CA1133933A - Method for treating effluent gas from sulfonation process - Google Patents
Method for treating effluent gas from sulfonation processInfo
- Publication number
- CA1133933A CA1133933A CA338,901A CA338901A CA1133933A CA 1133933 A CA1133933 A CA 1133933A CA 338901 A CA338901 A CA 338901A CA 1133933 A CA1133933 A CA 1133933A
- Authority
- CA
- Canada
- Prior art keywords
- oleum
- gas
- vapor
- lean
- feed stock
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims abstract description 36
- 238000006277 sulfonation reaction Methods 0.000 title abstract description 31
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 21
- 239000011593 sulfur Substances 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 34
- 239000007788 liquid Substances 0.000 claims description 16
- 239000012298 atmosphere Substances 0.000 claims description 10
- 239000003208 petroleum Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 5
- 239000010779 crude oil Substances 0.000 claims description 4
- 238000007599 discharging Methods 0.000 claims description 4
- 239000003921 oil Substances 0.000 claims description 4
- 230000003197 catalytic effect Effects 0.000 claims description 3
- 239000003518 caustics Substances 0.000 claims description 3
- 230000002378 acidificating effect Effects 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 239000007789 gas Substances 0.000 abstract description 45
- 239000006096 absorbing agent Substances 0.000 abstract description 32
- 229930195733 hydrocarbon Natural products 0.000 abstract description 9
- 150000002430 hydrocarbons Chemical class 0.000 abstract description 9
- 239000003795 chemical substances by application Substances 0.000 abstract description 5
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 172
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 56
- 235000011149 sulphuric acid Nutrition 0.000 description 21
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 10
- 239000004215 Carbon black (E152) Substances 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 5
- 229910002092 carbon dioxide Inorganic materials 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003595 mist Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000001473 noxious effect Effects 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 238000005201 scrubbing Methods 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- -1 "detergent alkylate" Chemical class 0.000 description 1
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000000779 depleting effect Effects 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000012717 electrostatic precipitator Substances 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910001935 vanadium oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B45/00—Formation or introduction of functional groups containing sulfur
- C07B45/02—Formation or introduction of functional groups containing sulfur of sulfo or sulfonyldioxy groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Treating Waste Gases (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/024,895 US4251456A (en) | 1979-03-29 | 1979-03-29 | Method for treating effluent gas from sulfonation process |
| US024,895 | 1979-03-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1133933A true CA1133933A (en) | 1982-10-19 |
Family
ID=21822917
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA338,901A Expired CA1133933A (en) | 1979-03-29 | 1979-10-31 | Method for treating effluent gas from sulfonation process |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US4251456A (enExample) |
| CA (1) | CA1133933A (enExample) |
| FR (1) | FR2452472A1 (enExample) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106044721A (zh) * | 2016-05-27 | 2016-10-26 | 新疆金塔投资（集团）有限公司 | 磺化反应尾气循环利用的方法 |
| CN114288829B (zh) * | 2021-12-29 | 2023-03-17 | 赞宇科技集团股份有限公司 | 一种aes尾气吸收液综合回收装置及回收工艺 |
| CN116903497B (zh) * | 2023-09-11 | 2024-03-29 | 南京为先科技有限责任公司 | 一种三氧化硫膜式磺化制备磺酸盐表面活性剂的方法 |
| CN118894797B (zh) * | 2024-07-10 | 2025-07-08 | 南京为先科技有限责任公司 | 一种基于尾气回掺的气液两相膜反应制备表面活性剂的方法 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB791995A (en) * | 1956-07-17 | 1958-03-19 | Shell Res Ltd | Sulphonation of organic liquids |
| FR1540232A (fr) * | 1966-10-11 | 1968-09-20 | Allied Chem | Procédé perfectionné de sulfonation de composés organiques |
| SE7407422L (sv) * | 1974-06-05 | 1975-12-08 | Modokemi Ab | Forbettrat forfarande vid kontinuerlig sulfonering och/eller sulfatering av organiska emnen |
-
1979
- 1979-03-29 US US06/024,895 patent/US4251456A/en not_active Expired - Lifetime
- 1979-10-31 CA CA338,901A patent/CA1133933A/en not_active Expired
-
1980
- 1980-03-28 FR FR8006966A patent/FR2452472A1/fr active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| US4251456A (en) | 1981-02-17 |
| FR2452472A1 (fr) | 1980-10-24 |
| FR2452472B1 (enExample) | 1984-01-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |