CA1080205A - Active and durable sulfuric acid catalyst - Google Patents
Active and durable sulfuric acid catalystInfo
- Publication number
- CA1080205A CA1080205A CA258,390A CA258390A CA1080205A CA 1080205 A CA1080205 A CA 1080205A CA 258390 A CA258390 A CA 258390A CA 1080205 A CA1080205 A CA 1080205A
- Authority
- CA
- Canada
- Prior art keywords
- catalyst
- diatomaceous earth
- weight
- calcined
- support
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 134
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 title claims description 22
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims abstract description 104
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 73
- 239000005909 Kieselgur Substances 0.000 claims abstract description 56
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 claims abstract description 30
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 26
- 230000003647 oxidation Effects 0.000 claims abstract description 25
- 241000814619 Aulacoseira granulata Species 0.000 claims abstract description 18
- 239000012190 activator Substances 0.000 claims abstract description 15
- 150000003682 vanadium compounds Chemical class 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims description 40
- 239000002245 particle Substances 0.000 claims description 38
- 229910052720 vanadium Inorganic materials 0.000 claims description 22
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 22
- 238000000034 method Methods 0.000 claims description 19
- 239000013505 freshwater Substances 0.000 claims description 12
- 238000001354 calcination Methods 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 238000007493 shaping process Methods 0.000 claims description 9
- 238000001035 drying Methods 0.000 claims description 2
- 230000003213 activating effect Effects 0.000 claims 1
- 229910052792 caesium Inorganic materials 0.000 claims 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims 1
- 229940044609 sulfur dioxide Drugs 0.000 description 46
- 235000010269 sulphur dioxide Nutrition 0.000 description 46
- 239000007789 gas Substances 0.000 description 40
- 239000011149 active material Substances 0.000 description 20
- 230000000694 effects Effects 0.000 description 20
- 238000012360 testing method Methods 0.000 description 19
- 239000000463 material Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 229910052760 oxygen Inorganic materials 0.000 description 8
- 241000206761 Bacillariophyta Species 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
- 230000003197 catalytic effect Effects 0.000 description 7
- 239000001301 oxygen Substances 0.000 description 7
- 239000008188 pellet Substances 0.000 description 7
- 238000001994 activation Methods 0.000 description 5
- 230000004913 activation Effects 0.000 description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 5
- 239000000377 silicon dioxide Substances 0.000 description 5
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 3
- 229910052939 potassium sulfate Inorganic materials 0.000 description 3
- 235000011151 potassium sulphates Nutrition 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 241001491711 Melosira Species 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- FLJPGEWQYJVDPF-UHFFFAOYSA-L caesium sulfate Chemical compound [Cs+].[Cs+].[O-]S([O-])(=O)=O FLJPGEWQYJVDPF-UHFFFAOYSA-L 0.000 description 2
- 239000002734 clay mineral Substances 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 238000007580 dry-mixing Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 230000001788 irregular Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000001878 scanning electron micrograph Methods 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001340 alkali metals Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 101150002692 artJ gene Proteins 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 239000011363 dried mixture Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229910000286 fullers earth Inorganic materials 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000003348 petrochemical agent Substances 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000008262 pumice Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001180 sulfating effect Effects 0.000 description 1
- 230000019635 sulfation Effects 0.000 description 1
- 238000005670 sulfation reaction Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 229910001935 vanadium oxide Inorganic materials 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/69—Sulfur trioxide; Sulfuric acid
- C01B17/74—Preparation
- C01B17/76—Preparation by contact processes
- C01B17/78—Preparation by contact processes characterised by the catalyst used
- C01B17/79—Preparation by contact processes characterised by the catalyst used containing vanadium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/16—Clays or other mineral silicates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
- B01J23/22—Vanadium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US61238375A | 1975-09-11 | 1975-09-11 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1080205A true CA1080205A (en) | 1980-06-24 |
Family
ID=24452926
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA258,390A Expired CA1080205A (en) | 1975-09-11 | 1976-08-04 | Active and durable sulfuric acid catalyst |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS5233895A (enExample) |
| BE (1) | BE846016A (enExample) |
| CA (1) | CA1080205A (enExample) |
| DE (1) | DE2640169A1 (enExample) |
| DK (1) | DK405876A (enExample) |
| FR (1) | FR2323633A1 (enExample) |
| GB (1) | GB1526873A (enExample) |
| NL (1) | NL7609923A (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8323610B2 (en) | 2010-04-12 | 2012-12-04 | Basf Se | Catalyst for the oxidation of SO2 to SO3 |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4193894A (en) * | 1979-01-11 | 1980-03-18 | Monsanto Company | Catalyst for oxidation of sulfur dioxide |
| UA70330C2 (uk) * | 1999-11-09 | 2004-10-15 | Любовь Манаєва | СПОСІБ ОДЕРЖАННЯ КАТАЛІЗАТОРА КОНВЕРСІЇ SO<sub>2</sub> В SO<sub>3</sub> З ВИКОРИСТАННЯМ СПРАЦЬОВАНОГО ВАНАДІЄВОГО КАТАЛІЗАТОРА |
| RU2186620C1 (ru) * | 2001-08-06 | 2002-08-10 | Манаева Любовь Николаевна | Способ приготовления катализатора конверсии so2 в so3 |
| CN102892501B (zh) * | 2010-04-12 | 2015-04-08 | 巴斯夫欧洲公司 | 用于将so2氧化成so3的催化剂 |
| EP2558198B1 (de) * | 2010-04-12 | 2022-12-14 | Basf Se | Katalysator zur oxidation von so2 zu so3 |
| CN110575834B (zh) * | 2018-06-10 | 2022-05-27 | 天津大学 | 稀土掺杂铁基催化剂及其制备方法和应用 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1371004A (en) * | 1914-10-09 | 1921-03-08 | Gen Chemical Corp | Oxidation of sulfur dioxid and catalyst therefor |
| FR688561A (fr) * | 1929-01-22 | 1930-08-26 | Verein Chemische & Metallurgische Prod | Procédé de fabrication de supports de catalyseurs |
| US1941426A (en) * | 1929-05-13 | 1933-12-26 | Calco Chemical Co Inc | Method of making sulphur trioxide |
| US2029530A (en) * | 1931-05-29 | 1936-02-04 | American Cyanamid & Chem Corp | Contact sulphuric acid process |
| BE793324A (fr) * | 1971-12-27 | 1973-06-27 | Du Pont | Preparation de catalyseur convenant a l'oxydation de gaz renfermant du so2 |
-
1976
- 1976-08-04 CA CA258,390A patent/CA1080205A/en not_active Expired
- 1976-08-31 JP JP51104204A patent/JPS5233895A/ja active Pending
- 1976-08-31 GB GB3596676A patent/GB1526873A/en not_active Expired
- 1976-09-06 FR FR7626769A patent/FR2323633A1/fr active Granted
- 1976-09-07 DE DE19762640169 patent/DE2640169A1/de active Pending
- 1976-09-07 NL NL7609923A patent/NL7609923A/xx not_active Application Discontinuation
- 1976-09-09 DK DK405876A patent/DK405876A/da unknown
- 1976-09-09 BE BE7000882A patent/BE846016A/xx unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8323610B2 (en) | 2010-04-12 | 2012-12-04 | Basf Se | Catalyst for the oxidation of SO2 to SO3 |
Also Published As
| Publication number | Publication date |
|---|---|
| GB1526873A (en) | 1978-10-04 |
| FR2323633A1 (fr) | 1977-04-08 |
| DK405876A (da) | 1977-03-12 |
| FR2323633B1 (enExample) | 1979-09-07 |
| DE2640169A1 (de) | 1977-03-24 |
| JPS5233895A (en) | 1977-03-15 |
| NL7609923A (nl) | 1977-03-15 |
| BE846016A (nl) | 1977-03-09 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |