2-10 carbon atoms; said second polyolefin having a shear viscosity that is not more than 30% of that of said first polyolefin when measured at 200°C and a shear rate of 400 sec-1, said composition being a composition of the second polyolefin and a reactive agent selected from the group consisting of cross-linking agents and modifying agents, and mixtures thereof, said reactive agent being capable of reacting with said polyolefins in a molten state.

2. The blend of Claim 1 in which the ratio of the first polyolefin to the second polyolefin is in the range of from 10:1 to 100:1.

3. The blend of Claim 1 in which the shear viscosity of the second polyolefin is 5-15% of that of the first polyolefin.

4. The blend of any one of Claim 1, Claim 2 and Claim 3 in which the reactive agent is a cross-linking agent.

5. The blend of any one of Claim 1, Claim 2 and Claim 3 in which the reactive agent is a modifying agent.

6. The blend of any one of Claim 1, Claim 2 and Claim 3 in which the ratio of the first polyolefin to the second polyolefin is in the range of from 50:1 to 100:1.

7. The blend of any one of Claim 1, Claim 2 and Claim 3 in which the first and second polyolefins are each selected from the group consisting of homopolymers of ethylene and copolymers of ethylene and at least one C4 - C10 higher alpha-olefin.

8. A polyolefin blend comprising, in physical admixture, a major portion of particles of a first poly-ethylene and a minor portion of particles of a composition of a normally solid second polyethylene, in which the first polyethylene is selected from the group consisting of homo-polymers of ethylene and copolymers of ethylene and at least one C4 - C10 higher alpha-olefin, said second polyethylene being a copolymer of ethylene and at least one C4 - C10 higher alpha-olefin having a density of at least 0.890 g/cm3 and a melt index of at least 40 dg/min., said second polyethylene having a shear viscosity that is not more than 30% of that of said first polyethylene when measured at 200°C and at a shear rate of 400 sec-1, said composition being a composition of the second polyethylene and a reactive agent selected from the group consisting of cross-linking agents and modifying agents, and mixtures thereof, said reactive agent being capable of reacting with said polyethylenes in a molten state.

9. The blend of Claim 8 in which the ratio of the first polyethylene to the second polyethylene is in the range 10:1 to 100:1.

10. The blend of Claim 8 in which the shear viscosity of the second polyethylene is 5-15% of that of the first polyethylene.

11. The blend of any one of Claim 8, Claim 9 and Claim 10 in which the density of the second polyethylene is at least 0.910 g/cm3.

12. The blend of any one of Claim 8, Claim 9 and Claim 10 in which the reactive agent is a cross-linking agent.

13. The blend of any one of Claim 8, Claim 9 and Claim 10 in which the reactive agent is a modifying agent.

14. The blend of any one of Claim 8, Claim 9 and Claim 10 in which the density of the second polyethylene is at least 0.910 g/cm3.

15. The blend of any one of Claim 8, Claim 9 and Claim 10 in which the first polyethylene contains a reactive agent.

16. The blend of any one of Claim 8, Claim 9 and Claim 10 in which the ratio of the first polyethylene to the second polyethylene is in the range 50:1 to 100:1.

17. The blend of any one of Claim 8, Claim 9 and Claim 10 in which the density of the second polyethylene is at least 0.008 g/cm3 lower than the density of the first polyethylene.

18. A polyolefin blend comprising, in physical admixture, a major portion of particles of a first polyethylene and a minor portion of particles of a composition of a second polyethylene, in which the first polyethylene is selected from the group consisting of homopolymers of ethylene and copolymers of ethylene and at least one C4 - C10 higher alpha-olefin, said second polyethylene being a copolymer of ethylene and at least one C4 - C10 higher alpha-olefin having a density of at least 0.890 g/cm3 and a melt index in the range of 40-200 dg/min., the density of the second polyethylene being at least about 0.005 g/cm3 lower than that of the first polyethylene and the melt index of the second polyethylene being at least 10 dg/min. higher than that of the first polyethylene, said composition being a composition of second polyethylene and a reactive agent selected from the group consisting of cross-linking agents and modifying agents, and mixtures thereof, said reactive agent being capable of reacting with said polyethylenes in a molten state.

19. The blend of Claim 18 in which the melt index of the second polyethylene is 20 dg/min. higher than that of the first polyethylene.

20. The blend of Claim 18 in which the melt index of the second polyethylene is 40-60 dg/min. higher than that of the first polyethylene.

210 The blend of any one of Claim 18, Claim 19 and Claim 20 in which the reactive agent is a cross-linking agent.

22. The blend of any one of Claim 18, Claim 19 and Claim 20 in which the reactive agent is a modifying agent.

23. The blend of any one of Claim 18, Claim 19 and Claim 20 in which the density of the second polyethylene is at least 0.910 g/cm3.

24. The blend of any one of Claim 18, Claim 19 and Claim 20 in which the first polyethylene contains a reactive agent.

25. The blend of any one of Claim 18, Claim 19 and Claim 20 in which the ratio of the first polyethylene to the second polyethylene is in the range of from 10:1 to 100:1.

26. The blend of any one of Claim 18, Claim 19 and Claim 20 in which the ratio of the first polyethylene to the second polyethylene is in the range of from 50:1 to 100:1.

27. The blend of any one of Claim 18, Claim 19 and Claim 20 in which the density of the second polyethylene is at least 0.008 g/cm3 lower than the density of the first polyethylene.

28. A process for the manufacture of articles from a polyolefin and a reactive agent capable of reacting with the polyolefin in a molten state, comprising feeding to melt processing apparatus a polyolefin blend comprising, in physical admixture, a major portion of particles of a first polyolefin and a minor portion of particles of a composition of a normally solid second polyolefin, said polyolefins being selected from the group consisting of homopolymers and copolymers of hydrocarbon alpha-olefins having 2 10 carbon atoms, said second polyolefin having a shear viscosity that is not more than 30% of that of said first polyolefin when measured at 200°C and a shear rate of 400 sec-1, said composition being a composition of the second polyolefin and a reactive agent selected from the group consisting of cross-linking agents and modifying agents, and mixtures thereof, melting and admixing said blend and forming an article from the resultant blend.

29. The process of Claim 28 in which the ratio of the first polyolefin to the second polyolefin is in the range of from 10:1 to 100:1.

30. The process of Claim 28 in which the shear viscosity of the second polyolefin is 5-15% of that of the first polyolefin.

31. The process of any one of Claim 28, Claim 29 and Claim 30 in which the reactive agent is a cross-linking agent.

32. The process of any one of Claim 28, Claim 29 and Claim 30 in which the reactive agent is a modifying agent.

33. The process of any one of Claim 28, Claim 29 and Claim 30 in which the ratio of the first polyolefin to the second polyolefin is in the range of from 50:1 to 100: 1.

34. The process of any one of Claim 28, Claim 29 and Claim 30 in which the first and second polyolefins are each selected from the group consisting of homopolymers of ethylene and copolymers of ethylene and at least one C4 - C10 higher alpha-olefin.

35. A process for the manufacture of articles from a polyolefin and a reactive agent capable of reacting with the polyolefin in a molten state, comprising feeding to melt processing apparatus a polyolefin blend comprising, in physical admixture, a major portion of particles of a first polyethylene and a minor portion of particles of a composition of a normally solid second polyethylene, in which the first polyethylene is selected from the group consisting of homopolymers of ethylene and copolymers of ethylene and at least one C4 - C10 higher alpha-olefin, said second polyethylene being a copolymer of ethylene and at least one C4 - C10 higher alpha-olefin having a density of at least 0.890 g/cm3 and a melt index of at least 40 dg/min, said second polyethylene having a shear viscosity that is not more than 30% of that of said first polyethylene when measured at 200°C and at a shear rate of 400 sec-1, said composition being a composition of the second polyethylene and a reactive agent selected from the group consisting of cross-linking agents and modifying agents, and mixtures thereof, melting and admixing said blend and forming an article from the resultant blend.

36. The process of Claim 35 in which the ratio of the first polyethylene to the second polyethylene is in the range 10:1 to 100:1.

37. The process of Claim 35 in which the shear viscosity of the second polyethylene is 5-15% of that of the first polyethylene.

38. The process of any one of Claim 35, Claim 36 and Claim 37 in which the density of the second polyethylene is at least 0.910 g/cm3.

39. The process of any one of Claim 35, Claim 36 and Claim 37 in which the reactive agent is a cross-linking agent.

40. The process of any one of Claim 35, Claim 36 and Claim 37 in which the reactive agent is a modifying agent.

41. The process of any one of Claim 35, Claim 36 and Claim 37 in which the density of the second polyethylene is at least 0.910 g/cm3.

42. The process of any one of Claim 35, Claim 36 and Claim 37 in which the first polyethylene contains a reactive agent.

43. The process of any one of Claim 35, Claim 36 and Claim 37 in which the ratio of the first polyethylene to the second polyethylene is in the range 50:1 to 100:1.

44. The process of any one of Claim 35, Claim 36 and Claim 37 in which the density of the second polyethylene is at least 0.008 g/cm3 lower than the density of the first polyethylene.

45. A process for the manufacture of articles from a polyolefin and a reactive agent capable of reacting with the polyolefin in a molten state, comprising feeding to melt processing apparatus a polyolefin blend comprising, in physical admixture, a major portion of particles of a first polyethylene and a minor portion of particles of a composition of a second polyethylene, in which the first polyethylene is selected from the group consisting of homopolymers of ethylene and copolymers of ethylene and at least one C4 - C10 higher alpha-olefin, said second polyethylene being a copolymer of ethylene and at least one C4 - C10 higher alpha-olefin having a density of at least 0.890 g/cm3 and a melt index in the range of 40-200 dg/min., the density of the second polyethylene being at least about 0.005 g/cm3 lower than that of the first polyethylene and the melt index of the second polyethylene being at least 10 dg/min. higher than that of the first polyethylene, said composition being a composition of second polyethylene and a reactive agent selected from the group consisting of cross-linking agents and modifying agents, and mixtures thereof, melting and admixing said blend and forming an article from the resultant blend.

46. The process of Claim 45 in which the melt index of the second polyethylene is 20 dg/min. higher than that of the first polyethylene.

47. The process of Claim 45 in which the melt index of the second polyethylene is 40-60 dg/min. higher than that of the first polyethylene.

48. The process of any one of Claim 45, Claim 46 and Claim 47 in which the reactive agent is a cross-linking agent.

49. The process of any one of Claim 45, Claim 46 and Claim 47 in which the reactive agent is a modifying agent.

50. The process of any one of Claim 45, Claim 46 and Claim 47 in which the density of the second polyethylene is at least 0.910 g/cm3.

51. The process of any one of Claim 45, Claim 46 and Claim 47 in which the first polyethylene contains a reactive agent.

52. The process of any one of Claim 45, Claim 46 and Claim 47 in which the ratio of the first polyethylene to the second polyethylene is in the range of from 10:1 to 100: 1.

53. The process of any one of Claim 45, Claim 46 and Claim 47 of in which the ratio of the first polyethylene to the second polyethylene is in the range of from 50:1 to 100: 1.

54. The process of any one of Claim 45, Claim 46 and Claim 47 in which the density of the second polyethylene is at least 0.008 g/cm3 lower than the density of the first polyethylene.

55. The process of any one of Claim 28, Claim 29 and Claim 30 in which the rate of extrusion of polyolefin so as to form the article is higher than the rate would be for extrusion of the same polyolefin in the absence of the reactive agent.

56. The process of any one of Claim 35, Claim 36 and Claim 37 in which the rate of extrusion of polyolefin so as to form the article is higher than the rate would be for extrusion of the same polyolefin in the absence of the reactive agent.

57. The process of any one of Claim 45, Claim 46 and Claim 47 in which the rate of extrusion of polyolefin so as to form the article is higher than the rate would be for extrusion of the same polyolefin in the absence of the reactive agent.

58. The process of any one of Claim 28, Claim 29 and Claim 30 in which the process is a blown film extrusion process and the rate of extrusion of polyolefin so as to form the article is higher than the rate would be for extrusion of the same polyolefin in the absence of the reactive agent.

59. The process of any one of Claim 35, Claim 36 and Claim 37 in which the process is a blown film extrusion process and the rate of extrusion of polyolefin so as to form the article is higher than the rate would be for extrusion of the same polyolefin in the absence of the reactive agent.

60. The process of any one of Claim 45, Claim 46 and Claim 47 in which the process is blown film extrusion process and the rate of extrusion of polyolefin so as to form the article is higher than the rate would be for extrusion of the same polyolefin in the absence of the reactive agent.

61. A blend of any one of Claim 1, Claim 8 and Claim 18 in which at least one of the major portion and the minor portion contains a fluorinated elastomer processing aid.

62. A blend of any one of Claim 1, Claim 8 and Claim 18 in which at least one of the major portion and the minor portion contains a fluorinated elastomer processing aid and in which the reactive agent is a cross-linking agent.

63. A blend of any one of Claim 1, Claim 8 and Claim 18 in which the minor portion contains a fluorinated elastomer processing aid.

64. A blend of any one of Claim 1, Claim 8 and Claim 18 in which the minor portion contains a fluorinated elastomer processing aid and in which the reactive agent is a cross-linking agent.

65. A process of any one of Claim 28, Claim 35 and Claim 45 in which, in the blend, at least one of the major portion and the minor portion contains a fluorinated elastomer processing aid.

66. A process of any one of Claim 28, Claim 35 and Claim 45 in which, in the blend, at least one of the major portion and the minor portion contains a fluorinated elastomer processing aid and in which the reactive agent is a cross-linking agent.

67. A process of any one of Claim 28, Claim 35 and Claim 45 in which, in the blend, the minor portion contains a fluorinated elastomer processing aid.

68. A process of any one of Claim 28, Claim 35 and Claim 45 in which, in the blend, the minor portion contains a fluorinated elastomer processing aid and in which the reactive agent is a cross-linking agent.

CLAIMS SUPPORTED BY THE SUPPLEMENTARY DISCLOSURE

69. A blend of any one of Claim 1, Claim 8 and Claim 18 in which at least one of the major portion and the minor portion contains a fluorinated elastomer processing aid, the polyolefin of each of said major portion and said minor portion being a copolymer of ethylene and at least one C4-C10 higher alpha-olefin.

70. A blend of any one of Claim 1, Claim 8 and Claim 18 in which at least one of the major portion and the minor portion contains a fluorinated elastomer processing aid and in which the reactive agent is a cross-linking agent, the polyolefin of each of said major portion and said minor portion being a copolymer of ethylene and at least one C4-C10 higher alpha-olefin.

71. A blend of any one of Claim 1, Claim 8 and Claim 18 in which the minor portion contains a fluorinated elastomer processing aid, the polyolefin of each of said major portion and said minor portion being a copolymer of ethylene and at least one C4-C10 higher alpha-olefin.

72. A blend of any one of Claim 1, Claim 8 and Claim 18 in which the minor portion contains a fluorinated elastomer processing aid and in which the reactive agent is a cross-linking agent, the polyolefin of each of said major portion and said minor portion being a copolymer of ethylene and at least one C4-C10 higher alpha-olefin.

73. A process of any one of Claim 28, Claim 35 and Claim 45 in which, in the blend, at least one of the major portion and the minor portion contains a fluorinated elastomer processing aid, the polyolefin of each of said major portion and said minor portion being a copolymer of ethylene and at least one C4-C10 higher alpha-olefin.

74. A process of any one of Claim 28, Claim 35 and Claim 45 in which, in the blend, at least one of the major portion and the minor portion contains a fluorinated elastomer processing aid and in which the reactive agent is a cross-linking agent, the polyolefin of each of said major portion and said minor portion being a copolymer of ethylene and at least one C4-C10 higher alpha-olefin.

75. A process of any one of Claim 28, Claim 35 and Claim 45 in which, in the blend, the minor portion contains a fluorinated elastomer processing aid, the polyolefin of each of said major portion and said minor portion being a copolymer of ethylene and at least one C4-C10 higher alpha-olefin.

76. A process of any one of Claim 28, Claim 35 and Claim 45 in which, in the blend, the minor portion contains a fluorinated elastomer processing aid and in which the reactive agent is a cross-linking agent, the polyolefin of each of said major portion and said minor portion being a copolymer of ethylene and at least one C4-C10 higher alpha-olefin.

77. A blend of any one of Claim 1, Claim 8 and Claim 18 in which the polyolefin of the major portion is at least 70% by weight of linear low density polyethylene.

78. A blend of any one of Claim 1, Claim 8 and Claim 18 in which the polyolefin of the major portion is at least 70% by weight of a copolymer of ethylene and at least one C4-C10 higher alpha-olefin, said copolymer having a density of 0.910 - 0.930 g/cm3.

79. A process of any one of Claim 28, Claim 35 and Claim 45 in which, in the blend, the polyolefin of the major portion is at least 70% by weight of linear low density polyethylene.

80. A process of any one of Claim 28, Claim 35 and Claim 45 in which, in the blend, the polyolefin of the major portion is at least 70% by weight of a copolymer of ethylene and at least one C4-C10 higher alpha-olefin, said copolymer having a density of 0.910 - 0.930 g/cm3.

81. A blend of any one of Claim 1, Claim 8 and Claim 18 in which the polyolefin of the major portion is at least 70% by weight of linear low density polyethylene and the ratio of the first polyolefin to the second polyolefin is in the range of from 50:1 to 100:1.

82. A blend of any one of Claim 1, Claim 8 and Claim 18 in which, in the blend, the polyolefin of the major portion is at least 70% by weight of a copolymer of ethylene and at least one C4-C10 higher alpha-olefin, said copolymer having a density of 0.910 - 0.930 g/cm3 and the ratio of the first polyolefin to the second polyolefin is in the range of from 50:1 to 100:1.

83. A process of any one of Claim 28, Claim 35 and Claim 45 in which the polyolefin of the major portion is at least 70% by weight of linear low density polyethylene and the ratio of the first polyolefin to the second polyolefin is in the range of from 50:1 to 100:1.

84. A process of any one of Claim 28, Claim 35 and Claim 45 in which, in the blend, the polyolefin of the major portion is at least 70% by weight of a copolymer of ethylene and at least one C4-C10 higher alpha-olefin, said copolymer having a density of 0.910 - 0.930 g/cm3 and the ratio of the first polyolefin to the second polyolefin is in the range of from 50:1 to 100:1.