CA1119003A - Process for extracting tungsten from alkali metal tungstate solutions - Google Patents
Process for extracting tungsten from alkali metal tungstate solutionsInfo
- Publication number
- CA1119003A CA1119003A CA000332684A CA332684A CA1119003A CA 1119003 A CA1119003 A CA 1119003A CA 000332684 A CA000332684 A CA 000332684A CA 332684 A CA332684 A CA 332684A CA 1119003 A CA1119003 A CA 1119003A
- Authority
- CA
- Canada
- Prior art keywords
- amine
- percent
- volume
- tungsten
- extractant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 title claims abstract description 23
- 229910052721 tungsten Inorganic materials 0.000 title claims abstract description 23
- 239000010937 tungsten Substances 0.000 title claims abstract description 23
- -1 alkali metal tungstate Chemical class 0.000 title claims abstract description 11
- 238000000034 method Methods 0.000 title claims abstract description 9
- 229910052783 alkali metal Inorganic materials 0.000 title claims abstract description 5
- 238000000605 extraction Methods 0.000 claims abstract description 14
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 150000004996 alkyl benzenes Chemical class 0.000 claims abstract description 7
- YKGBNAGNNUEZQC-UHFFFAOYSA-N 6-methyl-n,n-bis(6-methylheptyl)heptan-1-amine Chemical group CC(C)CCCCCN(CCCCCC(C)C)CCCCCC(C)C YKGBNAGNNUEZQC-UHFFFAOYSA-N 0.000 claims abstract description 6
- 125000005270 trialkylamine group Chemical group 0.000 claims abstract description 4
- 150000001412 amines Chemical class 0.000 claims description 18
- 239000012535 impurity Substances 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 2
- 239000003849 aromatic solvent Substances 0.000 claims description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims 1
- 239000002904 solvent Substances 0.000 abstract description 9
- 239000000470 constituent Substances 0.000 abstract description 3
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 abstract description 3
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 19
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 15
- XTAZYLNFDRKIHJ-UHFFFAOYSA-N n,n-dioctyloctan-1-amine Chemical compound CCCCCCCCN(CCCCCCCC)CCCCCCCC XTAZYLNFDRKIHJ-UHFFFAOYSA-N 0.000 description 13
- 239000003350 kerosene Substances 0.000 description 9
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 239000012527 feed solution Substances 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- FYGHSUNMUKGBRK-UHFFFAOYSA-N 1,2,3-trimethylbenzene Chemical compound CC1=CC=CC(C)=C1C FYGHSUNMUKGBRK-UHFFFAOYSA-N 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000011067 equilibration Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000012074 organic phase Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- UOHMMEJUHBCKEE-UHFFFAOYSA-N prehnitene Chemical compound CC1=CC=C(C)C(C)=C1C UOHMMEJUHBCKEE-UHFFFAOYSA-N 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- XMVONEAAOPAGAO-UHFFFAOYSA-N sodium tungstate Chemical compound [Na+].[Na+].[O-][W]([O-])(=O)=O XMVONEAAOPAGAO-UHFFFAOYSA-N 0.000 description 2
- 238000000638 solvent extraction Methods 0.000 description 2
- YTZKOQUCBOVLHL-UHFFFAOYSA-N tert-butylbenzene Chemical compound CC(C)(C)C1=CC=CC=C1 YTZKOQUCBOVLHL-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- PBWHJRFXUPLZDS-UHFFFAOYSA-N (1-Ethylpropyl)benzene Chemical compound CCC(CC)C1=CC=CC=C1 PBWHJRFXUPLZDS-UHFFFAOYSA-N 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- GDEQPEBFOWYWSA-UHFFFAOYSA-N 1,2-dimethyl-3-propan-2-ylbenzene Chemical compound CC(C)C1=CC=CC(C)=C1C GDEQPEBFOWYWSA-UHFFFAOYSA-N 0.000 description 1
- YQZBFMJOASEONC-UHFFFAOYSA-N 1-Methyl-2-propylbenzene Chemical compound CCCC1=CC=CC=C1C YQZBFMJOASEONC-UHFFFAOYSA-N 0.000 description 1
- DLFKJPZBBCZWOO-UHFFFAOYSA-N 8-methyl-n,n-bis(8-methylnonyl)nonan-1-amine Chemical compound CC(C)CCCCCCCN(CCCCCCCC(C)C)CCCCCCCC(C)C DLFKJPZBBCZWOO-UHFFFAOYSA-N 0.000 description 1
- JYFHYPJRHGVZDY-UHFFFAOYSA-N Dibutyl phosphate Chemical compound CCCCOP(O)(=O)OCCCC JYFHYPJRHGVZDY-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- CZIMGECIMULZMS-UHFFFAOYSA-N [W].[Na] Chemical compound [W].[Na] CZIMGECIMULZMS-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- BWZOPYPOZJBVLQ-UHFFFAOYSA-K aluminium glycinate Chemical compound O[Al+]O.NCC([O-])=O BWZOPYPOZJBVLQ-UHFFFAOYSA-K 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- BNMJSBUIDQYHIN-UHFFFAOYSA-N butyl dihydrogen phosphate Chemical compound CCCCOP(O)(O)=O BNMJSBUIDQYHIN-UHFFFAOYSA-N 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000005194 ethylbenzenes Chemical class 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G41/00—Compounds of tungsten
- C01G41/003—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/28—Amines
- C22B3/282—Aliphatic amines
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S423/00—Chemistry of inorganic compounds
- Y10S423/09—Reaction techniques
- Y10S423/14—Ion exchange; chelation or liquid/liquid ion extraction
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Geology (AREA)
- Geochemistry & Mineralogy (AREA)
- Manufacturing & Machinery (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Environmental & Geological Engineering (AREA)
- Inorganic Chemistry (AREA)
- Extraction Or Liquid Replacement (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US930,784 | 1978-08-03 | ||
| US05/930,784 US4175109A (en) | 1978-08-03 | 1978-08-03 | Process for extracting tungsten from alkali metal tungstate solutions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1119003A true CA1119003A (en) | 1982-03-02 |
Family
ID=25459763
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000332684A Expired CA1119003A (en) | 1978-08-03 | 1979-07-27 | Process for extracting tungsten from alkali metal tungstate solutions |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US4175109A (en:Method) |
| JP (1) | JPS5521597A (en:Method) |
| AT (1) | AT375625B (en:Method) |
| AU (1) | AU525322B2 (en:Method) |
| BR (1) | BR7904824A (en:Method) |
| CA (1) | CA1119003A (en:Method) |
| DE (1) | DE2929952A1 (en:Method) |
| FR (1) | FR2433586A1 (en:Method) |
| GB (1) | GB2027000B (en:Method) |
| MX (1) | MX152096A (en:Method) |
| SE (1) | SE444454B (en:Method) |
| ZA (1) | ZA793615B (en:Method) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4328190A (en) * | 1981-01-19 | 1982-05-04 | Amax Inc. | Solvent extraction of tungsten from aqueous tungstate solutions |
| US4360502A (en) * | 1981-08-13 | 1982-11-23 | Gte Products Corporation | Recovery of tungsten values from alkali tungstate solutions by solvent extraction |
| US4374099A (en) * | 1981-08-13 | 1983-02-15 | Gte Products Corporation | Recovery of tungsten values from alkali tungstate solutions by solvent extraction |
| US4360503A (en) * | 1981-08-13 | 1982-11-23 | Gte Products Corporation | Recovery of tungsten values from alkali tungstate solutions by solvent extraction |
| US4369165A (en) * | 1981-08-13 | 1983-01-18 | Gte Products Corporation | Recovery of tungsten values from alkali tungstate solutions by solvent extraction |
| US4379126A (en) * | 1981-08-13 | 1983-04-05 | Gte Products Corporation | Process for recovering tungsten values from alkali solutions |
| US4626425A (en) * | 1985-02-25 | 1986-12-02 | Gte Products Corporation | Recovery of tungsten from ammoniacal solutions |
| US4623534A (en) * | 1985-03-21 | 1986-11-18 | Gte Products Corporation | Method for producing ammonium paratungstate |
| US4759915A (en) * | 1985-10-11 | 1988-07-26 | Gte Products Corporation | Process for extracting tungsten from alkali metal tungstate solutions |
| US5023213A (en) * | 1986-12-09 | 1991-06-11 | United States Department Of Energy | Precursors in the preparation of transition metal nitrides and transition metal carbonitrides and their reaction intermediates |
| US4882131A (en) * | 1987-04-30 | 1989-11-21 | Gte Products Corporation | Process for recovering tungsten from organic solutions |
| US4954466A (en) * | 1989-11-30 | 1990-09-04 | Monsanto Company | Recovery of cobalt catalyst values |
| DE102007063691B4 (de) | 2007-02-02 | 2011-01-13 | H.C. Starck Gmbh | Ammoniumparawolframatdekahydrat und Verfahren zur Herstellung |
| JP5125371B2 (ja) * | 2007-10-02 | 2013-01-23 | 住友金属鉱山株式会社 | アミン系抽出剤のスクラビング方法 |
| US8287618B2 (en) | 2010-11-10 | 2012-10-16 | Kuwait Institute For Scientific Research | Method or process for recovering Mo, V, Ni, Co and Al from spent catalysts using ultrasonic assisted leaching with EDTA |
| CN113058289A (zh) * | 2021-02-19 | 2021-07-02 | 江钨世泰科钨品有限公司 | 一种钨酸钠溶液转型的萃取体系 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3052516A (en) * | 1959-02-10 | 1962-09-04 | Gen Mills Inc | Process for recovering tungsten values from solution |
| US3158438A (en) * | 1962-09-19 | 1964-11-24 | Union Carbide Corp | Solvent extraction process for recovering tungsten values from contaminated aqueous solutions |
| US3804941A (en) * | 1972-04-24 | 1974-04-16 | Kerr Mc Gee Chem Corp | Process for the extraction of tungsten from an aqueous alkaline solution |
| US3770869A (en) * | 1972-05-19 | 1973-11-06 | Gte Sylvania Inc | Recovery of molybdenum |
| SU456791A1 (ru) * | 1972-11-15 | 1975-01-15 | Новочеркасский Ордена Трудового Красного Знамени Политехнический Институт Им.Серго Орджоникидзе | Способ выделени молибдена |
| US4092400A (en) * | 1977-04-11 | 1978-05-30 | Engelhard Minerals & Chemicals Corp. | Process for recovering high purity tungsten compositions from wolframite ores |
-
1978
- 1978-08-03 US US05/930,784 patent/US4175109A/en not_active Expired - Lifetime
-
1979
- 1979-07-17 ZA ZA00793615A patent/ZA793615B/xx unknown
- 1979-07-24 SE SE7906341A patent/SE444454B/sv unknown
- 1979-07-24 DE DE19792929952 patent/DE2929952A1/de active Granted
- 1979-07-25 BR BR7904824A patent/BR7904824A/pt unknown
- 1979-07-27 CA CA000332684A patent/CA1119003A/en not_active Expired
- 1979-08-01 JP JP9742079A patent/JPS5521597A/ja active Granted
- 1979-08-02 MX MX178761A patent/MX152096A/es unknown
- 1979-08-02 AT AT0531379A patent/AT375625B/de not_active IP Right Cessation
- 1979-08-02 GB GB7926983A patent/GB2027000B/en not_active Expired
- 1979-08-03 FR FR7920002A patent/FR2433586A1/fr active Granted
- 1979-08-03 AU AU49546/79A patent/AU525322B2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| SE444454B (sv) | 1986-04-14 |
| BR7904824A (pt) | 1980-04-22 |
| FR2433586A1 (fr) | 1980-03-14 |
| GB2027000A (en) | 1980-02-13 |
| US4175109A (en) | 1979-11-20 |
| MX152096A (es) | 1985-05-29 |
| AU4954679A (en) | 1980-02-07 |
| AU525322B2 (en) | 1982-10-28 |
| ATA531379A (de) | 1984-01-15 |
| DE2929952C2 (en:Method) | 1987-12-23 |
| FR2433586B1 (en:Method) | 1984-10-12 |
| ZA793615B (en) | 1980-09-24 |
| DE2929952A1 (de) | 1980-02-21 |
| AT375625B (de) | 1984-08-27 |
| SE7906341L (sv) | 1980-02-04 |
| JPS5521597A (en) | 1980-02-15 |
| JPH0124849B2 (en:Method) | 1989-05-15 |
| GB2027000B (en) | 1982-09-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA1119003A (en) | Process for extracting tungsten from alkali metal tungstate solutions | |
| Rickelton et al. | The selective recovery of zinc with new thiophosphinic acids | |
| US4701311A (en) | Process for separating arsenic from acid solutions containing it | |
| US4898719A (en) | Liquid extraction procedure for the recovery of scandium | |
| FI70930C (fi) | Foerfarande foer vaetske-vaetske-extrahering av germanium | |
| CA1137457A (en) | Metallurgical extractant composition and process | |
| Qingyuan et al. | Separation of molybdenum from tungsten by di-2-ethylhexyl phosphoric acid extractant | |
| US4626280A (en) | Recovery of tungsten, scandium, iron, and manganese from tungsten bearing material | |
| Lakshmanan et al. | Extraction of cobalt by Kelex 100 and Kelex 100/Versatic 911 mixtures | |
| US4166837A (en) | Solvent-extraction process for recovery and separation of metal values | |
| US3582290A (en) | Metal extraction process | |
| US4185078A (en) | Extraction process for recovery of rhenium | |
| US4288413A (en) | Separating molybdenum values from an aqueous solution containing tungsten by solvent extraction | |
| US4568526A (en) | Process for selective liquid-liquid extraction of germanium | |
| US4278642A (en) | Method for removing molybdenum from tungstate solutions by solvent extraction | |
| US3607008A (en) | Separation of molybdenum values from tungsten values by solvent extraction | |
| US4882131A (en) | Process for recovering tungsten from organic solutions | |
| KR890004520B1 (ko) | 인산 습식 제조과정에서 인산염-함유 광석에 함유된 우라늄, 이트륨, 토륨 및 희토류를 총회수하는 방법 | |
| US4372923A (en) | Purification of solutions of gallium values by liquid/liquid extraction | |
| US4275037A (en) | Stripping metals from organic solvent with aqueous solution of polymeric phosphates | |
| KR100647744B1 (ko) | 음이온 추출 방법 | |
| US4041138A (en) | Process for the preparation of crystalline potassium tantalum fluoride | |
| US4049771A (en) | Extraction process for recovery of rhenium | |
| EP0028648B1 (en) | Method for recovering molybdenum from tungsten solutions | |
| CA1179145A (en) | Process for selective liquid-liquid extraction of germanium |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |