CA1078554A - Oil-out self-shining emulsion coating composition - Google Patents
Oil-out self-shining emulsion coating compositionInfo
- Publication number
- CA1078554A CA1078554A CA267,155A CA267155A CA1078554A CA 1078554 A CA1078554 A CA 1078554A CA 267155 A CA267155 A CA 267155A CA 1078554 A CA1078554 A CA 1078554A
- Authority
- CA
- Canada
- Prior art keywords
- weight
- composition
- wax
- water
- nonionic surfactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09G—POLISHING COMPOSITIONS; SKI WAXES
- C09G1/00—Polishing compositions
- C09G1/06—Other polishing compositions
- C09G1/08—Other polishing compositions based on wax
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
ABSTRACT OF THE DISCLOSURE
An emulsion coating composition which is self-shin-ing and non-crevice whitening comprising from about 0.05-2%
of an ethoxylated, nonionic surfactant having an ethylene oxide content of from 40-100, from about 15-70% by weight of a solvent, from about 0-30% by weight of a hard wax, from about 0-30% by weight of a soft wax wherein the combined amount of hard wax and soft wax in the composition is from about 3-35%, from about 0.3-4% of an emulsifier selected from the group consisting of oxazolines, fatty acid diethanolamides, quaternary ammonium compounds, mixtures of sorbitan monooleate and sorbitan monooleate plus 20 moles of ethylene oxide, imidazolines and mixtures thereof, and from about 20-75% by weight of water.
An emulsion coating composition which is self-shin-ing and non-crevice whitening comprising from about 0.05-2%
of an ethoxylated, nonionic surfactant having an ethylene oxide content of from 40-100, from about 15-70% by weight of a solvent, from about 0-30% by weight of a hard wax, from about 0-30% by weight of a soft wax wherein the combined amount of hard wax and soft wax in the composition is from about 3-35%, from about 0.3-4% of an emulsifier selected from the group consisting of oxazolines, fatty acid diethanolamides, quaternary ammonium compounds, mixtures of sorbitan monooleate and sorbitan monooleate plus 20 moles of ethylene oxide, imidazolines and mixtures thereof, and from about 20-75% by weight of water.
Description
~ ~7~ S~ ~
This invention relates to a~ improved oil-out emul-sion, sel~-shining coating compositions. More particularly, thi~ invention relate8 to Dil~out emulsion, sel~-shining woDd ~loor, vinyl and vinyl asbestos ~loors, and terrazo ~loor fin-ishes which do not crevice whiten, are substantially s~ shin-ing upon application, and which will clean water-borne stains ~rom a floor surface.
Mo~t ~inishe~ de~igned ~or application to wood floor surfaces, especially un~ealed wood ~loors, are ~olvent systems.
In those compositions, which contain water, the percentage of water varies widely depending on the intended use, Some prod-ucts designed primarily ~or fully sealed woods, such as furni ture can contain substantial amount~ o~ water. However, it has generally been recognized that large amounts of water are detri-mental to an unse~led wood sur~ace often encountered on floors.
Futhermore, most solvent wax ~ystem~ and emulslon systems have a property known as creviee-whitening, i.e., wax deposits in the interstice~ or crevices o~ the wood ~orming a white deposit.
Further, most prior solvent systems are not selr-shining but must be buffed to produce a shine, or if they are sel~-shining are not bu~able to maintain the fini~h.
Most prior oil-out emulsions deaigned for floor ~in-i~hing use anionic, nonionic, or anionic-nonionic emulsi~ication syste~. Although these surfactant combinations produced stable emulsion~, these products w~re not found satis~actory for a var-iety of re~s ons . . .
The ~ompositions o~ the pre~ent inv~ntion obviate theproblems of the prior art and provide a product which i~ ~ome-what glo8sy or ~hiny upon appllcation, doe~ not crevice whiten, contains high level~ o~ water thereby allowing a less e~pensive product to be produced having desirable per~ormance propertie~, ~, ., ~78SS~
.. .
and also the ini~ial gloss or shine can be buffed to hiyher levels of shine if desired.
The present invention provides a water-in-oil emul-sion coating composition comprising:
0.05-2% by weight of an ethoxylated noniorlic sur-factant having an ethylene o~ide content of 40-100 moles of ethylene oxide;
up to 30% by weight of a hard wax;
up to 30% b~-weight of a soft wax;
0.3-4% by weight of an emulsifier selected from oxazolines, imidazolines, quaternary ammonium com-pounds, fatty acid diethanolamides, mixtures of sorbitan monooleate and sorbitan monooleate plus 20 moles of ethylene oxide, and mixtures thereof;
15-70% by weight of a solvent selected from the group consisting of naphtha, isoparaffinic hydro-carbon solvents having a distillation range of from 190 to 540~, hydrocarbon ethers~ and chlorinated solvents; and 20-75% by weight water;
wherein thè total wax content of the composition is from 3-35%
by weight.
It is, therefore, the primary object of the present invention to provide an oil-out emulsion coating composition having a self-shining characteristic.
It is a further object to provide a floor finish which can be applied to a number of surfaces, such as wood, terrazo, vinyl tile, vinyl asbestos tile, etc.
It is a still further object of the present invention to provide an oil-out wood floor finish which does not crevice whiten.
It is a still further object of the present invention to provide a self-shining wood floor finish which can be buffed to improve the shine characteristics.
The oil-out, self-shining emulsion coating compositions ~, . . .
~855~
o~ the present inventi~n compri~e 15-70~ o~ a hy~rocarbon s~l-vent, 0.05-2% of an ethoxylated nonionic surfactant having an ethylene oxide content of from 40-100, Prom 0.3-4% of an emul-sifier selected from oxazoline, Patty acid, diethanolamides, quaternary ammonium compounds, mixtures o~ sorbitan monooleate and sorbitan monooleate plus 20 moles of ethylene oxide, imida-zolines and mixtures, up to 30~ of a hard wax, up to 30~ oP a soft wax wherein the combined amount oP hard and soPt waxes within the range o~ from 3-35~, and ~rom 20-75~ by weight o~
water.
The compositions of the present invention include from about 15-70% by weight and prePerably Prom 25-35~ by weight oP an organic solvent. This material may be selected from a wide variety of materials and includes materials ~uch as high flash naphtha, various isoparafPinic hydrocarbon solvents having a distillation range of from 190F. to 540F., prePer-ably from 250F. to 540F., hydrocarbon ethers, chlorinatéd~
solvents, etc. I~ the distillation range is too low, the sol-vent evaporates too quickly, imparing spreading and leveling capacity. IP the range is too high, the drying o~ the emulsion Ls retarded, producing a film which requires bufPing to form a gloss or luster.
The composition of the present invention includes at least one wax. The particular wax used depends partially on the substance to be coated. A floor would require higher amounts oP a hard wax while surfaces not sub~ect to heavy use could be coated with a softer wax compositLon.
As used in the pre~ent speclficaklon and clQims, the term "hard wax" rePers to waxes ha~ing a melt point above about 80C., while the term "soPt wax" re~ers to waxes having a melt point below about 80C.
785S~
The composition oP the present lnvention includes up t~ 30~ by weight hard wax, and up to 30~ by weighk soft wax7 with the proviso that the total wax conten~ is within 3-35% by weight. It is pre~erred that the composition~ o~ the present invention include from about 5 to about 15~ by weight so~t wax.
Representative hard waxes use~ul in the composition of the present invention include unoxidized microcrystalline, oxidi~ed microcrystalline, Montan acid derivatives, natural plant waxes such as candelilla, carnauba, etc., hydrogenated natural oils such as rice bran, castor oil, etc., oxidized polyethylene waxes, unoxidized polyethylene waxes, polyvinyl octadecyl ether, unoxidized Fisher-Tropsch~ oxidized Fisher-Tropsch, etc.
Representative soft waxes include para~fins, oxidized and unoxidized microcrystalline having a melt point below 80C., ozo~orites, beeswax, etc.
The compositions of the present inventi~n also include ~rom 0.05-2% by weight and preierably ~rom 0.01-0.2~ by weight o~ an ethoxylated nonionic surfactant having an ethylene oxide conkent per mole o~ 40-100. These compositions preferably have a HLB value o~ 16-19 and most pre~erably 17.5-18.5. Any non-ionic æur~actant ~ormed from a fatty alcohol or an aryl-alkyl group alcohol is suitable so long as the ethylene oxide content and the HLB is within the above ranges. Representative non-ionics include polyoxyethylene stearate plus 40-100 moles E0, polyoxyethylene fatty glyceride plus 40-100 moles EOJ polyoxy-ethylene sorbitol hexaoleate plus 40-100 moles E0, polyoxy-ethylene octadecylamine plus 40-100 moles E0, octyl phenoxy-polyethoxy ethanol plus 40~100 moles E0, nonyl phenoxypoly-ethoxy ethanol plus 40-100 moles E0, etc.
The compositions o~ the present inventim also include 1~78~5~ ~
.. .
from 0.3-4% and pre~erably Erom 0.4-0.7% o a cationic or non-ionic emulsiier selected from oxazoline, quaternary ammonium compounds, fatty acid diethanolamides, mixtures of sorbitan monooleate and sorbitan rnonooleate plus 20 moles of ethylene oxide, and imidazolines. These materials are available commer-cially under a wide variety of materials. Suitable compositions are those sold under the trade marks Alkaterge-T, Varisoft 475, mixtures of composition sold under the trade marks Span 80 and Tween 80, Atlas G-3634A, and Schercomol I.
The composition of the present invention also includes from 20-70% by weight water and preferably from 30-70% by weight water. The water used in these compositions need not be deion-ized or distilled as ordinary tap water is satisfactory.
The compositions of the present invention may be pre-pared in either liquid or paste form, depending on the relative -amounts of water and solvent used and the waxes used. For a liquid composition, from 25-55% by weight solvent and from 35-70% by weight water is preferred. For paste products, from 35-75% water is used and from 15-35% solvent. The coating composi-tions can be prepared with a non-volatile content of from about 4-40% by weight. The non-volatile content of the liquid should be from 4-12% and preferably 6-10% by weight. For the paste, the non-volatiles should be from 12-40~ and preferably from 12-20~ by weight.
The compositions of the present invention may be pre-pared by blending the oil-soluble materials together and the water-soluble materials together. Then the oil-soluble and water-soluble materials are then blended with agitation to form a stable water-in-oil emulsion. The order of mixing is not im-portant. Generally, it is preferred to melt the waxes prior to mixing with the water-soluble materials. The materials are mixed for approximately 10-30 minutes at 95C. These materials .. . . .
~ ~7 8 55 ~
are then force cooled t~ approx~mately r~m temperature. The composition can then be optlonally homogenized wlth any con-ventional homogenizer at a pressure o~ above 50 psig.
This invention relates to a~ improved oil-out emul-sion, sel~-shining coating compositions. More particularly, thi~ invention relate8 to Dil~out emulsion, sel~-shining woDd ~loor, vinyl and vinyl asbestos ~loors, and terrazo ~loor fin-ishes which do not crevice whiten, are substantially s~ shin-ing upon application, and which will clean water-borne stains ~rom a floor surface.
Mo~t ~inishe~ de~igned ~or application to wood floor surfaces, especially un~ealed wood ~loors, are ~olvent systems.
In those compositions, which contain water, the percentage of water varies widely depending on the intended use, Some prod-ucts designed primarily ~or fully sealed woods, such as furni ture can contain substantial amount~ o~ water. However, it has generally been recognized that large amounts of water are detri-mental to an unse~led wood sur~ace often encountered on floors.
Futhermore, most solvent wax ~ystem~ and emulslon systems have a property known as creviee-whitening, i.e., wax deposits in the interstice~ or crevices o~ the wood ~orming a white deposit.
Further, most prior solvent systems are not selr-shining but must be buffed to produce a shine, or if they are sel~-shining are not bu~able to maintain the fini~h.
Most prior oil-out emulsions deaigned for floor ~in-i~hing use anionic, nonionic, or anionic-nonionic emulsi~ication syste~. Although these surfactant combinations produced stable emulsion~, these products w~re not found satis~actory for a var-iety of re~s ons . . .
The ~ompositions o~ the pre~ent inv~ntion obviate theproblems of the prior art and provide a product which i~ ~ome-what glo8sy or ~hiny upon appllcation, doe~ not crevice whiten, contains high level~ o~ water thereby allowing a less e~pensive product to be produced having desirable per~ormance propertie~, ~, ., ~78SS~
.. .
and also the ini~ial gloss or shine can be buffed to hiyher levels of shine if desired.
The present invention provides a water-in-oil emul-sion coating composition comprising:
0.05-2% by weight of an ethoxylated noniorlic sur-factant having an ethylene o~ide content of 40-100 moles of ethylene oxide;
up to 30% by weight of a hard wax;
up to 30% b~-weight of a soft wax;
0.3-4% by weight of an emulsifier selected from oxazolines, imidazolines, quaternary ammonium com-pounds, fatty acid diethanolamides, mixtures of sorbitan monooleate and sorbitan monooleate plus 20 moles of ethylene oxide, and mixtures thereof;
15-70% by weight of a solvent selected from the group consisting of naphtha, isoparaffinic hydro-carbon solvents having a distillation range of from 190 to 540~, hydrocarbon ethers~ and chlorinated solvents; and 20-75% by weight water;
wherein thè total wax content of the composition is from 3-35%
by weight.
It is, therefore, the primary object of the present invention to provide an oil-out emulsion coating composition having a self-shining characteristic.
It is a further object to provide a floor finish which can be applied to a number of surfaces, such as wood, terrazo, vinyl tile, vinyl asbestos tile, etc.
It is a still further object of the present invention to provide an oil-out wood floor finish which does not crevice whiten.
It is a still further object of the present invention to provide a self-shining wood floor finish which can be buffed to improve the shine characteristics.
The oil-out, self-shining emulsion coating compositions ~, . . .
~855~
o~ the present inventi~n compri~e 15-70~ o~ a hy~rocarbon s~l-vent, 0.05-2% of an ethoxylated nonionic surfactant having an ethylene oxide content of from 40-100, Prom 0.3-4% of an emul-sifier selected from oxazoline, Patty acid, diethanolamides, quaternary ammonium compounds, mixtures o~ sorbitan monooleate and sorbitan monooleate plus 20 moles of ethylene oxide, imida-zolines and mixtures, up to 30~ of a hard wax, up to 30~ oP a soft wax wherein the combined amount oP hard and soPt waxes within the range o~ from 3-35~, and ~rom 20-75~ by weight o~
water.
The compositions of the present invention include from about 15-70% by weight and prePerably Prom 25-35~ by weight oP an organic solvent. This material may be selected from a wide variety of materials and includes materials ~uch as high flash naphtha, various isoparafPinic hydrocarbon solvents having a distillation range of from 190F. to 540F., prePer-ably from 250F. to 540F., hydrocarbon ethers, chlorinatéd~
solvents, etc. I~ the distillation range is too low, the sol-vent evaporates too quickly, imparing spreading and leveling capacity. IP the range is too high, the drying o~ the emulsion Ls retarded, producing a film which requires bufPing to form a gloss or luster.
The composition of the present invention includes at least one wax. The particular wax used depends partially on the substance to be coated. A floor would require higher amounts oP a hard wax while surfaces not sub~ect to heavy use could be coated with a softer wax compositLon.
As used in the pre~ent speclficaklon and clQims, the term "hard wax" rePers to waxes ha~ing a melt point above about 80C., while the term "soPt wax" re~ers to waxes having a melt point below about 80C.
785S~
The composition oP the present lnvention includes up t~ 30~ by weight hard wax, and up to 30~ by weighk soft wax7 with the proviso that the total wax conten~ is within 3-35% by weight. It is pre~erred that the composition~ o~ the present invention include from about 5 to about 15~ by weight so~t wax.
Representative hard waxes use~ul in the composition of the present invention include unoxidized microcrystalline, oxidi~ed microcrystalline, Montan acid derivatives, natural plant waxes such as candelilla, carnauba, etc., hydrogenated natural oils such as rice bran, castor oil, etc., oxidized polyethylene waxes, unoxidized polyethylene waxes, polyvinyl octadecyl ether, unoxidized Fisher-Tropsch~ oxidized Fisher-Tropsch, etc.
Representative soft waxes include para~fins, oxidized and unoxidized microcrystalline having a melt point below 80C., ozo~orites, beeswax, etc.
The compositions of the present inventi~n also include ~rom 0.05-2% by weight and preierably ~rom 0.01-0.2~ by weight o~ an ethoxylated nonionic surfactant having an ethylene oxide conkent per mole o~ 40-100. These compositions preferably have a HLB value o~ 16-19 and most pre~erably 17.5-18.5. Any non-ionic æur~actant ~ormed from a fatty alcohol or an aryl-alkyl group alcohol is suitable so long as the ethylene oxide content and the HLB is within the above ranges. Representative non-ionics include polyoxyethylene stearate plus 40-100 moles E0, polyoxyethylene fatty glyceride plus 40-100 moles EOJ polyoxy-ethylene sorbitol hexaoleate plus 40-100 moles E0, polyoxy-ethylene octadecylamine plus 40-100 moles E0, octyl phenoxy-polyethoxy ethanol plus 40~100 moles E0, nonyl phenoxypoly-ethoxy ethanol plus 40-100 moles E0, etc.
The compositions o~ the present inventim also include 1~78~5~ ~
.. .
from 0.3-4% and pre~erably Erom 0.4-0.7% o a cationic or non-ionic emulsiier selected from oxazoline, quaternary ammonium compounds, fatty acid diethanolamides, mixtures of sorbitan monooleate and sorbitan rnonooleate plus 20 moles of ethylene oxide, and imidazolines. These materials are available commer-cially under a wide variety of materials. Suitable compositions are those sold under the trade marks Alkaterge-T, Varisoft 475, mixtures of composition sold under the trade marks Span 80 and Tween 80, Atlas G-3634A, and Schercomol I.
The composition of the present invention also includes from 20-70% by weight water and preferably from 30-70% by weight water. The water used in these compositions need not be deion-ized or distilled as ordinary tap water is satisfactory.
The compositions of the present invention may be pre-pared in either liquid or paste form, depending on the relative -amounts of water and solvent used and the waxes used. For a liquid composition, from 25-55% by weight solvent and from 35-70% by weight water is preferred. For paste products, from 35-75% water is used and from 15-35% solvent. The coating composi-tions can be prepared with a non-volatile content of from about 4-40% by weight. The non-volatile content of the liquid should be from 4-12% and preferably 6-10% by weight. For the paste, the non-volatiles should be from 12-40~ and preferably from 12-20~ by weight.
The compositions of the present invention may be pre-pared by blending the oil-soluble materials together and the water-soluble materials together. Then the oil-soluble and water-soluble materials are then blended with agitation to form a stable water-in-oil emulsion. The order of mixing is not im-portant. Generally, it is preferred to melt the waxes prior to mixing with the water-soluble materials. The materials are mixed for approximately 10-30 minutes at 95C. These materials .. . . .
~ ~7 8 55 ~
are then force cooled t~ approx~mately r~m temperature. The composition can then be optlonally homogenized wlth any con-ventional homogenizer at a pressure o~ above 50 psig.
Claims (12)
1. A water-in-oil emulsion coating composition com-prising:
0.05-2% by weight of an ethoxylated nonionic surfac-tant having an ethylene oxide content of 40-100 moles of ethylene oxide;
up to 30% by weight of a hard wax;
up to 30% by weight of a soft wax;
0.3-4% by weight of an emulsifier selected from oxa-zolines, imidazolines, quaternary ammonium compounds, fatty acid diethanolamides, mixtures of sorbitan monooleate and sorbitan monooleate plus 20 moles of ethylene oxide, and mixtures thereof;
15-70% by weight of a solvent selected from the group consisting of naphtha, isoparaffinic hydrocarbon solvents having a distillation range of from 190 to 540°F, hydrocarbon ethers and chlorinated solvents; and 20-75% by weight water;
wherein the total wax content of the composition is from 3-35%
by weight.
0.05-2% by weight of an ethoxylated nonionic surfac-tant having an ethylene oxide content of 40-100 moles of ethylene oxide;
up to 30% by weight of a hard wax;
up to 30% by weight of a soft wax;
0.3-4% by weight of an emulsifier selected from oxa-zolines, imidazolines, quaternary ammonium compounds, fatty acid diethanolamides, mixtures of sorbitan monooleate and sorbitan monooleate plus 20 moles of ethylene oxide, and mixtures thereof;
15-70% by weight of a solvent selected from the group consisting of naphtha, isoparaffinic hydrocarbon solvents having a distillation range of from 190 to 540°F, hydrocarbon ethers and chlorinated solvents; and 20-75% by weight water;
wherein the total wax content of the composition is from 3-35%
by weight.
2. The composition of claim 1 wherein said nonionic surfactant has a HLB of from 16-19.
3. The composition of claim 1 wherein said emulsi-fier is an oxazoline.
4. The composition of claim 1 wherein said nonionic surfactant has a HLB of 17.5-18.5.
5. The composition of claim 1 wherein said composi-tion comprises:
0.01-0.2% nonionic surfactant, 5-15% hard wax, 5-15% soft wax, 0.4-0.7% emulsifier, 25-55% solvent, and 30-70% water.
0.01-0.2% nonionic surfactant, 5-15% hard wax, 5-15% soft wax, 0.4-0.7% emulsifier, 25-55% solvent, and 30-70% water.
6. The composition of claim 5 wherein said solvent is naphtha.
7, The composition of claim 5 wherein said nonionic surfactant has a HLB of from 16-19,
8. The composition of claim 5 wherein said emulsi-fier is an oxazoline.
9, The composition of claim 5 wherein said nonionic surfactant has a HLB of 17.5-18.5.
10. The composition of claim 1 wherein the total nonvolatiles are from 4-40% by weight.
11. The composition of claim 10 wherein the non-volatile content is 6-10% by weight,
12. The composition of claim 10 wherein the non-volatile content is 12-20% by weight.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/637,544 US4055433A (en) | 1975-12-04 | 1975-12-04 | Oil-out self-shining emulsion coating composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1078554A true CA1078554A (en) | 1980-06-03 |
Family
ID=24556389
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA267,155A Expired CA1078554A (en) | 1975-12-04 | 1976-12-03 | Oil-out self-shining emulsion coating composition |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US4055433A (en) |
| JP (1) | JPS5278785A (en) |
| AU (1) | AU499027B2 (en) |
| CA (1) | CA1078554A (en) |
| FR (1) | FR2333841A1 (en) |
| GB (1) | GB1532869A (en) |
| IT (1) | IT1066663B (en) |
| NL (1) | NL7613482A (en) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2824716A1 (en) * | 1978-06-06 | 1979-12-13 | Hoechst Ag | PROCESS FOR THE MANUFACTURING OF Aqueous CLEANING AGENT EMULSIONS CONTAINING DISINFECTANTS |
| CH648981GA3 (en) | 1979-02-13 | 1985-04-30 | ||
| US4317755A (en) * | 1980-06-11 | 1982-03-02 | S. C. Johnson & Son, Inc. | Self-polishing sealing composition |
| US4371398A (en) * | 1980-07-16 | 1983-02-01 | Petrolite Corporation | Polishes/polish restorers |
| US4479981A (en) * | 1982-05-03 | 1984-10-30 | Ashland Oil, Inc. | Water-borne hard coating compositions and processes therefor |
| US4497919A (en) * | 1983-09-22 | 1985-02-05 | Turtle Wax, Inc. | Emulsion polish compositions |
| US5368712A (en) * | 1989-11-02 | 1994-11-29 | Synporin Technologies, Inc. | Biologically mimetic synthetic ion channel transducers |
| GB2256648B (en) * | 1991-05-29 | 1995-08-30 | Colorcon Ltd | Wax polish composition |
| US5300141A (en) * | 1992-05-11 | 1994-04-05 | Floyd Meguiar | Anti-static compositions for molds, molded parts and painted surfaces |
| US5387363A (en) * | 1992-06-02 | 1995-02-07 | Elf Atochem North America, Inc. | Water in oil emulsions |
| DE4329244A1 (en) * | 1993-08-31 | 1995-03-02 | Sandoz Ag | Aqueous wax and silicone dispersions, their preparation and use |
| DE4433597C2 (en) * | 1993-09-28 | 1996-10-02 | Clariant Finance Bvi Ltd | Process for increasing the wet lubricity of textile material and wet lubricant therefor |
| JP3745491B2 (en) * | 1997-03-04 | 2006-02-15 | ユシロ化学工業株式会社 | Aqueous polishing composition for floors |
| US5945474A (en) * | 1997-10-06 | 1999-08-31 | Gaultier; Serge | Composition and method for removing a substance from a finished surface |
| US6066201A (en) * | 1998-11-09 | 2000-05-23 | Ergon, Inc. | Thixotropic wax emulsion compositions |
| DE19852752A1 (en) * | 1998-11-16 | 2000-05-18 | Werner & Mertz Gmbh | Leather care products |
| US6551974B1 (en) * | 1999-04-20 | 2003-04-22 | Ecolab Inc. | Polish compositions for gloss enhancement, and method |
| GB0016412D0 (en) | 2000-07-04 | 2000-08-23 | Reckitt & Colmann Prod Ltd | Improvements in or relating to organic compositions |
| AU2004284035B2 (en) * | 2003-06-05 | 2011-01-27 | Hexion Specialty Chemicals Inc. | Emulsions for lignocellulosic products, methods of their manufacture, improved lignocellulosic products and methods for their manufacture |
| EP1910507B1 (en) * | 2005-06-29 | 2018-06-13 | Hexion Research Belgium SA | Wax emulsions for lingnocellulosic products, methods of their manufacture and products formed therefrom |
| CA2747936C (en) * | 2008-12-22 | 2017-04-25 | Henkel Ag & Co. Kgaa | Water-based cleaner for cleaning solvent-based paints |
| US9403999B2 (en) * | 2014-04-01 | 2016-08-02 | Angus Chemical Company | Oxazoline compounds as open-time extenders for latex paints |
| CN105860856A (en) * | 2016-04-29 | 2016-08-17 | 四川力久知识产权服务有限公司 | Leather polishing wax emulsion and preparation method thereof |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1986936A (en) * | 1930-03-07 | 1935-01-08 | Du Pont | Polishing composition |
| US2441842A (en) * | 1944-08-24 | 1948-05-18 | Jr Leon M Prince | Wax emulsion |
| FR1174736A (en) * | 1956-05-16 | 1959-03-16 | Easy Glitter Wax Company | Emulsified wax compositions such as polishing materials |
| FR1303541A (en) * | 1961-07-31 | 1962-09-14 | emulsion for polishing | |
| SE347987B (en) * | 1967-08-05 | 1972-08-21 | Hoechst Ag | |
| US3447935A (en) * | 1967-12-21 | 1969-06-03 | Lawrence L Marley | Fluid polishing composition and method of making |
| US3819530A (en) * | 1968-07-15 | 1974-06-25 | Sun Oil Co | Stabilized wax emulsions |
| DE2063734C3 (en) * | 1970-12-24 | 1975-08-28 | Hoechst Ag, 6000 Frankfurt | Waxes with melt viscosities from 40 to 700 cP / 120 degrees C for ionic / non-ionic self-gloss emulsions and processes for their production |
| US3702769A (en) * | 1971-01-04 | 1972-11-14 | Dow Corning | Method of polishing leather with compositions containing reaction product of hydroxy endblocked siloxanes and aminofunctional silanes |
| US3929499A (en) * | 1972-09-08 | 1975-12-30 | Frederick L Thomas | High water-content water in oil emulsion |
-
1975
- 1975-12-04 US US05/637,544 patent/US4055433A/en not_active Expired - Lifetime
-
1976
- 1976-12-03 FR FR7636492A patent/FR2333841A1/en active Granted
- 1976-12-03 NL NL7613482A patent/NL7613482A/en not_active Application Discontinuation
- 1976-12-03 JP JP51144821A patent/JPS5278785A/en active Granted
- 1976-12-03 IT IT52458/76A patent/IT1066663B/en active
- 1976-12-03 CA CA267,155A patent/CA1078554A/en not_active Expired
- 1976-12-03 GB GB50583/76A patent/GB1532869A/en not_active Expired
- 1976-12-06 AU AU20296/76A patent/AU499027B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB1532869A (en) | 1978-11-22 |
| AU499027B2 (en) | 1979-04-05 |
| JPS6219469B2 (en) | 1987-04-28 |
| AU2029676A (en) | 1978-06-15 |
| FR2333841A1 (en) | 1977-07-01 |
| FR2333841B1 (en) | 1982-05-14 |
| US4055433A (en) | 1977-10-25 |
| NL7613482A (en) | 1977-06-07 |
| JPS5278785A (en) | 1977-07-02 |
| IT1066663B (en) | 1985-03-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |