CA1052727A - Nickel electrowinning process - Google Patents
Nickel electrowinning processInfo
- Publication number
- CA1052727A CA1052727A CA245,281A CA245281A CA1052727A CA 1052727 A CA1052727 A CA 1052727A CA 245281 A CA245281 A CA 245281A CA 1052727 A CA1052727 A CA 1052727A
- Authority
- CA
- Canada
- Prior art keywords
- nickel
- free
- sulfur
- gpl
- sulfate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims abstract description 95
- 229910052759 nickel Inorganic materials 0.000 title claims abstract description 46
- 238000005363 electrowinning Methods 0.000 title claims description 16
- 238000000034 method Methods 0.000 title claims description 9
- 239000003792 electrolyte Substances 0.000 claims abstract description 33
- 229920000642 polymer Polymers 0.000 claims abstract description 15
- 229920001353 Dextrin Polymers 0.000 claims abstract description 7
- 229920002678 cellulose Polymers 0.000 claims abstract description 6
- 239000001913 cellulose Substances 0.000 claims abstract description 6
- 239000004375 Dextrin Substances 0.000 claims abstract description 5
- 235000019425 dextrin Nutrition 0.000 claims abstract description 5
- 229920000084 Gum arabic Polymers 0.000 claims abstract description 4
- 235000010489 acacia gum Nutrition 0.000 claims abstract description 4
- 241000978776 Senegalia senegal Species 0.000 claims abstract 2
- 239000000205 acacia gum Substances 0.000 claims abstract 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 8
- 239000011593 sulfur Substances 0.000 claims description 8
- 229910052717 sulfur Inorganic materials 0.000 claims description 8
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 6
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 6
- 235000011152 sodium sulphate Nutrition 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 4
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 4
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 3
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 3
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 3
- 239000004327 boric acid Substances 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 10
- 239000010936 titanium Substances 0.000 description 10
- 229910052719 titanium Inorganic materials 0.000 description 10
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 5
- 238000004070 electrodeposition Methods 0.000 description 5
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 5
- 239000011324 bead Substances 0.000 description 4
- 229940037395 electrolytes Drugs 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 229920002472 Starch Polymers 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 238000007747 plating Methods 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 238000005488 sandblasting Methods 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 244000215068 Acacia senegal Species 0.000 description 2
- 235000006491 Acacia senegal Nutrition 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000007832 Na2SO4 Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- FZUJWWOKDIGOKH-UHFFFAOYSA-N sulfuric acid hydrochloride Chemical compound Cl.OS(O)(=O)=O FZUJWWOKDIGOKH-UHFFFAOYSA-N 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 235000007794 yellow potato Nutrition 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910004809 Na2 SO4 Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfate Natural products OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 101100162169 Xenopus laevis adrm1-a gene Proteins 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 229940105329 carboxymethylcellulose Drugs 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002402 hexoses Chemical class 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000009854 hydrometallurgy Methods 0.000 description 1
- 229920001477 hydrophilic polymer Polymers 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 1
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 1
- -1 of course Chemical compound 0.000 description 1
- 150000002972 pentoses Chemical group 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 229910052979 sodium sulfide Inorganic materials 0.000 description 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- WWNBZGLDODTKEM-UHFFFAOYSA-N sulfanylidenenickel Chemical compound [Ni]=S WWNBZGLDODTKEM-UHFFFAOYSA-N 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/06—Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese
- C25C1/08—Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese of nickel or cobalt
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Removal Of Specific Substances (AREA)
Priority Applications (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA245,281A CA1052727A (en) | 1976-02-09 | 1976-02-09 | Nickel electrowinning process |
| PH19351A PH13276A (en) | 1976-02-09 | 1977-01-17 | Nickel electrowinning process |
| AU21366/77A AU496727B2 (en) | 1976-02-09 | 1977-01-17 | Nickel-electrowinning process |
| IN65/CAL/1977A IN145229B (enExample) | 1976-02-09 | 1977-01-17 | |
| ZA00770225A ZA77225B (en) | 1976-02-09 | 1977-01-17 | Nickel electrowinning process |
| US05/762,737 US4078979A (en) | 1976-02-09 | 1977-01-26 | Nickel electrowinning process |
| NO770332A NO770332L (no) | 1976-02-09 | 1977-02-01 | Fremgangsm}te til utvinning av nikkel fra vandig elektrolytt. |
| FI770362A FI770362A7 (enExample) | 1976-02-09 | 1977-02-02 | |
| GB4498/77A GB1503480A (en) | 1976-02-09 | 1977-02-03 | Nickel electrowinning process |
| FR7703347A FR2340381A1 (fr) | 1976-02-09 | 1977-02-07 | Procede d'extraction electrolytique du nickel |
| JP1349277A JPS5297321A (en) | 1976-02-09 | 1977-02-09 | Electrolytic obtaining method of nickel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA245,281A CA1052727A (en) | 1976-02-09 | 1976-02-09 | Nickel electrowinning process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1052727A true CA1052727A (en) | 1979-04-17 |
Family
ID=4105185
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA245,281A Expired CA1052727A (en) | 1976-02-09 | 1976-02-09 | Nickel electrowinning process |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4078979A (enExample) |
| JP (1) | JPS5297321A (enExample) |
| CA (1) | CA1052727A (enExample) |
| FI (1) | FI770362A7 (enExample) |
| FR (1) | FR2340381A1 (enExample) |
| GB (1) | GB1503480A (enExample) |
| IN (1) | IN145229B (enExample) |
| NO (1) | NO770332L (enExample) |
| PH (1) | PH13276A (enExample) |
| ZA (1) | ZA77225B (enExample) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2152460C1 (ru) * | 1999-12-29 | 2000-07-10 | Открытое акционерное общество "Кольская горно-металлургическая компания" | Катодная ячейка электролизера для электролитического рафинирования никеля |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1352328A (en) * | 1914-12-28 | 1920-09-07 | Hanson & Van Winkle Company | Nickel-plating |
| US2061592A (en) * | 1935-03-21 | 1936-11-24 | Felix R Rapids | Composition for and method of metal electroplating |
| FR813548A (fr) * | 1936-11-16 | 1937-06-03 | Mond Nickel Co Ltd | Procédé pour l'obtention de dépôts brillants ou semi-brillants de nickel |
| US2615837A (en) * | 1947-11-20 | 1952-10-28 | Wyandotte Chemicals Corp | Electroplating bath and process |
| FR2029120A5 (enExample) * | 1969-01-10 | 1970-10-16 | Commissariat Energie Atomique | |
| CA1019278A (en) * | 1974-04-09 | 1977-10-18 | Inco Limited | Electrowinning nickel from sulfate electrolyte |
-
1976
- 1976-02-09 CA CA245,281A patent/CA1052727A/en not_active Expired
-
1977
- 1977-01-17 PH PH19351A patent/PH13276A/en unknown
- 1977-01-17 IN IN65/CAL/1977A patent/IN145229B/en unknown
- 1977-01-17 ZA ZA00770225A patent/ZA77225B/xx unknown
- 1977-01-26 US US05/762,737 patent/US4078979A/en not_active Expired - Lifetime
- 1977-02-01 NO NO770332A patent/NO770332L/no unknown
- 1977-02-02 FI FI770362A patent/FI770362A7/fi unknown
- 1977-02-03 GB GB4498/77A patent/GB1503480A/en not_active Expired
- 1977-02-07 FR FR7703347A patent/FR2340381A1/fr active Granted
- 1977-02-09 JP JP1349277A patent/JPS5297321A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| ZA77225B (en) | 1978-03-29 |
| FI770362A7 (enExample) | 1977-08-10 |
| AU2136677A (en) | 1978-07-27 |
| JPS5297321A (en) | 1977-08-16 |
| FR2340381A1 (fr) | 1977-09-02 |
| IN145229B (enExample) | 1978-09-16 |
| PH13276A (en) | 1980-02-27 |
| FR2340381B1 (enExample) | 1981-12-31 |
| US4078979A (en) | 1978-03-14 |
| NO770332L (no) | 1977-08-10 |
| GB1503480A (en) | 1978-03-08 |
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