CA1078138A - Production of chlorine dioxide - Google Patents
Production of chlorine dioxideInfo
- Publication number
- CA1078138A CA1078138A CA241,682A CA241682A CA1078138A CA 1078138 A CA1078138 A CA 1078138A CA 241682 A CA241682 A CA 241682A CA 1078138 A CA1078138 A CA 1078138A
- Authority
- CA
- Canada
- Prior art keywords
- alkali metal
- generator
- continuously
- acid
- column
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 title claims abstract description 44
- 239000004155 Chlorine dioxide Substances 0.000 title claims abstract description 22
- 235000019398 chlorine dioxide Nutrition 0.000 title claims abstract description 22
- 238000004519 manufacturing process Methods 0.000 title abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 26
- 238000000034 method Methods 0.000 claims abstract description 25
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical class [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims abstract description 15
- 230000007935 neutral effect Effects 0.000 claims abstract description 12
- 229910052936 alkali metal sulfate Chemical class 0.000 claims abstract description 7
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims abstract description 6
- 230000006872 improvement Effects 0.000 claims abstract description 4
- XTEGARKTQYYJKE-UHFFFAOYSA-M chlorate Inorganic materials [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 claims description 39
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 34
- 239000002253 acid Substances 0.000 claims description 28
- 239000002002 slurry Substances 0.000 claims description 28
- 239000013078 crystal Substances 0.000 claims description 24
- 238000006243 chemical reaction Methods 0.000 claims description 21
- -1 alkali metal chlorate Chemical class 0.000 claims description 18
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 12
- 239000011707 mineral Substances 0.000 claims description 12
- 229910052783 alkali metal Inorganic materials 0.000 claims description 10
- 238000005406 washing Methods 0.000 claims description 10
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 7
- 239000000460 chlorine Substances 0.000 claims description 7
- 229910052801 chlorine Inorganic materials 0.000 claims description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical group [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 6
- 229910001514 alkali metal chloride Inorganic materials 0.000 claims description 6
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 claims description 6
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
- 229910052785 arsenic Inorganic materials 0.000 claims description 3
- 239000003054 catalyst Substances 0.000 claims description 3
- 230000000694 effects Effects 0.000 claims description 3
- 238000001704 evaporation Methods 0.000 claims description 3
- 230000008020 evaporation Effects 0.000 claims description 3
- 229910052709 silver Inorganic materials 0.000 claims description 3
- 239000004332 silver Substances 0.000 claims description 3
- 239000011780 sodium chloride Substances 0.000 claims description 3
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical group CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 claims description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 2
- 229910052753 mercury Inorganic materials 0.000 claims description 2
- 229910001437 manganese ion Inorganic materials 0.000 claims 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 11
- 229910052938 sodium sulfate Inorganic materials 0.000 description 11
- 235000011152 sodium sulphate Nutrition 0.000 description 11
- 238000005086 pumping Methods 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 230000001419 dependent effect Effects 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 235000011007 phosphoric acid Nutrition 0.000 description 2
- 229960004838 phosphoric acid Drugs 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 101100453921 Caenorhabditis elegans kin-29 gene Proteins 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000002844 continuous effect Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- HFCSXCKLARAMIQ-UHFFFAOYSA-L disodium;sulfate;hydrate Chemical class O.[Na+].[Na+].[O-]S([O-])(=O)=O HFCSXCKLARAMIQ-UHFFFAOYSA-L 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000004076 pulp bleaching Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2415—Tubular reactors
- B01J19/242—Tubular reactors in series
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/14—Fractional distillation or use of a fractionation or rectification column
- B01D3/16—Fractionating columns in which vapour bubbles through liquid
- B01D3/24—Fractionating columns in which vapour bubbles through liquid with sloping plates or elements mounted stepwise
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C01B11/02—Oxides of chlorine
- C01B11/022—Chlorine dioxide (ClO2)
- C01B11/023—Preparation from chlorites or chlorates
- C01B11/025—Preparation from chlorites or chlorates from chlorates without any other reaction reducing agent than chloride ions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00164—Controlling or regulating processes controlling the flow
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA338,891A CA1078139A (en) | 1974-12-13 | 1979-10-31 | Production of chlorine dioxide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/532,666 US3975505A (en) | 1974-12-13 | 1974-12-13 | Production of chlorine dioxide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1078138A true CA1078138A (en) | 1980-05-27 |
Family
ID=24122676
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA241,682A Expired CA1078138A (en) | 1974-12-13 | 1975-12-11 | Production of chlorine dioxide |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US3975505A (enExample) |
| JP (1) | JPS5924081B2 (enExample) |
| AU (1) | AU503224B2 (enExample) |
| BR (1) | BR7508126A (enExample) |
| CA (1) | CA1078138A (enExample) |
| ES (1) | ES443485A1 (enExample) |
| FI (1) | FI753486A7 (enExample) |
| FR (1) | FR2294129A1 (enExample) |
| MX (1) | MX3000E (enExample) |
| SE (1) | SE415556B (enExample) |
| SU (1) | SU701527A3 (enExample) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4045542A (en) * | 1974-12-13 | 1977-08-30 | Hooker Chemicals & Plastics Corporation | Production of chlorine dioxide |
| US4156713A (en) * | 1974-12-13 | 1979-05-29 | Hooker Chemicals & Plastics Corp. | Production of chlorine dioxide |
| ZA786778B (en) * | 1978-01-03 | 1980-07-30 | Erco Ind Ltd | Improved washing procedure in chlorine dioxide production |
| US4206193A (en) * | 1978-12-18 | 1980-06-03 | Hooker Chemicals & Plastics Corp. | Versatile process for generating chlorine dioxide |
| US4290998A (en) * | 1978-12-21 | 1981-09-22 | Erco Industries Limited | Washing apparatus in chlorine dioxide production |
| US4886653A (en) * | 1988-03-25 | 1989-12-12 | Olin Corporation | Process and apparatus for producing an aqueous solution containing chlorine dioxide and chlorine |
| US4839152A (en) * | 1988-03-25 | 1989-06-13 | Olin Corporation | Process for producing an aqueous solution containing chlorine dioxide and chlorine |
| US5116595A (en) * | 1991-04-22 | 1992-05-26 | Tenneco Canada Inc. | Metathesis of acidic by-product of chlorine dioxide generating process |
| US5205995A (en) * | 1991-04-22 | 1993-04-27 | Sterling Canada Inc. | Metathesis of acidic by-product of chlorine dioxide generating apparatus |
| WO1994011300A1 (en) | 1992-11-09 | 1994-05-26 | Sterling Canada, Inc. | Metathesis of acidic by-product of chlorine dioxide generating process |
| US5399332A (en) * | 1993-10-20 | 1995-03-21 | Sterling Canada, Inc. | Dynamic leaching procedure for metathesis |
| US5458858A (en) * | 1994-02-08 | 1995-10-17 | Vulcan Chemicals | Integrated procedure for high yield production of chlorine dioxide |
| US5676920A (en) * | 1996-08-20 | 1997-10-14 | Sterling Canada, Inc. | Chlorine dioxide generating process |
| US5792441A (en) * | 1996-10-11 | 1998-08-11 | Pulp And Paper Research Institute Of Canada | Fixed-resin bed technologies for the treatment of the chlorine dioxide generator effluent and feeds stream |
| US6126702A (en) * | 1998-03-09 | 2000-10-03 | International Paper Company | Apparatus and method for treating sesquisulfate waste streams |
| US6716354B2 (en) | 2001-03-08 | 2004-04-06 | Cdg Technology, Inc. | Methods of treating water using combinations of chlorine dioxide, chlorine and ammonia |
| US20030138371A1 (en) * | 2002-01-18 | 2003-07-24 | Cdg Technology, Inc. | Method and apparatus for generating gaseous chlorine dioxide-chlorine mixtures |
| CA2674444C (en) * | 2007-01-12 | 2016-03-08 | Akzo Nobel N.V. | Process for the production of chlorine dioxide |
| EP2550393A2 (en) * | 2010-03-23 | 2013-01-30 | International Paper Company | Improved bctmp filtrate recycling system and method |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3563702A (en) * | 1968-03-05 | 1971-02-16 | Hooker Chemical Corp | Production of chlorine dioxide |
| US3760065A (en) * | 1970-05-29 | 1973-09-18 | Erco Ind Ltd | Production of chlorine dioxide |
| US3754081A (en) * | 1970-09-17 | 1973-08-21 | Hooker Chemical Corp | Process for the production of chlorine dioxide,chlorine and a mixtureof an alkali metal sulfate and bisulfate |
| US3793439A (en) * | 1971-02-17 | 1974-02-19 | Erco Ind Ltd | Production of chlorine dioxide |
| US3733395A (en) * | 1971-04-07 | 1973-05-15 | Hooker Chemical Corp | Process for producing chlorine dioxide,chlorine and a neutral sulfate salt in the sulfate or kraft process of preparing wood pulp |
-
1974
- 1974-12-13 US US05/532,666 patent/US3975505A/en not_active Expired - Lifetime
-
1975
- 1975-12-08 BR BR7508126*A patent/BR7508126A/pt unknown
- 1975-12-09 AU AU87365/75A patent/AU503224B2/en not_active Expired
- 1975-12-10 FR FR7537777A patent/FR2294129A1/fr not_active Withdrawn
- 1975-12-10 FI FI753486A patent/FI753486A7/fi not_active Application Discontinuation
- 1975-12-11 SE SE7513993A patent/SE415556B/xx unknown
- 1975-12-11 CA CA241,682A patent/CA1078138A/en not_active Expired
- 1975-12-11 JP JP50148328A patent/JPS5924081B2/ja not_active Expired
- 1975-12-11 MX MX100161U patent/MX3000E/es unknown
- 1975-12-12 SU SU752197704A patent/SU701527A3/ru active
- 1975-12-13 ES ES443485A patent/ES443485A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| BR7508126A (pt) | 1976-08-24 |
| SE415556B (sv) | 1980-10-13 |
| MX3000E (es) | 1980-01-23 |
| SE7513993L (sv) | 1976-06-14 |
| JPS5924081B2 (ja) | 1984-06-07 |
| SU701527A3 (ru) | 1979-11-30 |
| AU503224B2 (en) | 1979-08-30 |
| US3975505A (en) | 1976-08-17 |
| ES443485A1 (es) | 1977-08-01 |
| FI753486A7 (enExample) | 1976-06-14 |
| AU8736575A (en) | 1977-06-16 |
| JPS5186096A (enExample) | 1976-07-28 |
| FR2294129A1 (fr) | 1976-07-09 |
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| US4290998A (en) | Washing apparatus in chlorine dioxide production | |
| CA1117731A (en) | Washing procedure in chlorine dioxide production | |
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| JPH11255503A (ja) | 低食塩次亜塩素酸ソーダ水溶液の製造方法 | |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |