CA1145161A - Amorphous metal alloys and ribbons thereof - Google Patents

Abstract

Abstract of the Disclosure Amorphous metal alloys are disclosed which have good physical and magnetic properties, including ductility, elevated temperature stability and saturation flux density.
The alloys consist essentially of iron, boron and silicon in proportions of 80 to 84, 12 to 15 and 1 to 8 atom percent respectively. Such alloys in the form of a ribbon are useful in the construction of the magnetoelectric component of motors, generators, transformers or other electrical apparatus.

Description

11~5161 The present invention relates generally to the metal alloy art and is more particularly concerned with novel amorphous metal alloys having a unique combination of magnetic and physical properties, and is further concerned with ribbons and other useful articles made therefrom.
While it has been recognized by those skilled in the art that amorphous metals with high saturation magnetization might be used to advantage in electrical apparatus such as distribution and power transformers, such alloys are lacking in necessary ductility and stability for this purpose. Thus, the iron-rich alloy Fe80B20 has a 4~Msof 15,700-16tlOO
gauss but begins to crystallize within two hours at about 340C and is quite difficult to produce in ductile ribbon form for electrical machinery apparatus. Other amorphous ~: alloys known heretofore have somewhat greater stability and adequate ductility for this purpose, but their saturation magnetization is too low.
This invention based upon our new concepts to be ~,;~
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,_ ' 1 1 ~ 51 ~ 1 RD-9614 described enables avoidance of the prior art necessity of choosing between desired magnetization and physical properties in amorphous metals. In other words, it is now possible by virtue of this invention to provide an amorphous metal in the form of a ribbon sufficiently ductile to be readily used in electrical apparatus construction which has good magnetic properties and elevated temperature stability. Moreover, this unique combination of properties of special merit in terms of potential utility of amorphous metals in the general field of electric power generation, transmission and utilization can be obtained without incurring any offsetting disadvantage.
- This new result is the consequence of our finding that saturation magnetization of an amorphous metal alloy is influenced by the number of electrons available from the glass former constituents of the alloy. It is also the consequence of our observation that the stability of such alloys improves as a greater variety of glass forming atoms are included in them. Thus, we have found that although dhe btntary alloy Fe80B20 is difficult to prepare as a high duotilc amorphous ribbon, small additions of a second glass forming atom may help formulation of very ductile ribbons under ~ibbon forming conditions w~ich are otherwise the same.
We have further found that while additlons of silicon to Fe80B20 reduces 4~M8 because silicon has more available electrons than boron, the improvement in ductility is great and the saturation magnetization is only marginally

-2-1 1 4 51 ~ 1 RD-9614 diminished. Moreover, stability against crystallization tendency at elevated temperature is substantially improved in each instance where boron is substituted in part by silicon in alloys containing from 80 to 84 atom percent iron. In such alloys, silicon varies from 1 to 8 atom percent while boron ranges from 12 to 16 atom percent. Further, in accordance with the broad, general concept of this invention, phosphorus~ aluminum, carbon and even sulfur can be used under certain conditions in combination or individually with silicon to obtain the new results and advantages stated above.
According to that concept, such use in every instance must be made without diminishing the alloy iron content below about 80 atom percent. Likewise, the silicon content minimum in the alloys of this invention is about one atom percent. The maximum phosphorus and sulfur contents, both individual ~nd combLned, should not exceed 0.5 atom percent. The penalty for violating these limits is substantial loss of one or more of the desired ~agnetic or physical properties.
Briefly described, this invention in its composition ; aepect Insists of an amorphous metal alloy o iron, boron and silicon having an unique combination of desired physical and magnetic prop~rties including ductility, elevated temperature ~ . .
stability and saturation flux density by virtue of the fact that the alloy contains from 80 to 84 atom percent iron, from 12 to 15 atom percent boron and ~rom 1 to 8 atom percent 9 ilicon.

~145161 This invention in its article aspect consists of the novel alloy defined just above in the form of a ribbon suitable for use, for example, in the construction of the magnetoelectric component of motor, generator, transformer or other electrical apparatus.
In practicing this invention, novel alloys defined above and claimed herein are prepared suitably by mixing together the alloy constituents in the required proportions in the form of powders and then melting the mixture to provide molten alloy for casting to ribbon of the desired dimensions.
Cooling is carried out in the casting operation at a rate sufficient to produce amorphous material.
~ While variations in melting-point temperatures between alloys of this invention may impose requirements which vary with respect to allcy melting and casting operations, the ~:

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~14Sl~l preparation and processing of these alloys can be carried out with uniformly satisfactory results by following the above procedure and using the described equipment.
In other words, the results of this invention are reproducible in a substantially routine manner so long as the compositional limitations stated above and in the appended claims are strictly observed in the preparation of the alloys.
Those skilled in the art will gain a further and better understanding of this invention from the following illustrative, but not limiting, examples of the actual practice of the invention and comparative experiments carried out upon amorphous metals standing outside the critical limits of compositions of this invention.
EXAMPLE I
A ribbon of approximately 0.0025 cm thick by 0.13 cm wide of Fe8~B20 alloy was produced by directing a stream of the alloy onto the surface of a rapidly revolving chill roll or drum. The amorphous nature of the resulting ribbon was confirmed by X-ray diffraction, differential scanning calorimetry and by magnetic and physical property measurements. The degree of ductility was determined by measuring the radius of curvature at which fracture occurred in a simple bend test between ..,,~
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11~51~1 parallel plates. Ribbon segments were annealed in purified nitrogen for two hours at temperatures ranging from 100C to 400C. The crystallization temperature was taken as that temperature, for the two-hour anneal, at which the coercive force abruptly increased.
Saturation magnetization and Curie temperature were obtained by conventional induction techniques as described in Applied PhYsics, Vol. 29, p. 330, 1976, and Scripta Met., Vol. 11, p. 367, 1977. The results of these tests and those conducted on the ribbons produced as described below in Examples II through VII are set out in Table I.

EXAMPLE II

A ribbon o Fe40Ni4opl4B6 was prepared and tested as described in Example I or in the results set forth in Table I.

EXAMPLE III
~ .
Still another amorphous metal alloy ribbon of composition Fe40Ni40B20 was prepared and tested as described in Example I with the results stated in Table I.
:
;~ EXAMPLE IV

~ ~ A ribbon o~ Fe84 5B15Po 5 was prepared and . ' f -6- ~

11~516~

tested as stated in Example I with the results shown in Table I.

EXAMPLE V

A ribbon oi Fe84B15Sil was prepared and tested as described in Example I with the results shown in Table I.

EXAMPLE_VI

Another test ribbon of the physical specifications of Example I but of composition Fe80B16Si4 was prepared and tested as to stability with the result shown in Table I.
r EXAMP,LE VII
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Another test ribbon of Fe84B16 was prepared and tested as to stability with the results ~et out in Table I.
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~: EXAMPLE VIII

Finally~ a ribbon o~ the physical specifieations of Example I of Fe80B12Si8 was prepared ~: and tested as to stability with the results stated in Table I.

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~5161 TABLE I
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Yield M
Strain TB ~x ~ R.T. Tc Alloy ~Y- C C kG C
.
Fe40Ni40P14B60.018 ~100 352 7.9 255 Fe40Ni40B20 0~l8 240~5 358 10,4 396 Fe84B16 ~ - 300 15.6 320 Fe8~ 5B15Po 50.022 245+5 303 15.4 312 84 15 1 0.022 295+5 304 15.4 373 - :
- 80 20 0.021 273+5 343 16.1 382 ~ Fe80B16Si4 _ 380 15.~ 390 :; ~ Fe80Bl2si8 ~ - 380 14.9 400 --x ~ Temperature or initiation of crystallization in 2 hr.
: ~ anneal s ~ Satura~ion 1ux density T~ - Curie temperature t/(2r~-t); ~y i9 the yield strain obtained from the ; value of r at which plastic deformation was first observed.
TB ~ Temperature for initiation of embrittlement ln 2 hr. anneal :: :

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~5:~61 As shown by the tabulated data gathered during these tests, the temperature at which embrittlement TB occurs is highest for the ternary composition Fe84B15Sil and the inclusion of a small amount of phosphorus sharply reduces the embrittlement temperature. The ductility of the single metalloid alloys is greater than that of the alloys containing two metalloids, and e84B15Sil and Fe84.5B15Po 5 are greatest of the test group. The stability towards embrittlement and towards crystallization o~ the alloys is at a maximum in the alloys containing two metalloids and at a minimum in single metalloid alloys of these series. The saturation magnetization in the two-metalloid alloys of these series compares favorably with the maximum value of Fe80B20. Outstanding stability ic exhibited by the FegOB16Si4 and Fe80 12 8

Claims (5)

The embodiments of the invention in which an exclu-sive property or privilege is claimed are defined as follows:

1. An iron-boron-silicon amorphous metal alloy having a unique combination of physical and magnetic properties including ductility, elevated temperature stability and saturation flux density, said alloy consisting essentially of from 80 to 84 atom percent iron, from 12 to 15 atom percent boron and from one to eight atom percent silicon.

2. The alloy of claim 1, having the formula Fe80B12Si8.

3. The alloy of claim 1, having the formula Fe84B15Si1.

4. As an article of manufacture, a ribbon of the amorphous metal alloy of claim 1.

5. As an article of manufacture, a ribbon of the amorphous metal alloy of claim 3.