CA1054226A - Ion-selective electrode - Google Patents
Ion-selective electrodeInfo
- Publication number
- CA1054226A CA1054226A CA243,974A CA243974A CA1054226A CA 1054226 A CA1054226 A CA 1054226A CA 243974 A CA243974 A CA 243974A CA 1054226 A CA1054226 A CA 1054226A
- Authority
- CA
- Canada
- Prior art keywords
- ion
- conducting
- electrode
- matrix material
- matrix
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000002500 ions Chemical class 0.000 claims abstract description 34
- 239000011159 matrix material Substances 0.000 claims abstract description 25
- 238000000576 coating method Methods 0.000 claims abstract description 23
- 239000000463 material Substances 0.000 claims abstract description 21
- 239000011248 coating agent Substances 0.000 claims abstract description 20
- 239000000203 mixture Substances 0.000 claims abstract description 7
- 229910002692 Ag3SBr Inorganic materials 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 229910002691 Ag3SI Inorganic materials 0.000 claims description 3
- 238000000151 deposition Methods 0.000 claims description 2
- 230000008021 deposition Effects 0.000 claims description 2
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 claims description 2
- 235000011180 diphosphates Nutrition 0.000 claims description 2
- FJOLTQXXWSRAIX-UHFFFAOYSA-K silver phosphate Chemical compound [Ag+].[Ag+].[Ag+].[O-]P([O-])([O-])=O FJOLTQXXWSRAIX-UHFFFAOYSA-K 0.000 claims description 2
- 229940019931 silver phosphate Drugs 0.000 claims description 2
- 229910000161 silver phosphate Inorganic materials 0.000 claims description 2
- 238000004544 sputter deposition Methods 0.000 claims description 2
- BWFPGXWASODCHM-UHFFFAOYSA-N copper monosulfide Chemical compound [Cu]=S BWFPGXWASODCHM-UHFFFAOYSA-N 0.000 claims 1
- OMZSGWSJDCOLKM-UHFFFAOYSA-N copper(II) sulfide Chemical compound [S-2].[Cu+2] OMZSGWSJDCOLKM-UHFFFAOYSA-N 0.000 claims 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 11
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 11
- 239000008188 pellet Substances 0.000 description 5
- -1 iodide-sulphide Chemical class 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229910052946 acanthite Inorganic materials 0.000 description 3
- 150000004645 aluminates Chemical class 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 230000035945 sensitivity Effects 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 239000004332 silver Substances 0.000 description 3
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 3
- FSJWWSXPIWGYKC-UHFFFAOYSA-M silver;silver;sulfanide Chemical compound [SH-].[Ag].[Ag+] FSJWWSXPIWGYKC-UHFFFAOYSA-M 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 239000011149 active material Substances 0.000 description 2
- ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical class Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- VREFGVBLTWBCJP-UHFFFAOYSA-N alprazolam Chemical compound C12=CC(Cl)=CC=C2N2C(C)=NN=C2CN=C1C1=CC=CC=C1 VREFGVBLTWBCJP-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- INQOMBQAUSQDDS-UHFFFAOYSA-N iodomethane Chemical compound IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 description 1
- HXJNJLSAZAGIBV-UHFFFAOYSA-M iodosilver silver Chemical compound [Ag].I[Ag] HXJNJLSAZAGIBV-UHFFFAOYSA-M 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000002674 ointment Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 235000002020 sage Nutrition 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/28—Electrolytic cell components
- G01N27/30—Electrodes, e.g. test electrodes; Half-cells
- G01N27/333—Ion-selective electrodes or membranes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/447—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on phosphates, e.g. hydroxyapatite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3289—Noble metal oxides
- C04B2235/3291—Silver oxides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
- C04B2235/444—Halide containing anions, e.g. bromide, iodate, chlorite
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Ceramic Engineering (AREA)
- Electrochemistry (AREA)
- Manufacturing & Machinery (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Molecular Biology (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Conductive Materials (AREA)
- Investigating Or Analyzing Materials By The Use Of Fluid Adsorption Or Reactions (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Measuring Oxygen Concentration In Cells (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL7500823A NL7500823A (nl) | 1975-01-24 | 1975-01-24 | Ion-selektieve elektrode. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1054226A true CA1054226A (en) | 1979-05-08 |
Family
ID=19823043
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA243,974A Expired CA1054226A (en) | 1975-01-24 | 1976-01-21 | Ion-selective electrode |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US4083764A (enExample) |
| JP (1) | JPS5197491A (enExample) |
| BE (1) | BE837822A (enExample) |
| CA (1) | CA1054226A (enExample) |
| DE (1) | DE2600846C3 (enExample) |
| FR (1) | FR2298794A1 (enExample) |
| GB (1) | GB1531923A (enExample) |
| NL (1) | NL7500823A (enExample) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS578441A (en) * | 1980-06-18 | 1982-01-16 | Matsushita Electric Ind Co Ltd | Production of ion selective electrode |
| US4400255A (en) * | 1981-06-29 | 1983-08-23 | General Motors Corporation | Control of electron bombardment of the exhaust oxygen sensor during electrode sputtering |
| EP0126103B1 (en) * | 1982-10-29 | 1987-01-28 | Radiometer A/S | Ion-sensitive measuring electrode device |
| US4968409A (en) * | 1984-03-21 | 1990-11-06 | Chevron Research Company | Hydrocarbon processing of gas containing feed in a countercurrent moving catalyst bed |
| US5322611A (en) * | 1991-01-31 | 1994-06-21 | Solomon Zaromb | Humidity-resistant ambient-temperature solid-electrolyte amperometric sensing apparatus |
| US5552032A (en) * | 1995-04-24 | 1996-09-03 | Beckman Instruments, Inc. | Solid state ion selective electrode and method of using the same |
| JP4448243B2 (ja) * | 2000-09-13 | 2010-04-07 | 株式会社堀場製作所 | リン酸イオン選択性電極およびその作製方法 |
| RU2381493C1 (ru) * | 2008-12-22 | 2010-02-10 | ГОУ ВПО Саратовский Государственный Технический Университет (СГТУ) | Способ изготовления твердотельного ион-селективного электрода |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3563874A (en) * | 1967-10-02 | 1971-02-16 | Orion Research | Halide-sensitive electrochemical electrodes and method of making same |
| US3723589A (en) * | 1969-08-25 | 1973-03-27 | Bissett Berman Corp | Solid electrolyte electrolytic cell |
| US3649506A (en) * | 1969-10-14 | 1972-03-14 | Beckman Instruments Inc | Solid state glass electrode |
| US3657093A (en) * | 1970-03-03 | 1972-04-18 | Perkin Elmer Corp | Ion selective electrode for activity determination of cations which do not form as ionic semiconductors |
| DE2040200C3 (de) * | 1970-08-13 | 1974-02-14 | Jenaer Glaswerk Schott & Gen., 6500 Mainz | Membran für Elektroden zur Messung von Ionenkonzentrationen |
| US3892833A (en) * | 1972-11-10 | 1975-07-01 | Matsushita Electric Industrial Co Ltd | Method of making an ion-selective electrode |
| US3824170A (en) * | 1973-01-15 | 1974-07-16 | Control Data Corp | Ion selective electrode comprising cuprous sulfide and method of making said electrode |
| US3857777A (en) * | 1973-08-10 | 1974-12-31 | Environmental Protection Agenc | Ion exchange membrane for measuring orthophosphate |
-
1975
- 1975-01-24 NL NL7500823A patent/NL7500823A/xx not_active Application Discontinuation
- 1975-12-15 US US05/640,704 patent/US4083764A/en not_active Expired - Lifetime
-
1976
- 1976-01-12 DE DE2600846A patent/DE2600846C3/de not_active Expired
- 1976-01-21 JP JP51005095A patent/JPS5197491A/ja active Pending
- 1976-01-21 CA CA243,974A patent/CA1054226A/en not_active Expired
- 1976-01-21 GB GB2321/76A patent/GB1531923A/en not_active Expired
- 1976-01-22 BE BE163726A patent/BE837822A/xx unknown
- 1976-01-23 FR FR7601838A patent/FR2298794A1/fr active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| BE837822A (fr) | 1976-07-22 |
| JPS5197491A (en) | 1976-08-27 |
| FR2298794B1 (enExample) | 1981-09-18 |
| NL7500823A (nl) | 1976-07-27 |
| DE2600846A1 (de) | 1976-08-19 |
| DE2600846C3 (de) | 1980-07-10 |
| DE2600846B2 (de) | 1979-09-27 |
| FR2298794A1 (fr) | 1976-08-20 |
| GB1531923A (en) | 1978-11-15 |
| US4083764A (en) | 1978-04-11 |
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