CA1087878A - Cemented carbide-steel composites for earthmoving and mining applications - Google Patents
Cemented carbide-steel composites for earthmoving and mining applicationsInfo
- Publication number
- CA1087878A CA1087878A CA292,776A CA292776A CA1087878A CA 1087878 A CA1087878 A CA 1087878A CA 292776 A CA292776 A CA 292776A CA 1087878 A CA1087878 A CA 1087878A
- Authority
- CA
- Canada
- Prior art keywords
- percent
- carbide
- steel
- binder
- cemented carbide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 80
- 239000010959 steel Substances 0.000 title claims abstract description 80
- 239000002131 composite material Substances 0.000 title claims abstract description 35
- 238000005065 mining Methods 0.000 title abstract description 17
- 239000011230 binding agent Substances 0.000 claims abstract description 73
- 239000000203 mixture Substances 0.000 claims abstract description 70
- 150000001247 metal acetylides Chemical class 0.000 claims abstract description 43
- 239000011651 chromium Substances 0.000 claims abstract description 30
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 27
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000006104 solid solution Substances 0.000 claims abstract description 21
- 229910000851 Alloy steel Inorganic materials 0.000 claims abstract description 19
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 14
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 238000005266 casting Methods 0.000 claims abstract description 12
- 238000000034 method Methods 0.000 claims abstract description 11
- CNEOGBIICRAWOH-UHFFFAOYSA-N methane;molybdenum Chemical compound C.[Mo] CNEOGBIICRAWOH-UHFFFAOYSA-N 0.000 claims abstract description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 79
- 239000000306 component Substances 0.000 claims description 76
- 229910045601 alloy Inorganic materials 0.000 claims description 67
- 239000000956 alloy Substances 0.000 claims description 67
- 229910052721 tungsten Inorganic materials 0.000 claims description 49
- 239000000843 powder Substances 0.000 claims description 43
- 239000010937 tungsten Substances 0.000 claims description 30
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 27
- 238000005245 sintering Methods 0.000 claims description 27
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 27
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 23
- 229910052799 carbon Inorganic materials 0.000 claims description 23
- 239000000463 material Substances 0.000 claims description 22
- 229910052751 metal Inorganic materials 0.000 claims description 22
- 239000002184 metal Substances 0.000 claims description 22
- 229910052750 molybdenum Inorganic materials 0.000 claims description 19
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 18
- 239000011733 molybdenum Substances 0.000 claims description 18
- 238000002844 melting Methods 0.000 claims description 15
- 230000000694 effects Effects 0.000 claims description 14
- 238000004519 manufacturing process Methods 0.000 claims description 14
- 230000008018 melting Effects 0.000 claims description 14
- 229910039444 MoC Inorganic materials 0.000 claims description 12
- 229910052759 nickel Inorganic materials 0.000 claims description 12
- 238000005219 brazing Methods 0.000 claims description 10
- QIJNJJZPYXGIQM-UHFFFAOYSA-N 1lambda4,2lambda4-dimolybdacyclopropa-1,2,3-triene Chemical compound [Mo]=C=[Mo] QIJNJJZPYXGIQM-UHFFFAOYSA-N 0.000 claims description 7
- 239000004615 ingredient Substances 0.000 claims description 5
- 239000010949 copper Substances 0.000 claims description 4
- 238000003825 pressing Methods 0.000 claims description 4
- 238000001238 wet grinding Methods 0.000 claims description 4
- 238000007906 compression Methods 0.000 claims description 3
- 230000006835 compression Effects 0.000 claims description 3
- 238000009792 diffusion process Methods 0.000 claims description 3
- 229910001092 metal group alloy Inorganic materials 0.000 claims description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 229940045605 vanadium Drugs 0.000 claims 8
- 235000016768 molybdenum Nutrition 0.000 claims 6
- 238000001035 drying Methods 0.000 claims 2
- OAXLZNWUNMCZSO-UHFFFAOYSA-N methanidylidynetungsten Chemical compound [W]#[C-] OAXLZNWUNMCZSO-UHFFFAOYSA-N 0.000 abstract description 8
- 238000005553 drilling Methods 0.000 abstract description 3
- 239000012071 phase Substances 0.000 description 21
- 229910052742 iron Inorganic materials 0.000 description 16
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 16
- 238000005275 alloying Methods 0.000 description 15
- 230000015572 biosynthetic process Effects 0.000 description 12
- 238000007792 addition Methods 0.000 description 11
- -1 chromium carbides Chemical class 0.000 description 8
- 229910017052 cobalt Inorganic materials 0.000 description 8
- 239000010941 cobalt Substances 0.000 description 8
- 230000007423 decrease Effects 0.000 description 8
- 238000001000 micrograph Methods 0.000 description 8
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 7
- 230000005496 eutectics Effects 0.000 description 6
- 239000010410 layer Substances 0.000 description 6
- 238000003801 milling Methods 0.000 description 6
- 229910003470 tongbaite Inorganic materials 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 239000011572 manganese Substances 0.000 description 5
- 238000010791 quenching Methods 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 229910003178 Mo2C Inorganic materials 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 238000000280 densification Methods 0.000 description 4
- 238000011161 development Methods 0.000 description 4
- 230000018109 developmental process Effects 0.000 description 4
- 238000005552 hardfacing Methods 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052748 manganese Inorganic materials 0.000 description 4
- 230000000171 quenching effect Effects 0.000 description 4
- 230000035939 shock Effects 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 238000011282 treatment Methods 0.000 description 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 3
- 230000002411 adverse Effects 0.000 description 3
- 238000000137 annealing Methods 0.000 description 3
- 229910001349 ledeburite Inorganic materials 0.000 description 3
- 239000011435 rock Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000006467 substitution reaction Methods 0.000 description 3
- 238000005496 tempering Methods 0.000 description 3
- INZDTEICWPZYJM-UHFFFAOYSA-N 1-(chloromethyl)-4-[4-(chloromethyl)phenyl]benzene Chemical compound C1=CC(CCl)=CC=C1C1=CC=C(CCl)C=C1 INZDTEICWPZYJM-UHFFFAOYSA-N 0.000 description 2
- 229910001208 Crucible steel Inorganic materials 0.000 description 2
- 229910009043 WC-Co Inorganic materials 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 229910001566 austenite Inorganic materials 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 229910001567 cementite Inorganic materials 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- UFGZSIPAQKLCGR-UHFFFAOYSA-N chromium carbide Chemical compound [Cr]#C[Cr]C#[Cr] UFGZSIPAQKLCGR-UHFFFAOYSA-N 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 230000001627 detrimental effect Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 238000000265 homogenisation Methods 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- KSOKAHYVTMZFBJ-UHFFFAOYSA-N iron;methane Chemical compound C.[Fe].[Fe].[Fe] KSOKAHYVTMZFBJ-UHFFFAOYSA-N 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- WTEVQBCEXWBHNA-YFHOEESVSA-N neral Chemical compound CC(C)=CCC\C(C)=C/C=O WTEVQBCEXWBHNA-YFHOEESVSA-N 0.000 description 2
- 230000036961 partial effect Effects 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 238000007790 scraping Methods 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- 241001279686 Allium moly Species 0.000 description 1
- 229910000906 Bronze Inorganic materials 0.000 description 1
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 229910017112 Fe—C Inorganic materials 0.000 description 1
- WQZGKKKJIJFFOK-VSOAQEOCSA-N L-altropyranose Chemical compound OC[C@@H]1OC(O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-VSOAQEOCSA-N 0.000 description 1
- 235000010678 Paulownia tomentosa Nutrition 0.000 description 1
- 240000002834 Paulownia tomentosa Species 0.000 description 1
- 208000003629 Rupture Diseases 0.000 description 1
- 229910001315 Tool steel Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000001996 bearing alloy Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- WTEVQBCEXWBHNA-JXMROGBWSA-N citral A Natural products CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 229940000425 combination drug Drugs 0.000 description 1
- 238000007596 consolidation process Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000001687 destabilization Effects 0.000 description 1
- 230000000368 destabilizing effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229910000743 fusible alloy Inorganic materials 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 229910001009 interstitial alloy Inorganic materials 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- MGRWKWACZDFZJT-UHFFFAOYSA-N molybdenum tungsten Chemical compound [Mo].[W] MGRWKWACZDFZJT-UHFFFAOYSA-N 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 229910002058 ternary alloy Inorganic materials 0.000 description 1
- 230000000930 thermomechanical effect Effects 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C33/00—Making ferrous alloys
- C22C33/02—Making ferrous alloys by powder metallurgy
- C22C33/0257—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements
- C22C33/0278—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements with at least one alloying element having a minimum content above 5%
- C22C33/0292—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements with at least one alloying element having a minimum content above 5% with more than 5% preformed carbides, nitrides or borides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D19/00—Casting in, on, or around objects which form part of the product
- B22D19/06—Casting in, on, or around objects which form part of the product for manufacturing or repairing tools
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F7/00—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression
- B22F7/06—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite workpieces or articles from parts, e.g. to form tipped tools
- B22F7/08—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite workpieces or articles from parts, e.g. to form tipped tools with one or more parts not made from powder
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/10—Alloys containing non-metals
- C22C1/1036—Alloys containing non-metals starting from a melt
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
- C22C29/06—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
- C22C29/067—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds comprising a particular metallic binder
-
- E—FIXED CONSTRUCTIONS
- E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
- E02F—DREDGING; SOIL-SHIFTING
- E02F9/00—Component parts of dredgers or soil-shifting machines, not restricted to one of the kinds covered by groups E02F3/00 - E02F7/00
- E02F9/28—Small metalwork for digging elements, e.g. teeth scraper bits
- E02F9/2808—Teeth
- E02F9/285—Teeth characterised by the material used
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21C—MINING OR QUARRYING
- E21C35/00—Details of, or accessories for, machines for slitting or completely freeing the mineral from the seam, not provided for in groups E21C25/00 - E21C33/00, E21C37/00 or E21C39/00
- E21C35/18—Mining picks; Holders therefor
- E21C35/183—Mining picks; Holders therefor with inserts or layers of wear-resisting material
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21C—MINING OR QUARRYING
- E21C35/00—Details of, or accessories for, machines for slitting or completely freeing the mineral from the seam, not provided for in groups E21C25/00 - E21C33/00, E21C37/00 or E21C39/00
- E21C35/18—Mining picks; Holders therefor
- E21C35/183—Mining picks; Holders therefor with inserts or layers of wear-resisting material
- E21C35/1833—Multiple inserts
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21C—MINING OR QUARRYING
- E21C35/00—Details of, or accessories for, machines for slitting or completely freeing the mineral from the seam, not provided for in groups E21C25/00 - E21C33/00, E21C37/00 or E21C39/00
- E21C35/18—Mining picks; Holders therefor
- E21C35/183—Mining picks; Holders therefor with inserts or layers of wear-resisting material
- E21C35/1835—Chemical composition or specific material
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21C—MINING OR QUARRYING
- E21C35/00—Details of, or accessories for, machines for slitting or completely freeing the mineral from the seam, not provided for in groups E21C25/00 - E21C33/00, E21C37/00 or E21C39/00
- E21C35/18—Mining picks; Holders therefor
- E21C35/183—Mining picks; Holders therefor with inserts or layers of wear-resisting material
- E21C35/1837—Mining picks; Holders therefor with inserts or layers of wear-resisting material characterised by the shape
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F5/00—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
- B22F2005/001—Cutting tools, earth boring or grinding tool other than table ware
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C2204/00—End product comprising different layers, coatings or parts of cermet
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
- Y10T428/12576—Boride, carbide or nitride component
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Mining & Mineral Resources (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Geochemistry & Mineralogy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Structural Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Composite Materials (AREA)
- Civil Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Powder Metallurgy (AREA)
- Ceramic Products (AREA)
- Manufacture Of Alloys Or Alloy Compounds (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US05/749,343 US4101318A (en) | 1976-12-10 | 1976-12-10 | Cemented carbide-steel composites for earthmoving and mining applications |
US749,343 | 1985-06-27 |
Publications (1)
Publication Number | Publication Date |
---|---|
CA1087878A true CA1087878A (en) | 1980-10-21 |
Family
ID=25013331
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA292,776A Expired CA1087878A (en) | 1976-12-10 | 1977-12-09 | Cemented carbide-steel composites for earthmoving and mining applications |
Country Status (10)
Families Citing this family (61)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2391016A1 (fr) * | 1977-05-20 | 1978-12-15 | Permanence Corp | Procede de realisation de structures composites en metal et carbure metallique |
US4216034A (en) * | 1977-07-27 | 1980-08-05 | Sumitomo Electric Industries, Ltd. | Process for the production of a hard solid solution |
SE425003B (sv) * | 1978-02-28 | 1982-08-23 | Sandvik Ab | Modifikation av molybden-volfram-karbonitrid enligt kraven i patentet 7800756-4 |
US4257809A (en) * | 1979-01-05 | 1981-03-24 | General Electric Company | Molybdenum monocarbide-tungsten monocarbide solid solutions |
US4650722A (en) * | 1980-06-13 | 1987-03-17 | Union Carbide Corporation | Hard faced article |
US4484644A (en) * | 1980-09-02 | 1984-11-27 | Ingersoll-Rand Company | Sintered and forged article, and method of forming same |
CA1192019A (en) * | 1981-04-27 | 1985-08-20 | Nicholas Makrides | Casting having wear resistant compacts and method of manufacture |
WO1982004375A1 (en) * | 1981-06-09 | 1982-12-23 | Real Michael William | Wear-resistant materials |
DE3123963C2 (de) * | 1981-06-19 | 1985-05-15 | Berchem & Schaberg Gmbh, 4650 Gelsenkirchen | Gesteinsschneidkopf für einen Schneidkopf-Saugbagger |
US4454205A (en) * | 1981-10-09 | 1984-06-12 | Esco Corporation | Method of drill bit manufacture and product |
US4462293A (en) * | 1982-09-27 | 1984-07-31 | Gunzner Fred G | Wear-resistant and shock-resistant tools and method of manufacture thereof |
SE449383B (sv) * | 1982-12-06 | 1987-04-27 | Sandvik Ab | Slitdetaljer sasom snoplogsker, veghyvelsker, grevtender m m med hog slitstyrka |
SE450259C (sv) * | 1983-03-23 | 1996-07-22 | Sandvik Ab | Verktyg för brytning eller avverkning av fasta material, såsom asfalt |
SE440753B (sv) * | 1983-05-13 | 1985-08-19 | Santrade Ltd | Verktyg for skerande bearbetning bestaende av kerna och holje |
US4770253A (en) * | 1987-02-20 | 1988-09-13 | Kennametal Inc. | Grader blade with tiered inserts on leading edge |
US4859543A (en) * | 1987-04-28 | 1989-08-22 | Kennametal Inc. | Earth working tool having a working element fabricated from cemented tungsten carbide compositions with enhanced properties |
US4954058A (en) * | 1988-06-27 | 1990-09-04 | Deere & Company | Method for making composite sintered apex seal material |
US4956012A (en) * | 1988-10-03 | 1990-09-11 | Newcomer Products, Inc. | Dispersion alloyed hard metal composites |
US5066546A (en) * | 1989-03-23 | 1991-11-19 | Kennametal Inc. | Wear-resistant steel castings |
US5057147A (en) * | 1990-06-15 | 1991-10-15 | Gte Products Corporation | Method for preparation of WC-NI grade powder |
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-
1976
- 1976-12-10 US US05/749,343 patent/US4101318A/en not_active Expired - Lifetime
-
1977
- 1977-10-05 JP JP11910277A patent/JPS5372710A/ja active Pending
- 1977-11-21 FR FR7734954A patent/FR2373500A1/fr active Granted
- 1977-11-23 BR BR7707794A patent/BR7707794A/pt unknown
- 1977-12-07 GB GB51037/77A patent/GB1597715A/en not_active Expired
- 1977-12-08 AU AU31362/77A patent/AU504992B2/en not_active Expired
- 1977-12-09 SE SE7714037A patent/SE7714037L/xx not_active Application Discontinuation
- 1977-12-09 DE DE2754999A patent/DE2754999C2/de not_active Expired
- 1977-12-09 CA CA292,776A patent/CA1087878A/en not_active Expired
- 1977-12-12 AT AT886977A patent/AT352641B/de not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
GB1597715A (en) | 1981-09-09 |
FR2373500A1 (fr) | 1978-07-07 |
DE2754999C2 (de) | 1987-02-19 |
AU504992B2 (en) | 1979-11-01 |
AT352641B (de) | 1979-09-25 |
DE2754999A1 (de) | 1978-08-10 |
US4101318A (en) | 1978-07-18 |
FR2373500B1 (US08188275-20120529-C00054.png) | 1983-11-25 |
JPS5372710A (en) | 1978-06-28 |
ATA886977A (de) | 1979-02-15 |
SE7714037L (sv) | 1978-06-11 |
BR7707794A (pt) | 1978-09-12 |
AU3136277A (en) | 1979-06-14 |
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