CA1043817A - Stabilized methylchloroform - Google Patents
Stabilized methylchloroformInfo
- Publication number
- CA1043817A CA1043817A CA176,891A CA176891A CA1043817A CA 1043817 A CA1043817 A CA 1043817A CA 176891 A CA176891 A CA 176891A CA 1043817 A CA1043817 A CA 1043817A
- Authority
- CA
- Canada
- Prior art keywords
- weight percent
- nitromethane
- dimethoxyethane
- dioxolane
- proportions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 title claims abstract description 5
- 239000000203 mixture Substances 0.000 claims abstract description 47
- 239000007788 liquid Substances 0.000 claims abstract description 15
- WNXJIVFYUVYPPR-UHFFFAOYSA-N 1,3-dioxolane Chemical compound C1COCO1 WNXJIVFYUVYPPR-UHFFFAOYSA-N 0.000 claims abstract description 14
- LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 claims abstract description 10
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000003381 stabilizer Substances 0.000 claims abstract description 8
- 229910052751 metal Inorganic materials 0.000 claims abstract description 7
- 239000002184 metal Substances 0.000 claims abstract description 7
- BGJSXRVXTHVRSN-UHFFFAOYSA-N 1,3,5-trioxane Chemical compound C1OCOCO1 BGJSXRVXTHVRSN-UHFFFAOYSA-N 0.000 claims abstract description 5
- HIZVCIIORGCREW-UHFFFAOYSA-N 1,4-dioxene Chemical compound C1COC=CO1 HIZVCIIORGCREW-UHFFFAOYSA-N 0.000 claims abstract description 5
- SPEUIVXLLWOEMJ-UHFFFAOYSA-N 1,1-dimethoxyethane Chemical compound COC(C)OC SPEUIVXLLWOEMJ-UHFFFAOYSA-N 0.000 claims abstract 10
- RHHFKRKUIWRDCN-UHFFFAOYSA-N O1COCC1.[N+](=O)([O-])C.COC(C)OC Chemical compound O1COCC1.[N+](=O)([O-])C.COC(C)OC RHHFKRKUIWRDCN-UHFFFAOYSA-N 0.000 claims abstract 2
- 150000002118 epoxides Chemical class 0.000 claims abstract 2
- 238000000638 solvent extraction Methods 0.000 claims description 16
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 5
- 230000015556 catabolic process Effects 0.000 claims description 4
- 238000006731 degradation reaction Methods 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 abstract description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 6
- 238000009835 boiling Methods 0.000 abstract description 4
- 238000005192 partition Methods 0.000 abstract description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000956 alloy Substances 0.000 abstract description 3
- 229910045601 alloy Inorganic materials 0.000 abstract description 3
- 229910052742 iron Inorganic materials 0.000 abstract description 3
- 229910052725 zinc Inorganic materials 0.000 abstract description 3
- 239000011701 zinc Substances 0.000 abstract description 3
- 150000002739 metals Chemical class 0.000 abstract description 2
- 238000010992 reflux Methods 0.000 abstract description 2
- 238000007792 addition Methods 0.000 abstract 1
- 239000012141 concentrate Substances 0.000 abstract 1
- 239000003112 inhibitor Substances 0.000 description 32
- 239000002904 solvent Substances 0.000 description 17
- 239000004615 ingredient Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 150000002924 oxiranes Chemical class 0.000 description 5
- 241001550224 Apha Species 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- 239000013527 degreasing agent Substances 0.000 description 3
- GELKGHVAFRCJNA-UHFFFAOYSA-N 2,2-Dimethyloxirane Chemical compound CC1(C)CO1 GELKGHVAFRCJNA-UHFFFAOYSA-N 0.000 description 2
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- DQCMWCVJSOFDSA-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl.CC(Cl)(Cl)Cl DQCMWCVJSOFDSA-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical group CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 1
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical class C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005555 metalworking Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- UHHKSVZZTYJVEG-UHFFFAOYSA-N oxepane Chemical class C1CCCOCC1 UHHKSVZZTYJVEG-UHFFFAOYSA-N 0.000 description 1
- HZIVRQOIUMAXID-UHFFFAOYSA-N oxocane Chemical class C1CCCOCCC1 HZIVRQOIUMAXID-UHFFFAOYSA-N 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G5/00—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
- C23G5/02—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents
- C23G5/028—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing halogenated hydrocarbons
- C23G5/02854—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing halogenated hydrocarbons characterised by the stabilising or corrosion inhibiting additives
- C23G5/02883—Nitrogen-containing compounds
- C23G5/02887—Nitro-compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/38—Separation; Purification; Stabilisation; Use of additives
- C07C17/42—Use of additives, e.g. for stabilisation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US28124272A | 1972-08-16 | 1972-08-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1043817A true CA1043817A (en) | 1978-12-05 |
Family
ID=23076512
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA176,891A Expired CA1043817A (en) | 1972-08-16 | 1973-07-19 | Stabilized methylchloroform |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS5640691B2 (enrdf_load_stackoverflow) |
| BE (1) | BE803675A (enrdf_load_stackoverflow) |
| BR (1) | BR7306269D0 (enrdf_load_stackoverflow) |
| CA (1) | CA1043817A (enrdf_load_stackoverflow) |
| DE (1) | DE2340662A1 (enrdf_load_stackoverflow) |
| FR (1) | FR2196309B1 (enrdf_load_stackoverflow) |
| GB (1) | GB1439970A (enrdf_load_stackoverflow) |
| NL (1) | NL7310711A (enrdf_load_stackoverflow) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0024113B2 (en) * | 1979-07-25 | 1991-10-02 | Imperial Chemical Industries Plc | Stabilisation of 1,1,1,-trichloroethane |
| US4992604A (en) * | 1989-07-24 | 1991-02-12 | Ppg Industries, Inc. | Stabilized 1,1,1-trichloroethane compositions |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1332268A (fr) * | 1962-07-13 | 1963-07-12 | Pittsburgh Plate Glass Co | Méthylchloroforme stabilisé |
| DE1468786C3 (de) * | 1964-01-16 | 1975-02-27 | Ppg Industries, Inc., Pittsburgh, Pa. (V.St.A.) | Verfahren zur Stabilisierung von 1,1,1-Trichloräthan |
| JPS525A (en) * | 1975-06-21 | 1977-01-05 | Kurosawa Kensetsu Kk | Method of joining preecast blocks for foundation where to install construction on |
-
1973
- 1973-07-19 CA CA176,891A patent/CA1043817A/en not_active Expired
- 1973-08-02 NL NL7310711A patent/NL7310711A/xx not_active Application Discontinuation
- 1973-08-02 JP JP8644373A patent/JPS5640691B2/ja not_active Expired
- 1973-08-10 DE DE19732340662 patent/DE2340662A1/de active Pending
- 1973-08-14 GB GB3844673A patent/GB1439970A/en not_active Expired
- 1973-08-15 BR BR626973A patent/BR7306269D0/pt unknown
- 1973-08-16 FR FR7329875A patent/FR2196309B1/fr not_active Expired
- 1973-08-16 BE BE134638A patent/BE803675A/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| BE803675A (fr) | 1974-02-18 |
| BR7306269D0 (pt) | 1974-07-18 |
| JPS4992004A (enrdf_load_stackoverflow) | 1974-09-03 |
| GB1439970A (en) | 1976-06-16 |
| DE2340662A1 (de) | 1974-02-28 |
| AU5838073A (en) | 1975-01-23 |
| FR2196309A1 (enrdf_load_stackoverflow) | 1974-03-15 |
| JPS5640691B2 (enrdf_load_stackoverflow) | 1981-09-22 |
| FR2196309B1 (enrdf_load_stackoverflow) | 1977-02-25 |
| NL7310711A (enrdf_load_stackoverflow) | 1974-02-19 |
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