CA1249239A - Recovery of glycerine from saline waters - Google Patents
Recovery of glycerine from saline watersInfo
- Publication number
- CA1249239A CA1249239A CA000484239A CA484239A CA1249239A CA 1249239 A CA1249239 A CA 1249239A CA 000484239 A CA000484239 A CA 000484239A CA 484239 A CA484239 A CA 484239A CA 1249239 A CA1249239 A CA 1249239A
- Authority
- CA
- Canada
- Prior art keywords
- glycerine
- stream
- water
- liquid phase
- saline
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 title claims abstract description 90
- 235000011187 glycerol Nutrition 0.000 title claims abstract description 45
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 title claims abstract description 32
- 239000011780 sodium chloride Substances 0.000 title claims abstract description 24
- 238000011084 recovery Methods 0.000 title abstract description 7
- 239000003643 water by type Substances 0.000 title abstract description 4
- 238000000034 method Methods 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 150000003839 salts Chemical class 0.000 claims abstract description 22
- 239000007791 liquid phase Substances 0.000 claims abstract description 20
- 239000012141 concentrate Substances 0.000 claims abstract description 17
- 238000001704 evaporation Methods 0.000 claims abstract description 15
- 238000007865 diluting Methods 0.000 claims abstract description 4
- 239000012528 membrane Substances 0.000 claims description 28
- 238000000909 electrodialysis Methods 0.000 claims description 16
- 239000000047 product Substances 0.000 claims description 13
- 150000001450 anions Chemical class 0.000 claims description 10
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 239000003822 epoxy resin Substances 0.000 claims description 7
- 238000004508 fractional distillation Methods 0.000 claims description 7
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 claims description 7
- 229920000647 polyepoxide Polymers 0.000 claims description 7
- 239000003513 alkali Substances 0.000 claims description 4
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 4
- 238000005349 anion exchange Methods 0.000 claims description 4
- 238000005341 cation exchange Methods 0.000 claims description 4
- 238000004064 recycling Methods 0.000 claims description 2
- 229910017053 inorganic salt Inorganic materials 0.000 claims 1
- 239000002244 precipitate Substances 0.000 claims 1
- 238000004821 distillation Methods 0.000 abstract description 2
- 238000005194 fractionation Methods 0.000 abstract 1
- 230000008020 evaporation Effects 0.000 description 10
- 230000000694 effects Effects 0.000 description 7
- 125000000129 anionic group Chemical group 0.000 description 6
- 125000002091 cationic group Chemical group 0.000 description 5
- 239000002699 waste material Substances 0.000 description 5
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 150000001768 cations Chemical group 0.000 description 4
- 239000003792 electrolyte Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000005342 ion exchange Methods 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 241000518994 Conta Species 0.000 description 2
- 238000005119 centrifugation Methods 0.000 description 2
- 238000011033 desalting Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 230000003014 reinforcing effect Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 125000006850 spacer group Chemical group 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229930185605 Bisphenol Natural products 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 229920000298 Cellophane Polymers 0.000 description 1
- 241000905957 Channa melasoma Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 241000208125 Nicotiana Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 239000003011 anion exchange membrane Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 238000006065 biodegradation reaction Methods 0.000 description 1
- 150000003842 bromide salts Chemical class 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- -1 such as Substances 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
- B01D61/44—Ion-selective electrodialysis
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
- C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2311/00—Details relating to membrane separation process operations and control
- B01D2311/26—Further operations combined with membrane separation processes
- B01D2311/2642—Aggregation, sedimentation, flocculation, precipitation or coagulation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2311/00—Details relating to membrane separation process operations and control
- B01D2311/26—Further operations combined with membrane separation processes
- B01D2311/2646—Decantation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2311/00—Details relating to membrane separation process operations and control
- B01D2311/26—Further operations combined with membrane separation processes
- B01D2311/2669—Distillation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2311/00—Details relating to membrane separation process operations and control
- B01D2311/26—Further operations combined with membrane separation processes
- B01D2311/2673—Evaporation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Water Supply & Treatment (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Urology & Nephrology (AREA)
- Health & Medical Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
- Removal Of Specific Substances (AREA)
- Gas Separation By Absorption (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Treatment Of Liquids With Adsorbents In General (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US631,125 | 1984-07-16 | ||
| US06/631,125 US4599178A (en) | 1984-07-16 | 1984-07-16 | Recovery of glycerine from saline waters |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1249239A true CA1249239A (en) | 1989-01-24 |
Family
ID=24529868
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000484239A Expired CA1249239A (en) | 1984-07-16 | 1985-06-17 | Recovery of glycerine from saline waters |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US4599178A (https=) |
| EP (1) | EP0168893B1 (https=) |
| JP (1) | JPS6144833A (https=) |
| AT (1) | ATE50511T1 (https=) |
| CA (1) | CA1249239A (https=) |
| DE (1) | DE3576122D1 (https=) |
| ES (1) | ES8607201A1 (https=) |
| ZA (1) | ZA855308B (https=) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3721474A1 (de) * | 1987-06-30 | 1989-01-12 | Huels Chemische Werke Ag | Verfahren zur herstellung von hexadiin(2,4)-diol-1,6 |
| US6023003A (en) * | 1998-01-13 | 2000-02-08 | Reading & Bates Development Co. | Process and system for recovering glycol from glycol/brine streams |
| DE19838425A1 (de) * | 1998-08-24 | 2000-03-02 | Degussa | Verfahren zur Abtrennung mehrfunktioneller Alkohole von wasserlöslichen Salzen aus wäßrigen Systemen |
| ATE501997T1 (de) * | 2003-11-20 | 2011-04-15 | Solvay | Verfahren zur herstellung von dichlorpropanol |
| US7235183B2 (en) * | 2004-06-22 | 2007-06-26 | Crown Iron Works Company | Glycerine foots salt separation system |
| CA2608722A1 (en) * | 2005-05-20 | 2006-09-28 | Solvay (Societe Anonyme) | Method for making an epoxide starting with a polyhydroxylated aliphatic hydrocarbon and a chlorinating agent |
| KR20080037613A (ko) | 2005-05-20 | 2008-04-30 | 솔베이(소시에떼아노님) | 폴리히드록실화 지방족 탄화수소의 클로로히드린으로의전환 방법 |
| DE102006028501A1 (de) * | 2006-06-21 | 2007-12-27 | Lurgi Ag | Verfahren und Vorrichtung zur Behandlung einer Rückstände enthaltenden glyzerinreichen Phase |
| US20080067069A1 (en) | 2006-06-22 | 2008-03-20 | Siemens Water Technologies Corp. | Low scale potential water treatment |
| US7744760B2 (en) * | 2006-09-20 | 2010-06-29 | Siemens Water Technologies Corp. | Method and apparatus for desalination |
| US20100032617A1 (en) * | 2007-02-20 | 2010-02-11 | Solvay (Societe Anonyme) | Process for manufacturing epichlorohydrin |
| FR2913684B1 (fr) * | 2007-03-14 | 2012-09-14 | Solvay | Procede de fabrication de dichloropropanol |
| TW200911773A (en) * | 2007-06-12 | 2009-03-16 | Solvay | Epichlorohydrin, manufacturing process and use |
| FR2918058A1 (fr) * | 2007-06-28 | 2009-01-02 | Solvay | Produit a base de glycerol, procede pour sa purification et son utilisation dans la fabrication de dichloropropanol |
| JP2011502032A (ja) * | 2007-10-02 | 2011-01-20 | ソルヴェイ（ソシエテ アノニム） | 容器の耐腐食性を向上させるためのケイ素を含有する組成物の使用 |
| AU2008331796B2 (en) * | 2007-11-30 | 2013-01-10 | Evoqua Water Technologies Llc | Systems and methods for water treatment |
| TWI478875B (zh) * | 2008-01-31 | 2015-04-01 | Solvay | 使水性組成物中之有機物質降解之方法 |
| WO2009121853A1 (en) * | 2008-04-03 | 2009-10-08 | Solvay (Société Anonyme) | Composition comprising glycerol, process for obtaining same and use thereof in the manufacture of dichloropropanol |
| FR2935968B1 (fr) * | 2008-09-12 | 2010-09-10 | Solvay | Procede pour la purification de chlorure d'hydrogene |
| WO2010033817A2 (en) * | 2008-09-18 | 2010-03-25 | Redox Tech, Llc | Crude glycerol purification process |
| FR2939434B1 (fr) * | 2008-12-08 | 2012-05-18 | Solvay | Procede de traitement de glycerol. |
| DE102009017098B3 (de) * | 2009-04-15 | 2010-08-12 | Lurgi Gmbh | Verfahren zur kontinuierlichen Herstellung von Reinglycerin aus Kaliumsulfat enthaltendem Rohglycerin |
| JP6049087B2 (ja) | 2010-09-30 | 2016-12-21 | ソルヴェイ（ソシエテ アノニム） | 天然起源のエピクロロヒドリンの誘導体 |
| CN104230046B (zh) * | 2014-08-21 | 2015-09-30 | 波鹰(厦门)科技有限公司 | 一种高盐含甘油高浓度有机废水中氯化钠及甘油的分离装置 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB845653A (en) * | 1958-03-12 | 1960-08-24 | Permutit Co Ltd | Improvements relating to electrodialytic cells |
| DE123476C (https=) * | 1960-09-19 | |||
| CH489259A (de) * | 1968-06-08 | 1970-04-30 | Dietzsch Gmbh Hans Joachim | Verfahren zur Herstellung von kapillaren Austauschern |
| US3715402A (en) * | 1969-08-08 | 1973-02-06 | Basf Wyandotte Corp | Removal of catalysts from polyols |
| US4036749A (en) * | 1975-04-30 | 1977-07-19 | Anderson Donald R | Purification of saline water |
-
1984
- 1984-07-16 US US06/631,125 patent/US4599178A/en not_active Expired - Lifetime
-
1985
- 1985-06-17 CA CA000484239A patent/CA1249239A/en not_active Expired
- 1985-07-09 DE DE8585201150T patent/DE3576122D1/de not_active Expired - Lifetime
- 1985-07-09 AT AT85201150T patent/ATE50511T1/de not_active IP Right Cessation
- 1985-07-09 EP EP19850201150 patent/EP0168893B1/en not_active Expired - Lifetime
- 1985-07-15 JP JP60155864A patent/JPS6144833A/ja active Granted
- 1985-07-15 ES ES545182A patent/ES8607201A1/es not_active Expired
- 1985-07-15 ZA ZA855308A patent/ZA855308B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE3576122D1 (de) | 1990-04-05 |
| EP0168893B1 (en) | 1990-02-28 |
| ATE50511T1 (de) | 1990-03-15 |
| EP0168893A3 (en) | 1987-08-19 |
| US4599178A (en) | 1986-07-08 |
| JPH0542415B2 (https=) | 1993-06-28 |
| ES8607201A1 (es) | 1986-05-16 |
| EP0168893A2 (en) | 1986-01-22 |
| ES545182A0 (es) | 1986-05-16 |
| ZA855308B (en) | 1986-02-26 |
| JPS6144833A (ja) | 1986-03-04 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |