CA1045028A - Micellar dispersions via sulfonating whole or topped crude - Google Patents
Micellar dispersions via sulfonating whole or topped crudeInfo
- Publication number
- CA1045028A CA1045028A CA244,369A CA244369A CA1045028A CA 1045028 A CA1045028 A CA 1045028A CA 244369 A CA244369 A CA 244369A CA 1045028 A CA1045028 A CA 1045028A
- Authority
- CA
- Canada
- Prior art keywords
- crude oil
- oil
- sulfonating
- micellar dispersion
- sulfur trioxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000006185 dispersion Substances 0.000 title claims abstract description 37
- 239000010779 crude oil Substances 0.000 claims abstract description 37
- 238000006277 sulfonation reaction Methods 0.000 claims abstract description 19
- 239000003921 oil Substances 0.000 claims abstract description 16
- 239000000203 mixture Substances 0.000 claims abstract description 7
- 239000004064 cosurfactant Substances 0.000 claims abstract description 6
- 238000002347 injection Methods 0.000 claims abstract description 4
- 239000007924 injection Substances 0.000 claims abstract description 4
- 238000004519 manufacturing process Methods 0.000 claims abstract description 4
- 230000003472 neutralizing effect Effects 0.000 claims abstract description 3
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 claims description 54
- 229930195733 hydrocarbon Natural products 0.000 claims description 21
- 150000002430 hydrocarbons Chemical class 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 239000003208 petroleum Substances 0.000 claims description 13
- 239000004215 Carbon black (E152) Substances 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 12
- 230000008569 process Effects 0.000 claims description 10
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 10
- 230000015572 biosynthetic process Effects 0.000 claims description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- 239000012530 fluid Substances 0.000 claims description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 4
- 238000011084 recovery Methods 0.000 claims description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 3
- 239000003570 air Substances 0.000 claims description 2
- 238000004891 communication Methods 0.000 claims description 2
- 230000006872 improvement Effects 0.000 claims description 2
- 239000003345 natural gas Substances 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 238000004064 recycling Methods 0.000 claims 1
- 239000003085 diluting agent Substances 0.000 abstract description 9
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 239000007788 liquid Substances 0.000 abstract description 2
- -1 e.g. Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 description 14
- 238000006243 chemical reaction Methods 0.000 description 13
- 239000002904 solvent Substances 0.000 description 12
- 239000007810 chemical reaction solvent Substances 0.000 description 10
- 239000000654 additive Substances 0.000 description 9
- 125000003118 aryl group Chemical group 0.000 description 8
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 239000007795 chemical reaction product Substances 0.000 description 6
- 238000000605 extraction Methods 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 238000005755 formation reaction Methods 0.000 description 5
- 238000006386 neutralization reaction Methods 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 239000012736 aqueous medium Substances 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 239000003792 electrolyte Substances 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 125000001273 sulfonato group Chemical class [O-]S(*)(=O)=O 0.000 description 3
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000000908 ammonium hydroxide Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000012267 brine Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- JSZOAYXJRCEYSX-UHFFFAOYSA-N 1-nitropropane Chemical compound CCC[N+]([O-])=O JSZOAYXJRCEYSX-UHFFFAOYSA-N 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 150000007514 bases Chemical class 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000007809 chemical reaction catalyst Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000011552 falling film Substances 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000007529 inorganic bases Chemical class 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000003908 quality control method Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000008234 soft water Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- CZDYPVPMEAXLPK-UHFFFAOYSA-N tetramethylsilane Chemical compound C[Si](C)(C)C CZDYPVPMEAXLPK-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US55961175A | 1975-03-18 | 1975-03-18 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1045028A true CA1045028A (en) | 1978-12-26 |
Family
ID=24234268
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA244,369A Expired CA1045028A (en) | 1975-03-18 | 1976-01-28 | Micellar dispersions via sulfonating whole or topped crude |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JPS51116186A (https=) |
| AU (1) | AU497788B2 (https=) |
| CA (1) | CA1045028A (https=) |
| DE (1) | DE2603539A1 (https=) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102604670A (zh) * | 2012-02-10 | 2012-07-25 | 胜利油田中胜环保有限公司 | 油田驱油用石油磺酸盐原料的制备方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3244622A (en) * | 1962-05-18 | 1966-04-05 | Phillips Petroleum Co | Drilling fluid |
| US3506071A (en) * | 1967-12-26 | 1970-04-14 | Marathon Oil Co | Use of water-external micellar dispersions in oil recovery |
| US3698479A (en) * | 1969-08-08 | 1972-10-17 | Amoco Prod Co | Solubilized oil-water solutions suitable for miscible flooding |
| US3673124A (en) * | 1969-08-27 | 1972-06-27 | Union Oil Co | Soluble oil composition |
| US3776309A (en) * | 1971-05-28 | 1973-12-04 | Exxon Production Research Co | Viscous surfactant water flooding |
| US3804171A (en) * | 1971-11-24 | 1974-04-16 | Continental Oil Co | Method for recovering hydrocarbons using an anionic water flood additive |
-
1976
- 1976-01-28 CA CA244,369A patent/CA1045028A/en not_active Expired
- 1976-01-29 DE DE19762603539 patent/DE2603539A1/de not_active Ceased
- 1976-03-02 JP JP2257576A patent/JPS51116186A/ja active Granted
- 1976-03-17 AU AU12096/76A patent/AU497788B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE2603539A1 (de) | 1976-09-30 |
| AU1209676A (en) | 1977-09-22 |
| JPS51116186A (en) | 1976-10-13 |
| AU497788B2 (en) | 1979-01-11 |
| JPS5513271B2 (https=) | 1980-04-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4148821A (en) | Process for sulfonation | |
| US4147638A (en) | Sulfonation of crude oils to produce petroleum sulfonates | |
| US4390474A (en) | Sulfonation petroleum composition | |
| US2433396A (en) | Process for production of sulfonic acids | |
| US3933201A (en) | Method using overbased branched-chain alkylaromatic sulfonates as waterflood additives | |
| WO1994001684A1 (en) | Process for recovering and causing highly viscous petroleum products to flow | |
| US3366174A (en) | Method for waterflooding petroliferous strata | |
| US3956372A (en) | Process for the production of petroleum sulfonate | |
| US2523582A (en) | Sulfonation process | |
| US2413310A (en) | Process for the recovery of hydrocarbons from a sludge | |
| US4614623A (en) | Sulfonation of crude oils with gaseous SO3 to produce petroleum sulfonates | |
| US4560517A (en) | Sulfonation of crude oils with gaseous SO3 to produce petroleum sulfonates | |
| CA1045028A (en) | Micellar dispersions via sulfonating whole or topped crude | |
| RU2128167C1 (ru) | Способ извлечения и перемещения высоковязких нефтяных продуктов и водная дисперсия высоковязкого нефтяного продукта в воде | |
| US4361520A (en) | Refinement of sulfonated hydrocarbons | |
| US3965984A (en) | Waterflood method using overbased normal alkylaromatic sulfonates | |
| US3240280A (en) | Drilling and/or servicing of wells | |
| US4404110A (en) | Ozonation of petroleum feedstocks | |
| US2396673A (en) | Petroleum mahogany sulphonic products | |
| US3878894A (en) | Process for recovering hydrocarbons using overbased linear alkylate sulfonates as waterflood additives | |
| EP0012759B1 (en) | Stabilized petroleum sulfonate products and their use in subterranean oil recovery | |
| US4414119A (en) | Injectivity of crude oil and petroleum sulfonate slugs by the addition of an alkylbenzene sulfonate | |
| CA1227494A (en) | Process for producing petroleum sulfonates | |
| CA1117973A (en) | Sulfonation of crude oils with gaseous so.sub.3 to produce petroleum sulfonates | |
| US2519930A (en) | Recovering sulfonates of oilsoluble sulfonic acids from acid-treated hydrocarbon oils |