CA1051809A - Alkylation reaction chamber - Google Patents
Alkylation reaction chamberInfo
- Publication number
- CA1051809A CA1051809A CA224,831A CA224831A CA1051809A CA 1051809 A CA1051809 A CA 1051809A CA 224831 A CA224831 A CA 224831A CA 1051809 A CA1051809 A CA 1051809A
- Authority
- CA
- Canada
- Prior art keywords
- vessel
- reaction chamber
- acid
- reactant
- disposed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000005804 alkylation reaction Methods 0.000 title claims abstract description 20
- 239000000376 reactant Substances 0.000 claims abstract description 45
- 238000006243 chemical reaction Methods 0.000 claims abstract description 37
- 239000007921 spray Substances 0.000 claims abstract description 20
- 230000000712 assembly Effects 0.000 claims abstract description 17
- 238000000429 assembly Methods 0.000 claims abstract description 17
- 239000002253 acid Substances 0.000 claims description 20
- 239000000047 product Substances 0.000 claims description 15
- 229940090044 injection Drugs 0.000 claims description 13
- 238000002347 injection Methods 0.000 claims description 13
- 239000007924 injection Substances 0.000 claims description 13
- 239000007795 chemical reaction product Substances 0.000 claims description 8
- 239000003054 catalyst Substances 0.000 abstract description 16
- 239000003377 acid catalyst Substances 0.000 abstract description 9
- 230000029936 alkylation Effects 0.000 abstract description 7
- WYTGDNHDOZPMIW-RCBQFDQVSA-N alstonine Natural products C1=CC2=C3C=CC=CC3=NC2=C2N1C[C@H]1[C@H](C)OC=C(C(=O)OC)[C@H]1C2 WYTGDNHDOZPMIW-RCBQFDQVSA-N 0.000 abstract description 4
- 239000012071 phase Substances 0.000 description 25
- 239000006185 dispersion Substances 0.000 description 21
- 239000004215 Carbon black (E152) Substances 0.000 description 18
- 229930195733 hydrocarbon Natural products 0.000 description 14
- 150000002430 hydrocarbons Chemical class 0.000 description 14
- 239000002826 coolant Substances 0.000 description 5
- 150000001336 alkenes Chemical class 0.000 description 4
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- -1 alkyl phosphate Chemical compound 0.000 description 3
- 230000002035 prolonged effect Effects 0.000 description 3
- AFABGHUZZDYHJO-UHFFFAOYSA-N 2-Methylpentane Chemical compound CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000001282 iso-butane Substances 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 238000005191 phase separation Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910015900 BF3 Inorganic materials 0.000 description 1
- 238000005727 Friedel-Crafts reaction Methods 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001350 alkyl halides Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000001896 cresols Chemical class 0.000 description 1
- 238000011143 downstream manufacturing Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 239000011707 mineral Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 150000005673 monoalkenes Chemical class 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/26—Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J14/00—Chemical processes in general for reacting liquids with liquids; Apparatus specially adapted therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0006—Controlling or regulating processes
- B01J19/0013—Controlling the temperature of the process
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00076—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
- B01J2219/00081—Tubes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00076—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
- B01J2219/00083—Coils
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00121—Controlling the temperature by direct heating or cooling
- B01J2219/00123—Controlling the temperature by direct heating or cooling adding a temperature modifying medium to the reactants
- B01J2219/00126—Cryogenic coolants
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US462071A US3914111A (en) | 1974-04-18 | 1974-04-18 | Alkylation reaction chamber |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1051809A true CA1051809A (en) | 1979-04-03 |
Family
ID=23835065
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA224,831A Expired CA1051809A (en) | 1974-04-18 | 1975-04-17 | Alkylation reaction chamber |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US3914111A (OSRAM) |
| JP (1) | JPS5542048B2 (OSRAM) |
| AR (1) | AR210327A1 (OSRAM) |
| BR (1) | BR7502350A (OSRAM) |
| CA (1) | CA1051809A (OSRAM) |
| ES (1) | ES436486A1 (OSRAM) |
| FR (1) | FR2267996B1 (OSRAM) |
| GB (1) | GB1503747A (OSRAM) |
| IN (1) | IN144650B (OSRAM) |
| IT (1) | IT1035339B (OSRAM) |
| RO (1) | RO64346A (OSRAM) |
| SU (1) | SU1099834A3 (OSRAM) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3982903A (en) * | 1974-04-18 | 1976-09-28 | Universal Oil Products Company | Alkylation reaction chamber |
| US4024200A (en) * | 1974-12-16 | 1977-05-17 | Uop Inc. | Countercurrent flow reaction chamber for plural stages of HF alkylation |
| US4420462A (en) * | 1982-03-22 | 1983-12-13 | Clyde Robert A | Catalytic heat exchanger |
| US5227556A (en) * | 1990-04-17 | 1993-07-13 | The Dow Chemical Company | Turbulent flow process, monoalkyl aromatic production process and reactor for such process |
| DE102005049457A1 (de) * | 2005-10-15 | 2007-05-16 | Degussa | Vorrichtung zur Durchführung chemischer Reaktionen |
| US7947232B2 (en) * | 2006-12-07 | 2011-05-24 | Exxonmobil Research & Engineering Company | HF alkylation reactor |
| US8747783B2 (en) * | 2009-06-24 | 2014-06-10 | Uop Llc | Acid alkylation system and process for controlling temperature in a settler |
| US20110060178A1 (en) * | 2009-09-04 | 2011-03-10 | Nafis Douglas A | Slurry column gasoline alkylation using gas phase olefin injection |
| FR3008627B1 (fr) | 2013-07-19 | 2017-02-24 | Arkema France | Cuve de conversion thermique utilisee dans un procede d'amidification de cyanohydrine d'acetone |
| RU2700768C1 (ru) * | 2018-06-25 | 2019-09-20 | Общество с ограниченной ответственностью "МилИнвест" (ООО "МилИнвест") | Реактор сернокислотного алкилирования |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2855449A (en) * | 1954-03-12 | 1958-10-07 | Phillips Petroleum Co | Method of and apparatus for the acid-catalyzed alkylation of hydrocarbons |
| US3006739A (en) * | 1958-12-03 | 1961-10-31 | Phillips Petroleum Co | Apparatus for contacting immiscible fluids |
| US3150934A (en) * | 1960-01-14 | 1964-09-29 | Texaco Inc | Apparatus for effecting fluidfluid contact |
| US3212860A (en) * | 1962-03-23 | 1965-10-19 | Phillips Petroleum Co | Method of and apparatus for contacting immiscible fluids |
| US3249649A (en) * | 1963-02-28 | 1966-05-03 | Phillips Petroleum Co | Catalytic alkylation |
| US3501536A (en) * | 1969-02-26 | 1970-03-17 | Universal Oil Prod Co | Alkylation with spiralling flow path of reactants and alkylate |
| US3560587A (en) * | 1969-04-14 | 1971-02-02 | Universal Oil Prod Co | Hydrogen fluoride alkylation with reaction cooler and reaction soaker vessels |
| US3607970A (en) * | 1969-04-25 | 1971-09-21 | Universal Oil Prod Co | Process for producing high octane alkylated hydrocarbons substantially free of alkyl fluoride compounds |
| US3705017A (en) * | 1970-11-27 | 1972-12-05 | Universal Oil Prod Co | Apparatus for a catalytic reaction |
-
1974
- 1974-04-18 US US462071A patent/US3914111A/en not_active Expired - Lifetime
-
1975
- 1975-04-09 IN IN715/CAL/75A patent/IN144650B/en unknown
- 1975-04-10 ES ES436486A patent/ES436486A1/es not_active Expired
- 1975-04-16 FR FR7511783A patent/FR2267996B1/fr not_active Expired
- 1975-04-16 IT IT49133/75A patent/IT1035339B/it active
- 1975-04-17 CA CA224,831A patent/CA1051809A/en not_active Expired
- 1975-04-17 GB GB15842/75A patent/GB1503747A/en not_active Expired
- 1975-04-17 BR BR2994/75A patent/BR7502350A/pt unknown
- 1975-04-17 RO RO7582011A patent/RO64346A/ro unknown
- 1975-04-17 JP JP4588875A patent/JPS5542048B2/ja not_active Expired
- 1975-04-18 AR AR256419A patent/AR210327A1/es active
- 1975-04-18 SU SU752127182A patent/SU1099834A3/ru active
Also Published As
| Publication number | Publication date |
|---|---|
| JPS50148302A (OSRAM) | 1975-11-27 |
| FR2267996A1 (OSRAM) | 1975-11-14 |
| GB1503747A (en) | 1978-03-15 |
| RO64346A (fr) | 1979-05-15 |
| US3914111A (en) | 1975-10-21 |
| JPS5542048B2 (OSRAM) | 1980-10-28 |
| SU1099834A3 (ru) | 1984-06-23 |
| BR7502350A (pt) | 1976-02-17 |
| IN144650B (OSRAM) | 1978-06-03 |
| IT1035339B (it) | 1979-10-20 |
| AR210327A1 (es) | 1977-07-29 |
| ES436486A1 (es) | 1977-01-01 |
| FR2267996B1 (OSRAM) | 1979-07-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3622493A (en) | Use of plasma torch to promote chemical reactions | |
| US5600053A (en) | Process and apparatus for controlling reaction temperatures | |
| US6106789A (en) | Alkylation reactor with internal acid cooling zones | |
| US5762887A (en) | Apparatus for controlling reaction temperatures | |
| CA1051809A (en) | Alkylation reaction chamber | |
| EP0766999B1 (en) | Process and apparatus for controlling reaction temperature | |
| EP2318555B1 (en) | Improved quench zone design using spray nozzles | |
| US3541000A (en) | Method and means for treating mixed phase vapor and liquid reactants under exothermic reaction conditions and temperature control | |
| US6764660B1 (en) | Process and apparatus for controlling reaction temperatures with heating arrangement in series flow | |
| AU4303485A (en) | Reactor for exothermic/endothermic reactions | |
| US3133128A (en) | Contacting of fluids | |
| IL28027A (en) | Method and device for multi-stage contact between reactants | |
| US3213157A (en) | Catalytic alkylation method and apparatus | |
| US2412135A (en) | Method and apparatus for hydrocarbon conversion | |
| US5445799A (en) | Apparatus and method for thermocracking a fluid | |
| CN100460050C (zh) | 一种流化床气固接触设备 | |
| US3212860A (en) | Method of and apparatus for contacting immiscible fluids | |
| US3982903A (en) | Alkylation reaction chamber | |
| US3108048A (en) | Apparatus for contacting of different density fluids | |
| US3501536A (en) | Alkylation with spiralling flow path of reactants and alkylate | |
| US6472482B1 (en) | Gas-phase polymerization with direct cooling | |
| US7947232B2 (en) | HF alkylation reactor | |
| US3914110A (en) | Alkylation reaction cooler | |
| US2894050A (en) | Alkylation of hydrocarbons | |
| US3179712A (en) | Extractive condensation process using a multistage column |