CA1125659A - Fatty alcohol with liquid siloxane to form powder product - Google Patents
Fatty alcohol with liquid siloxane to form powder productInfo
- Publication number
- CA1125659A CA1125659A CA336,164A CA336164A CA1125659A CA 1125659 A CA1125659 A CA 1125659A CA 336164 A CA336164 A CA 336164A CA 1125659 A CA1125659 A CA 1125659A
- Authority
- CA
- Canada
- Prior art keywords
- siloxane
- stick
- slurry
- fatty alcohol
- perspirant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Landscapes
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
FATTY ALCOHOL WITH LIQUID SILOXANE
TO FORM POWDER PRODUCT
Abstract of the Disclosure A powder stick composition for topical application, and particularly a powder stick containing an anti-perspirant as an active ingredient. The stick is produced by incorporat-ing an active ingredient, a finely divided inert filler, and a fatty alcohol with a siloxane at an elevated temperature to form a slurry. The slurry is then molded into stick form at atmospheric pressure, and the molded stick is dried to evap-orate a major portion of the siloxane. The resulting stick is firm, has a uniform distribution of the active ingredient throughout the cross section and has excellent pay-off characteristics.
TO FORM POWDER PRODUCT
Abstract of the Disclosure A powder stick composition for topical application, and particularly a powder stick containing an anti-perspirant as an active ingredient. The stick is produced by incorporat-ing an active ingredient, a finely divided inert filler, and a fatty alcohol with a siloxane at an elevated temperature to form a slurry. The slurry is then molded into stick form at atmospheric pressure, and the molded stick is dried to evap-orate a major portion of the siloxane. The resulting stick is firm, has a uniform distribution of the active ingredient throughout the cross section and has excellent pay-off characteristics.
Description
~25~
Background of the Invention .
Antiperspirant products are frequently produced in stick form, such as wax sticks, soap gel sticks, and pressed powder sticks. A wax stick, in addition to the antiperspirant active ingredient, is composed of waxes and esters and contains a relatively high percentage of a solvent. Wax stickshave certain inherent disadvantages in that the waxes have a ten-dency to stain clothing~ and the wax residue cannot be removed from the clothing by normal washing procedures. As the wax stick contains a high proportion of solvent, the solvent will evaporate if the stick is unsealed and exposed to the atmosphere, thereby resulting in shrinkage and'dog-boning" of the stick, with a resulting unattractive appearance.
As the wax stick has a relatively high propo~tion of solvent, this reduces -the proportion of active ingredient that can be included in the stick, limitinq the active ingredient to a maximum percentage of about ~0%.
Soap gel anti-perspirant sticks have also been used in the past.~ The conventional soap gel system includes sodium ~; 20 stearate and a low molecular weight alcohol, such as ethanol, ; as well as an anti-perspirant active ingredient in a maximum amount of about 20~. In addition, soap gel sticks have nor-mally used calcium carbonate as a filler. Because of the hygros-~ copic nature of the ingredients, the product has a tendency to -~ 25 absorb water, expand and crack. Furthermore, the calcium " carbonate filler tends to neutralize the anti-perspirant, which is normally aluminum chlorohydra-te, thereby rendering the anti-perspirant salt ineffective. As a further disad~antage, the alcohol will evaporate ir the stick is exposed to the atmos-phere, causing shrinking and "dog-boning" of the stlck.
s~c:~
Attempts have also been made in the past to provide a dry, pressed powder, anti-perspirant stick. In sticks of this type, the active ingredient is incorpora-ted with an inert filler and binder and the dry mixture is compressed or extruded at high pressure into stick form. The compression operation is slow and requires a dwell of several minutes at hi~h pressure, making the process unsatisfactory from a commercial standpoint.
Extrusion of the dry mixture is particularly difficult due to the abrasive nature of the dry powdered mixture. Further, in both compressing and extruding processes, the anti-perspirant active ingredient is damaging to the expensive processin~
equipment.
Summary of the Invention -- . _ .
The invention is directed to a powder stick for ` 15 topical application, such as an anti-perspirant stick, or a cosmetic stick, which is produced without the application of super-at-mospheric pressures~ In preparing the stic~, the active ingredient, a Eatty alcohol and a finely divide~ inert filler are mixea with li~uid siloxane at an eleva~ed temperature to ~orm a slurry. The slurry is then molded into a stick form at atmospheric pressure, and after molding, the stick is dried in air to evaporate a major portion of the siloxane.-The resulting powder stick is hard and firm for stickstrength, but yet will not glaze over during application to the skin.
As the dried stick has a relatively low residual propor-tion o~ the siloxane solvent, the stick is stable and will retain its shape and consistency, even if unsealed and exposed -to the atmosphere for extended periods of time.
3Q The liquid siloxane serves to disperse the fatty alcohol .
. .
5~9 and results in a uniform distribution of the fatty alcohol through-out th~ filler, thereby providing uniform characteristics for the.
stick throughout its entire cross-section. The uniform dis tribution of the ingredients results in the stick being resistant S to humidity absoxption and prevents degradation of the stick : under high.humidity conditions. ' ~ , As the siloxane is substantially entirely evaporated prior to packaging, the stick contains a high proportion of powder form ingredients, generally up to 90%.
Other objects and advantages will appear in the course of the followin~ description.
Description of the Preferred Embodiment The powder stick of the invention is pre~ared from a slurry having the following general formula-tion in weight percen-t:
Finely divided inert fi:ller 7.0~ to I0%
Fatty alcohol 5% to 30%
Siloxane 25% to 60%' When preparing an anti-perspirant stick ac~ording to the invention, the slurry has the following formulation in weight percent:
Finely divided inert filler 66% to :-3%
Anti-perspirant active ingredient 10% to 35%
Fatty alchol 4% to 12 Siloxane 20% to 50%
When preparing deodorant sticks according to the invention the slurry has the following formulation in weight percent:
Finely divided inert filler 69.9% to --5%
Fatty alcohol 5% to 30%
Deodorant active ingredient 0.1% to 5%
Siloxane 25% to 60 s~
In preparing a costmetic stick according to the invention, such as an eye shadow stick or blush stickl the slurry used in preparing the stick h~s the following formulation in weight percent:
Finely divided inert filler 75% to .3%
Fatty alcohol 4% to 12~
Cosmetic coloring materials 1% to 35%
Siloxane 20% to 50%
~ The finely divided filler can take the form of materials .~ 10 such as aluminum hydroxide, koalin, talc, mica, corn starch, calcium carbonate, silicon dioxide, calcined clay, barium sulfate, .
aluminum oxide, aluminum silicate, and the like.
The fatty alcohols serve as a binder for the system .; and contain from 12 to 22 carbon atoms in the molecule. The : 15 fatty alcohol can take the form of cetyl alcohol, stearyl alcohol, ; and the like.
The siloxane is normally a l.iquid at room temperature.
Chemically it is composed primarily of two components-: D4 cyclo- :
dimethicone and D5 cyclodimethicone. The D4 component repres-:1 20 ents the ma~ority with the D5 being a minor constituent.
Chemically D4 cyclodimethicone may be symbolically written as:
_ _ .
~ C13 r L~
: 1 4 ll ~
.:
and D5 cyclodimethicone may be symbolically wri-tten as:
si - o 3 I .
I 5 ~ .
When preparing an anti-perspirant stick, the anti-perspirant active ingredient can be aluminum chlorohydrate, aluminum hydroxychloride, zirconium hydroxy chloride, aluminum chloride, or other acceptable anti-perspirant materials.
When forming a deodorant stick, the deodorant active ingredient can take the form of:
(A) - 2,4,4' - trichloro - 2'hydroxydiphenyl ether (B) - 1,-(2-hydroxyethyl) carbamoyl methyl pyridinium chloride laurate (C) - Benzenthonium chloride (D) - Zinc phenolsulfonate (E~ - Aluminum chlorohydroxide When preparing a cosmetic coloring stick, such as an eye shadow stick or blush stick, the cosmetically acceptable coloring materials can take the form of titanium dioxide, ferric ferrocyanide or ferric ammonium ferrocyanide, iron oxides, ultramarines, chromium oxide, chromium hydroxide, pearlescents, organic dyes and lakes.
In addition to the above ingredients, the slurry can also contain small amounts, up to 2% by weight, of a fatty acid ester containing from 12 to 22 carbon atoms, such as iso-propyl myristate or isopropyl palmitate, which prevents dusting of the stick; and/or magnesium stearate which aid in preventing glazing ~.
565~
of the stick; and/or a preservative such as methyl paraben or propyl paraben; or perfumes.
To prepare the powder stick of the învention, the fatty alcohol is dispersed in the liquid siloxane at a tempera-ture of 60C to 70C. The remaining ingredients,such as thefiller, active ingredient and other additives,are then mixed into the liquid dispersion to provide a slurry. The slurry is then poured ~y gravity at atmospheric temperature into a case or mold. The slurry at this time has a temperature slightly above the solidif~cationtemperature of the siloxane and generally in the range of about 50C to 60C. On cooling, the slurry will solidify to form a solid stick.
The stick is then exposed to air movement, either by blowing air over the molded product or subjecting the molded product to a vacuum. In practice, the drying air preferably l has a relative humidity of about 15% and is at a temperature in the range of about 25C to 30C~ The air movement serves to evaporate a major portion of the siloxane from the molded product so that the dried product has a residual siloxane content ~f less than 2% by weight. While it is possible to evaporate the entire siloxane content, it is normally uneconomical to go beyond the 2~ level though this can be accomplished by varia-tions in relative humidity and atmospheric pressure.
As ~he siloxane is a relatively expensive material, it is preferred to carry out the drying in a closed chamber or hood so that the siloxane vapor can be recovered for reuse through use of a condensing unit.
The resulting dried powder stick has excellent strength yet provides adequate pay-off on the skin and is not so hard that it will glaze over after several applications to the skin-S65~
Through use o~ the siloxane solvent, the powdered ingredients and the fatty alcohols are uniformly distribu~ed throughout the stick, therehy insuring the same level of effect-iveness for each application to the skin.
As the dried product contains only a minimum propor-tion o~ the evaporable siloxane, and waxes and fatty esters, the product is stable even if exposed to the atmosphere, wili remain effective over a substantial period of time and can be removed from fabric or clothing by machine washing with little or no stain effect.
The powdered stick of the invention is extremely resistant to humidity conditions and will not decompose or crumble under high humidity conditions.
As a further advantage, the product has a low level of dusting so as to be attractive to the consumer during use.
! The following formulations in weight percent illustrate the preparation of the powder stick of the invention:
AMTI-PERSPIRANT STICK:
Siloxane 28.0 Aluminum Chlorohydrate 18.0 Aluminum Hydroxide 41.6 Stearyl Alcohol 10.8 Isopropyl Myristate 0.7 Magnesium Stearate - 0.7 Perfume 0.2 ANTI-PERSPIRANT STICK:
Siloxane 28.0 Aluminum Chlorohydrate 28.8 Aluminum Hydroxide 19.6 Kaolin 10.0 Stearyl Alcohol 10.8 Isopropyl Myristate 0.7 Magnesium Silicate 0.7 Spray Dried Fragrance 1.4 5~
ANTI-PERSPIRANT STICK:
Siloxane 28.0 Aluminum Chlorohydra-te28.8 Talc 15.0 Cornstarch 15.3 Cetyl Alcohol 10.8 Isopropyl Palmitate 0.7 Magnesium Stearate 0.7 Perfume 0.7 ANTI-PERSPIRANT STICK:
Siloxane 28.0 Aluminum Chlorohydrate50.4 Kaolin 8.9 .
Stearyl ~lcohol 10.8 Isopropyl Myristatea . 7 ~:
Magnesium Stearate 0.7 Perfume 0.5 !
EYE SHADOW STICK:
Siloxane 37.00 Stearyl Alcohol 4.00 ;` . Titanium Dioxide 3.20 Oxy Black 3068 0.78 Lo Micron Umber 27366.45 Aluminum Hydroxide-38.07 ~ethyl Paraben 0.25 Propyl Paraben 0.10 - B Germall 115 ~a ~rac~f~ar/~ O.15 Flamenco Satina 100 Pearlescence ~a ~racle~k) 7.00 r~(len~
Flamenco Super Pearlescence~ 3.00 - ~
~2~5~
DEODOR~NT STICK:
Siloxane 25.00 Stearyl Alcohol 10.00 Calcium Carbonate 53.25 Cornstarch 5.00 .~ Titanium Dioxide 6.00 Triclosan (~a ~radem~flc) 0.25 Perfume 0.50 In all of the above samples, the fatty alcohol was added to the liquid siloxane at a temperature of 65C and the remaining ingredients were then blended into the liquid to form a slurry. In each case the slurry, a-t a temperature of about 55 C, was poured into plastic molds to form the sticks. Air at a temperature of 28C was passed over the sticks ~or a period 15 of 72 hours to evaporate the major proportion of the siloxane to prov.ide the finished stick composition. In each example the dried stick has a residual siloxane content of less than 2~ by weight.
:; In molding the stick, the slurry can be poured directly into a component of the final package~ or alternately, the slurry can be introduced into a separate mold and subsequently trans-forred to the package.
.
.
'.~
Background of the Invention .
Antiperspirant products are frequently produced in stick form, such as wax sticks, soap gel sticks, and pressed powder sticks. A wax stick, in addition to the antiperspirant active ingredient, is composed of waxes and esters and contains a relatively high percentage of a solvent. Wax stickshave certain inherent disadvantages in that the waxes have a ten-dency to stain clothing~ and the wax residue cannot be removed from the clothing by normal washing procedures. As the wax stick contains a high proportion of solvent, the solvent will evaporate if the stick is unsealed and exposed to the atmosphere, thereby resulting in shrinkage and'dog-boning" of the stick, with a resulting unattractive appearance.
As the wax stick has a relatively high propo~tion of solvent, this reduces -the proportion of active ingredient that can be included in the stick, limitinq the active ingredient to a maximum percentage of about ~0%.
Soap gel anti-perspirant sticks have also been used in the past.~ The conventional soap gel system includes sodium ~; 20 stearate and a low molecular weight alcohol, such as ethanol, ; as well as an anti-perspirant active ingredient in a maximum amount of about 20~. In addition, soap gel sticks have nor-mally used calcium carbonate as a filler. Because of the hygros-~ copic nature of the ingredients, the product has a tendency to -~ 25 absorb water, expand and crack. Furthermore, the calcium " carbonate filler tends to neutralize the anti-perspirant, which is normally aluminum chlorohydra-te, thereby rendering the anti-perspirant salt ineffective. As a further disad~antage, the alcohol will evaporate ir the stick is exposed to the atmos-phere, causing shrinking and "dog-boning" of the stlck.
s~c:~
Attempts have also been made in the past to provide a dry, pressed powder, anti-perspirant stick. In sticks of this type, the active ingredient is incorpora-ted with an inert filler and binder and the dry mixture is compressed or extruded at high pressure into stick form. The compression operation is slow and requires a dwell of several minutes at hi~h pressure, making the process unsatisfactory from a commercial standpoint.
Extrusion of the dry mixture is particularly difficult due to the abrasive nature of the dry powdered mixture. Further, in both compressing and extruding processes, the anti-perspirant active ingredient is damaging to the expensive processin~
equipment.
Summary of the Invention -- . _ .
The invention is directed to a powder stick for ` 15 topical application, such as an anti-perspirant stick, or a cosmetic stick, which is produced without the application of super-at-mospheric pressures~ In preparing the stic~, the active ingredient, a Eatty alcohol and a finely divide~ inert filler are mixea with li~uid siloxane at an eleva~ed temperature to ~orm a slurry. The slurry is then molded into a stick form at atmospheric pressure, and after molding, the stick is dried in air to evaporate a major portion of the siloxane.-The resulting powder stick is hard and firm for stickstrength, but yet will not glaze over during application to the skin.
As the dried stick has a relatively low residual propor-tion o~ the siloxane solvent, the stick is stable and will retain its shape and consistency, even if unsealed and exposed -to the atmosphere for extended periods of time.
3Q The liquid siloxane serves to disperse the fatty alcohol .
. .
5~9 and results in a uniform distribution of the fatty alcohol through-out th~ filler, thereby providing uniform characteristics for the.
stick throughout its entire cross-section. The uniform dis tribution of the ingredients results in the stick being resistant S to humidity absoxption and prevents degradation of the stick : under high.humidity conditions. ' ~ , As the siloxane is substantially entirely evaporated prior to packaging, the stick contains a high proportion of powder form ingredients, generally up to 90%.
Other objects and advantages will appear in the course of the followin~ description.
Description of the Preferred Embodiment The powder stick of the invention is pre~ared from a slurry having the following general formula-tion in weight percen-t:
Finely divided inert fi:ller 7.0~ to I0%
Fatty alcohol 5% to 30%
Siloxane 25% to 60%' When preparing an anti-perspirant stick ac~ording to the invention, the slurry has the following formulation in weight percent:
Finely divided inert filler 66% to :-3%
Anti-perspirant active ingredient 10% to 35%
Fatty alchol 4% to 12 Siloxane 20% to 50%
When preparing deodorant sticks according to the invention the slurry has the following formulation in weight percent:
Finely divided inert filler 69.9% to --5%
Fatty alcohol 5% to 30%
Deodorant active ingredient 0.1% to 5%
Siloxane 25% to 60 s~
In preparing a costmetic stick according to the invention, such as an eye shadow stick or blush stickl the slurry used in preparing the stick h~s the following formulation in weight percent:
Finely divided inert filler 75% to .3%
Fatty alcohol 4% to 12~
Cosmetic coloring materials 1% to 35%
Siloxane 20% to 50%
~ The finely divided filler can take the form of materials .~ 10 such as aluminum hydroxide, koalin, talc, mica, corn starch, calcium carbonate, silicon dioxide, calcined clay, barium sulfate, .
aluminum oxide, aluminum silicate, and the like.
The fatty alcohols serve as a binder for the system .; and contain from 12 to 22 carbon atoms in the molecule. The : 15 fatty alcohol can take the form of cetyl alcohol, stearyl alcohol, ; and the like.
The siloxane is normally a l.iquid at room temperature.
Chemically it is composed primarily of two components-: D4 cyclo- :
dimethicone and D5 cyclodimethicone. The D4 component repres-:1 20 ents the ma~ority with the D5 being a minor constituent.
Chemically D4 cyclodimethicone may be symbolically written as:
_ _ .
~ C13 r L~
: 1 4 ll ~
.:
and D5 cyclodimethicone may be symbolically wri-tten as:
si - o 3 I .
I 5 ~ .
When preparing an anti-perspirant stick, the anti-perspirant active ingredient can be aluminum chlorohydrate, aluminum hydroxychloride, zirconium hydroxy chloride, aluminum chloride, or other acceptable anti-perspirant materials.
When forming a deodorant stick, the deodorant active ingredient can take the form of:
(A) - 2,4,4' - trichloro - 2'hydroxydiphenyl ether (B) - 1,-(2-hydroxyethyl) carbamoyl methyl pyridinium chloride laurate (C) - Benzenthonium chloride (D) - Zinc phenolsulfonate (E~ - Aluminum chlorohydroxide When preparing a cosmetic coloring stick, such as an eye shadow stick or blush stick, the cosmetically acceptable coloring materials can take the form of titanium dioxide, ferric ferrocyanide or ferric ammonium ferrocyanide, iron oxides, ultramarines, chromium oxide, chromium hydroxide, pearlescents, organic dyes and lakes.
In addition to the above ingredients, the slurry can also contain small amounts, up to 2% by weight, of a fatty acid ester containing from 12 to 22 carbon atoms, such as iso-propyl myristate or isopropyl palmitate, which prevents dusting of the stick; and/or magnesium stearate which aid in preventing glazing ~.
565~
of the stick; and/or a preservative such as methyl paraben or propyl paraben; or perfumes.
To prepare the powder stick of the învention, the fatty alcohol is dispersed in the liquid siloxane at a tempera-ture of 60C to 70C. The remaining ingredients,such as thefiller, active ingredient and other additives,are then mixed into the liquid dispersion to provide a slurry. The slurry is then poured ~y gravity at atmospheric temperature into a case or mold. The slurry at this time has a temperature slightly above the solidif~cationtemperature of the siloxane and generally in the range of about 50C to 60C. On cooling, the slurry will solidify to form a solid stick.
The stick is then exposed to air movement, either by blowing air over the molded product or subjecting the molded product to a vacuum. In practice, the drying air preferably l has a relative humidity of about 15% and is at a temperature in the range of about 25C to 30C~ The air movement serves to evaporate a major portion of the siloxane from the molded product so that the dried product has a residual siloxane content ~f less than 2% by weight. While it is possible to evaporate the entire siloxane content, it is normally uneconomical to go beyond the 2~ level though this can be accomplished by varia-tions in relative humidity and atmospheric pressure.
As ~he siloxane is a relatively expensive material, it is preferred to carry out the drying in a closed chamber or hood so that the siloxane vapor can be recovered for reuse through use of a condensing unit.
The resulting dried powder stick has excellent strength yet provides adequate pay-off on the skin and is not so hard that it will glaze over after several applications to the skin-S65~
Through use o~ the siloxane solvent, the powdered ingredients and the fatty alcohols are uniformly distribu~ed throughout the stick, therehy insuring the same level of effect-iveness for each application to the skin.
As the dried product contains only a minimum propor-tion o~ the evaporable siloxane, and waxes and fatty esters, the product is stable even if exposed to the atmosphere, wili remain effective over a substantial period of time and can be removed from fabric or clothing by machine washing with little or no stain effect.
The powdered stick of the invention is extremely resistant to humidity conditions and will not decompose or crumble under high humidity conditions.
As a further advantage, the product has a low level of dusting so as to be attractive to the consumer during use.
! The following formulations in weight percent illustrate the preparation of the powder stick of the invention:
AMTI-PERSPIRANT STICK:
Siloxane 28.0 Aluminum Chlorohydrate 18.0 Aluminum Hydroxide 41.6 Stearyl Alcohol 10.8 Isopropyl Myristate 0.7 Magnesium Stearate - 0.7 Perfume 0.2 ANTI-PERSPIRANT STICK:
Siloxane 28.0 Aluminum Chlorohydrate 28.8 Aluminum Hydroxide 19.6 Kaolin 10.0 Stearyl Alcohol 10.8 Isopropyl Myristate 0.7 Magnesium Silicate 0.7 Spray Dried Fragrance 1.4 5~
ANTI-PERSPIRANT STICK:
Siloxane 28.0 Aluminum Chlorohydra-te28.8 Talc 15.0 Cornstarch 15.3 Cetyl Alcohol 10.8 Isopropyl Palmitate 0.7 Magnesium Stearate 0.7 Perfume 0.7 ANTI-PERSPIRANT STICK:
Siloxane 28.0 Aluminum Chlorohydrate50.4 Kaolin 8.9 .
Stearyl ~lcohol 10.8 Isopropyl Myristatea . 7 ~:
Magnesium Stearate 0.7 Perfume 0.5 !
EYE SHADOW STICK:
Siloxane 37.00 Stearyl Alcohol 4.00 ;` . Titanium Dioxide 3.20 Oxy Black 3068 0.78 Lo Micron Umber 27366.45 Aluminum Hydroxide-38.07 ~ethyl Paraben 0.25 Propyl Paraben 0.10 - B Germall 115 ~a ~rac~f~ar/~ O.15 Flamenco Satina 100 Pearlescence ~a ~racle~k) 7.00 r~(len~
Flamenco Super Pearlescence~ 3.00 - ~
~2~5~
DEODOR~NT STICK:
Siloxane 25.00 Stearyl Alcohol 10.00 Calcium Carbonate 53.25 Cornstarch 5.00 .~ Titanium Dioxide 6.00 Triclosan (~a ~radem~flc) 0.25 Perfume 0.50 In all of the above samples, the fatty alcohol was added to the liquid siloxane at a temperature of 65C and the remaining ingredients were then blended into the liquid to form a slurry. In each case the slurry, a-t a temperature of about 55 C, was poured into plastic molds to form the sticks. Air at a temperature of 28C was passed over the sticks ~or a period 15 of 72 hours to evaporate the major proportion of the siloxane to prov.ide the finished stick composition. In each example the dried stick has a residual siloxane content of less than 2~ by weight.
:; In molding the stick, the slurry can be poured directly into a component of the final package~ or alternately, the slurry can be introduced into a separate mold and subsequently trans-forred to the package.
.
.
'.~
Claims (11)
1. A method of preparing a cosmetic powder product, comprising the steps of mixing at an elevated temperature a fatty alcohol containing 12 to 20 carbon atoms in the molecule, a finely divided filler and a sufficient quantity of a liquid evaporable siloxane to form a liquid moldable slurry, molding the slurry into a product, and evaporating a substantial por-tion of the siloxane from the molded product to provide a dried powder product having excellent pay-off and high resistance to humidity absorption.
2. The method of claim 1, wherein the slurry has the following composition in weight percent:
Fatty alcohol 5% to 30%
Filler 70% to 10%
Siloxane 25% to 60%.
Fatty alcohol 5% to 30%
Filler 70% to 10%
Siloxane 25% to 60%.
3. The method of claim 1, wherein the siloxane is at a temperature in the range of 60°C to 70°C during the step of mixing.
4. The method of claim 1, wherein the step of mold-ing the slurry comprises pouring the slurry by gravity into a mold.
5. The method of claim 1, wherein said composition includes an active anti-perspirant ingredient, said slurry having the following composition in weight per cent:
Fatty alcohol 4% to 12%
Anti-perspirant ingredient 10% to 35%
Filler 66% to 3%
Siloxane 20% to 50%
Fatty alcohol 4% to 12%
Anti-perspirant ingredient 10% to 35%
Filler 66% to 3%
Siloxane 20% to 50%
6. The method of claim 1, wherein said composition contains a cosmetic coloring material, said slurry having the following composition in weight percent:
Filler 75% to 3%
Fatty Alcohol 4% to 12%
Cosmetic coloring material 1% to 35%
Siloxane 20% to 50%.
Filler 75% to 3%
Fatty Alcohol 4% to 12%
Cosmetic coloring material 1% to 35%
Siloxane 20% to 50%.
7. The method of claim 5, wherein the anti-perspirant material is aluminum chlorohydrate.
8. The method of claim 5, wherein the anti-perspirant material is zirconium hydroxy chloride.
9. The method of claim 1, wherein the step of evaporating the siloxane is carried out by flowing a gas over the molded product.
10. The method of claim 7, wherein the dried product has a residual siloxane content of less than 2% by weight of the product.
11. A powder product composition for topical application, consisting essentially by weight of from 95%
to 5% of a finely divided inert filler, from 5% to 25% of a fatty alcohol containing 12 to 22 carbon atoms in the molecule, and up to 2% siloxane.
to 5% of a finely divided inert filler, from 5% to 25% of a fatty alcohol containing 12 to 22 carbon atoms in the molecule, and up to 2% siloxane.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US94524178A | 1978-09-25 | 1978-09-25 | |
| US945,241 | 1978-09-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1125659A true CA1125659A (en) | 1982-06-15 |
Family
ID=25482839
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA336,164A Expired CA1125659A (en) | 1978-09-25 | 1979-09-24 | Fatty alcohol with liquid siloxane to form powder product |
Country Status (3)
| Country | Link |
|---|---|
| AU (1) | AU528078B2 (en) |
| CA (1) | CA1125659A (en) |
| MX (1) | MX6440E (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3327001A1 (en) * | 1983-07-27 | 1985-02-14 | Württembergische Parfümerie - Fabrik GmbH, 7332 Eislingen | SOLID POWDER PREPARATION AND METHOD FOR PRODUCING THE SAME |
| US4578266A (en) * | 1983-07-29 | 1986-03-25 | Revlon, Inc. | Silicone-based cosmetic products containing pigment |
| US4832944A (en) * | 1983-10-03 | 1989-05-23 | Revlon Inc. | Nail enamel containing silicone-coated pigments |
| US5718890A (en) * | 1995-11-14 | 1998-02-17 | The Proctor & Gamble Company | Antiperspirant cream compositions comprising select triglyceride gellants |
| US5871717A (en) * | 1995-11-14 | 1999-02-16 | Procter & Gamble Company | Antiperspirant cream compositions having improved rheology |
| US5882637A (en) * | 1995-11-14 | 1999-03-16 | The Procter & Gamble Company | Antiperspirant cream compositions comprising fatty alcohol gellants |
| US5891425A (en) * | 1996-10-29 | 1999-04-06 | Procter & Gamble Company | Antiperspirant cream composition having improved rheology |
| US6143284A (en) * | 1998-04-02 | 2000-11-07 | The Procter & Gamble Company | Packaged antiperspirant cream composition |
-
1979
- 1979-09-19 AU AU50944/79A patent/AU528078B2/en not_active Ceased
- 1979-09-24 CA CA336,164A patent/CA1125659A/en not_active Expired
- 1979-09-25 MX MX840079U patent/MX6440E/en unknown
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3327001A1 (en) * | 1983-07-27 | 1985-02-14 | Württembergische Parfümerie - Fabrik GmbH, 7332 Eislingen | SOLID POWDER PREPARATION AND METHOD FOR PRODUCING THE SAME |
| US4578266A (en) * | 1983-07-29 | 1986-03-25 | Revlon, Inc. | Silicone-based cosmetic products containing pigment |
| US4832944A (en) * | 1983-10-03 | 1989-05-23 | Revlon Inc. | Nail enamel containing silicone-coated pigments |
| US5718890A (en) * | 1995-11-14 | 1998-02-17 | The Proctor & Gamble Company | Antiperspirant cream compositions comprising select triglyceride gellants |
| US5871717A (en) * | 1995-11-14 | 1999-02-16 | Procter & Gamble Company | Antiperspirant cream compositions having improved rheology |
| US5882637A (en) * | 1995-11-14 | 1999-03-16 | The Procter & Gamble Company | Antiperspirant cream compositions comprising fatty alcohol gellants |
| US5891425A (en) * | 1996-10-29 | 1999-04-06 | Procter & Gamble Company | Antiperspirant cream composition having improved rheology |
| US5891424A (en) * | 1996-10-29 | 1999-04-06 | Procter & Gamble | Antiperspirant cream compositions having improved rheology |
| US5902570A (en) * | 1996-10-29 | 1999-05-11 | Procter & Gamble Company | Antiperspirant cream compositions having improved rheology |
| US6143284A (en) * | 1998-04-02 | 2000-11-07 | The Procter & Gamble Company | Packaged antiperspirant cream composition |
Also Published As
| Publication number | Publication date |
|---|---|
| MX6440E (en) | 1985-05-31 |
| AU5094479A (en) | 1980-04-03 |
| AU528078B2 (en) | 1983-04-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4414200A (en) | Powder stick composition for topical application | |
| DE60037322T2 (en) | Use of the organopolysiloxane M3T in cosmetic compositions | |
| US3800034A (en) | Method for preparing pressed powder makeup sticks and product produced | |
| EP0013390B1 (en) | Cosmetic stick composition | |
| US4126679A (en) | Cosmetic stick | |
| US3708435A (en) | Method of cleaning human skin | |
| EP1176941B1 (en) | Multi-phase antiperspirant stick | |
| US5000947A (en) | Shaped articles containing liquefiable powders for delivery of cosmetic and other personal care agents | |
| US4954532A (en) | Cosmetic formulaton | |
| CA1125659A (en) | Fatty alcohol with liquid siloxane to form powder product | |
| MXPA01001684A (en) | Oil-in-water emulsion comprising gellan and a particular surfactant and uses. | |
| US5039518A (en) | Cosmetic sticks | |
| US6048518A (en) | Low residue solid antiperspirant | |
| US4923478A (en) | Cosmetic stick composition | |
| US6350440B1 (en) | Mixtures of volatile linear siloxanes | |
| JPH0222728B2 (en) | ||
| US4263274A (en) | Antiperspirant compositions and methods | |
| US20040052827A1 (en) | Cosmetic pencil | |
| JPS63162613A (en) | Non-pressure powder cosmetic product and manufacture | |
| KR102211786B1 (en) | Composition for cosmetics having improved water absorbability and oil absorbability | |
| JPH072621B2 (en) | Manufacturing method of solid powder cosmetics | |
| KR19980053454A (en) | Stick-type pack cosmetics and preparation method thereof | |
| JPS6366111A (en) | Cosmetic blended with spherical organic complex clay mineral | |
| JP4127342B2 (en) | Makeup cosmetics | |
| JPH07100645B2 (en) | Stick cosmetics |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |