CA1233047A - Amorphous metal alloy powders and bulk objects and synthesis of same by solid state decomposition reactions - Google Patents
Amorphous metal alloy powders and bulk objects and synthesis of same by solid state decomposition reactionsInfo
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- CA1233047A CA1233047A CA000475705A CA475705A CA1233047A CA 1233047 A CA1233047 A CA 1233047A CA 000475705 A CA000475705 A CA 000475705A CA 475705 A CA475705 A CA 475705A CA 1233047 A CA1233047 A CA 1233047A
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- metal alloy
- amorphous metal
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- substantially amorphous
- amorphous
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/04—Making non-ferrous alloys by powder metallurgy
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/006—Amorphous articles
- B22F3/007—Amorphous articles by diffusion starting from non-amorphous articles prepared by powder metallurgy
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/002—Making metallic powder or suspensions thereof amorphous or microcrystalline
- B22F9/004—Making metallic powder or suspensions thereof amorphous or microcrystalline by diffusion, e.g. solid state reaction
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/16—Making metallic powder or suspensions thereof using chemical processes
- B22F9/30—Making metallic powder or suspensions thereof using chemical processes with decomposition of metal compounds, e.g. by pyrolysis
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Abstract
ABSTRACT
Amorphous metal alloy powders are synthesized by solid state decomposition reactions. At least one precursor compound is thermally decomposed at a temperature below the crystallization temperature of the amorphous metal alloy to be formed. The decomposition product comprises an intimate mixture of the elements of the alloy and, after heat-treating if necessary, exhibits amorphous characteristics. Amorphous metal alloy shapes are synthesized by providing an intimate mixture of the components of the amorphous alloy, which mixture includes at least one ductile component. The mixture may be subjected to well-known forming techniques at a temperature below the crystallization temperature of the amorphous metal alloy to be formed. The ductile component of the mixture acts as a binder matrix to provide strength and uniform properties to the formed object.
Amorphous metal alloy powders are synthesized by solid state decomposition reactions. At least one precursor compound is thermally decomposed at a temperature below the crystallization temperature of the amorphous metal alloy to be formed. The decomposition product comprises an intimate mixture of the elements of the alloy and, after heat-treating if necessary, exhibits amorphous characteristics. Amorphous metal alloy shapes are synthesized by providing an intimate mixture of the components of the amorphous alloy, which mixture includes at least one ductile component. The mixture may be subjected to well-known forming techniques at a temperature below the crystallization temperature of the amorphous metal alloy to be formed. The ductile component of the mixture acts as a binder matrix to provide strength and uniform properties to the formed object.
Description
~3~3~
AMORPHOUS METAL ALLOY POWDERS
AND BULK OBJECTS AND SYNTHESIS OF
SAME BY SOLID STATE DECOMPOSITION REACTIONS
FIELD OF THE INVENTION
This invention relates to amorphous metal alloy powders and shapes and the novel preparation of such powders by solid state reactions. More specifically, this invention relates to the synthesis of amorphous metal alloy powders by the thermal decomposition no metal-bearing compounds and the synthesis of amorphous metal alloy shapes by solid state reactions that utilize a ductile matrix precursor.
BACKGROUND OF EYE INVENTION
Amorphous metal alloy materials have become of interest in recent years due to their unique combinations of mechanical, chemical and electrical properties that are especially well-suited for newly-emerging applications. Examples of amorphous metal material properties include the following:
- uniform electronic structure, - compositional variable properties, - high hardness and strength, ; - flexibility, - soft magnetic and ferroelectronie properties, - very high resistance to corrosion and wear, - unusual alloy compositions, and - high resistance to radiation damage.
These characteristics are desirable for applications such as low temperature welding alloys magnetic bubble memories, high field superconducting devices and soft magnetic materials for power transformer cores.
The unique combination of properties of amorphous metal alloy materials may be attributed to the disordered atomic structure of amorphous materials which ensures that the material is chemically homogeneous and free from the extended defects, such as dislocations I
~23~
and grain boundaries, that are known to limit the performance of crystalline materials. The amorphous state is characterized by a lack of long range periodicity, whereas a characteristic of the crystalline state it its long range periodicity.
Generally, the room temperature stability of amorphous materials depends on various kinetic barriers to the growth of crystal nuclei and to nucleation barriers that hinder the formation of stable crystal nuclei. Such barriers typically are present if the material to be made amorphous it first heated to a molten state then rapidly quenched or cooled through the crystal nucleation temperature range at a rate that is sufficiently fast to prevent significant nucleation to occur. Such cooling rates are on the order of lo C~second. Rapid cooling dramatically increases the viscosity of the molten alloy and quickly decreases the length over which atoms can diffuse. This has the effect of preventing crystalline nuclei from forming and yields a metastable, or amorphous phase.
Processes that provide such cooling rates include sputtering vacuum evaporation plasma spraying and direct quenching prom the liquid state. It has been found that alloys produced by one method often cannot be similarity produced by another method even though the pathway to formation is in theory the same.
Direct quenching from the liquid state has found the greatest commercial success since a variety of alloys are known that can be manufactured by this technique in various forms such as thin films, ribbons and wires. United States patent number 3,856,513 to Chin et at. describes novel metal alloy compositions obtained by direct quenching from the melt and includes a general discussion of this process. Chin et at. describes magnetic amorphous metal alloys formed by sub~ectlng the alloy composition to rapid cooling from a temperature above its melting temperature. A stream of the molten metal is directed into the nip of rotating double rolls maintained at room temperature. The quenched metal, obtained in the form of a ribbon, was substantially amorphous as indicated by x-ray diffraction measurements, was ductile, and had a tensile strength of about 350,000 psi.
United States patent number ~,036,63B to Ray ok 31.
describes binary amorphous alloys of iron or cobalt and boron. The claimed amorphous alloys were formed by a vacuum melt-casting process wherein molten alloy was ejected through an orifice and against a rotating cylinder in a partial vacuum of about lo molter. Such amorphous alloys were obtained as continuous ribbons and all exhibited high mechanical hardness and ductility.
The thicknesses of essentially all amorphous foils and ribbons formed by rapid cooling from the melt are limited by the rate of heat transfer through the material. Generally the thicknesses of such f11~s are less than So m. The few materials that can be prepared in this manner include those disclosed by Chin et at. and Ray et at.
Amorphous metal alloy materials prepared by electrode position processes have been reported by Lash more and Weinroth in Plating and Surface Finishing, 72 (August 1982). These materials include Co-P, Nip, Core and Co-W compositions. However, the as-formed alloys are in homogeneous and so can be used in only a limited number of applications.
The above-listed prior art processes for producing amorphous metal alloys depend upon controlling the kinetics of the solidification process; controlling the formation of the alloy from the liquid (molten) state or from the vapor state by rapidly removing heat energy during solidification. Most recently, an amorphous metal alloy composition was synthesized without resort to rapid heat removal. Ye et at. reported that a metastable crystalline compound Zr3Rh, in the form of a thln-film could be transformed into a thln-fllm, amorphous metal alloy by the controlled introduction of hydrogen gas; Applied Physics Letter 42 (3), pp. 242-244, February l, 1983. The amorphous metal alloy had an approximate composition of Zr3RhH~ 5.
Ye et at. specified three requirements as prerequisites for the formation of amorphous alloys by solid state r reactions: at least a three component system; a large disparity in the atomic diffusion rates of two of the atomic species; and an absence of a polymorphic crystalline alternative as a final state. Thus, Ye et at. teach that solid state reactions would have muted applications for the synthesis of amorphous metal alloy materials.
The known amorphous metal alloy and processes for making such alloys which are discussed above suffer from the disadvantage that the so-formed amorphous alloy is produced in a limited form, that is, as a thin film such as a ribbon, wire or platelet. These limited shapes place severe restrictions on the applications for which amorphous metal materials may be used.
To produce bulk amorphous metal alloy objects the formed amorphous alloy must be mechanically reduced to a powder as by chipping, crushing, grinding and ball milling, and then recombined in the desired shape. These are difficult processes when it is realized that most amorphous metal alloys have high mechanical strengths and also possesses high harnesses.
What is lacking in the area of amorphous metal alloy preparation is a simple process for the direct formation of a large variety of amorphous metal alloys. Especially lacking is a process that would synthesize amorphous metal alloy materials directly as powders suitable for forming bulk amorphous metal alloy shapes.
Hence, it is one object of the present invention to provide novel amorphous metal alloy compositions.
It is another object of the present invention to provide a process for the direct preparation of a large variety of homogeneous amorphous metal alloy compositions.
It is a further object of the present invention to provide a process for the direct preparation of a large variety of homogeneous amorphous metal alloy compositions in a powder form.
It it till another object of the present invention to provide a process for the direct preparation of a large variety of homogeneous amorphous metal alloy powders by solid state reaction.
It is yet another object of this invention to provide novel bulk amorphous metal alloy objects.
It is another object of the present invention to provide a process for the synthesis of bulk amorphous metal alloy objects.
These and additional objects of the present invention will become apparent in the description of the invention and examples that follow.
SUMMARY US THE INYE~TION
The present lnvent10n relate to a process for the synthesis of a substantially amorphous metal alloy comprising thornily decomposing at least one precursor m~tal-hear~ng compound at temperature below the crystalline temperature of the amorphous metal alloy to be formed the at least one precursor ~etat-bear7ng compound having a decomposit10n temperature below the crystall~zat10n temperature of the amorphous alloy to be wormed and containing the metals which ccmpr~se the substantially amorphous metal alloy.
Thus invention also relates to a process for the synthesis of a substantially amorphous metal alloy comprising the steps of:
a) decomposing at least one precursor met21-bearing compound at a temperature below the crystal kitten temperature of the amorphous eel alloy to be synthesized so as to form an ~nt1mate mixture of the components of the amorphous metal alloy to be synthesized, the at least one precursor metal-bear1ng compound containing the metals which comprise the substantially amorphous alloy; and b) heat-treating the notate mixture so as to form the amorphous metal alloy.
The present ~nvent10n also relates to process for the product10n of substantially amorphous metal alloy objects comprising:
a) preparing an 1nt~mate mixture of the components of the amorphous metal alloy by solid state ricketiness, at least one component of the ~nt1m~te mixture being a ductile component; and b) forming the intimate mixture into an object at a temperature below the crystall~zat10n temperature of the metal alloy so as to form an amorphous Allah Lowe object.
The present invention further relates to a process for the synthesis of an enhanced substantially amorphous metal alloy comprising thermally decomposing at least one precursor metal-bearing compound in the presence of an initial substantially amorphous metal alloy at a temperature below the crystallization temperatures of the initial sub-staunchly amorphous metal alloy and the enhanced substantially amorphous metal alloy to be formed, the at least one precursor metal-bearing compound " ~3~3~
-Spa-containing addition elements to be incorporated into the initial metal alloy so as to form an enhanced substantially amorphous metal alloy.
The present invention still further relates to a process for the synthesis of an enhanced substantially amorphous metal alloy comprising the steps of:
(a) decomposing at least one precursor, metal-bearing compound in the presence of an initial substantially amorphous metal alloy at a temperature below the crystallization temperature of the enhanced substantially amorphous metal alloy to be sync the sized so as to form an intimate mixture of the components of the enhanced amorphous metal alloy to be synthesized and (b) heat treating the mixture so as to form an enhanced substantially amorphous metal alloy.
The invention yet further relates to a process for the production of substantially amorphous metal alloy objects comprising:
a) preparing an intimate mixture of the components of the amorphous metal alloy by a solid state reaction, at least one component of the intimate mixture being a ductile component; and b) forming the intimate mixture into an object at a temperature below the crystallization temperature of the metal alloy so as Jo form an amorphous metal alloy object.
The present invention also relates to novel, substantially amorphous metal alloy objects synthesized in accordance with the above-summarized process.
Therefore the present invention also relates to a substantially amorphous metal alloy powder synthesized by Jo .
I.
-5b thermally decomposing at least one precursor metal-bearing compound at a temperature below the crystallization temperature of the amorphous metal alloy, the at least one precursor metal-bearing compound containing the metals that comprise the substantially amorphous metal alloy.
Detailed DESCRIPTION OF THE INVENTION
In accordance with this invention, there are provided novel processes for the synthesis of substantially amorphous metal alloys.
I
", 33~7 There are also provided novel, substantially amorphous metal alloy objects and a process for the production of such substantially amorphous metal alloy objects. The term "substantially" us used herein in reference to the amorphous metal alloy means that the metal alloys are at least fifty percent amorphous. Preferably the metal alloy us at least eighty percent amorphous and most preferably about one hundred percent amorphous, as indicated by x-ray diffraction analysis. The use of the phrase amorphous metal alloys" herein refers to amorphous metal-contain1ng alloys that may also comprise non-metallic elements. Amorphous metal alloys my include non-metallic elements such as boron, carbon, nitrogen, silicon, phosphorus, arsenic, germanium and antimony.
The solid state processes disclosed herein include the step of thermally decomposing at least one metal-bearing compound at a temperature below the crystallization temperature of the amorphous metal alloy to be formed. The at least one precursor metal-bear~ng compound is preferably chosen so that its decomposition temperature is at least 25C below the crystallization temperature of the amorphous metal alloy to be formed and most preferably is at least 100C below the crystallization temperature of the amorphous metal alloy to be formed.
Typical precursor metal-bearing compounds have decomposition temperatures between about 20C and about 500C. A substantial number of precursor metal-bearing compounds suitable for use in the processes of this invention have decomposition temperatures between about 150C and about 400C.
The thermal decomposition of the at least one precursor metal-bearing compound yields an intimate mixture of the components of the desired metal alloy. This decomposition step is preferably performed in a reactor having collection means so that about a one hundred percent yield of material will be realized. This may be achieved by maintaining a cooled reactor portion downstream of the thermal decomposition portion of the reactor wherein the thermally decomposed products will be deposited. Alternatively and most preferably, the decomposition step may be performed in a sealed reactor to prevent evaporation of the metal alloy components. Upon ;~33~
cooling, about a one hundred percent yield of the reaction products may be recovered therefronl.
The decomposition of the precursor compounds may occur under an atmosphere suitable for the synthesis of the desired amorphous metal alloy. the precursor compounds may be disposed in a sealed reaction vessel thaw has been partially or fully evacuated prior to heating. If the amorphous metal alloy to be synthesized does not contain oxygen, then it is preferred that the thermal decomposition of the precursor compounds be done under an inert or reducing atmosphere or in a sealed reaction vessel that has been partially or fully evacuated. If some tolerance to oxygen is possible then an inert or reducing atmosphere or vacuum may not be necessary.
A precursor compound may also exist at room temperature in the gaseous state and may itself provide the initial atmosphere under which the thermal decomposition will be performed. In this manner, a reactive atmosphere exists for the thermal decomposition reaction.
Precursor compounds may also be used that are solid at about 20C, but which vaporize at slightly elevated temperatures. These compounds may be disposed in an evacuated reactor and upon heating, provide a reactive atmosphere for the decomposition reaction.
The precursor metal-bearing compounds suitable for use in this invention may include organometallic compounds such as monomers, d7mers, trimmers and polymers having metallo-organic ligands composed of saturated and/or unsaturated hydrocarbons, aromatic or heteroaromat k Lindsey, and may also include oxygen, boron, carbon, nitrogen, phosphorus, arsenic, germanium, antimony and/or silicon-containing ligands, and combina~lons thereof. Precursor metalk~bearing compounds may also be halogen compounds, oxides, nitrates, nitrides, carbides, brides or metal-bearing salts, with the restriction that the decomposition temperature of the precursor compound be less than the crystallization temperature of the amorphous metal alloy to be synthesized.
As disclosed earlier, precursor compounds may also be provided that do not contain a metal but which contribute a non-metallic element to the amorphous alloy composition.
~33~7 The thermal decomposition of precursor compounds yields a product consisting essentially of the components of the desired amorphous metal alloy. The components are intimately mixed, the maximum size of the particles in the mixture preferably being from about 10 Angstroms to about 1000 Angstroms, and most preferably from about 10 Angstroms to about 500 Angstroms. These decomposition products may be represented by the following empirical formulae:
Maul a wherein M is at least one metal selected from the metals in Groups VI-B, VII-B, VIII, I-B, JIB and III~ of the Periodic Table; and : X is at least one element selected from groups III-A, IV-A and V-A of the Periodic Table; and wherein a ranges from about 0.1 to about 0.9;
and b l-b : wherein N it at least one metal selected from the metals in Groups III-B, IV-B, Y-B and VI-B of the Periodic Table;
and Y is selected from Groups VIII, I-B and II-B of the Periodic Table; and wherein b ranges from about 0.2 to about 0.8 The thermal decomposition of the precursor compounds may occur at high enough temperatures and for a period of time long enough to permit alloying of the metal elements concurrent with the decomposition. Under such circumstances the product which results from the decomposition step is a substantially amorphous metal alloy.
This product is synthesized as a solid, powder material having a maximum particle size of from abut 10 Angstroms to about 3L~3~
1000 Angstroms. This powder is suitable for compaction, with or without a binder, into a solid shape.
If the decomposition temperature is not sufficiently high, or the period of decomposition is too brief, to enable alloying of the reactant products during the decomposition of the precursor compounds, then the powder that is obtained is an intimate mixture comprising the alloy components. A subsequent heat-treating step at a temperature below the crystallization temperature of the amorphous metal alloy will allow diffusion of at least one metal component so as to form an amorphous metal alloy. This heat-treating step is carried out under an atmosphere conducive to the formation of the amorphous metal alloy. This may occur under vacuum conditions, from about O torn. to about 500 torn., or in an inert, reducing or reactive atmosphere.
Prior to the heat-treating step, the powder obtained from the decomposition of the precursor compounds may be pressed into a shape so that, upon heat-treating, a bulk amorphous metal alloy shape is obtained. It is also possible to compact the heat-treated amorphous petal alloy powder into a solid shape.
It has also surprisingly been found that the amorphous metal alloy products of thermal decomposition and decomposition/heat-treating processes may be mixed with another precursor metal-bearing compound Jo yield a new, enhanced amorphous metal alloy material which has incorporated into the prior amorphous metal alloy elements from the newly-added precursor. This may be accomplished by disposing the prior amorphous metal alloy on a reactor with the newly-added precursor metal-bearlng compound and heat-treating this mixture at a temperature that will decompose the precursor compound but that is below the crystallization temperatures of the prior amorphous metal alloy and the enhanced amorphous metal alloy that is to be synthesized. The newly-added precursor may be a solid, liquid or gaseous material upon insertion into the reaction vessel. As with the above-discussion, the decomposition of the precursor material may occur in a partial or full vacuum, or under an inert, reducing, or reactive atmosphere.
The solid state reaction that occurs to ally an intimate mixture of elements may be viewed by examining the free energy of the system. The intimate mixture of elements corresponds to a relatively high free energy of the system. At about room temperature such mixtures are generally canticle restricted to this state. Adding energy to this system, as at the thermal decomposition temperature or during subsequent heat-treatments, allows the components to begin to inter-diffuse. The free energy of the system is lowered by an increase in the entropy of mixing a decrease in the enthalpy due to the formation of heteropolar bonds. The absolute minimuln in free energy in these systems will occur far the equilibrium crystalline alloys. For many alloy combinations, however, a local minimum in the free energy can exist in an amorphous phase. For alloy combinations such as these, the requirements for the formation of an amorphous phase by a solid state reaction are that the intimate mixture of components have a free energy higher than that of the amorphous phase and that the diffusion process to form the alloy be performed at temperatures sufficiently below the characteristic temperatures for the formation of crystalline nuclei.
Amorphous metal alloys are generally characterized as having high strengths and harnesses and so are quite resistant to deformation. Typical amorphous shapes, such as ribbons and wires, are formed simultaneously with the formation of the amorphous state.
These shapes exhibit the characteristics of an amorphous material.
However, attempts to form bulk amorphous shapes, that is, shapes having significant thicknesses in all dimensions, have not been satisfactory. These attempts generally include reducing an amorphous metal alloy, such as a ribbon, to an amorphous powder by physical means and then compacting the powder into a shape. Generally, the compacted shape does not retain all the desirable traits of the individual particles.
Whereas the process disclosed herein above teaches the synthesis of amorphous metal alloy powders, it now becomes known, in accordance with the invention claimed herein, that the intimate mixture obtained as an intermediate in the formation of Applicants' amorphous metal alloy powders may be effectively formed unto bulk ~3~3~'7 objects when at least one component of the intimate mixture is Dakota. By ductile is meant a component that it mailable, pliant and easily molded without cracking or fracturing. A typical Dakota component will demonstrate deformation of at least ten percent under a moderate load of between about Lowe psi and 5,000 psi. the ductile component of the intimate mixture provides an infrastructure that, when subjected to forming processes, deforms and binds the other components of the alloy within a matrix.
The ductile component of the alloy originates in a precursor compound that is used in the solid state reactions to form the intimate mixture of the alloy components. Examples of ductile components include pure metal elements, such as iron, nickel, copper, cobalt and tantalum, and metal solid solutions. Preferably the ductile component is a pure metal element.
To provide enhanced bonding strength and properties to the formed amorphous metal alloy object, it is preferred that the ductile component comprise from about lo atomic percent to about 95 atomic percent of the amorphous metal alloy based on the total composition of the amorphous metal alloy.
The intimate mixture of the components of the amorphous metal alloy, which has not yet been heat-treated to induce the amorphous state is subjected to a forming process. Forming processes include well-known powder forming techniques such as cold-pressing, hot-pressing, pressure less sistering, slipcast1ng, injection molding and extrusion In accordance with this invent10n, the only restriction on the forming process is that the process be performed at a temperature below the crystallization temperature of the metal alloy.
If the forming process includes the use of temperature above ambient temperature, then the intimate mixture may be formed and made amorphous simultaneously. If the forming process does not include elevated temperatures, then a further step, heat-treating, will be required to induce the amorphous state Many intimate mixtures may be reactive with oxygen, and so, may require forming and heat-treating processing which occurs in an oxygen-free atmosphere such as an inert, reducing or reactive ~3;~7 atmosphere or under vacuum conditions. A reactive atmosphere may be provided that reacts with the bulk object so as to enhance the formation of the amorphous alloy.
Amorphous metal alloy shapes generally have a density of from about 10 percent to about 99 percent of theoretical. The density may be controlled by the forming process so as meet a variety of needs. Thus, the same amorphous metal alloy composition may be formed into an amorphous metal alloy shape having a density between about lo percent and about 90 percent of theoretical. It has also been observed that the process of this invention permits the attainment of a desired-density object at temperatures lower than those necessary to achieve the same sistered state when the metal alloy powder used to form the object is derived from the physical reduction of a prior art, thin-film amorphous shape such as a ribbon.
The forming process may be used to provide an amorphous metal alloy in a finished shape or in a solid shape amenable to further machining. Thus, billies, rods, flat plates may be formed as well as cylindrical shapes, toxoids and other intricate, finished shapes.
The above-described processes for synthesizing amorphous metal alloys are not hindered by the processing limitations of prior art processes. The methods disclosed herein do not depend on extremely high cooling rates or heat transfer properties, nor i; very high temperature or very low vacuum equipment necessary. Further, the processes of this invention provide or the synthesis of substantially amorphous metal alloy powders, which amorphous alloy powders may be pressed into desired shapes to form solid amorphous alloy shapes. Alternatively, the methods disclosed herein provide an intonate mixture of elements that may be formed into a desired shape and, upon subsequent heat-treating, may be converted into a substantially amorphous metal alloy shape. The method disclosed herein does not depend on reducing an amorphous material to a powder state and then recombining an amorphous powder but utilizes an intimate mixture of the components of a metal alloy into a bulk shape and thereafter, or concurrently, inducing the amorphous state by heat treating at a temperature below the crystallization temperature of the metal alloy. These bulk amorphous metal alloy shapes may find new and useful applications, since such shapes have not teen conveniently fabricated by any other techniques.
EXAMPLE
The following examples more thoroughly illustrate the present invention and are not intended in any way to be limitative thereof. Each of the following examples describes the co-decomposition of organometallic compounds to yield amorphous metal alloy powders.
Example 1 This example demonstrates the formation of an amorphous iron-molybdenum composition.
Equimolar amounts of about 2 Molly each of cyclopentadienyliron dicarbonyl diver [C5H5Fe(C0~]2and cyclopentadienylmolybdenum tricarbonyl diver [C5H5Mo~C03)]2 were disposed in a stainless steel bomb reactor. The reactor was purged with argon and sealed under an argon atmosphere. the bomb reactor was then heated to a temperature of about 300C for about 24 hours. The decomposition temperature of cyclopentadienyliron dicarbonyl diver is about 195C, and the decomposition temperature of cyclopentadienylmolybdenum tricarbonyl diver is about 180C.
After cooling to about 20C, the reactor was opened and a black-colored solid, in powder form, was removed therefrom. The powder was washed with tetrahydrofuran to remove any organic-soluble materials, then dried at a temperature of about 60C under vacuum.
The powder was next divided into four fractions, a first fraction was set aside for later analysis, and the other three fractions were Further treated in the following manner; one fraction was heat-treated at about 270C under vacuum for about 168 hours, another fraction was heat-treated at about 325C under vacuum for about 168 hours, and still another fraction was heat-treated at about 800C under vacuum for about 10 minutes.
X-ray diffraction data indicated that the powder removed from the bomb reactor after co-decomposition of the precursor materials comprised an amorphous iron-molybdenum alloy having an approximate composition of Fume. The fractions of the powder that were heat-treated at about 270C and about 325C were also found to comprise an amorphous lron-molybdenum alloy of approximate composition Foe, as indicated by x-ray diffraction, but the fraction of the powder that was heat-treated at about 800C was crystalline.
Differential scanning calorimetry was implemented to determine that the amorphous alloy powder fractions had glass transition temperatures of about 325~C and crystallization temperatures of about 420C. Mossbauer Effect Spectra of the amorphous powder fractions indicated that these amorphous iron-molybdenum alloy powders have internal magnetic fields and magnetic moments similar to other iron-containing amorphous alloys.
Amorphous iron-molybdenum alloy compositions have not been reported as formed by any other method except sputtering, which method cannot synthesize the amorphous alloy in powder form.
Example 2 This example demonstrates the formation of an amorphous iron-molybdenum composition using alternative precursor organometallic compounds.
Equimolar amounts of iron pentacarbonyl (Fake and molybdenum carbonyl (Mohawk) could be sealed under an inert atmosphere such as an argon atmosphere or under a vacuum in a bomb reactor and heated to about 270~C for about 120 hours to thermally decompose about all of the precursor compounds and to alloy the reactant product elements. the decomposition temperature of iron pentacarbonyl is about 150C, and the decomposition temperature of molybdenum carbonyl is about 150C.
The resultant solid, powder material that is obtained by this decomposition can be confirmed by x-ray diffraction to be amorphous iron-molybdenum alloy. The approximate composition will be amorphous Fume.
,, I k7 This example demonstrates the formation of an amorphous iron-molybdenum nitrogen composition.
Equimolar amounts of iron pentacarbonyl fake) and mo91ybdenum carbonyl (Mohawk) may be disposed in a reactor and sealed under an atmosphere of ammonia. The reactor could then be heated to a temperature above the decomposition temperatures of iron pentacarbonyl and molybdenum carbonyl, which it above about 270~C for a period of time that would insure decomposition of the reactant materials and alloying of the component elements.
The product that would be obtained as a solid powder material will be an amorphous iron-molybdenum-nitrogen alloy of approximate composition Famine the nitrogen having been derived from the ammonia atmosphere under which the solid products were sealed prior to heating.
Example 4 This example describes the formation of an amorphous iron-chromium-molybdenum composition.
Top following three organometallic precursor materials could be disposed in a bomb reactor in about the following molar ratios:
1.0 mow equivalent iron dodecarbonyl (Fake), 0.5 mow equivalent chromium carbonyl (Crook), and 3 mow equivalents molybdenum carbonyl (Mohawk). the decomposition temperature of Ron dodecarbonyl is about 140C. The decomposition temperature of chromium carbonyl is about 200C. The decomposition temperature of molybdenum carbonyl is about 150C.
The reactor may then be sealed under an inert atmosphere and heated to a temperature above about 270C for a period of lime suPPicient to decompose the precursor compounds and to alloy the elements of the amorphous composition.
The solid, powder material that is obtained from this thermal decomposition will be an amorphous iron-chromium-molybdenum material of approximate composition Faker Moe.
Example 5 1~33~47 Example q above could also have been performed under an atmosphere other than an inert atmosphere so as to modify the product amorphous metal alloy.
The inert atmosphere of Example 4 may be replaced with a phosphorus atmosphere obtained by disposing solid elemental phosphorus, such as red phosphorus in the reactor with the other precursor compounds and sealing the reactor under a vacuum. At elevated temperatures, the phosphorus would vaporize producing a phosphorus atmosphere during the decomposition of the other precursor compounds. The resultant amorphous metal alloy from the thermal decomposition reaction may have an approximate composition of 3 0.5 3-Example 6 This example demonstrate the formation of an amorphous tungsten-nickel-carbon capstone.
Precursor materials, mes~tylene tungsten tricarbonyl (CgH12W(CO)3) and bis(triphenylphosphine) nickel dicarbonyl [)(C6H5)3P]2Ni(CO)2, may be disposed in a bomb reactor in a molar ratio of about 1:2. The decomposition temperature of mesitylene tungsten tricarbonyl is about 165C, and the decomposition temperature of bis(triphenylphosphine) nickel dicarbonyl is about 215C. The reactor may be sealed under an inert atmosphere such as an argon atmosphere and then heated to a temperature above about 215C for a time long enough to insure that the precursor compounds have substantially decomposed and alloyed.
A solid, powder material would result that is an amorphous tungsten-nickel-carbon-phoszphorus maternal having an approximate composition of Wink UP.
~Ej~m~le 7 The formation of an amorphous cobalt rhenium composition is described in this example.
The following two organometallic precursor materials may be disposed in a bomb reactor in about the following molar ratios: 1 mol. rhenium carbonyl (Wreck) and 2 mows cobalt carbonyl (C02(CO)8). The reactor may then be sealed under an inert atmosphere, such as an argon atmosphere and heated to bout at least 170C for a time sufficient to thermally decompose the precursor compounds. the decomposition temperature of rhenium carbonyl is about 170C. The decomposition temperature so cobalt carbonyl is about 55C. The resultant solid, powder material that is obtained by this decomposition will be an amorphous alloy of cobalt rhenium. The approximate composition will be amorphous Core.
Example 8 The formation of an amorphous tungsten-cobalt-iron composition is described in this example.
The following organometallic precursor materials may be disposed in a bomb reactor in about the following molar ratios: 1 mow equivalent tungsten carbonyl (WACO), 1 mow equivalent cobalt carbonyl (Cook), and 2 mows equivalents iron nonacrbonyl (Fake). Tungsten carbonyl has a decomposition temperature of about 170C. Cobalt carbonyl has a decompos~tlon temperature of about 55C. Iron nonacrbonyl has a decomposition temperature of about 100C.
The reactor may be sealed under an inert atmosphere and heated to a temperature above about 270~C so as to substantially thermally decompose the precursor compounds and to alloy the product elements.
The powder removed from the bomb reactor after the co-decomposit~on of the precursor materials will comprise an amorphous tungsten-cobalt-iron composition of approximately
AMORPHOUS METAL ALLOY POWDERS
AND BULK OBJECTS AND SYNTHESIS OF
SAME BY SOLID STATE DECOMPOSITION REACTIONS
FIELD OF THE INVENTION
This invention relates to amorphous metal alloy powders and shapes and the novel preparation of such powders by solid state reactions. More specifically, this invention relates to the synthesis of amorphous metal alloy powders by the thermal decomposition no metal-bearing compounds and the synthesis of amorphous metal alloy shapes by solid state reactions that utilize a ductile matrix precursor.
BACKGROUND OF EYE INVENTION
Amorphous metal alloy materials have become of interest in recent years due to their unique combinations of mechanical, chemical and electrical properties that are especially well-suited for newly-emerging applications. Examples of amorphous metal material properties include the following:
- uniform electronic structure, - compositional variable properties, - high hardness and strength, ; - flexibility, - soft magnetic and ferroelectronie properties, - very high resistance to corrosion and wear, - unusual alloy compositions, and - high resistance to radiation damage.
These characteristics are desirable for applications such as low temperature welding alloys magnetic bubble memories, high field superconducting devices and soft magnetic materials for power transformer cores.
The unique combination of properties of amorphous metal alloy materials may be attributed to the disordered atomic structure of amorphous materials which ensures that the material is chemically homogeneous and free from the extended defects, such as dislocations I
~23~
and grain boundaries, that are known to limit the performance of crystalline materials. The amorphous state is characterized by a lack of long range periodicity, whereas a characteristic of the crystalline state it its long range periodicity.
Generally, the room temperature stability of amorphous materials depends on various kinetic barriers to the growth of crystal nuclei and to nucleation barriers that hinder the formation of stable crystal nuclei. Such barriers typically are present if the material to be made amorphous it first heated to a molten state then rapidly quenched or cooled through the crystal nucleation temperature range at a rate that is sufficiently fast to prevent significant nucleation to occur. Such cooling rates are on the order of lo C~second. Rapid cooling dramatically increases the viscosity of the molten alloy and quickly decreases the length over which atoms can diffuse. This has the effect of preventing crystalline nuclei from forming and yields a metastable, or amorphous phase.
Processes that provide such cooling rates include sputtering vacuum evaporation plasma spraying and direct quenching prom the liquid state. It has been found that alloys produced by one method often cannot be similarity produced by another method even though the pathway to formation is in theory the same.
Direct quenching from the liquid state has found the greatest commercial success since a variety of alloys are known that can be manufactured by this technique in various forms such as thin films, ribbons and wires. United States patent number 3,856,513 to Chin et at. describes novel metal alloy compositions obtained by direct quenching from the melt and includes a general discussion of this process. Chin et at. describes magnetic amorphous metal alloys formed by sub~ectlng the alloy composition to rapid cooling from a temperature above its melting temperature. A stream of the molten metal is directed into the nip of rotating double rolls maintained at room temperature. The quenched metal, obtained in the form of a ribbon, was substantially amorphous as indicated by x-ray diffraction measurements, was ductile, and had a tensile strength of about 350,000 psi.
United States patent number ~,036,63B to Ray ok 31.
describes binary amorphous alloys of iron or cobalt and boron. The claimed amorphous alloys were formed by a vacuum melt-casting process wherein molten alloy was ejected through an orifice and against a rotating cylinder in a partial vacuum of about lo molter. Such amorphous alloys were obtained as continuous ribbons and all exhibited high mechanical hardness and ductility.
The thicknesses of essentially all amorphous foils and ribbons formed by rapid cooling from the melt are limited by the rate of heat transfer through the material. Generally the thicknesses of such f11~s are less than So m. The few materials that can be prepared in this manner include those disclosed by Chin et at. and Ray et at.
Amorphous metal alloy materials prepared by electrode position processes have been reported by Lash more and Weinroth in Plating and Surface Finishing, 72 (August 1982). These materials include Co-P, Nip, Core and Co-W compositions. However, the as-formed alloys are in homogeneous and so can be used in only a limited number of applications.
The above-listed prior art processes for producing amorphous metal alloys depend upon controlling the kinetics of the solidification process; controlling the formation of the alloy from the liquid (molten) state or from the vapor state by rapidly removing heat energy during solidification. Most recently, an amorphous metal alloy composition was synthesized without resort to rapid heat removal. Ye et at. reported that a metastable crystalline compound Zr3Rh, in the form of a thln-film could be transformed into a thln-fllm, amorphous metal alloy by the controlled introduction of hydrogen gas; Applied Physics Letter 42 (3), pp. 242-244, February l, 1983. The amorphous metal alloy had an approximate composition of Zr3RhH~ 5.
Ye et at. specified three requirements as prerequisites for the formation of amorphous alloys by solid state r reactions: at least a three component system; a large disparity in the atomic diffusion rates of two of the atomic species; and an absence of a polymorphic crystalline alternative as a final state. Thus, Ye et at. teach that solid state reactions would have muted applications for the synthesis of amorphous metal alloy materials.
The known amorphous metal alloy and processes for making such alloys which are discussed above suffer from the disadvantage that the so-formed amorphous alloy is produced in a limited form, that is, as a thin film such as a ribbon, wire or platelet. These limited shapes place severe restrictions on the applications for which amorphous metal materials may be used.
To produce bulk amorphous metal alloy objects the formed amorphous alloy must be mechanically reduced to a powder as by chipping, crushing, grinding and ball milling, and then recombined in the desired shape. These are difficult processes when it is realized that most amorphous metal alloys have high mechanical strengths and also possesses high harnesses.
What is lacking in the area of amorphous metal alloy preparation is a simple process for the direct formation of a large variety of amorphous metal alloys. Especially lacking is a process that would synthesize amorphous metal alloy materials directly as powders suitable for forming bulk amorphous metal alloy shapes.
Hence, it is one object of the present invention to provide novel amorphous metal alloy compositions.
It is another object of the present invention to provide a process for the direct preparation of a large variety of homogeneous amorphous metal alloy compositions.
It is a further object of the present invention to provide a process for the direct preparation of a large variety of homogeneous amorphous metal alloy compositions in a powder form.
It it till another object of the present invention to provide a process for the direct preparation of a large variety of homogeneous amorphous metal alloy powders by solid state reaction.
It is yet another object of this invention to provide novel bulk amorphous metal alloy objects.
It is another object of the present invention to provide a process for the synthesis of bulk amorphous metal alloy objects.
These and additional objects of the present invention will become apparent in the description of the invention and examples that follow.
SUMMARY US THE INYE~TION
The present lnvent10n relate to a process for the synthesis of a substantially amorphous metal alloy comprising thornily decomposing at least one precursor m~tal-hear~ng compound at temperature below the crystalline temperature of the amorphous metal alloy to be formed the at least one precursor ~etat-bear7ng compound having a decomposit10n temperature below the crystall~zat10n temperature of the amorphous alloy to be wormed and containing the metals which ccmpr~se the substantially amorphous metal alloy.
Thus invention also relates to a process for the synthesis of a substantially amorphous metal alloy comprising the steps of:
a) decomposing at least one precursor met21-bearing compound at a temperature below the crystal kitten temperature of the amorphous eel alloy to be synthesized so as to form an ~nt1mate mixture of the components of the amorphous metal alloy to be synthesized, the at least one precursor metal-bear1ng compound containing the metals which comprise the substantially amorphous alloy; and b) heat-treating the notate mixture so as to form the amorphous metal alloy.
The present ~nvent10n also relates to process for the product10n of substantially amorphous metal alloy objects comprising:
a) preparing an 1nt~mate mixture of the components of the amorphous metal alloy by solid state ricketiness, at least one component of the ~nt1m~te mixture being a ductile component; and b) forming the intimate mixture into an object at a temperature below the crystall~zat10n temperature of the metal alloy so as to form an amorphous Allah Lowe object.
The present invention further relates to a process for the synthesis of an enhanced substantially amorphous metal alloy comprising thermally decomposing at least one precursor metal-bearing compound in the presence of an initial substantially amorphous metal alloy at a temperature below the crystallization temperatures of the initial sub-staunchly amorphous metal alloy and the enhanced substantially amorphous metal alloy to be formed, the at least one precursor metal-bearing compound " ~3~3~
-Spa-containing addition elements to be incorporated into the initial metal alloy so as to form an enhanced substantially amorphous metal alloy.
The present invention still further relates to a process for the synthesis of an enhanced substantially amorphous metal alloy comprising the steps of:
(a) decomposing at least one precursor, metal-bearing compound in the presence of an initial substantially amorphous metal alloy at a temperature below the crystallization temperature of the enhanced substantially amorphous metal alloy to be sync the sized so as to form an intimate mixture of the components of the enhanced amorphous metal alloy to be synthesized and (b) heat treating the mixture so as to form an enhanced substantially amorphous metal alloy.
The invention yet further relates to a process for the production of substantially amorphous metal alloy objects comprising:
a) preparing an intimate mixture of the components of the amorphous metal alloy by a solid state reaction, at least one component of the intimate mixture being a ductile component; and b) forming the intimate mixture into an object at a temperature below the crystallization temperature of the metal alloy so as Jo form an amorphous metal alloy object.
The present invention also relates to novel, substantially amorphous metal alloy objects synthesized in accordance with the above-summarized process.
Therefore the present invention also relates to a substantially amorphous metal alloy powder synthesized by Jo .
I.
-5b thermally decomposing at least one precursor metal-bearing compound at a temperature below the crystallization temperature of the amorphous metal alloy, the at least one precursor metal-bearing compound containing the metals that comprise the substantially amorphous metal alloy.
Detailed DESCRIPTION OF THE INVENTION
In accordance with this invention, there are provided novel processes for the synthesis of substantially amorphous metal alloys.
I
", 33~7 There are also provided novel, substantially amorphous metal alloy objects and a process for the production of such substantially amorphous metal alloy objects. The term "substantially" us used herein in reference to the amorphous metal alloy means that the metal alloys are at least fifty percent amorphous. Preferably the metal alloy us at least eighty percent amorphous and most preferably about one hundred percent amorphous, as indicated by x-ray diffraction analysis. The use of the phrase amorphous metal alloys" herein refers to amorphous metal-contain1ng alloys that may also comprise non-metallic elements. Amorphous metal alloys my include non-metallic elements such as boron, carbon, nitrogen, silicon, phosphorus, arsenic, germanium and antimony.
The solid state processes disclosed herein include the step of thermally decomposing at least one metal-bearing compound at a temperature below the crystallization temperature of the amorphous metal alloy to be formed. The at least one precursor metal-bear~ng compound is preferably chosen so that its decomposition temperature is at least 25C below the crystallization temperature of the amorphous metal alloy to be formed and most preferably is at least 100C below the crystallization temperature of the amorphous metal alloy to be formed.
Typical precursor metal-bearing compounds have decomposition temperatures between about 20C and about 500C. A substantial number of precursor metal-bearing compounds suitable for use in the processes of this invention have decomposition temperatures between about 150C and about 400C.
The thermal decomposition of the at least one precursor metal-bearing compound yields an intimate mixture of the components of the desired metal alloy. This decomposition step is preferably performed in a reactor having collection means so that about a one hundred percent yield of material will be realized. This may be achieved by maintaining a cooled reactor portion downstream of the thermal decomposition portion of the reactor wherein the thermally decomposed products will be deposited. Alternatively and most preferably, the decomposition step may be performed in a sealed reactor to prevent evaporation of the metal alloy components. Upon ;~33~
cooling, about a one hundred percent yield of the reaction products may be recovered therefronl.
The decomposition of the precursor compounds may occur under an atmosphere suitable for the synthesis of the desired amorphous metal alloy. the precursor compounds may be disposed in a sealed reaction vessel thaw has been partially or fully evacuated prior to heating. If the amorphous metal alloy to be synthesized does not contain oxygen, then it is preferred that the thermal decomposition of the precursor compounds be done under an inert or reducing atmosphere or in a sealed reaction vessel that has been partially or fully evacuated. If some tolerance to oxygen is possible then an inert or reducing atmosphere or vacuum may not be necessary.
A precursor compound may also exist at room temperature in the gaseous state and may itself provide the initial atmosphere under which the thermal decomposition will be performed. In this manner, a reactive atmosphere exists for the thermal decomposition reaction.
Precursor compounds may also be used that are solid at about 20C, but which vaporize at slightly elevated temperatures. These compounds may be disposed in an evacuated reactor and upon heating, provide a reactive atmosphere for the decomposition reaction.
The precursor metal-bearing compounds suitable for use in this invention may include organometallic compounds such as monomers, d7mers, trimmers and polymers having metallo-organic ligands composed of saturated and/or unsaturated hydrocarbons, aromatic or heteroaromat k Lindsey, and may also include oxygen, boron, carbon, nitrogen, phosphorus, arsenic, germanium, antimony and/or silicon-containing ligands, and combina~lons thereof. Precursor metalk~bearing compounds may also be halogen compounds, oxides, nitrates, nitrides, carbides, brides or metal-bearing salts, with the restriction that the decomposition temperature of the precursor compound be less than the crystallization temperature of the amorphous metal alloy to be synthesized.
As disclosed earlier, precursor compounds may also be provided that do not contain a metal but which contribute a non-metallic element to the amorphous alloy composition.
~33~7 The thermal decomposition of precursor compounds yields a product consisting essentially of the components of the desired amorphous metal alloy. The components are intimately mixed, the maximum size of the particles in the mixture preferably being from about 10 Angstroms to about 1000 Angstroms, and most preferably from about 10 Angstroms to about 500 Angstroms. These decomposition products may be represented by the following empirical formulae:
Maul a wherein M is at least one metal selected from the metals in Groups VI-B, VII-B, VIII, I-B, JIB and III~ of the Periodic Table; and : X is at least one element selected from groups III-A, IV-A and V-A of the Periodic Table; and wherein a ranges from about 0.1 to about 0.9;
and b l-b : wherein N it at least one metal selected from the metals in Groups III-B, IV-B, Y-B and VI-B of the Periodic Table;
and Y is selected from Groups VIII, I-B and II-B of the Periodic Table; and wherein b ranges from about 0.2 to about 0.8 The thermal decomposition of the precursor compounds may occur at high enough temperatures and for a period of time long enough to permit alloying of the metal elements concurrent with the decomposition. Under such circumstances the product which results from the decomposition step is a substantially amorphous metal alloy.
This product is synthesized as a solid, powder material having a maximum particle size of from abut 10 Angstroms to about 3L~3~
1000 Angstroms. This powder is suitable for compaction, with or without a binder, into a solid shape.
If the decomposition temperature is not sufficiently high, or the period of decomposition is too brief, to enable alloying of the reactant products during the decomposition of the precursor compounds, then the powder that is obtained is an intimate mixture comprising the alloy components. A subsequent heat-treating step at a temperature below the crystallization temperature of the amorphous metal alloy will allow diffusion of at least one metal component so as to form an amorphous metal alloy. This heat-treating step is carried out under an atmosphere conducive to the formation of the amorphous metal alloy. This may occur under vacuum conditions, from about O torn. to about 500 torn., or in an inert, reducing or reactive atmosphere.
Prior to the heat-treating step, the powder obtained from the decomposition of the precursor compounds may be pressed into a shape so that, upon heat-treating, a bulk amorphous metal alloy shape is obtained. It is also possible to compact the heat-treated amorphous petal alloy powder into a solid shape.
It has also surprisingly been found that the amorphous metal alloy products of thermal decomposition and decomposition/heat-treating processes may be mixed with another precursor metal-bearing compound Jo yield a new, enhanced amorphous metal alloy material which has incorporated into the prior amorphous metal alloy elements from the newly-added precursor. This may be accomplished by disposing the prior amorphous metal alloy on a reactor with the newly-added precursor metal-bearlng compound and heat-treating this mixture at a temperature that will decompose the precursor compound but that is below the crystallization temperatures of the prior amorphous metal alloy and the enhanced amorphous metal alloy that is to be synthesized. The newly-added precursor may be a solid, liquid or gaseous material upon insertion into the reaction vessel. As with the above-discussion, the decomposition of the precursor material may occur in a partial or full vacuum, or under an inert, reducing, or reactive atmosphere.
The solid state reaction that occurs to ally an intimate mixture of elements may be viewed by examining the free energy of the system. The intimate mixture of elements corresponds to a relatively high free energy of the system. At about room temperature such mixtures are generally canticle restricted to this state. Adding energy to this system, as at the thermal decomposition temperature or during subsequent heat-treatments, allows the components to begin to inter-diffuse. The free energy of the system is lowered by an increase in the entropy of mixing a decrease in the enthalpy due to the formation of heteropolar bonds. The absolute minimuln in free energy in these systems will occur far the equilibrium crystalline alloys. For many alloy combinations, however, a local minimum in the free energy can exist in an amorphous phase. For alloy combinations such as these, the requirements for the formation of an amorphous phase by a solid state reaction are that the intimate mixture of components have a free energy higher than that of the amorphous phase and that the diffusion process to form the alloy be performed at temperatures sufficiently below the characteristic temperatures for the formation of crystalline nuclei.
Amorphous metal alloys are generally characterized as having high strengths and harnesses and so are quite resistant to deformation. Typical amorphous shapes, such as ribbons and wires, are formed simultaneously with the formation of the amorphous state.
These shapes exhibit the characteristics of an amorphous material.
However, attempts to form bulk amorphous shapes, that is, shapes having significant thicknesses in all dimensions, have not been satisfactory. These attempts generally include reducing an amorphous metal alloy, such as a ribbon, to an amorphous powder by physical means and then compacting the powder into a shape. Generally, the compacted shape does not retain all the desirable traits of the individual particles.
Whereas the process disclosed herein above teaches the synthesis of amorphous metal alloy powders, it now becomes known, in accordance with the invention claimed herein, that the intimate mixture obtained as an intermediate in the formation of Applicants' amorphous metal alloy powders may be effectively formed unto bulk ~3~3~'7 objects when at least one component of the intimate mixture is Dakota. By ductile is meant a component that it mailable, pliant and easily molded without cracking or fracturing. A typical Dakota component will demonstrate deformation of at least ten percent under a moderate load of between about Lowe psi and 5,000 psi. the ductile component of the intimate mixture provides an infrastructure that, when subjected to forming processes, deforms and binds the other components of the alloy within a matrix.
The ductile component of the alloy originates in a precursor compound that is used in the solid state reactions to form the intimate mixture of the alloy components. Examples of ductile components include pure metal elements, such as iron, nickel, copper, cobalt and tantalum, and metal solid solutions. Preferably the ductile component is a pure metal element.
To provide enhanced bonding strength and properties to the formed amorphous metal alloy object, it is preferred that the ductile component comprise from about lo atomic percent to about 95 atomic percent of the amorphous metal alloy based on the total composition of the amorphous metal alloy.
The intimate mixture of the components of the amorphous metal alloy, which has not yet been heat-treated to induce the amorphous state is subjected to a forming process. Forming processes include well-known powder forming techniques such as cold-pressing, hot-pressing, pressure less sistering, slipcast1ng, injection molding and extrusion In accordance with this invent10n, the only restriction on the forming process is that the process be performed at a temperature below the crystallization temperature of the metal alloy.
If the forming process includes the use of temperature above ambient temperature, then the intimate mixture may be formed and made amorphous simultaneously. If the forming process does not include elevated temperatures, then a further step, heat-treating, will be required to induce the amorphous state Many intimate mixtures may be reactive with oxygen, and so, may require forming and heat-treating processing which occurs in an oxygen-free atmosphere such as an inert, reducing or reactive ~3;~7 atmosphere or under vacuum conditions. A reactive atmosphere may be provided that reacts with the bulk object so as to enhance the formation of the amorphous alloy.
Amorphous metal alloy shapes generally have a density of from about 10 percent to about 99 percent of theoretical. The density may be controlled by the forming process so as meet a variety of needs. Thus, the same amorphous metal alloy composition may be formed into an amorphous metal alloy shape having a density between about lo percent and about 90 percent of theoretical. It has also been observed that the process of this invention permits the attainment of a desired-density object at temperatures lower than those necessary to achieve the same sistered state when the metal alloy powder used to form the object is derived from the physical reduction of a prior art, thin-film amorphous shape such as a ribbon.
The forming process may be used to provide an amorphous metal alloy in a finished shape or in a solid shape amenable to further machining. Thus, billies, rods, flat plates may be formed as well as cylindrical shapes, toxoids and other intricate, finished shapes.
The above-described processes for synthesizing amorphous metal alloys are not hindered by the processing limitations of prior art processes. The methods disclosed herein do not depend on extremely high cooling rates or heat transfer properties, nor i; very high temperature or very low vacuum equipment necessary. Further, the processes of this invention provide or the synthesis of substantially amorphous metal alloy powders, which amorphous alloy powders may be pressed into desired shapes to form solid amorphous alloy shapes. Alternatively, the methods disclosed herein provide an intonate mixture of elements that may be formed into a desired shape and, upon subsequent heat-treating, may be converted into a substantially amorphous metal alloy shape. The method disclosed herein does not depend on reducing an amorphous material to a powder state and then recombining an amorphous powder but utilizes an intimate mixture of the components of a metal alloy into a bulk shape and thereafter, or concurrently, inducing the amorphous state by heat treating at a temperature below the crystallization temperature of the metal alloy. These bulk amorphous metal alloy shapes may find new and useful applications, since such shapes have not teen conveniently fabricated by any other techniques.
EXAMPLE
The following examples more thoroughly illustrate the present invention and are not intended in any way to be limitative thereof. Each of the following examples describes the co-decomposition of organometallic compounds to yield amorphous metal alloy powders.
Example 1 This example demonstrates the formation of an amorphous iron-molybdenum composition.
Equimolar amounts of about 2 Molly each of cyclopentadienyliron dicarbonyl diver [C5H5Fe(C0~]2and cyclopentadienylmolybdenum tricarbonyl diver [C5H5Mo~C03)]2 were disposed in a stainless steel bomb reactor. The reactor was purged with argon and sealed under an argon atmosphere. the bomb reactor was then heated to a temperature of about 300C for about 24 hours. The decomposition temperature of cyclopentadienyliron dicarbonyl diver is about 195C, and the decomposition temperature of cyclopentadienylmolybdenum tricarbonyl diver is about 180C.
After cooling to about 20C, the reactor was opened and a black-colored solid, in powder form, was removed therefrom. The powder was washed with tetrahydrofuran to remove any organic-soluble materials, then dried at a temperature of about 60C under vacuum.
The powder was next divided into four fractions, a first fraction was set aside for later analysis, and the other three fractions were Further treated in the following manner; one fraction was heat-treated at about 270C under vacuum for about 168 hours, another fraction was heat-treated at about 325C under vacuum for about 168 hours, and still another fraction was heat-treated at about 800C under vacuum for about 10 minutes.
X-ray diffraction data indicated that the powder removed from the bomb reactor after co-decomposition of the precursor materials comprised an amorphous iron-molybdenum alloy having an approximate composition of Fume. The fractions of the powder that were heat-treated at about 270C and about 325C were also found to comprise an amorphous lron-molybdenum alloy of approximate composition Foe, as indicated by x-ray diffraction, but the fraction of the powder that was heat-treated at about 800C was crystalline.
Differential scanning calorimetry was implemented to determine that the amorphous alloy powder fractions had glass transition temperatures of about 325~C and crystallization temperatures of about 420C. Mossbauer Effect Spectra of the amorphous powder fractions indicated that these amorphous iron-molybdenum alloy powders have internal magnetic fields and magnetic moments similar to other iron-containing amorphous alloys.
Amorphous iron-molybdenum alloy compositions have not been reported as formed by any other method except sputtering, which method cannot synthesize the amorphous alloy in powder form.
Example 2 This example demonstrates the formation of an amorphous iron-molybdenum composition using alternative precursor organometallic compounds.
Equimolar amounts of iron pentacarbonyl (Fake and molybdenum carbonyl (Mohawk) could be sealed under an inert atmosphere such as an argon atmosphere or under a vacuum in a bomb reactor and heated to about 270~C for about 120 hours to thermally decompose about all of the precursor compounds and to alloy the reactant product elements. the decomposition temperature of iron pentacarbonyl is about 150C, and the decomposition temperature of molybdenum carbonyl is about 150C.
The resultant solid, powder material that is obtained by this decomposition can be confirmed by x-ray diffraction to be amorphous iron-molybdenum alloy. The approximate composition will be amorphous Fume.
,, I k7 This example demonstrates the formation of an amorphous iron-molybdenum nitrogen composition.
Equimolar amounts of iron pentacarbonyl fake) and mo91ybdenum carbonyl (Mohawk) may be disposed in a reactor and sealed under an atmosphere of ammonia. The reactor could then be heated to a temperature above the decomposition temperatures of iron pentacarbonyl and molybdenum carbonyl, which it above about 270~C for a period of time that would insure decomposition of the reactant materials and alloying of the component elements.
The product that would be obtained as a solid powder material will be an amorphous iron-molybdenum-nitrogen alloy of approximate composition Famine the nitrogen having been derived from the ammonia atmosphere under which the solid products were sealed prior to heating.
Example 4 This example describes the formation of an amorphous iron-chromium-molybdenum composition.
Top following three organometallic precursor materials could be disposed in a bomb reactor in about the following molar ratios:
1.0 mow equivalent iron dodecarbonyl (Fake), 0.5 mow equivalent chromium carbonyl (Crook), and 3 mow equivalents molybdenum carbonyl (Mohawk). the decomposition temperature of Ron dodecarbonyl is about 140C. The decomposition temperature of chromium carbonyl is about 200C. The decomposition temperature of molybdenum carbonyl is about 150C.
The reactor may then be sealed under an inert atmosphere and heated to a temperature above about 270C for a period of lime suPPicient to decompose the precursor compounds and to alloy the elements of the amorphous composition.
The solid, powder material that is obtained from this thermal decomposition will be an amorphous iron-chromium-molybdenum material of approximate composition Faker Moe.
Example 5 1~33~47 Example q above could also have been performed under an atmosphere other than an inert atmosphere so as to modify the product amorphous metal alloy.
The inert atmosphere of Example 4 may be replaced with a phosphorus atmosphere obtained by disposing solid elemental phosphorus, such as red phosphorus in the reactor with the other precursor compounds and sealing the reactor under a vacuum. At elevated temperatures, the phosphorus would vaporize producing a phosphorus atmosphere during the decomposition of the other precursor compounds. The resultant amorphous metal alloy from the thermal decomposition reaction may have an approximate composition of 3 0.5 3-Example 6 This example demonstrate the formation of an amorphous tungsten-nickel-carbon capstone.
Precursor materials, mes~tylene tungsten tricarbonyl (CgH12W(CO)3) and bis(triphenylphosphine) nickel dicarbonyl [)(C6H5)3P]2Ni(CO)2, may be disposed in a bomb reactor in a molar ratio of about 1:2. The decomposition temperature of mesitylene tungsten tricarbonyl is about 165C, and the decomposition temperature of bis(triphenylphosphine) nickel dicarbonyl is about 215C. The reactor may be sealed under an inert atmosphere such as an argon atmosphere and then heated to a temperature above about 215C for a time long enough to insure that the precursor compounds have substantially decomposed and alloyed.
A solid, powder material would result that is an amorphous tungsten-nickel-carbon-phoszphorus maternal having an approximate composition of Wink UP.
~Ej~m~le 7 The formation of an amorphous cobalt rhenium composition is described in this example.
The following two organometallic precursor materials may be disposed in a bomb reactor in about the following molar ratios: 1 mol. rhenium carbonyl (Wreck) and 2 mows cobalt carbonyl (C02(CO)8). The reactor may then be sealed under an inert atmosphere, such as an argon atmosphere and heated to bout at least 170C for a time sufficient to thermally decompose the precursor compounds. the decomposition temperature of rhenium carbonyl is about 170C. The decomposition temperature so cobalt carbonyl is about 55C. The resultant solid, powder material that is obtained by this decomposition will be an amorphous alloy of cobalt rhenium. The approximate composition will be amorphous Core.
Example 8 The formation of an amorphous tungsten-cobalt-iron composition is described in this example.
The following organometallic precursor materials may be disposed in a bomb reactor in about the following molar ratios: 1 mow equivalent tungsten carbonyl (WACO), 1 mow equivalent cobalt carbonyl (Cook), and 2 mows equivalents iron nonacrbonyl (Fake). Tungsten carbonyl has a decomposition temperature of about 170C. Cobalt carbonyl has a decompos~tlon temperature of about 55C. Iron nonacrbonyl has a decomposition temperature of about 100C.
The reactor may be sealed under an inert atmosphere and heated to a temperature above about 270~C so as to substantially thermally decompose the precursor compounds and to alloy the product elements.
The powder removed from the bomb reactor after the co-decomposit~on of the precursor materials will comprise an amorphous tungsten-cobalt-iron composition of approximately
2 4 Example 9 This example demonstrates the formation of an amorphous chromium-iron-nickel-boron composition synthesized by adding a chromium-hearing precursor compound to an amorphous iron-nickel-boron alloy.
Chromium carbonyl (Crook) was mixed with a substantially amorphous metal alloy of iron-nickel-boron, having an approximate composition Fe2Ni2B, in a molar ratio of about 1:2 and were then disposed in a bomb reactor, evacuated and sealed. Chromium carbonyl thermally decompose at about 200~C. The crystallization temperature 1~33~7 of the amorphous Fe2Ni2B alloy is abut 410C, its glass transition temperature is about 330C.
The sealed reactor was heated to about 250C and maintained t about that temperature for about 120 hours. Upon cooling and opening the reactor and examining its components, no chromium carbonyl was found to be present. However, x-ray diffraction analysis determined that the powder that was removed from the reactor after this heat-treating was amorphous, having an approximate composition of Cry 5Fe2Ni2B. Thus, the process disclosed herein may include the enhancement of an amorphous metal alloy by further decomposing a metal-bearing precursor compound in the presence of an amorphous metal alloy whereby the metal in the precursor compound is incorporated into the alloy, and which alloy remains substantially amorphous.
The above-described examples demonstrate the formation of amorphous metal alloy compositions by decomposition of precursor metal-bearing materials. The formation of such amorphous materials could only be obtained previously by processes that utilize high temperature, energy intensive equipment. In addition, the novel processes described herein above produce amorphous metal alloy powders, whereas prior art processes yield the amorphous material only in a solid, thin-film or ribbon-like form which must first be reduced to a powder if it is to be formed into a solid shape.
This example demonstrates the formation of a solid shape having amorphous characteristics and an approximate composition ox Phony 2B .
Exam e 10 In this Example, an intimate mixture of the components of the amorphous metal alloy was obtained by a chemical reduction process.
Equimolar amounts of iron chloride, Focal, and nickel chloride, Nucleus, were dissolved in distilled water to form a reaction solution. This solution was degassed with argon so as to purge oxygen from the solution. An argon-degassed solution of sodium bordered, Nub, was then added drops to the reaction aye solution. The solution was stirred for about sixteen hours to insure that the reaction had gone to completion.
A black precipitate was recovered from the solution and dried at about 60C under vacuum. This precipitate was an intimate mixture of the components of the metal alloy to be formed. The intimate mixture comprised iron metal and nickel bride. Thy pure iron metal is the ductile component of the mixture.
This powder mixture was kept under an argon atmosphere to prevent oxidation and compacted into a disc having a diameter of about 1 cm and a thickness of about 0 1 cm at a pressure of about 1~,000 psi and at about 20C. The disc was sealed in an evacuated glass tube and heat treated at about 250C for about 312 hours.
X-ray diffraction analysis revealed that the resultant disc was a solid amorphous metal alloy having a composition of about Fe2Ni2B. This disc had a density that was about 98 percent of theoretical.
The formation of amorphous metal alloy shapes could only be formed previously by first reducing an already-amorphous material into a powder and then compacting the powder. Such a process is not desirable since it inherently is energy 1ntensiYe and cannot reliably produce consistent, homogeneous amorphous shapes. The disadvantages of the prior art are removed with the 3bove-described process.
The selection of precursor materials, decomposition temperatures, heat-treating temperatures and other reactant conditions can be determined from the proceeding Specification without departing from the spirit of the Invention herein disclosed and described. The scope of the invention is intended to include modifications and variations that fall within the scope of the appended claims.
Chromium carbonyl (Crook) was mixed with a substantially amorphous metal alloy of iron-nickel-boron, having an approximate composition Fe2Ni2B, in a molar ratio of about 1:2 and were then disposed in a bomb reactor, evacuated and sealed. Chromium carbonyl thermally decompose at about 200~C. The crystallization temperature 1~33~7 of the amorphous Fe2Ni2B alloy is abut 410C, its glass transition temperature is about 330C.
The sealed reactor was heated to about 250C and maintained t about that temperature for about 120 hours. Upon cooling and opening the reactor and examining its components, no chromium carbonyl was found to be present. However, x-ray diffraction analysis determined that the powder that was removed from the reactor after this heat-treating was amorphous, having an approximate composition of Cry 5Fe2Ni2B. Thus, the process disclosed herein may include the enhancement of an amorphous metal alloy by further decomposing a metal-bearing precursor compound in the presence of an amorphous metal alloy whereby the metal in the precursor compound is incorporated into the alloy, and which alloy remains substantially amorphous.
The above-described examples demonstrate the formation of amorphous metal alloy compositions by decomposition of precursor metal-bearing materials. The formation of such amorphous materials could only be obtained previously by processes that utilize high temperature, energy intensive equipment. In addition, the novel processes described herein above produce amorphous metal alloy powders, whereas prior art processes yield the amorphous material only in a solid, thin-film or ribbon-like form which must first be reduced to a powder if it is to be formed into a solid shape.
This example demonstrates the formation of a solid shape having amorphous characteristics and an approximate composition ox Phony 2B .
Exam e 10 In this Example, an intimate mixture of the components of the amorphous metal alloy was obtained by a chemical reduction process.
Equimolar amounts of iron chloride, Focal, and nickel chloride, Nucleus, were dissolved in distilled water to form a reaction solution. This solution was degassed with argon so as to purge oxygen from the solution. An argon-degassed solution of sodium bordered, Nub, was then added drops to the reaction aye solution. The solution was stirred for about sixteen hours to insure that the reaction had gone to completion.
A black precipitate was recovered from the solution and dried at about 60C under vacuum. This precipitate was an intimate mixture of the components of the metal alloy to be formed. The intimate mixture comprised iron metal and nickel bride. Thy pure iron metal is the ductile component of the mixture.
This powder mixture was kept under an argon atmosphere to prevent oxidation and compacted into a disc having a diameter of about 1 cm and a thickness of about 0 1 cm at a pressure of about 1~,000 psi and at about 20C. The disc was sealed in an evacuated glass tube and heat treated at about 250C for about 312 hours.
X-ray diffraction analysis revealed that the resultant disc was a solid amorphous metal alloy having a composition of about Fe2Ni2B. This disc had a density that was about 98 percent of theoretical.
The formation of amorphous metal alloy shapes could only be formed previously by first reducing an already-amorphous material into a powder and then compacting the powder. Such a process is not desirable since it inherently is energy 1ntensiYe and cannot reliably produce consistent, homogeneous amorphous shapes. The disadvantages of the prior art are removed with the 3bove-described process.
The selection of precursor materials, decomposition temperatures, heat-treating temperatures and other reactant conditions can be determined from the proceeding Specification without departing from the spirit of the Invention herein disclosed and described. The scope of the invention is intended to include modifications and variations that fall within the scope of the appended claims.
Claims (31)
1. A process for the synthesis of a substantially amorphous metal alloy comprising thermally decomposing at least one precursor metal-bearing compound at a temperature below the crystallization temperature of the amorphous metal alloy to be formed, the at least one precursor metal-bearing compound having a decomposition temperature below the crystallization temperature of the amorphous alloy to be formed and containing the metals which comprise the substantially amorphous metal alloy.
2. The process in accordance with claim 1 wherein said substantially amorphous metal alloy is obtained as a powder.
3. The process in accordance with claim 2 wherein said powder is further processed into a solid shape.
4. The process in accordance with claim 1 wherein the amorphous metal alloy formed is at least 50 percent amorphous.
5. The process in accordance with claim 1 wherein said thermal decomposition occurs under an inert atmosphere.
6. The process in accordance with claim 1 wherein said decomposition occurs under a reactive atmosphere.
7. The process in accordance with claim 1 wherein said at least one precursor metal-bearing compound is an organometallic compound.
8. A process for the synthesis of an enhanced substantially amorphous metal alloy comprising thermally decomposing at least one precursor metal-bearing compound in the presence of an initial substantially amorphous metal alloy at a temperature below the crystallization temperatures of the initial substantially amorphous metal alloy and the enhanced substantially amorphous metal alloy to be formed, the at least one precursor metal-bearing compound containing additional elements to be incorporated into the initial metal alloy so as to form an enhanced substantially amorphous metal alloy.
9. A process for the synthesis of a substantially amorphous metal alloy comprising the steps of:
(a) decomposing at least one precursor metal-bearing compound at a temperature below the crystallization temperature of the amorphous metal alloy to be synthesized so as to form an intimate mixture of the components of the amorphous metal alloy to be synthesized, the at least one precursor metal-bearing compound containing the metals which comprise the substantially amorphous alloy; and (b) heat-treating the intimate mixture so as to form the substantially amorphous metal alloy.
(a) decomposing at least one precursor metal-bearing compound at a temperature below the crystallization temperature of the amorphous metal alloy to be synthesized so as to form an intimate mixture of the components of the amorphous metal alloy to be synthesized, the at least one precursor metal-bearing compound containing the metals which comprise the substantially amorphous alloy; and (b) heat-treating the intimate mixture so as to form the substantially amorphous metal alloy.
10. The process in accordance with claim 9 wherein said substantially amorphous metal alloy is synthesized as a powder.
11. The process in accordance with claim 9 wherein prior to step (b) said intimate mixture of the components of the amorphous metal alloy to be synthesized is pressed into a shape.
12. The process in accordance with claim 9 wherein said substantially amorphous metal alloy of step (b) is formed into a solid shape.
13. The process in accordance with claim 9 wherein said formed substantially amorphous metal alloy is at least 50 percent amorphous.
14. The process in accordance with claim 9 wherein said process synthesizes an amorphous metal alloy composition including nonmetallic elements.
15. The process in accordance with claim 14 wherein heat-treating of the intimate mixture occurs under an atmosphere comprising said nonmetallic elements.
16. The process in accordance with claim 9 wherein said heat-treating of the intimate mixture is performed under an inert atmosphere.
17. The process in accordance with claim 9 wherein said heat-treating of the intimate mixture is performed under a reactive atmosphere.
18. The process in accordance with claim 9 wherein said intimate mixture comprises particles having a maximum particle size of from about 10 Angstroms to about 1000 Angstroms.
19. A process for the synthesis of an enhanced substantially amorphous metal alloy comprising the steps of:
(a) decomposing at least one precursor metal-bearing compound in the presence of an initial substantially amorphous metal alloy at a temperature below the crystallization temperature of the enhanced substantially amorphous metal alloy to be synthesized so as to form an intimate mixture of the components of the enhanced amorphous metal alloy to be synthesized; and (b) heat-treating the mixture so as to form an enhanced substantially amorphous metal alloy.
(a) decomposing at least one precursor metal-bearing compound in the presence of an initial substantially amorphous metal alloy at a temperature below the crystallization temperature of the enhanced substantially amorphous metal alloy to be synthesized so as to form an intimate mixture of the components of the enhanced amorphous metal alloy to be synthesized; and (b) heat-treating the mixture so as to form an enhanced substantially amorphous metal alloy.
20. A substantially amorphous metal alloy powder synthesized by thermally decomposing at least one precursor metal-bearing compound at a temperature below the crystallization temperature of the amorphous metal alloy, the at least one precursor metal-bearing compound containing the metals that comprise the substantially amorphous metal alloy.
21. The substantially amorphous metal alloy powder in accordance with claim 20 wherein said amorphous metal alloy powder is at least 50 percent amorphous.
22. The substantially amorphous metal alloy powder in accordance with claim 20 wherein the amorphous metal alloy composition includes nonmetallic elements.
23. The substantially amorphous metal alloy powder in accordance with claim 20 wherein the amorphous metal alloy composition includes nonmetallic elements selected from the group comprising boron, carbon, nitrogen, silicon, phosphorus, arsenic, germanium and antimony.
24. The substantially amorphous metal alloy powder in accordance with claim 20 wherein said powder has a maximum particle size of from about 10 Angstroms to about 1,000 Angstroms.
25. The substantially amorphous metal alloy powder in accordance with claim 20 wherein said powder has a maximum particle size of from about 10 Angstroms to about 500 Angstroms.
26. A process for the production of substantially amorphous metal alloy objects comprising:
a) preparing an intimate mixture of the components of the amorphous metal alloy by a solid state reaction, at least one component of the intimate mixture being a ductile component; and b) forming the intimate mixture into an object at a temperature below the crystallization temperature of the metal alloy so as to form an amorphous metal alloy object.
a) preparing an intimate mixture of the components of the amorphous metal alloy by a solid state reaction, at least one component of the intimate mixture being a ductile component; and b) forming the intimate mixture into an object at a temperature below the crystallization temperature of the metal alloy so as to form an amorphous metal alloy object.
27. The process in accordance with claim 26 wherein said intimate mixture comprises particles having a maximum particle size of from about 10 Angstroms to about 1000 Angstroms.
28. The process in accordance with claim 26 wherein said ductile component is a material selected from the group comprising pure metal elements and metal solid solutions.
29. The process in accordance with claim 26 wherein said ductile component is a metal element selected from the group comprising iron, nickel, copper, cobalt and tantalum.
30. The process in accordance with claim 26 wherein said ductile component comprises from about 10 atomic percent to about 95 atomic percent of the amorphous metal alloy based on the total composition of the amorphous metal alloy.
31. The process in accordance with claim 26 wherein step b) comprises the step of forming the intimate mixture into an object followed by heat treating the so-formed object so as to induce the amorphous state.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/586,467 US4557766A (en) | 1984-03-05 | 1984-03-05 | Bulk amorphous metal alloy objects and process for making the same |
| US586,467 | 1984-03-05 | ||
| US586,380 | 1984-03-05 | ||
| US06/586,380 US4537624A (en) | 1984-03-05 | 1984-03-05 | Amorphous metal alloy powders and synthesis of same by solid state decomposition reactions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1233047A true CA1233047A (en) | 1988-02-23 |
Family
ID=27079692
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000475705A Expired CA1233047A (en) | 1984-03-05 | 1985-03-04 | Amorphous metal alloy powders and bulk objects and synthesis of same by solid state decomposition reactions |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0154548B1 (en) |
| AU (1) | AU571655B2 (en) |
| BR (1) | BR8500991A (en) |
| CA (1) | CA1233047A (en) |
| DE (1) | DE3572610D1 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4537625A (en) * | 1984-03-09 | 1985-08-27 | The Standard Oil Company (Ohio) | Amorphous metal alloy powders and synthesis of same by solid state chemical reduction reactions |
| US4585617A (en) * | 1985-07-03 | 1986-04-29 | The Standard Oil Company | Amorphous metal alloy compositions and synthesis of same by solid state incorporation/reduction reactions |
| IN165517B (en) * | 1985-12-31 | 1989-11-04 | Standard Oil Co Ohio | |
| DE3714239C2 (en) * | 1987-04-29 | 1996-05-15 | Krupp Ag Hoesch Krupp | Process for the production of a material with a structure of nanocrystalline structure |
| FR2723015B1 (en) * | 1994-07-29 | 1996-09-13 | Commissariat Energie Atomique | PROCESS FOR OBTAINING IRON OR IRON POWDERS BY ORGANIC LIQUID PHASE PRECIPITATION |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2686714A (en) * | 1950-12-22 | 1954-08-17 | Basf Ag | Metal powders for magnetic mass cores |
| GB930989A (en) * | 1958-09-12 | 1963-07-10 | Monsanto Chemicals | Production of inorganic compounds |
| US3986901A (en) * | 1975-04-30 | 1976-10-19 | International Business Machines Corporation | Controlled catalyst for manufacturing magnetic alloy particles having selective coercivity |
| US4282034A (en) * | 1978-11-13 | 1981-08-04 | Wisconsin Alumni Research Foundation | Amorphous metal structures and method |
| DE3014121A1 (en) * | 1980-04-12 | 1981-10-15 | Heinrich Dr. 6236 Eschborn Winter | Alloy prodn. in solid shaped form - by alloy formation in plasma, rapid solidification and pressing and sintering prodn. particles |
| CA1151881A (en) * | 1980-08-21 | 1983-08-16 | Eric A. Devuyst | Cobalt metal powder by hydrogen reduction |
| US4564396A (en) * | 1983-01-31 | 1986-01-14 | California Institute Of Technology | Formation of amorphous materials |
-
1985
- 1985-03-04 CA CA000475705A patent/CA1233047A/en not_active Expired
- 1985-03-04 AU AU39437/85A patent/AU571655B2/en not_active Ceased
- 1985-03-05 DE DE8585301507T patent/DE3572610D1/en not_active Expired
- 1985-03-05 BR BR8500991A patent/BR8500991A/en unknown
- 1985-03-05 EP EP19850301507 patent/EP0154548B1/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| EP0154548A2 (en) | 1985-09-11 |
| AU3943785A (en) | 1985-09-12 |
| EP0154548A3 (en) | 1986-01-08 |
| AU571655B2 (en) | 1988-04-21 |
| BR8500991A (en) | 1985-10-29 |
| EP0154548B1 (en) | 1989-08-30 |
| DE3572610D1 (en) | 1989-10-05 |
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