CA1133236A - Flue gas scrubbing process using fly ash alkali - Google Patents
Flue gas scrubbing process using fly ash alkaliInfo
- Publication number
- CA1133236A CA1133236A CA343,324A CA343324A CA1133236A CA 1133236 A CA1133236 A CA 1133236A CA 343324 A CA343324 A CA 343324A CA 1133236 A CA1133236 A CA 1133236A
- Authority
- CA
- Canada
- Prior art keywords
- scrubber
- fly ash
- slurry
- scrubber slurry
- flue gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000010881 fly ash Substances 0.000 title claims abstract description 63
- 239000003546 flue gas Substances 0.000 title claims abstract description 30
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims abstract description 29
- 238000005201 scrubbing Methods 0.000 title abstract description 13
- 239000003513 alkali Substances 0.000 title description 28
- 239000002002 slurry Substances 0.000 claims abstract description 69
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims abstract description 44
- 239000007787 solid Substances 0.000 claims abstract description 34
- 239000006228 supernatant Substances 0.000 claims abstract description 32
- 239000002699 waste material Substances 0.000 claims abstract description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 16
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 5
- -1 alkali metal cations Chemical class 0.000 claims abstract description 5
- 239000002253 acid Substances 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 8
- 238000002386 leaching Methods 0.000 claims description 6
- 238000004064 recycling Methods 0.000 claims 2
- 230000002378 acidificating effect Effects 0.000 claims 1
- 239000007789 gas Substances 0.000 abstract description 7
- 238000005086 pumping Methods 0.000 abstract description 7
- 239000003245 coal Substances 0.000 abstract description 6
- 239000002562 thickening agent Substances 0.000 abstract description 5
- 230000008901 benefit Effects 0.000 abstract description 4
- 235000019738 Limestone Nutrition 0.000 description 11
- 150000001768 cations Chemical class 0.000 description 11
- 239000006028 limestone Substances 0.000 description 11
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 9
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 6
- 235000011941 Tilia x europaea Nutrition 0.000 description 6
- 239000006096 absorbing agent Substances 0.000 description 6
- 239000004571 lime Substances 0.000 description 6
- 239000011575 calcium Substances 0.000 description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
- 229910052791 calcium Inorganic materials 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 2
- 239000002956 ash Substances 0.000 description 2
- 239000012065 filter cake Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- 238000005200 wet scrubbing Methods 0.000 description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- 241000274177 Juniperus sabina Species 0.000 description 1
- 241001397173 Kali <angiosperm> Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910052936 alkali metal sulfate Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 239000011365 complex material Substances 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 239000012717 electrostatic precipitator Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 235000001520 savin Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 230000000153 supplemental effect Effects 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treating Waste Gases (AREA)
- Incineration Of Waste (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/018,291 US4228139A (en) | 1979-03-06 | 1979-03-06 | Flue gas scrubbing process using fly ash alkali |
| US18,291 | 1979-03-06 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1133236A true CA1133236A (en) | 1982-10-12 |
Family
ID=21787198
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA343,324A Expired CA1133236A (en) | 1979-03-06 | 1980-01-09 | Flue gas scrubbing process using fly ash alkali |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4228139A (cg-RX-API-DMAC7.html) |
| EP (1) | EP0017348B1 (cg-RX-API-DMAC7.html) |
| JP (1) | JPS55121825A (cg-RX-API-DMAC7.html) |
| AU (1) | AU533856B2 (cg-RX-API-DMAC7.html) |
| BR (1) | BR7907829A (cg-RX-API-DMAC7.html) |
| CA (1) | CA1133236A (cg-RX-API-DMAC7.html) |
| DE (1) | DE3069256D1 (cg-RX-API-DMAC7.html) |
| DK (1) | DK149603C (cg-RX-API-DMAC7.html) |
| NO (1) | NO151311C (cg-RX-API-DMAC7.html) |
| ZA (1) | ZA795064B (cg-RX-API-DMAC7.html) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4366133A (en) * | 1981-06-01 | 1982-12-28 | Combustion Engineering, Inc. | Process for limiting chloride buildup in SO2 scrubber slurry |
| DE3241540A1 (de) * | 1982-11-10 | 1984-05-10 | L. & C. Steinmüller GmbH, 5270 Gummersbach | Verfahren zur fortlaufenden entnahme von waschsuspension mit erhoehter feststoffkonzentration aus einem waschturm einer mit kalk oder kalkstein als absorptionsmittel arbeitenden rauchgasentschwefelungsanlage |
| US5100633A (en) * | 1985-11-07 | 1992-03-31 | Passamaquoddy Technology Limited Partnership | Method for scrubbing pollutants from an exhaust gas stream |
| US4716027A (en) * | 1986-07-25 | 1987-12-29 | Passamaquoddy Tribe, A Sovereign Indian Tribe Recognized By The Government Of The United States Of America | Method for simultaneously scrubbing cement kiln exhaust gas and producing useful by-products therefrom |
| US4708855A (en) * | 1985-11-07 | 1987-11-24 | Passanaquoddy Tribe | Method and system for exhaust gas stream scrubbing |
| ES292673Y (es) * | 1986-03-03 | 1987-03-01 | Depurator, S.A. | Dispositivo depurador de gases de combustion |
| AT389238B (de) * | 1987-08-18 | 1989-11-10 | Simmering Graz Pauker Ag | Verfahren zur behandlung der rauchgase und verbrennungsrueckstaende einer verbrennungsanlage, insbesondere abfallverbrennungsanlage |
| NZ225964A (en) * | 1987-09-16 | 1991-11-26 | Passamaquoddy Tribe | Scrubbing acid gases from exhaust stream using slurry of ash |
| JPH08318123A (ja) * | 1995-05-26 | 1996-12-03 | Mitsubishi Heavy Ind Ltd | スラリ濃縮槽及び湿式排煙脱硫装置の吸収塔 |
| CN101247878B (zh) * | 2005-08-26 | 2013-05-08 | 太平洋水泥株式会社 | 溶解反应装置及方法 |
| WO2007081561A2 (en) * | 2006-01-03 | 2007-07-19 | University Of Wyoming | Apparatus and method for sequestering flue gas co2 |
| US8506918B2 (en) * | 2006-01-03 | 2013-08-13 | University Of Wyoming | Apparatus and method to sequester contaminants |
| US8673257B2 (en) * | 2006-01-03 | 2014-03-18 | University Of Wyoming | Apparatus and method to sequester contaminants |
| US11485649B2 (en) * | 2015-09-03 | 2022-11-01 | Questor Technology Inc. | System for reducing produced water disposal volumes utilizing waste heat |
| CN105477963A (zh) * | 2015-12-01 | 2016-04-13 | 宁夏启元药业有限公司 | 一种燃煤锅炉烟气环保深度治理的方法及其装置 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB396969A (en) * | 1931-11-10 | 1933-08-17 | Metallgesellschaft Ag | Process for removing acid constituents from gases, and rendering said constituents utilisable |
| US4002724A (en) * | 1973-10-11 | 1977-01-11 | Mckie R Thomas | Sulfur dioxide collection |
| US4080428A (en) * | 1974-09-19 | 1978-03-21 | Heinz Holter | Process for the purification of flue and other waste gas |
| DE2642326A1 (de) * | 1976-09-21 | 1978-03-23 | Saarbergwerke Ag | Verfahren zum reinigen von rauchgasen |
| US4164547A (en) * | 1977-05-06 | 1979-08-14 | American Air Filter Company, Inc. | Process for removing sulfur dioxide in a wet scrubber |
-
1979
- 1979-03-06 US US06/018,291 patent/US4228139A/en not_active Expired - Lifetime
- 1979-09-25 ZA ZA00795064A patent/ZA795064B/xx unknown
- 1979-10-30 AU AU52335/79A patent/AU533856B2/en not_active Ceased
- 1979-11-15 JP JP14831079A patent/JPS55121825A/ja active Granted
- 1979-11-30 BR BR7907829A patent/BR7907829A/pt not_active IP Right Cessation
-
1980
- 1980-01-09 CA CA343,324A patent/CA1133236A/en not_active Expired
- 1980-03-04 NO NO800616A patent/NO151311C/no unknown
- 1980-03-05 DK DK94080A patent/DK149603C/da not_active IP Right Cessation
- 1980-03-06 EP EP80300688A patent/EP0017348B1/en not_active Expired
- 1980-03-06 DE DE8080300688T patent/DE3069256D1/de not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| NO151311B (no) | 1984-12-10 |
| NO800616L (no) | 1980-09-08 |
| DK94080A (da) | 1980-09-07 |
| JPS55121825A (en) | 1980-09-19 |
| DK149603C (da) | 1987-01-05 |
| DK149603B (da) | 1986-08-11 |
| NO151311C (no) | 1985-03-20 |
| AU5233579A (en) | 1980-09-11 |
| EP0017348B1 (en) | 1984-09-26 |
| BR7907829A (pt) | 1980-10-14 |
| JPS6336818B2 (cg-RX-API-DMAC7.html) | 1988-07-21 |
| US4228139A (en) | 1980-10-14 |
| ZA795064B (en) | 1980-09-24 |
| AU533856B2 (en) | 1983-12-15 |
| DE3069256D1 (en) | 1984-10-31 |
| EP0017348A1 (en) | 1980-10-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |