CA1222719A - Methods of forming a protective diffusion layer on nickel, cobalt and iron base alloys - Google Patents
Methods of forming a protective diffusion layer on nickel, cobalt and iron base alloysInfo
- Publication number
- CA1222719A CA1222719A CA000435041A CA435041A CA1222719A CA 1222719 A CA1222719 A CA 1222719A CA 000435041 A CA000435041 A CA 000435041A CA 435041 A CA435041 A CA 435041A CA 1222719 A CA1222719 A CA 1222719A
- Authority
- CA
- Canada
- Prior art keywords
- aluminum
- platinum
- gas phase
- aluminizing
- activator
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims abstract description 25
- 238000009792 diffusion process Methods 0.000 title claims abstract description 15
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims abstract description 12
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 8
- 239000000956 alloy Substances 0.000 title claims abstract description 8
- 229910017052 cobalt Inorganic materials 0.000 title claims abstract description 6
- 239000010941 cobalt Substances 0.000 title claims abstract description 6
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 title claims abstract description 6
- 229910052742 iron Inorganic materials 0.000 title claims abstract description 6
- 229910052759 nickel Inorganic materials 0.000 title claims abstract description 6
- 230000001681 protective effect Effects 0.000 title claims abstract description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 43
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 21
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 17
- 238000005269 aluminizing Methods 0.000 claims abstract description 16
- 239000011248 coating agent Substances 0.000 claims abstract description 12
- 238000000576 coating method Methods 0.000 claims abstract description 12
- 229910052751 metal Inorganic materials 0.000 claims abstract description 9
- 239000002184 metal Substances 0.000 claims abstract description 9
- 238000000151 deposition Methods 0.000 claims abstract 2
- 239000000203 mixture Substances 0.000 claims description 10
- 239000000945 filler Substances 0.000 claims description 9
- 239000012190 activator Substances 0.000 claims description 7
- 239000012298 atmosphere Substances 0.000 claims description 7
- 229910000838 Al alloy Inorganic materials 0.000 claims description 3
- 238000009713 electroplating Methods 0.000 claims description 3
- 238000007747 plating Methods 0.000 claims description 3
- 238000007598 dipping method Methods 0.000 claims 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims 2
- 238000005507 spraying Methods 0.000 claims 2
- 238000004544 sputter deposition Methods 0.000 claims 2
- 238000007740 vapor deposition Methods 0.000 claims 2
- 239000007789 gas Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 239000012159 carrier gas Substances 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 241000193803 Therea Species 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000012300 argon atmosphere Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
Classifications
- 
        - C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C10/00—Solid state diffusion of only metal elements or silicon into metallic material surfaces
- C23C10/06—Solid state diffusion of only metal elements or silicon into metallic material surfaces using gases
- C23C10/16—Solid state diffusion of only metal elements or silicon into metallic material surfaces using gases more than one element being diffused in more than one step
 
- 
        - C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C10/00—Solid state diffusion of only metal elements or silicon into metallic material surfaces
- C23C10/06—Solid state diffusion of only metal elements or silicon into metallic material surfaces using gases
- C23C10/14—Solid state diffusion of only metal elements or silicon into metallic material surfaces using gases more than one element being diffused in one step
 
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Formation Of Insulating Films (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title | 
|---|---|---|---|
| US06/437,952 US4501776A (en) | 1982-11-01 | 1982-11-01 | Methods of forming a protective diffusion layer on nickel, cobalt and iron base alloys | 
| US437,952 | 1989-11-17 | 
Publications (1)
| Publication Number | Publication Date | 
|---|---|
| CA1222719A true CA1222719A (en) | 1987-06-09 | 
Family
ID=23738608
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date | 
|---|---|---|---|
| CA000435041A Expired CA1222719A (en) | 1982-11-01 | 1983-08-22 | Methods of forming a protective diffusion layer on nickel, cobalt and iron base alloys | 
Country Status (17)
| Country | Link | 
|---|---|
| US (1) | US4501776A (OSRAM) | 
| JP (1) | JPS5983757A (OSRAM) | 
| AT (1) | AT381728B (OSRAM) | 
| AU (1) | AU563370B2 (OSRAM) | 
| BE (1) | BE898043A (OSRAM) | 
| CA (1) | CA1222719A (OSRAM) | 
| CH (1) | CH660028A5 (OSRAM) | 
| DE (1) | DE3329908A1 (OSRAM) | 
| ES (1) | ES8504965A1 (OSRAM) | 
| FR (1) | FR2535345B1 (OSRAM) | 
| GB (1) | GB2129017B (OSRAM) | 
| IL (1) | IL69831A (OSRAM) | 
| IT (1) | IT1170535B (OSRAM) | 
| MX (1) | MX162228A (OSRAM) | 
| NL (1) | NL190559C (OSRAM) | 
| SE (1) | SE8305243L (OSRAM) | 
| ZA (1) | ZA835915B (OSRAM) | 
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title | 
|---|---|---|---|---|
| AU579199B2 (en) * | 1984-11-09 | 1988-11-17 | Qantas Defence Services Pty Limited | Corrosion resistant coating process | 
| US4861441A (en) * | 1986-08-18 | 1989-08-29 | Nippon Steel Corporation | Method of making a black surface treated steel sheet | 
| FR2638174B1 (fr) * | 1988-10-26 | 1991-01-18 | Onera (Off Nat Aerospatiale) | Procede de protection de surface de pieces metalliques contre la corrosion a temperature elevee, et piece traitee par ce procede | 
| US5139824A (en) * | 1990-08-28 | 1992-08-18 | Liburdi Engineering Limited | Method of coating complex substrates | 
| US5071678A (en) * | 1990-10-09 | 1991-12-10 | United Technologies Corporation | Process for applying gas phase diffusion aluminide coatings | 
| US5221354A (en) * | 1991-11-04 | 1993-06-22 | General Electric Company | Apparatus and method for gas phase coating of hollow articles | 
| US6620460B2 (en) | 1992-04-15 | 2003-09-16 | Jet-Lube, Inc. | Methods for using environmentally friendly anti-seize/lubricating systems | 
| US5500252A (en) * | 1992-09-05 | 1996-03-19 | Rolls-Royce Plc | High temperature corrosion resistant composite coatings | 
| DE69417515T2 (de) * | 1993-11-19 | 1999-07-15 | Walbar Inc., Peabody, Mass. | Verbessertes Verfahren für eine mit Platingruppen-Silicid modifizierte Aluminid-Beschichtung und Produkte | 
| US5650235A (en) * | 1994-02-28 | 1997-07-22 | Sermatech International, Inc. | Platinum enriched, silicon-modified corrosion resistant aluminide coating | 
| US5658614A (en) * | 1994-10-28 | 1997-08-19 | Howmet Research Corporation | Platinum aluminide CVD coating method | 
| EP0731187A1 (en) * | 1995-03-07 | 1996-09-11 | Turbine Components Corporation | Method of forming a protective diffusion layer on nickel, cobalt and iron based alloys | 
| US5716720A (en) * | 1995-03-21 | 1998-02-10 | Howmet Corporation | Thermal barrier coating system with intermediate phase bondcoat | 
| US6066405A (en) * | 1995-12-22 | 2000-05-23 | General Electric Company | Nickel-base superalloy having an optimized platinum-aluminide coating | 
| US5897966A (en) * | 1996-02-26 | 1999-04-27 | General Electric Company | High temperature alloy article with a discrete protective coating and method for making | 
| US5788823A (en) * | 1996-07-23 | 1998-08-04 | Howmet Research Corporation | Platinum modified aluminide diffusion coating and method | 
| US5800695A (en) * | 1996-10-16 | 1998-09-01 | Chromalloy Gas Turbine Corporation | Plating turbine engine components | 
| US6458473B1 (en) | 1997-01-21 | 2002-10-01 | General Electric Company | Diffusion aluminide bond coat for a thermal barrier coating system and method therefor | 
| US5928725A (en) * | 1997-07-18 | 1999-07-27 | Chromalloy Gas Turbine Corporation | Method and apparatus for gas phase coating complex internal surfaces of hollow articles | 
| US5985122A (en) | 1997-09-26 | 1999-11-16 | General Electric Company | Method for preventing plating of material in surface openings of turbine airfoils | 
| DE19859763A1 (de) * | 1998-12-23 | 2000-06-29 | Abb Alstom Power Ch Ag | Verfahren zum Unschädlichmachen von beim Beschichten mit einer Schutzschicht entstehenden Verengungen in den Kühllöchern von gasgekühlten Teilen | 
| US6485780B1 (en) * | 1999-08-23 | 2002-11-26 | General Electric Company | Method for applying coatings on substrates | 
| US6305077B1 (en) | 1999-11-18 | 2001-10-23 | General Electric Company | Repair of coated turbine components | 
| US6444060B1 (en) | 1999-12-22 | 2002-09-03 | General Electric Company | Enhancement of an unused protective coating | 
| US6589668B1 (en) * | 2000-06-21 | 2003-07-08 | Howmet Research Corporation | Graded platinum diffusion aluminide coating | 
| US20050029109A1 (en) * | 2002-05-07 | 2005-02-10 | Gang Zhang | Method of electrochemically fabricating multilayer structures having improved interlayer adhesion | 
| US20050045585A1 (en) | 2002-05-07 | 2005-03-03 | Gang Zhang | Method of electrochemically fabricating multilayer structures having improved interlayer adhesion | 
| FR2843896A1 (fr) * | 2002-12-09 | 2004-03-05 | Commissariat Energie Atomique | Substrat poreux contenant une phase metallique a gradient de concentration et procede de fabrication de ce substrat | 
| JP4907072B2 (ja) * | 2003-10-15 | 2012-03-28 | ゼネラル・エレクトリック・カンパニイ | 選択的領域気相アルミナイズ方法 | 
| JP4986402B2 (ja) * | 2004-03-03 | 2012-07-25 | 大阪瓦斯株式会社 | Al拡散コーティング層の形成方法及びAl拡散コーティング層を有する耐熱部材 | 
| US20060222776A1 (en) * | 2005-03-29 | 2006-10-05 | Honeywell International, Inc. | Environment-resistant platinum aluminide coatings, and methods of applying the same onto turbine components | 
| US7531220B2 (en) * | 2006-02-07 | 2009-05-12 | Honeywell International Inc. | Method for forming thick quasi-single phase and single phase platinum nickel aluminide coatings | 
| US20090068016A1 (en) * | 2007-04-20 | 2009-03-12 | Honeywell International, Inc. | Shrouded single crystal dual alloy turbine disk | 
| EP2188412A1 (de) * | 2007-09-13 | 2010-05-26 | Siemens Aktiengesellschaft | Korrosionsbeständiges druckbehälterstahlerzeugnis, ein verfahren zur herstellung desselben und eine gasturbinenkomponente | 
| US20100247793A1 (en) * | 2007-10-26 | 2010-09-30 | The Secretary, Department of Atomic Energy,Govt. of India | Process for producing body centered cubic (b2) nickel aluminide (nial) coating of controlled thickness on nickle-based alloy surfaces | 
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title | 
|---|---|---|---|---|
| DE1521180B1 (de) * | 1963-09-19 | 1970-05-14 | Coast Metlas Inc | Verfahren zum UEberziehen von Metallgegenstaenden mit einer Aluminiumlegierung | 
| GB980727A (en) * | 1963-09-23 | 1965-01-20 | Coast Metals Inc | Method of applying metallic coatings | 
| DE1796175C2 (de) * | 1968-09-14 | 1974-05-30 | Deutsche Edelstahlwerke Gmbh, 4150 Krefeld | Hochtemperaturkorrosions- und zunderbeständige Diffusionsschutzschicht auf Gegenständen aus hochwarmfesten Legierungen auf Nickel- und/oder Kobaltbasis | 
| BE757636A (fr) * | 1969-11-03 | 1971-04-01 | Deutsche Edelstahlwerke Ag | Procede de protection en surface pour objets metalliques | 
| BE759275A (fr) * | 1969-12-05 | 1971-04-30 | Deutsche Edelstahlwerke Ag | Procede d'application de couches protectrices diffusees sur despieces en alliage a base de cobalt | 
| US3999956A (en) * | 1975-02-21 | 1976-12-28 | Chromalloy American Corporation | Platinum-rhodium-containing high temperature alloy coating | 
| GB1549845A (en) * | 1975-04-04 | 1979-08-08 | Secr Defence | Diffusion coating of metal or other articles | 
| US3979273A (en) * | 1975-05-27 | 1976-09-07 | United Technologies Corporation | Method of forming aluminide coatings on nickel-, cobalt-, and iron-base alloys | 
| US4132816A (en) * | 1976-02-25 | 1979-01-02 | United Technologies Corporation | Gas phase deposition of aluminum using a complex aluminum halide of an alkali metal or an alkaline earth metal as an activator | 
| CA1117278A (en) * | 1979-06-14 | 1982-02-02 | Grigori S. Victorovich | Process for treatment of selenium-bearing materials | 
- 
        1982
        - 1982-11-01 US US06/437,952 patent/US4501776A/en not_active Expired - Lifetime
 
- 
        1983
        - 1983-08-11 ZA ZA835915A patent/ZA835915B/xx unknown
- 1983-08-15 GB GB08321905A patent/GB2129017B/en not_active Expired
- 1983-08-18 DE DE19833329908 patent/DE3329908A1/de active Granted
- 1983-08-22 CA CA000435041A patent/CA1222719A/en not_active Expired
- 1983-08-24 JP JP58155686A patent/JPS5983757A/ja active Granted
- 1983-09-15 FR FR838314689A patent/FR2535345B1/fr not_active Expired
- 1983-09-27 IL IL69831A patent/IL69831A/xx not_active IP Right Cessation
- 1983-09-28 SE SE8305243A patent/SE8305243L/ unknown
- 1983-10-19 NL NLAANVRAGE8303606,A patent/NL190559C/xx not_active IP Right Cessation
- 1983-10-20 BE BE0/211745A patent/BE898043A/fr not_active IP Right Cessation
- 1983-10-24 IT IT49209/83A patent/IT1170535B/it active
- 1983-10-24 AT AT0377283A patent/AT381728B/de not_active IP Right Cessation
- 1983-10-28 ES ES526879A patent/ES8504965A1/es not_active Expired
- 1983-10-31 AU AU20860/83A patent/AU563370B2/en not_active Ceased
- 1983-10-31 CH CH5886/83A patent/CH660028A5/fr not_active IP Right Cessation
- 1983-10-31 MX MX199271A patent/MX162228A/es unknown
 
Also Published As
| Publication number | Publication date | 
|---|---|
| IL69831A (en) | 1987-12-20 | 
| SE8305243D0 (sv) | 1983-09-28 | 
| AU2086083A (en) | 1984-05-10 | 
| JPS5983757A (ja) | 1984-05-15 | 
| FR2535345A1 (fr) | 1984-05-04 | 
| ATA377283A (de) | 1986-04-15 | 
| DE3329908C2 (OSRAM) | 1987-09-10 | 
| IT8349209A0 (it) | 1983-10-24 | 
| DE3329908A1 (de) | 1984-05-03 | 
| NL190559B (nl) | 1993-11-16 | 
| US4501776A (en) | 1985-02-26 | 
| ZA835915B (en) | 1984-04-25 | 
| IL69831A0 (en) | 1983-12-30 | 
| BE898043A (fr) | 1984-02-15 | 
| NL190559C (nl) | 1994-04-18 | 
| GB8321905D0 (en) | 1983-09-14 | 
| CH660028A5 (fr) | 1987-03-13 | 
| FR2535345B1 (fr) | 1989-03-31 | 
| SE8305243L (sv) | 1984-05-02 | 
| ES526879A0 (es) | 1985-05-01 | 
| GB2129017A (en) | 1984-05-10 | 
| AT381728B (de) | 1986-11-25 | 
| IT1170535B (it) | 1987-06-03 | 
| JPH0336899B2 (OSRAM) | 1991-06-03 | 
| ES8504965A1 (es) | 1985-05-01 | 
| GB2129017B (en) | 1986-04-23 | 
| MX162228A (es) | 1991-04-11 | 
| NL8303606A (nl) | 1984-06-01 | 
| AU563370B2 (en) | 1987-07-09 | 
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Legal Events
| Date | Code | Title | Description | 
|---|---|---|---|
| MKEX | Expiry |