CA1128693A - Bulk anionic polymerisation process using an alkali metal amide and the salt of the same alkali metal with a hydroxylic compound - Google Patents

Bulk anionic polymerisation process using an alkali metal amide and the salt of the same alkali metal with a hydroxylic compound

Info

Publication number
CA1128693A
CA1128693A CA316,663A CA316663A CA1128693A CA 1128693 A CA1128693 A CA 1128693A CA 316663 A CA316663 A CA 316663A CA 1128693 A CA1128693 A CA 1128693A
Authority
CA
Canada
Prior art keywords
alkali metal
initiator
amide
polymerization
process according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA316,663A
Other languages
English (en)
French (fr)
Inventor
Sylvie Boileau
Serge Lecolier
Serge Raynal
Gilberte Ndebeka
Paul Caubere
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Societe Nationale des Poudres et Explosifs
Original Assignee
Societe Nationale des Poudres et Explosifs
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Societe Nationale des Poudres et Explosifs filed Critical Societe Nationale des Poudres et Explosifs
Application granted granted Critical
Publication of CA1128693A publication Critical patent/CA1128693A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
    • C08G69/14—Lactams
    • C08G69/16—Preparatory processes
    • C08G69/18—Anionic polymerisation
    • C08G69/20—Anionic polymerisation characterised by the catalysts used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/46—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/823—Preparation processes characterised by the catalyst used for the preparation of polylactones or polylactides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2648—Alkali metals or compounds thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CA316,663A 1977-11-23 1978-11-22 Bulk anionic polymerisation process using an alkali metal amide and the salt of the same alkali metal with a hydroxylic compound Expired CA1128693A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR77.35221 1977-11-23
FR7735221A FR2410005A1 (fr) 1977-11-23 1977-11-23 Procede de polymerisation anionique en masse a l'aide d'amidure d'un metal alcalin et d'un hydroxylate du meme metal alcalin

Publications (1)

Publication Number Publication Date
CA1128693A true CA1128693A (en) 1982-07-27

Family

ID=9197949

Family Applications (1)

Application Number Title Priority Date Filing Date
CA316,663A Expired CA1128693A (en) 1977-11-23 1978-11-22 Bulk anionic polymerisation process using an alkali metal amide and the salt of the same alkali metal with a hydroxylic compound

Country Status (8)

Country Link
US (1) US4243787A (US07582779-20090901-C00044.png)
EP (1) EP0002159B1 (US07582779-20090901-C00044.png)
JP (1) JPS5483083A (US07582779-20090901-C00044.png)
CA (1) CA1128693A (US07582779-20090901-C00044.png)
DE (1) DE2861096D1 (US07582779-20090901-C00044.png)
ES (1) ES475224A1 (US07582779-20090901-C00044.png)
FR (1) FR2410005A1 (US07582779-20090901-C00044.png)
IT (1) IT1109583B (US07582779-20090901-C00044.png)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS591509A (ja) * 1982-05-21 1984-01-06 Daicel Chem Ind Ltd 重合性高分子の製造方法
US4910274A (en) * 1987-11-27 1990-03-20 The Dow Chemical Company Preparation of monohydroxy-containing polymers
US5483008A (en) * 1992-02-07 1996-01-09 Research Development Corporation Of Japan Polyether having heterofunctional groups at both ends, process for the preparation thereof and polymerization initiator therefor
JP2593032B2 (ja) * 1992-02-07 1997-03-19 新技術事業団 両末端ヘテロ官能性ポリエーテル並びに該ポリエーテルを製造する方法及び重合開始剤
US5475073A (en) * 1994-11-18 1995-12-12 Arco Chemical Technology, L.P. Hydroxy-functional acrylate resins
DE19646066A1 (de) * 1996-11-08 1998-05-14 Basf Ag Initiatorsysteme für die anionische Polymerisation von Vinylmonomeren mit polaren Gruppen
FR2761996B1 (fr) * 1997-04-10 1999-06-25 Atochem Elf Sa Systeme d'amorcage comprenant un ligand aminoalcoolate pour la (co)polymerisation anionique de monomere(s) (meth)acryliques et procede l'utilisant
FR2761997B1 (fr) 1997-04-10 2003-09-05 Atochem Elf Sa Systeme d'armorcage comprenant un ligand heterocyclique pour la polymerisation anionique de menomere(s) (meth)acrylique(s) et procede de polymerisation l'utilisant
US9012598B2 (en) * 2012-08-01 2015-04-21 Seeo, Inc. Poly(ethyleneoxide) functionalization through alkylation
US10488753B2 (en) 2015-09-08 2019-11-26 Canon Kabushiki Kaisha Substrate pretreatment and etch uniformity in nanoimprint lithography
US10509313B2 (en) 2016-06-28 2019-12-17 Canon Kabushiki Kaisha Imprint resist with fluorinated photoinitiator and substrate pretreatment for reducing fill time in nanoimprint lithography

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2849432A (en) * 1956-02-06 1958-08-26 Firestone Tire & Rubber Co Polymerization of diolefines
BE585501A (US07582779-20090901-C00044.png) * 1958-12-13 1900-01-01
NL300980A (US07582779-20090901-C00044.png) * 1962-12-03
DE2355941A1 (de) * 1973-11-09 1975-05-15 Bayer Ag Polymerisation und copolymerisation von dienen
DE2449784A1 (de) * 1974-10-19 1976-04-22 Bayer Ag Polymerisation und copolymerisation von dienen
FR2352834A1 (fr) * 1977-05-23 1977-12-23 Poudres & Explosifs Ste Nale Initiateurs de polymerisation anionique a base d'amidures alcalins et procede de polymerisation anionique les utilisant

Also Published As

Publication number Publication date
FR2410005B1 (US07582779-20090901-C00044.png) 1980-05-23
US4243787A (en) 1981-01-06
EP0002159A1 (fr) 1979-05-30
JPS5483083A (en) 1979-07-02
IT1109583B (it) 1985-12-23
FR2410005A1 (fr) 1979-06-22
ES475224A1 (es) 1979-04-01
EP0002159B1 (fr) 1981-09-16
DE2861096D1 (en) 1981-12-03
IT7869672A0 (it) 1978-11-22

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