CA1137964A - Catalysts for the hydrotreatment of hydrocarbons and use thereof in the reforming and isomerization of hydrocarbons in the presence of hydrogen - Google Patents
Catalysts for the hydrotreatment of hydrocarbons and use thereof in the reforming and isomerization of hydrocarbons in the presence of hydrogenInfo
- Publication number
- CA1137964A CA1137964A CA000352218A CA352218A CA1137964A CA 1137964 A CA1137964 A CA 1137964A CA 000352218 A CA000352218 A CA 000352218A CA 352218 A CA352218 A CA 352218A CA 1137964 A CA1137964 A CA 1137964A
- Authority
- CA
- Canada
- Prior art keywords
- catalyst
- metal
- catalyst according
- platinum
- hydrocarbons
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 103
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 23
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 23
- 238000006317 isomerization reaction Methods 0.000 title claims abstract description 16
- 229910052739 hydrogen Inorganic materials 0.000 title claims description 18
- 239000001257 hydrogen Substances 0.000 title claims description 18
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims description 17
- 238000002407 reforming Methods 0.000 title claims description 4
- 229910052751 metal Inorganic materials 0.000 claims abstract description 53
- 239000002184 metal Substances 0.000 claims abstract description 52
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 34
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910052718 tin Inorganic materials 0.000 claims abstract description 16
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 11
- 239000011734 sodium Substances 0.000 claims abstract description 11
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 11
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 10
- 150000002367 halogens Chemical class 0.000 claims abstract description 10
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000011591 potassium Substances 0.000 claims abstract description 5
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000011575 calcium Substances 0.000 claims abstract description 4
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 4
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 4
- 229910052592 oxide mineral Inorganic materials 0.000 claims abstract description 4
- 230000000737 periodic effect Effects 0.000 claims abstract description 4
- 229910052788 barium Inorganic materials 0.000 claims abstract description 3
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims abstract description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 15
- 229910052697 platinum Inorganic materials 0.000 claims description 15
- 150000002739 metals Chemical class 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 14
- 238000000151 deposition Methods 0.000 claims description 9
- 230000008021 deposition Effects 0.000 claims description 9
- 125000004429 atom Chemical group 0.000 claims description 8
- 239000000460 chlorine Substances 0.000 claims description 6
- 229910052801 chlorine Inorganic materials 0.000 claims description 6
- 239000011148 porous material Substances 0.000 claims description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- 238000009835 boiling Methods 0.000 claims description 3
- 238000005470 impregnation Methods 0.000 claims description 3
- 230000006872 improvement Effects 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 239000011593 sulfur Substances 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 229910052729 chemical element Inorganic materials 0.000 claims 1
- 125000001309 chloro group Chemical group Cl* 0.000 claims 1
- 150000002431 hydrogen Chemical class 0.000 claims 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 abstract description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 15
- 239000000243 solution Substances 0.000 description 13
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 12
- 230000008569 process Effects 0.000 description 11
- 239000011135 tin Substances 0.000 description 11
- 239000000203 mixture Substances 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 6
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 6
- 230000003197 catalytic effect Effects 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000006356 dehydrogenation reaction Methods 0.000 description 5
- 238000011282 treatment Methods 0.000 description 5
- 239000008096 xylene Substances 0.000 description 5
- 150000003738 xylenes Chemical class 0.000 description 5
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical group CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 4
- 238000001354 calcination Methods 0.000 description 4
- IVSZLXZYQVIEFR-UHFFFAOYSA-N m-xylene Chemical group CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 2
- 238000007792 addition Methods 0.000 description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 238000004587 chromatography analysis Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 230000006870 function Effects 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000007363 ring formation reaction Methods 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 239000001119 stannous chloride Substances 0.000 description 2
- 235000011150 stannous chloride Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- MRMOZBOQVYRSEM-UHFFFAOYSA-N tetraethyllead Chemical compound CC[Pb](CC)(CC)CC MRMOZBOQVYRSEM-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 101100281518 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) fox-2 gene Proteins 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000005899 aromatization reaction Methods 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 229910001510 metal chloride Inorganic materials 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000004876 x-ray fluorescence Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
- C10G35/06—Catalytic reforming characterised by the catalyst used
- C10G35/085—Catalytic reforming characterised by the catalyst used containing platinum group metals or compounds thereof
- C10G35/09—Bimetallic catalysts in which at least one of the metals is a platinum group metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
- B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
- B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7913029A FR2457318A1 (fr) | 1979-05-22 | 1979-05-22 | Catalyseurs d'hydrotraitement d'hydrocarbures et applications desdits catalyseurs |
| FR79/13029 | 1979-05-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1137964A true CA1137964A (en) | 1982-12-21 |
Family
ID=9225737
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000352218A Expired CA1137964A (en) | 1979-05-22 | 1980-05-20 | Catalysts for the hydrotreatment of hydrocarbons and use thereof in the reforming and isomerization of hydrocarbons in the presence of hydrogen |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US4329258A (enExample) |
| EP (1) | EP0020240B1 (enExample) |
| JP (1) | JPS5695338A (enExample) |
| AU (1) | AU532666B2 (enExample) |
| CA (1) | CA1137964A (enExample) |
| DE (1) | DE3061998D1 (enExample) |
| FR (1) | FR2457318A1 (enExample) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4430517A (en) | 1981-12-02 | 1984-02-07 | Uop Inc. | Dehydrogenation process using a catalytic composition |
| CA1212374A (en) * | 1981-12-02 | 1986-10-07 | Tamotsu Imai | Dehydrogenation catalyst composition |
| NL8202647A (nl) * | 1982-07-01 | 1984-02-01 | Shell Int Research | Werkwijze voor de bereiding van een katalysator. |
| US4506032A (en) * | 1983-03-22 | 1985-03-19 | Uop Inc. | Dehydrogenation catalyst composition |
| US4595673A (en) * | 1984-11-29 | 1986-06-17 | Uop Inc. | Dehydrogenation catalyst compositions and method of their preparation |
| AU581519B2 (en) * | 1984-11-29 | 1989-02-23 | Uop Inc. | Hydrocarbon conversion catalyst containing a bifurcated alkali component |
| GB8518820D0 (en) | 1985-07-25 | 1985-08-29 | British Petroleum Co Plc | Chemical process |
| FR2603044B1 (fr) * | 1986-08-25 | 1988-11-04 | Inst Francais Du Petrole | Procede de regeneration d'un catalyseur d'hydroconversion d'hydrocarbures |
| BE1002425A4 (fr) * | 1988-02-11 | 1991-02-05 | Fina Research | Procede de preparation de catalyseurs contenant un metal du groupe du platine. |
| BE1002043A3 (fr) * | 1988-02-11 | 1990-06-05 | Fina Research | Procede de deshydrogenation catalytique d'hydrocarbures paraffiniques. |
| EP0328507B1 (en) * | 1988-02-11 | 1991-06-19 | Fina Research S.A. | Process for preparing catalysts containing a metal of the platinum group, and uses thereof |
| CA2019846A1 (en) * | 1989-07-03 | 1991-01-03 | William C. Baird, Jr. | Platinum-tin containing reforming catalysts and reforming process |
| US5015614A (en) * | 1989-07-03 | 1991-05-14 | Exxon Research And Engineering Company | Novel alumina support materials |
| US4966879A (en) * | 1989-07-03 | 1990-10-30 | Exxon Research & Engineering Company | Novel platinum-iridium reforming catalysts |
| US4966880A (en) * | 1989-07-03 | 1990-10-30 | Exxon Research & Engineering Company | Novel platinum-tin-alumina reforming catalysts |
| US5013704A (en) * | 1989-07-03 | 1991-05-07 | Exxon Research And Engineering Company | Novel platinum-rhenium-alumina catalysts for reforming |
| US4966881A (en) * | 1989-07-03 | 1990-10-30 | Exxon Research & Engineering Company | Novel platinum-alumina reforming catalysts |
| US4966878A (en) * | 1989-07-03 | 1990-10-30 | Exxon Research & Engineering Company | Novel platinum agglomerated iridium catalysts |
| FR2704864B1 (fr) | 1993-05-06 | 1995-11-17 | Inst Francais Du Petrole | Procede d'hydroreformage catalytique. |
| US5736478A (en) * | 1995-03-24 | 1998-04-07 | Wisconsin Alumni Research Foundation | Catalyst to dehydrogenate paraffin hydrocarbons |
| FR2735487B1 (fr) * | 1995-06-16 | 1997-08-22 | Inst Francais Du Petrole | Procede de transformation catalytique d'hydrocarbures en composes aromatiques avec un catalyseur contenant des metaux alcalins ou alcalino-terreux |
| DE69514336D1 (de) | 1995-06-23 | 2000-02-10 | Indian Petrochemicals Corp Ltd | Zusammengesetzter Katalysator für die Dehydrierung von paraffinen in Monoolefinen und Verfahren für seine Herstellung |
| US9199893B2 (en) | 2014-02-24 | 2015-12-01 | Uop Llc | Process for xylenes production |
| US20150239802A1 (en) * | 2014-02-24 | 2015-08-27 | Uop Llc | High temperature reforming process and catalyst for use therein |
| US11097257B2 (en) | 2019-09-10 | 2021-08-24 | Saudi Arabian Oil Company | Catalytic hydrocarbon dehydrogenation |
| US11338269B2 (en) | 2019-09-10 | 2022-05-24 | Saudi Arabian Oil Company | Catalytic hydrocarbon dehydrogenation |
| FR3156335A1 (fr) | 2023-12-06 | 2025-06-13 | Axens | Catalyseur de reformage catalytique ayant une acidite optimisee |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2651598A (en) * | 1951-03-17 | 1953-09-08 | Atlantic Refining Co | Reforming process and catalyst |
| US3783123A (en) * | 1970-03-09 | 1974-01-01 | Union Oil Co | Hydrocarbon conversion process |
| US3851003A (en) * | 1970-12-28 | 1974-11-26 | Universal Oil Prod Co | Dehydrogenation method and multicomponent catalytic composite for use therein |
| US3846281A (en) * | 1972-04-03 | 1974-11-05 | Exxon Research Engineering Co | Platinum-magnesium reforming catalyst |
| US3998900A (en) * | 1973-03-05 | 1976-12-21 | Universal Oil Products Company | Dehydrogenation of hydrocarbons with a multimetallic catalytic composite |
| US3968053A (en) * | 1973-10-12 | 1976-07-06 | Universal Oil Products Company | Catalytic reforming with an activated bimetallic catalytic composite |
| US3915845A (en) * | 1973-12-06 | 1975-10-28 | Universal Oil Prod Co | Hydrocarbon conversion with a multimetallic catalytic composite |
| US3926779A (en) * | 1974-01-21 | 1975-12-16 | Texaco Inc | Upgrading of paraffinic gasoline blending components by cyclization with a platinum/magnesium oxide alumina matrix catalyst |
| US4003852A (en) * | 1974-04-08 | 1977-01-18 | Uop Inc. | Nonacidic multimetallic dehydrogenation catalyst |
| US4141817A (en) * | 1976-10-04 | 1979-02-27 | Exxon Research & Engineering Co. | Hydrocarbon conversion processes utilizing a catalyst comprising a Group VIII noble metal component supported on Group IIA metal oxide-refractory metal oxide supports |
-
1979
- 1979-05-22 FR FR7913029A patent/FR2457318A1/fr active Granted
-
1980
- 1980-05-20 CA CA000352218A patent/CA1137964A/en not_active Expired
- 1980-05-21 AU AU58616/80A patent/AU532666B2/en not_active Ceased
- 1980-05-21 EP EP80400705A patent/EP0020240B1/fr not_active Expired
- 1980-05-21 US US06/152,126 patent/US4329258A/en not_active Expired - Lifetime
- 1980-05-21 DE DE8080400705T patent/DE3061998D1/de not_active Expired
- 1980-05-22 JP JP6837980A patent/JPS5695338A/ja active Pending
-
1981
- 1981-12-14 US US06/330,102 patent/US4363721A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| DE3061998D1 (en) | 1983-03-24 |
| EP0020240A1 (fr) | 1980-12-10 |
| US4329258A (en) | 1982-05-11 |
| AU532666B2 (en) | 1983-10-06 |
| AU5861680A (en) | 1980-11-27 |
| US4363721A (en) | 1982-12-14 |
| FR2457318B1 (enExample) | 1984-02-17 |
| FR2457318A1 (fr) | 1980-12-19 |
| JPS5695338A (en) | 1981-08-01 |
| EP0020240B1 (fr) | 1983-02-16 |
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