CA1069643A - Chlorure de polyvinyle resistant a l'impact, a base de copolymeres de type ethylene-acetate de vinyle et de type ethylene-acrylate d'alkyle - Google Patents
Chlorure de polyvinyle resistant a l'impact, a base de copolymeres de type ethylene-acetate de vinyle et de type ethylene-acrylate d'alkyleInfo
- Publication number
- CA1069643A CA1069643A CA226,406A CA226406A CA1069643A CA 1069643 A CA1069643 A CA 1069643A CA 226406 A CA226406 A CA 226406A CA 1069643 A CA1069643 A CA 1069643A
- Authority
- CA
- Canada
- Prior art keywords
- weight
- ethylene
- copolymers
- copolymer
- vinyl acetate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000915 polyvinyl chloride Polymers 0.000 title claims abstract description 27
- 239000004800 polyvinyl chloride Substances 0.000 title claims abstract description 27
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 title abstract description 8
- 239000005038 ethylene vinyl acetate Substances 0.000 title abstract description 7
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 title abstract description 6
- 229920000800 acrylic rubber Polymers 0.000 title abstract description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 title description 4
- 229920000578 graft copolymer Polymers 0.000 claims abstract description 40
- 229920001577 copolymer Polymers 0.000 claims abstract description 36
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims abstract description 17
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000000203 mixture Substances 0.000 claims abstract description 16
- 239000005977 Ethylene Substances 0.000 claims abstract description 11
- 239000000654 additive Substances 0.000 claims abstract description 9
- 229920005601 base polymer Polymers 0.000 claims abstract description 9
- 229920001038 ethylene copolymer Polymers 0.000 claims abstract description 7
- 125000005250 alkyl acrylate group Chemical group 0.000 claims abstract description 4
- 229920002959 polymer blend Polymers 0.000 claims abstract 2
- 239000003381 stabilizer Substances 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 238000000354 decomposition reaction Methods 0.000 claims description 2
- 239000000945 filler Substances 0.000 claims description 2
- 239000000314 lubricant Substances 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 229940093470 ethylene Drugs 0.000 claims 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract description 10
- 239000000463 material Substances 0.000 abstract description 7
- 229940117958 vinyl acetate Drugs 0.000 description 11
- 239000000460 chlorine Substances 0.000 description 10
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 9
- 229910052801 chlorine Inorganic materials 0.000 description 8
- 239000012071 phase Substances 0.000 description 8
- 238000005096 rolling process Methods 0.000 description 7
- 230000000875 corresponding effect Effects 0.000 description 6
- 238000007792 addition Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 3
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
- 241000543381 Cliftonia monophylla Species 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229920006228 ethylene acrylate copolymer Polymers 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- DNPFOADIPJWGQH-UHFFFAOYSA-N octan-3-yl prop-2-enoate Chemical class CCCCCC(CC)OC(=O)C=C DNPFOADIPJWGQH-UHFFFAOYSA-N 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000007790 solid phase Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 238000010408 sweeping Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- PRIUALOJYOZZOJ-UHFFFAOYSA-L 2-ethylhexyl 2-[dibutyl-[2-(2-ethylhexoxy)-2-oxoethyl]sulfanylstannyl]sulfanylacetate Chemical compound CCCCC(CC)COC(=O)CS[Sn](CCCC)(CCCC)SCC(=O)OCC(CC)CCCC PRIUALOJYOZZOJ-UHFFFAOYSA-L 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 102100024133 Coiled-coil domain-containing protein 50 Human genes 0.000 description 1
- 101000910772 Homo sapiens Coiled-coil domain-containing protein 50 Proteins 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- FYLJKQFMQFOLSZ-UHFFFAOYSA-N cyclohexylperoxycyclohexane Chemical compound C1CCCCC1OOC1CCCCC1 FYLJKQFMQFOLSZ-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- PCLNQXZJUFRJSJ-UHFFFAOYSA-N hexan-3-yl prop-2-enoate Chemical class CCCC(CC)OC(=O)C=C PCLNQXZJUFRJSJ-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- ATADHKWKHYVBTJ-UHFFFAOYSA-N hydron;4-[1-hydroxy-2-(methylamino)ethyl]benzene-1,2-diol;chloride Chemical compound Cl.CNCC(O)C1=CC=C(O)C(O)=C1 ATADHKWKHYVBTJ-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000002103 osmometry Methods 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 125000005634 peroxydicarbonate group Chemical group 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- MBYLVOKEDDQJDY-UHFFFAOYSA-N tris(2-aminoethyl)amine Chemical compound NCCN(CCN)CCN MBYLVOKEDDQJDY-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2421900A DE2421900B2 (de) | 1974-05-07 | 1974-05-07 | Schlagfeste Massen auf der Basis von Polyvinylchlorid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1069643A true CA1069643A (fr) | 1980-01-08 |
Family
ID=5914801
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA226,406A Expired CA1069643A (fr) | 1974-05-07 | 1975-05-06 | Chlorure de polyvinyle resistant a l'impact, a base de copolymeres de type ethylene-acetate de vinyle et de type ethylene-acrylate d'alkyle |
Country Status (10)
| Country | Link |
|---|---|
| JP (1) | JPS5123559A (fr) |
| BE (1) | BE828724A (fr) |
| CA (1) | CA1069643A (fr) |
| DE (1) | DE2421900B2 (fr) |
| FR (1) | FR2270294B1 (fr) |
| GB (1) | GB1510537A (fr) |
| IT (1) | IT1044327B (fr) |
| NL (1) | NL7505396A (fr) |
| NO (1) | NO751570L (fr) |
| SE (1) | SE411455B (fr) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5599941A (en) * | 1979-01-23 | 1980-07-30 | Kanegafuchi Chem Ind Co Ltd | Impact-resistant resin composition having improved processability |
| CN101189279A (zh) * | 2005-06-03 | 2008-05-28 | 大曹株式会社 | 醚类聚合物的制备方法 |
-
1974
- 1974-05-07 DE DE2421900A patent/DE2421900B2/de not_active Withdrawn
-
1975
- 1975-05-02 NO NO751570A patent/NO751570L/no unknown
- 1975-05-02 GB GB18566/75A patent/GB1510537A/en not_active Expired
- 1975-05-05 IT IT49426/75A patent/IT1044327B/it active
- 1975-05-05 BE BE156052A patent/BE828724A/fr unknown
- 1975-05-06 FR FR7514236A patent/FR2270294B1/fr not_active Expired
- 1975-05-06 JP JP50054125A patent/JPS5123559A/ja active Pending
- 1975-05-06 SE SE7505235A patent/SE411455B/xx unknown
- 1975-05-06 CA CA226,406A patent/CA1069643A/fr not_active Expired
- 1975-05-07 NL NL7505396A patent/NL7505396A/xx not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| NO751570L (fr) | 1975-11-10 |
| JPS5123559A (fr) | 1976-02-25 |
| SE411455B (sv) | 1979-12-27 |
| DE2421900B2 (de) | 1980-01-10 |
| BE828724A (fr) | 1975-09-01 |
| SE7505235L (sv) | 1975-11-10 |
| IT1044327B (it) | 1980-03-20 |
| GB1510537A (en) | 1978-05-10 |
| DE2421900A1 (de) | 1975-12-04 |
| NL7505396A (nl) | 1975-11-11 |
| FR2270294A1 (fr) | 1975-12-05 |
| FR2270294B1 (fr) | 1980-12-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |