CA1078919A - Electrolytes solides pour piles et batteries seches - Google Patents
Electrolytes solides pour piles et batteries sechesInfo
- Publication number
- CA1078919A CA1078919A CA271,882A CA271882A CA1078919A CA 1078919 A CA1078919 A CA 1078919A CA 271882 A CA271882 A CA 271882A CA 1078919 A CA1078919 A CA 1078919A
- Authority
- CA
- Canada
- Prior art keywords
- metal
- sulfur
- material according
- batteries
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000007784 solid electrolyte Substances 0.000 title claims description 10
- 239000000463 material Substances 0.000 claims abstract description 28
- 229910052751 metal Inorganic materials 0.000 claims abstract description 19
- 239000002184 metal Substances 0.000 claims abstract description 19
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 15
- 239000011593 sulfur Substances 0.000 claims abstract description 15
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000011734 sodium Substances 0.000 claims abstract description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 6
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 6
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052738 indium Inorganic materials 0.000 claims abstract description 6
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 6
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 6
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 6
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical group [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052711 selenium Inorganic materials 0.000 claims abstract description 4
- 239000011669 selenium Chemical group 0.000 claims abstract description 4
- 229910052714 tellurium Chemical group 0.000 claims abstract description 4
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical group [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 claims abstract description 4
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical group [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 claims abstract description 3
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims abstract description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052776 Thorium Chemical group 0.000 claims abstract description 3
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052792 caesium Inorganic materials 0.000 claims abstract description 3
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052733 gallium Inorganic materials 0.000 claims abstract description 3
- 229910052735 hafnium Inorganic materials 0.000 claims abstract description 3
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical group [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052746 lanthanum Inorganic materials 0.000 claims abstract description 3
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims abstract description 3
- 230000000737 periodic effect Effects 0.000 claims abstract description 3
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 3
- 239000011591 potassium Substances 0.000 claims abstract description 3
- 229910052701 rubidium Inorganic materials 0.000 claims abstract description 3
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052706 scandium Inorganic materials 0.000 claims abstract description 3
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052716 thallium Inorganic materials 0.000 claims abstract description 3
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052727 yttrium Inorganic materials 0.000 claims abstract description 3
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000003792 electrolyte Substances 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 150000004771 selenides Chemical class 0.000 claims description 3
- 150000004763 sulfides Chemical class 0.000 claims description 3
- XSOKHXFFCGXDJZ-UHFFFAOYSA-N telluride(2-) Chemical compound [Te-2] XSOKHXFFCGXDJZ-UHFFFAOYSA-N 0.000 claims 1
- 150000004772 tellurides Chemical class 0.000 claims 1
- 125000006850 spacer group Chemical group 0.000 description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 5
- 150000004770 chalcogenides Chemical class 0.000 description 5
- 229910006247 ZrS2 Inorganic materials 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 238000005481 NMR spectroscopy Methods 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- BNOODXBBXFZASF-UHFFFAOYSA-N [Na].[S] Chemical compound [Na].[S] BNOODXBBXFZASF-UHFFFAOYSA-N 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 241000219495 Betulaceae Species 0.000 description 1
- 229910020050 NbSe3 Inorganic materials 0.000 description 1
- 229910003092 TiS2 Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000003708 ampul Substances 0.000 description 1
- WVMYSOZCZHQCSG-UHFFFAOYSA-N bis(sulfanylidene)zirconium Chemical compound S=[Zr]=S WVMYSOZCZHQCSG-UHFFFAOYSA-N 0.000 description 1
- AGOYDEPGAOXOCK-KCBOHYOISA-N clarithromycin Chemical compound O([C@@H]1[C@@H](C)C(=O)O[C@@H]([C@@]([C@H](O)[C@@H](C)C(=O)[C@H](C)C[C@](C)([C@H](O[C@H]2[C@@H]([C@H](C[C@@H](C)O2)N(C)C)O)[C@H]1C)OC)(C)O)CC)[C@H]1C[C@@](C)(OC)[C@@H](O)[C@H](C)O1 AGOYDEPGAOXOCK-KCBOHYOISA-N 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000004320 controlled atmosphere Methods 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 239000002001 electrolyte material Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 239000010416 ion conductor Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 235000015047 pilsener Nutrition 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052979 sodium sulfide Inorganic materials 0.000 description 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- GKCNVZWZCYIBPR-UHFFFAOYSA-N sulfanylideneindium Chemical compound [In]=S GKCNVZWZCYIBPR-UHFFFAOYSA-N 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- -1 telluride sulfides Chemical class 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S505/00—Superconductor technology: apparatus, material, process
- Y10S505/80—Material per se process of making same
- Y10S505/81—Compound
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S505/00—Superconductor technology: apparatus, material, process
- Y10S505/80—Material per se process of making same
- Y10S505/815—Process of making per se
- Y10S505/824—Battery, thermo or photo-electric
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Secondary Cells (AREA)
- Conductive Materials (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Primary Cells (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7604598A FR2341953A1 (fr) | 1976-02-19 | 1976-02-19 | Nouveaux materiaux a conductivite ionique, applicables a la constitution d'electrolytes solides pour piles et batteries seches |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1078919A true CA1078919A (fr) | 1980-06-03 |
Family
ID=9169328
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA271,882A Expired CA1078919A (fr) | 1976-02-19 | 1977-02-16 | Electrolytes solides pour piles et batteries seches |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US4237201A (enExample) |
| JP (1) | JPS52101425A (enExample) |
| AU (1) | AU510148B2 (enExample) |
| BE (1) | BE850902A (enExample) |
| CA (1) | CA1078919A (enExample) |
| DE (1) | DE2706830A1 (enExample) |
| DK (1) | DK70477A (enExample) |
| FR (1) | FR2341953A1 (enExample) |
| GB (1) | GB1530111A (enExample) |
| IE (1) | IE44617B1 (enExample) |
| IT (1) | IT1075281B (enExample) |
| LU (1) | LU76729A1 (enExample) |
| NL (1) | NL7701381A (enExample) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4322485A (en) * | 1979-06-13 | 1982-03-30 | United Kingdom Atomic Energy Authority | Preparation of materials |
| FR2477128A1 (fr) | 1980-02-29 | 1981-09-04 | Saft Leclanche | Composition vitreuse conductrice de cations alcalins et procede de preparation d'une telle composition |
| US4406754A (en) * | 1980-03-28 | 1983-09-27 | Kabushiki Kaisha Kobe Seiko Sho | Method and probe for the rapid determination of sulfur level |
| JPS5960814A (ja) * | 1982-09-29 | 1984-04-06 | 株式会社日立製作所 | 酸化リチウム系非晶質イオン導電体 |
| US4828945A (en) * | 1987-03-27 | 1989-05-09 | Japan Synthetic Rubber Co., Ltd. | Solid electrolyte sheet and process for producing the same |
| US5194298A (en) * | 1990-09-14 | 1993-03-16 | Kaun Thomas D | Method of preparing corrosion resistant composite materials |
| US5330708A (en) * | 1993-04-26 | 1994-07-19 | The University Of Iowa Research Foundation | Sulfide alloys that exhibit thermal bistability |
| US5531936A (en) * | 1994-08-31 | 1996-07-02 | Board Of Trustees Operating Michigan State University | Alkali metal quaternary chalcogenides and process for the preparation thereof |
| US6013204A (en) * | 1997-03-28 | 2000-01-11 | Board Of Trustees Operating Michigan State University | Alkali metal chalcogenides of bismuth alone or with antimony |
| CN110649208B (zh) * | 2018-09-29 | 2022-06-17 | 合肥工业大学 | 一种锂硫电池复合隔膜及其制备方法 |
| US20230115956A1 (en) * | 2020-03-13 | 2023-04-13 | The Regents Of The University Of California | Chlorine-Based Sodium Solid Electrolyte |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4009052A (en) * | 1975-02-24 | 1977-02-22 | Exxon Research And Engineering Company | Chalcogenide battery |
| US4009092A (en) * | 1976-02-27 | 1977-02-22 | E. I. Du Pont De Nemours And Company | Substituted lithium phosphates and solid electrolytes therefrom |
| US4097345A (en) * | 1976-10-15 | 1978-06-27 | E. I. Du Pont De Nemours And Company | Na5 GdSi4 O 12 and related rare earth sodium ion conductors and electrolytic cells therefrom |
| US4117103A (en) * | 1977-05-04 | 1978-09-26 | Massachusetts Institute Of Technology | Lithium ion transport compositions |
| US4143213A (en) * | 1978-04-26 | 1979-03-06 | Exxon Research & Engineering Co. | Cells having cathodes containing chalcogenide compounds of the formula Ma FeXb and species thereof exhibiting alkali metal incorporation |
-
1976
- 1976-02-19 FR FR7604598A patent/FR2341953A1/fr active Granted
-
1977
- 1977-01-31 BE BE1007914A patent/BE850902A/xx not_active IP Right Cessation
- 1977-02-09 GB GB5401/77A patent/GB1530111A/en not_active Expired
- 1977-02-09 NL NL7701381A patent/NL7701381A/xx not_active Application Discontinuation
- 1977-02-10 AU AU22148/77A patent/AU510148B2/en not_active Expired
- 1977-02-10 LU LU76729A patent/LU76729A1/xx unknown
- 1977-02-11 IT IT20232/77A patent/IT1075281B/it active
- 1977-02-16 CA CA271,882A patent/CA1078919A/fr not_active Expired
- 1977-02-17 DE DE19772706830 patent/DE2706830A1/de not_active Withdrawn
- 1977-02-18 DK DK70477A patent/DK70477A/da not_active Application Discontinuation
- 1977-02-18 IE IE354/77A patent/IE44617B1/en unknown
- 1977-02-18 JP JP1631777A patent/JPS52101425A/ja active Pending
-
1979
- 1979-02-02 US US06/008,724 patent/US4237201A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| IE44617B1 (en) | 1982-01-27 |
| GB1530111A (en) | 1978-10-25 |
| FR2341953B1 (enExample) | 1979-07-20 |
| IE44617L (en) | 1977-08-19 |
| DE2706830A1 (de) | 1977-09-01 |
| FR2341953A1 (fr) | 1977-09-16 |
| IT1075281B (it) | 1985-04-22 |
| AU2214877A (en) | 1978-08-17 |
| DK70477A (da) | 1977-08-20 |
| NL7701381A (nl) | 1977-08-23 |
| AU510148B2 (en) | 1980-06-12 |
| BE850902A (fr) | 1977-08-01 |
| JPS52101425A (en) | 1977-08-25 |
| US4237201A (en) | 1980-12-02 |
| LU76729A1 (enExample) | 1977-08-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |