CA1042630A - Vibrating chemical reactor/regenerator - Google Patents
Vibrating chemical reactor/regeneratorInfo
- Publication number
- CA1042630A CA1042630A CA230,137A CA230137A CA1042630A CA 1042630 A CA1042630 A CA 1042630A CA 230137 A CA230137 A CA 230137A CA 1042630 A CA1042630 A CA 1042630A
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- Canada
- Prior art keywords
- reaction chamber
- closed circuit
- regeneration
- catalyst particles
- catalyst
- Prior art date
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- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Abstract
ABSTRACT OF THE DISCLOSURE
A system for imparting vibratory energy to solid particulate matter includes a resiliently mounted vibrator body, and a pair of counterweights on opposite ends of a rotating vertical shaft engaged with the vibrator body but adapted to rotate with the counterweights independently of the vibrator body. A drive motor engaged with the vertical shaft rotates the shaft about its axis to rotate the counter-weights and thereby impart a relatively large amplitude vibratory motion to the vibrator body. A closed conduit carried on the vibrator body contains solid particulate matter which travels in a fluidized condition along a linear path through the conduit in response to vibration of the vibrator body. In one form of the invention, the vibrator body comprises a reaction chamber for receiving a gas flow and contacting it with an appropriate solid particulate catalyst contained in the reaction chamber and adapted to promote desired reactions between chemical components of the gas phase. The vibrational energy imparted to the reaction chamber causes catalyst particles to flow in a continuous fluidized circulating path from the reaction chamber through a suitable catalytic regeneration chamber and back to the reaction chamber.
Preferably, the drive motor is coupled with the rotating shaft of the vibrator body through a vertically extending torsion shaft having suitable torsional strength for required torque transmission but with sufficient torsional and lateral flexibility to prevent substantial vibrational energy from being transmitted by the vibrator body to the drive motor and its bearings.
A system for imparting vibratory energy to solid particulate matter includes a resiliently mounted vibrator body, and a pair of counterweights on opposite ends of a rotating vertical shaft engaged with the vibrator body but adapted to rotate with the counterweights independently of the vibrator body. A drive motor engaged with the vertical shaft rotates the shaft about its axis to rotate the counter-weights and thereby impart a relatively large amplitude vibratory motion to the vibrator body. A closed conduit carried on the vibrator body contains solid particulate matter which travels in a fluidized condition along a linear path through the conduit in response to vibration of the vibrator body. In one form of the invention, the vibrator body comprises a reaction chamber for receiving a gas flow and contacting it with an appropriate solid particulate catalyst contained in the reaction chamber and adapted to promote desired reactions between chemical components of the gas phase. The vibrational energy imparted to the reaction chamber causes catalyst particles to flow in a continuous fluidized circulating path from the reaction chamber through a suitable catalytic regeneration chamber and back to the reaction chamber.
Preferably, the drive motor is coupled with the rotating shaft of the vibrator body through a vertically extending torsion shaft having suitable torsional strength for required torque transmission but with sufficient torsional and lateral flexibility to prevent substantial vibrational energy from being transmitted by the vibrator body to the drive motor and its bearings.
Description
Il ' , ~04Z630 MECHA~ICAL VIBRATOR FOR USE IN MATERIAL TRANSPORT APPARATUS
AND THE LIKE
This invention relates to a method and apparatus for producing vibrational energy and for using the resulting vibrational energy in a material transport system.
In the past there have been a variety of industrial applications for mechanical vibrators, such as in separators for screenable materials, grinding mills, and finishing mills for deburring metals, for example. A typical mechanical vibrator contemplated by this invention is the FM Series fini~hing mill manufactured by SWECO, Inc. of Los Angeles, California. Sucha mechanical vibrator includes an annular vessel for containing part~ to be finished and a suitable grinding media. A double-énded electric motor i8 fixed to the lower end of a cylindrical column, and calibrated counterweights are mounted at both end3 of the motor shaft. The motor and the vessel are supported by compression springs, and the angular velocity developed by the motor output shaft vibrates the vessel and the material contained in it.
The present invention is based, in part, on the recognition that the drive motor of the mechanical vibrator described above i~ integrated into the active or vibrating portion of the system which result~ in a large amount of vibration being transmitted to the motor and the motor bearing~ during use of the vibrator.
Con~equently, the motor bearings wear out in a relatively short .
AND THE LIKE
This invention relates to a method and apparatus for producing vibrational energy and for using the resulting vibrational energy in a material transport system.
In the past there have been a variety of industrial applications for mechanical vibrators, such as in separators for screenable materials, grinding mills, and finishing mills for deburring metals, for example. A typical mechanical vibrator contemplated by this invention is the FM Series fini~hing mill manufactured by SWECO, Inc. of Los Angeles, California. Sucha mechanical vibrator includes an annular vessel for containing part~ to be finished and a suitable grinding media. A double-énded electric motor i8 fixed to the lower end of a cylindrical column, and calibrated counterweights are mounted at both end3 of the motor shaft. The motor and the vessel are supported by compression springs, and the angular velocity developed by the motor output shaft vibrates the vessel and the material contained in it.
The present invention is based, in part, on the recognition that the drive motor of the mechanical vibrator described above i~ integrated into the active or vibrating portion of the system which result~ in a large amount of vibration being transmitted to the motor and the motor bearing~ during use of the vibrator.
Con~equently, the motor bearings wear out in a relatively short .
2 length of t~me. The bearings are pa~t of the motor and are difficult to remove for replacement, which adds substantially to the maintenancé co~t of the vibrator ~ss¢mbly. In addition, the recomm~ndation~ of the motor ~upplier m w t ~e considered ~hen~v~r it i~ de~ired to change the bearlng~.
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. ( SUMMARY ~042630 -In accordance with this invention, there is provided catalyst xegeneration apparatus comprising:
(a) a closed circuit for simultaneously utilizing i 5 and regenerating a particulate catalyst circulated through the closed circuit, the closed circuit including a reaction chamber of closed cross-section having a spaced apart inlet and outlet, a regeneration chamber of closed cross-section having a spaced apart inlet and outlet, and gas seal conduit means of closed cross-section in which the reaction chamber outlet communicates by a tubular feed conduit with the regenerator inlet, and the regenerator outlet communicates by a tubular return conduit with the reaction chamber inlet;
(b) means mounting the closed circuit in a sub-stantially horizontal position;
(c) a predetermined quantity of a particulate catalyst contained in the closed circuit;
(d) means for introducing a stream of reactant gas to the reaction chamber;
(e) means for withdrawing said stream of reactant gas from the reaction chamber;
(f) means for passing said stream of reactant gas through the reaction chamber to contact the particulate catalyst contained in the reaction chamber prior to the gas being with-drawn from the reaction chamber to promote suitable reactions between components of the reactant gas;
(g) means for regenerating spent catalyst particles passing through the regeneration chamber; and (h) means for vibrating the horizontally disposed closea circuit as a unit to continuously circulate said catalyst ( particles in a fluidized, generally random cross-sectional dispersion through the closed circuit so that the particles travel in the reaction chamber and then through the feed conduit, the regeneration chamber, and the return conduit, and then back to the reaction chamber, to allow spent catalyst to be constantly regenerated from its passage through the regeneration means;
(i) said quantity of catalyst particles and the cross-section dimensions of the gas seal conduit means both being sufficient to cause the catalyst particles to circulate through said conduit means in a generally uniform, substantially completely filled cross-sectional dispersion to provide resistance to appreciable gas flow through the inlet and outlet openings of the reaction chamber so the regeneration of the lS catalyst particles takes place in the regeneration chamber without being affected by reactions between the reactant gas and the fluidized catalyst particles circulating through the reaction chamber.
In accordance with a further aspect of this invention, there is provided a method for carrying out gas phase ¦ reactions in the presence of a solid particulate catalyst and for continuously regenerating the catalyst so that the re-generation and reaction steps are isolated from each other, the method including the steps of:
(a) disposing a solid particulate catalyst in a closed circuit comprising a reaction chamber of closed cross-section having a spaced apart inlet and outlet, a regeneration ch~mber of closed cross-section having a spaced apart inlet and outlet, and gas seal means of closed cross-section in ~ich said reaction chamber outlet communicates by a tubular ~r~, 104Z63~
feed conduit with said regenerator inlet, and said regenerator outlet communicates by a tubular return conduit with said reaction chamber inlet, (b) mounting the closed circuit in a horizontal position and vibrating the closed circuit as a unit to impart : circulating fluidized translatory motion to the catalyst particles to cause the particles to travel in a generally uniform random cross-sectional dispersion through the closed circuit so that the particles continuously travel in the reaction chamber and then through the feed conduit, the re-generation chamber, and the return conduit o~ the closed circuit, respectively, and then back to the reaction chamber;
(cl passing a stream of reactant gas through the reaction chamber and through the catalyst particles therein, the reactant gas flowing in a direction through the reaction chamber which is countercurrent to the flow of catalyst particles through the reaction chamber, for promoting suitable reactions between components of the reactant gas; and (d) regenerating the fluidized catalyst particles being continuously circulated through the regeneration ¦ chamber;
¦ (e) the vibration further causing the catalyst particles to be circulated through the gas seal conduit means in a generally uniform, substantially completely filled cross-sectional dispersion to provide resistance to appre- -ciable gas flow through th~ inlet and outlet openings of the reaction chamber so that regeneration of the catalyst particles occurs in the regeneration chamber without being affected by reactions between the reactant gas and the fluidized catalyst particles flowing through the reaction cha~ber.
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' I` lQ4Z630 ¦This invention, in part, provides a mechanical vibrator ¦ in which the drive motor is separated from the active or ¦ vibrating portion of the vibrator assembly. Briefly, the ~ ¦ vibrator includes a vibrator body, a rotatable shaft mounted I to the vibrator body to rotate about its axis $ndependently ¦ of thè vibrator body, spaced apart counterweights engaged ¦ with opposite ends of the shaft to rotate with the shaft, ¦ and means for resiliently mounting the vibrator body. A drive :i I motor located remote from the vibrator body is engaged with the ¦ rotatable shaft through an elongated torsion shaft having both torsional and lateral flexibility. The drive motor rotates the shaft and counterweights to v$brate the vi~rator body.
The torsion shaft has suff$ciènt lateral flexibility and low ~'1 mass to permit substantial unrestrained vibration of the vibrator body and to prevent any appreciable vibrational energy from being transmitted to the drive motor an~ its bearings.
Since the drive motor is separated from the vibrating portion of the system, the bearings which mount the rotatable ~J' shaft to the vibrator body can be changed without disturbing the drive motor. Since the bearings can be changed at will, it i8 ~180 practicable to use different types of vibrator shaft bearings depend$ng upon the particular use of the vibrator.
Preferred uses of the vibrator assembly would be as a separator, grinding mill, or finishing mill. The separat$on of the drive motor from the vibrating portion of the system also is an advant~ge ~f explos~on or fire hazards ar~ present because of the type of process mator~als uséd 1~ the applications discu~ed ~bov , A ~, . 1042630 1In one embodiment of the invention, carrier means are mounted on the vibrator body for containing a suitable medium to receive the vibrational energy developed by the vibrator.
The vibrator is subjected to large amplitude vibrations sufficient to cause solid particulate matter contained in the carrier means to travel through the carrier in a fluidized condition. Thus, the vibrator of this invention can be used as a material transport apparatus, and in the preferred form of the invention, the vibrator body comprises a closed reaction 0 chamber for receiving a flow of gas to be contacted with a ~uitable particulate catalyst contaiped in the reaction chamber for promoting desired reactions~ between chemical components of the gas phase. The vibrational energy imparted to the reaction chamber causes the catalyst pàrticles to flow continuously in a fluidized condition from the reaction chamber through a suitable catalyst regeneration chamber and back through the reaction chamber.
These and other aspects of the invention will be more fully understood by referring to the following detailed description and the accompanying drawings.
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DRAWINGS
PIG. 1 is a frag~enta~y schematic elevation view, partly in cross-section, showing a mechanical vibrator according to 2 th$~ invention, FIG. 2 i8 a schematlc plan view illustrating a phase angle relationship between a pair of counterweights in the vibrator of PIG. l; ; "j I ~
FIG. 3 is an"enlarged fragmentary cross-sectional elevation 30 view illstrating partlculatc matter flowing in a fluidized ¢ondition through the tubular ~onduit of the vibrator ~hown in P~G. 1~ G
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FIG. 4 is a fragmentary schematic elevation view, partl~ in cross-section, illustrating a preferred use of the vibrator of FIG. 1 in a finishing or grinding mill;
FIG. 5 is a fragmentary semi-schematic perspective view illustrating the use of the vibrator of FIG. 1 in a system for regenerating a catalyst; and FIG. 6 (appearing on sheet 1 of the drawings) is a semi-schematic plan view, partly broken away, illustrating a particulate catalyst circulating in a fluidized condition through the catalyst regeneration system of FIG. 5.
FIG. 1 schematically illustrates a mechanical vibrator 10 having a vibrator body 12 which is resiliently supported by several radially spaced apart coil springs 14. Preferably, vibrator body 12 is mounted by three equidistantly spaced apart springs. An asymmetrically loaded, vertically extending, rigid rotatable shaft 16 is supported by the vibrator body. The top and bottom ends of shaft 16 carry vertically spaced apart counterweights 18 and 20, respectively, adapted to rotate with the shaft in corresponding horizontal planes. Shaft 16 is mounted to vibrator body 12 by a pair of vertically spaced apart anti-friction bearings 22 which allow the shaft 16 and counterweights to rotate independently of the vibrator body.
A variable speed electric motor 24 drives a rotary double-ended motor output shaft 26 which, in turn, is coupled to shaft 16 by a vertically extending, tubular, elongated torsion drive shaft 28. The torsion shaft preferably is tubular and of relatively small diameter and thus is relatively o . 1 104Z630 1 ¦ light in weight as well as having torsional and lateral ¦ flexibility and suitable torsional strength to transmit torques ¦ of the required magnitudc. By way of example, the tor~ion ¦ shaft in many applications can comprise a thin plastic tube ¦ approximately 3/32 inch in diameter.
During use of vibrator 10, motor 24 drives torsion shaft 28 which, in turn, rotates shaft 16 about its axis at-a constant angular velocity. This causes the spring supported body 12 and shaft 16 to vibrate as a unit, the vibration 0¦ consisting of small periodic movements that consist of either translations in the horizontal plane, or tipping of the vertical axis, or a combination of both, depending upon the mass of the rotating counterweights and their'angular l displacement (the angleoc shown in FIG. 2). The mass of the 15¦ counterweights i8 small compared to that of the spring supported ¦ body. Moreover, the torsion drive tube is kept somewhat slac~
¦ in its connection 30 to rigid shaft 16, so t~at angular and/or ¦ translational displacement of the spring supported body and ¦ rotating shaft assembly are not app~eciabiy affected by the 201 presence of the torsion shaft.
¦ One preferred use of vibrator 10 is in a vibrating finishing or grindlng mill 32 illustrated in FIG. 4~ Such a ¦ mill includes an annular open-topped 'vessel 34 carried by a l vibrator body 112 which is resiliently mounted on a base 36 2S¦ by coil springs 114. Finishing 4r grinding operations take place in the well ~nown manner by operating a drive motor 124 to rotate a vibrator shaft 116 and count~rweights 118, 120 to lmpart v~brat~on~ of a suitable frequency to vessel 34 and the materlal contained in the vessel.
~ `- o ~04Z630 1 The advantage of the -Qystem shown in FIG. 4 is that motor 124 is not integrated into the vibrating portion of the system. Most of the vibrational energy developed by the vibrator and vessel is absorbed by flexible tor~ion shaft 128 S and therefore is not transmitted to the motor. Thu~, the useful life of the motor is substantially inc~eased when compared with the prior art vibrators in which the motor is A~ integrated directly into the vibrating portion of the . ~ system. Moreover, if shaft bearings ~ need replacement, they can be readily changed without disturbing the motor.
Bearings ~ also can be readily changed at will in accordance with the particular application of the vibrator assembly.
I have constructed a vibrator in accordance with the model shown in FIG. 1 and have observed the motion of various 1 objects resulting from vibratory energy being imparted to them from vibrator 10. In one series of experimènts, a continuous circular tubular conduit 38 was supported around the bottom of vibrator body 12, and observations were made ; of the motions of variou~ solid particulate objects placed 2 inside the conduit and induced by ~he vibrating motion of vibrator body 12. It was observed that objects moved in a sy3tematic fashion within the conduit. The objects used included steel balls, lead balls, gran~lated sugar, table ~alt, flour, and irregular shapes of lead, plastic, and felt.
2 It wa~ also observed that conduit 38 could be raised at one end to form a helix and that objects could be moved uphill, ~.e. against gravity, through the helix.
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Il 1 In experiments conducted with vibrator 10, several distinct modes of material transport have been observed, and are as follows:
(1) In response to relatively small a~plitude S horizontal displacement and angular displacement of vibrator body 12 and relatively smali angular velocities of rotating shaft 16, particulate objects other than balls tend to slide along the bottom surfaçe of conduit 38. There was a.pronounced dependence upon the phase relationship between the two counterweights. For example, if the angleo~.shown in FIG. 2 was changed from positive (top weight leading the bottom weight in a counterclockwise direction of rotation, as.illustrated in PIG. 2) to negati~e ~top weight following the bottom lS weight in a countercloc~wise direction of rotation), the direction of material transport was reversed.
~2) In response to larger vibrational amplitudes and larger angular frequencies, ob~ects other than balls moved through the conduit in a "fluidized"
condition. That i8, at any cross-section of the conduit, the moving particles 38 were suspended in a random array illustrated in FIG. 3. The pI~cle v~t also was sensitive . to phase relationships (the angle ~ in FIG. 2) between the çounter-weights, since reversing the lead angles between the . counterweights resulted in a reversed fluidized flow.
Moreover, the type of fluidized flow appeared to be relat~vely ind-pendent of the particulate concentration up to the po~nt where the part~cle~ sub~tantially filled the tubc cros~-section.
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~ , 1 ~ . o 1 ¦ ~3) At still larger values of vibrational ¦ amplitude and angular rotation, but where the displace-¦ ment of the vibrator body in the vertical direction was ¦ kept within previous ranges, fluidized flow again wa~
5 ¦ observed with object-~ other than balls. In this ¦ instance, velocities of particle tra~smis~ion were large, ¦ but were ~ep~ent of angular relationships between the counterweights. That is, changing the values of the l angle ~ in FIG. 2 from positive to negative did not 10¦ change the direction of flow, which always remained in one direction, i.e. the direction of rotation of shaft 16.
(4) At moderate values of vibrational amplitude and rotational frequency, balls were transmitted through the conduit 38 in a whirling fashion. That is, the balls rolled on the inner diameter of the conduit in a helical path directed along the tangential centerIine of the conduit. The direction of ball translation again was the same for positive or negative values of the angle in FIG. 2, but the translational velocity was found to be zero when the top and bottom counterweights were aligned 80 that the angleo~-~s 180.
The fiuidized particle transport-provided by vibrator 10 can be used in a gas-solid phase fluidized bed reactor; By 2S way of example, a typical prior art fluidized bed reactor is used to carry out various physical or chemical reactions by suspending an otherwise static bed of solid particles in a stream of ga~. Vibrator lO provides a different type of . ', . .
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. 104Z630 1 fluidiz~d bed reactor in which the fluidized stream of particulate matter can be made to flow aqainst an air strQam ~as well as against gravity). For example, in my observations it wa~ noted that particles of table salt could be induced to flow in a fluidized condition against air streams hav~ng a nominal flow rate (velocity of gas stream in an empty tube) of at least 200 centimeters per second. Furthermore, the flow experiment was conducted with a plastic tube nearly completely filled with salt, i.e., its cross-sectional area 0 was nearly packed tlght, which corresponds to particulate concentrations found normally in commercial fluidized reactors. Thus, the vibrator assembly 10 can be used in certain small scale chemical treatment operations in which a solid particulate material can be reacted with a stream of 1 gas flowing countercurrent to the 1uidized flow of the part$culate material.
Referring to FIGS. S and 6, one preferred use o~ the material transport properties of vibrator 10 is in a gas-solid phase catalytic reactor 40 in which a dry solid partiçulate 2 catalyst i8 continuously circulated in a flu~dized cqndition from a reaction chamber through a catalyst regeneration chamber. The catalytic reactor includes a reaction chamber 41 in which a typical react~on takes place between gas components, catalyzed by ~a) particulate solid(s). The system shown in 25 FIGS. 5 and 6 will be described in the context of a single ~tage reactor-regenerator for treatlng automobile exhaust ga~e~, although it ~tlll be under~tood that the ~y~tem al~o can be uJed ln other ga8 pha~e, Bolid catAlyzed reaction~ ~or contlnuou~ly reg~nerating and/or cooling a parti¢ulato cataly~t.
' ~.~- 0 1 Reaction chambcr 41 is of tubular configuration and is affixed to a rigid base 42 which, in turn, i8 supported by three radially spaced apart coil springs 214 suspended from corresponding fixed brackets 44. Base 42 holds the tubular reaction chamber 41 in a substantially horizontal position.
Base 42 also supports an elongated tubular catalyst regeneration chambèr 46 in a substantially horizontal po~ition extending substantially parallel to reaction chamber 41. An elongated feed tube 48 i8 rigidly attached to ba~e 42 so as to extend between reaction chamber 41 and regeneration chamber 46. Feed tube 48 is held in a substantially horizontal position by base 42, and the ends of the feed tube open into corresponding front portion~ of the reaction chamber and the regeneration chamber. Similarly, a horizontally disposed elongated return tube 50 is attached to the base and extends between end portions of the regeneration chamber and the reaction chamber. As shown best in FIG. 6, a suitab~e solid particulate catalyst 52 i~ contained in the re~ction chamber.
A gas inlet tube 54 opens into a front portion of reaction chamber 41. A lead pipe 56 coming from the engine manifold is connected to inlet 54 by a flexible hose connection 57. An elongated gas exit tube 58 opens into an end portion of reaction chamber 41. A flexible hose connection 59 connects gas exit tube 58 with a remaining portion of the 2S system which will be described below. The flexible hose connections are made of a high temperature material having ~uff~cient flexib~llty to accommodate three-dimensional motion of the ~pr~ng-~upported ma~s reiative to the fixed portion~ of the 8ystem ~uch as supports 44 and lcad plpe 56). "
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~O~Z630 1 During use of the reactor, exhaust gases flow from lead pipe 56 into inlet 54 and then through reaction chamber 40 where certain components of the gas are reacted in the presence of catalyst 52. The gases which remain after c~ntact with the catalyst pass from the reaction chamber through exit tube 58.
During use, the spring-supported mass is vibrated at a sufficiently high amplitude and suitable frequ~ncy ~o impart fluidized motion to the catalyst. The fluidized catalyst particles travel in a continuous circulating path from the -reaction chamber through the regeneration chamber and back tothe reaction chamber. Vibrational motion of the spring-~upported mass is produced by a, vibrator assembly substantially as shown in FIG. 1. The vibrator assembly includes an elongated rigid shaft 216 similax to shaft 16 described above and mounted lS to base 42 via anti-friction bearings 222. Top and bottom counterweights 218 and 220, respectively, are carried by shaft 216 to rotate with the shaft ~ndependently of ~ase-42. A drive motor 224 i8 coupled to a vertically ex~ending tubular torsion' 'shaft 228 identical in construction tc shaft 28 discussed above.
20 ~he torsion shaft is engaged with the rigid shaft 216 in the manner described above in FIG. 1 80 that the drive motor will rotate ~haft 216 to vibrate the spring-supported mass.
The mass of counterweights 218, 220 and the phase angle oc between the counterweights are adjusted so tha~ relatively 2 large amplitude vibrations, with a suitable phase relationship betweén the translational and angular components, are imparted, to the spr~ng-~upported mass which, in turn, generates the continuous circulating flow of catalyst in a ~luidized condition. ~8 shown ~est in FIG. 6, the c~taly~t flow8 ln 30 a cloc~wis¢ dircction from xeact,ion . ,, . -`1 Il 104Z630 1 chamber 41 through feed tube 48, through regeneration chamber 46 and back through return tube 50 to the reaction chamber.
Preferably, a tubular furnace 60 is located in the regenera-tion chamber so that the circulating catalyst particles can pass through the furnace. A pair of electrical leads 62 supply electrical power to the tubular fu~nace. Gas flow for the treatment of the catalyst (such as by burning off carbon by the passage of air through the regeneration chamber) . can enter an open end 46a of the regeneration chamber.
Gaseous products from the catalyst treatment exit the regeneration chamber at an open end 46b. The method of us$ng high temperature txeatment to regenerate the catalyst in chamber 46 is shown by way of example only, since it is to be understood that other suitable methods of regenerating solid catalyst particles can be used without departing from the scope of the invention.
One high temperature treatment method consists of forming tubular furnace 60 from the same material as the catalyst particles and maintaining the furnace at a su~stantially 20 higher temperature than the catalyst particles. In use, the relatively cold catalyst particles impinge on the relatively high temperature surface of the tubuiar furnace and then rebound from the surface. The material and temperatures are both controlled 80 that mutual adhesion of the two contacting 25 ~urfaces i~ greater than the intrinsic strength of either materlal. Pre~erably, the particles are solid rather than belng porou~. As the partlcle~-pas~ through the furnace, 80me partlcles ~tlck to the surface of the furnace and then ' ' ,11 1 divide at a new parting line when rebounding, which cau~es a fresh layer ~on a microscopic scale) of material from the furnace surface to cover a portion of the rebounding particle's outer surface. Consequently, with each collision, a bit of S fresh catalyst surface is created. Complete regeneration of the particles can be achieved by this process by the continuous circulation of the particles through the!furnace.
It shouid be understood that the separate regeneration chamber could be used to cool or heat the solid catalyst particles to provide control of the temperature in the reaction chamber. In addition, two or more regeneration (heating or cooling or other treatments) circuits can be used in combination with one reaction chamber. The rates of circulation in each of the two or more regeneration circuits can be independently controlled, and in the case of a temperature controlling circuit, the rates of circulation could be controlled ~y a feedback coupling with a temperature sensing device placed either in the reaction chamber or in the gas stream which either enters or exits the reaction chamber.
Preferably, the flow of exhaust gas through reaction chamber 41 runs countercurxent to the flow of the catalyst through the reaction chamber. This relative flow produces good contact between thè exhaust gas and the catalyst. The volume of catalyst circulating through the system is 25 controlled 80 that feed tube 48 and return tube 50 are both mainta~ned in a fully packed conditlon during thç continuous c~rculation of the catalyst. ~his fully packed condition of the cataly~t part~cle~ provides an effect~ve ga~ seal at exit port 41a and inlet port 41b ~see PIG. 61 of the reaction . ..
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. I 104Z630 ¦ chamb~r to maintain gas flow through the reaction chamber and prevent the exhaust gas from going through feed tube 48 or return tube 50 to the regeneration chamber. The fully I packed condition of feed and return tubes 48 an~ S0, 5¦ respectively, can be maintained by suitable choice of their ¦ diameters (with respect to the reaction a~d re'generator tube diameters) and/or suitable positioning of, orifices-~n the feed and return tube entrances and exits.
Thus, the gas-solid phase catalytic reactor provides 0¦ means for continuously recirculating a catalyst through a separate regeneration chamber and back through a reaction chamber where the catalyst is reacted wi~h a stream of gas ~lowing through the reaction chamber The fluidized flow of catalyst through the reaction chamber i3 produced by means 5¦ independent of the gas flow, and the catalyst flows counter-current to the gas flow which aids in preventing unusually large flow rates'of gas'from blowing the catalyst particles out of-the reaction chamber. However, in some applications ¦ it may be desirable to provide means for trapping unusually 20 ¦ large surges of catalyst from the reaction chamber. FIG. 5 ¦ illustrates a presently preferred method of trapping large ~urges in the catalyst. The method contemplates adding a ¦cyclone separator 64 to the system. All exi,t gases from ¦reaction chamber 41 pass through gas exit tube 58 and are 25 ¦then circulated through the cyclone separator by an inlet ¦line 66 coupled to exit tube 58 by flexible hose connection 159~ All gases remaining after treatment by the catalyst in ¦the reaction chamber pas~ to the atmosphere from the cyclone ¦~eparator through an,exit tube 70. Any unusually large surges 30 ¦in the cataly~t caused by back-fi~ing of tho engino or other-¦wi~ unusually largo flow rate~ oP ga8 thro~,gh the reaction 1 chamber will pass through inlet tube 66 into the top of the cyclone separator and will then be returned by the separator to return tube 50 via a suitable bypass line 71 connected to the bottom of the cyclone separator by a flexible hose connection 72.
When compared with fixed-bed type catalytic reactors, the catalytic reactor of this invention has the advantage of being able to continuously regenerate the catalyst 80 that the useful life of the reactor is extended substantially.
Mpreover, the fluidized condition of the catalyst substantially prevents the occurrence of hot spot~ which tend to be a problem in fixed-bed reactors.
The reactor of this invention also has advantage~ over conventional fluidized bed reactors. For example, the reactor of this invention does not depend upon input gas flow conditions ~o obtain the fluidized motion of the particles. By way of contrast, the effective operation of a fluidized bed reactor would be extremely difficult where there are substantial fluctuations in the gas flow rate to the reactor as is the case 20 with exhaust gases of automobiles during normal operation.
That is, the reactor of this invention is espec~ally suitable in applications, such as in treating the exhaust gases of automobiles, where there are substanti~l fluctuations in the gas flow rate to the reactor. ~hat is, during normal operation 25 of an automobile, exhaust gases will pass through the reaction chamber at various flow rates, but these differing input gas flow rates will not affect the fluidized motion of the catalyst particles which obtain their flu~dized condition independently of the gas flow. ~hus, the reactor of this invention can 30 accommodate various surg¢~ in the rate of gas flow through the reactor without ~ubstantial ~nterruptions in the circulating flow of catalytic materi~l to and from the regeneration chamber, or ~lthout ~ub~t~ntl~l lolJ- o~ c~t~ly~t t0 'Gh~ he~.
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. ( SUMMARY ~042630 -In accordance with this invention, there is provided catalyst xegeneration apparatus comprising:
(a) a closed circuit for simultaneously utilizing i 5 and regenerating a particulate catalyst circulated through the closed circuit, the closed circuit including a reaction chamber of closed cross-section having a spaced apart inlet and outlet, a regeneration chamber of closed cross-section having a spaced apart inlet and outlet, and gas seal conduit means of closed cross-section in which the reaction chamber outlet communicates by a tubular feed conduit with the regenerator inlet, and the regenerator outlet communicates by a tubular return conduit with the reaction chamber inlet;
(b) means mounting the closed circuit in a sub-stantially horizontal position;
(c) a predetermined quantity of a particulate catalyst contained in the closed circuit;
(d) means for introducing a stream of reactant gas to the reaction chamber;
(e) means for withdrawing said stream of reactant gas from the reaction chamber;
(f) means for passing said stream of reactant gas through the reaction chamber to contact the particulate catalyst contained in the reaction chamber prior to the gas being with-drawn from the reaction chamber to promote suitable reactions between components of the reactant gas;
(g) means for regenerating spent catalyst particles passing through the regeneration chamber; and (h) means for vibrating the horizontally disposed closea circuit as a unit to continuously circulate said catalyst ( particles in a fluidized, generally random cross-sectional dispersion through the closed circuit so that the particles travel in the reaction chamber and then through the feed conduit, the regeneration chamber, and the return conduit, and then back to the reaction chamber, to allow spent catalyst to be constantly regenerated from its passage through the regeneration means;
(i) said quantity of catalyst particles and the cross-section dimensions of the gas seal conduit means both being sufficient to cause the catalyst particles to circulate through said conduit means in a generally uniform, substantially completely filled cross-sectional dispersion to provide resistance to appreciable gas flow through the inlet and outlet openings of the reaction chamber so the regeneration of the lS catalyst particles takes place in the regeneration chamber without being affected by reactions between the reactant gas and the fluidized catalyst particles circulating through the reaction chamber.
In accordance with a further aspect of this invention, there is provided a method for carrying out gas phase ¦ reactions in the presence of a solid particulate catalyst and for continuously regenerating the catalyst so that the re-generation and reaction steps are isolated from each other, the method including the steps of:
(a) disposing a solid particulate catalyst in a closed circuit comprising a reaction chamber of closed cross-section having a spaced apart inlet and outlet, a regeneration ch~mber of closed cross-section having a spaced apart inlet and outlet, and gas seal means of closed cross-section in ~ich said reaction chamber outlet communicates by a tubular ~r~, 104Z63~
feed conduit with said regenerator inlet, and said regenerator outlet communicates by a tubular return conduit with said reaction chamber inlet, (b) mounting the closed circuit in a horizontal position and vibrating the closed circuit as a unit to impart : circulating fluidized translatory motion to the catalyst particles to cause the particles to travel in a generally uniform random cross-sectional dispersion through the closed circuit so that the particles continuously travel in the reaction chamber and then through the feed conduit, the re-generation chamber, and the return conduit o~ the closed circuit, respectively, and then back to the reaction chamber;
(cl passing a stream of reactant gas through the reaction chamber and through the catalyst particles therein, the reactant gas flowing in a direction through the reaction chamber which is countercurrent to the flow of catalyst particles through the reaction chamber, for promoting suitable reactions between components of the reactant gas; and (d) regenerating the fluidized catalyst particles being continuously circulated through the regeneration ¦ chamber;
¦ (e) the vibration further causing the catalyst particles to be circulated through the gas seal conduit means in a generally uniform, substantially completely filled cross-sectional dispersion to provide resistance to appre- -ciable gas flow through th~ inlet and outlet openings of the reaction chamber so that regeneration of the catalyst particles occurs in the regeneration chamber without being affected by reactions between the reactant gas and the fluidized catalyst particles flowing through the reaction cha~ber.
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' I` lQ4Z630 ¦This invention, in part, provides a mechanical vibrator ¦ in which the drive motor is separated from the active or ¦ vibrating portion of the vibrator assembly. Briefly, the ~ ¦ vibrator includes a vibrator body, a rotatable shaft mounted I to the vibrator body to rotate about its axis $ndependently ¦ of thè vibrator body, spaced apart counterweights engaged ¦ with opposite ends of the shaft to rotate with the shaft, ¦ and means for resiliently mounting the vibrator body. A drive :i I motor located remote from the vibrator body is engaged with the ¦ rotatable shaft through an elongated torsion shaft having both torsional and lateral flexibility. The drive motor rotates the shaft and counterweights to v$brate the vi~rator body.
The torsion shaft has suff$ciènt lateral flexibility and low ~'1 mass to permit substantial unrestrained vibration of the vibrator body and to prevent any appreciable vibrational energy from being transmitted to the drive motor an~ its bearings.
Since the drive motor is separated from the vibrating portion of the system, the bearings which mount the rotatable ~J' shaft to the vibrator body can be changed without disturbing the drive motor. Since the bearings can be changed at will, it i8 ~180 practicable to use different types of vibrator shaft bearings depend$ng upon the particular use of the vibrator.
Preferred uses of the vibrator assembly would be as a separator, grinding mill, or finishing mill. The separat$on of the drive motor from the vibrating portion of the system also is an advant~ge ~f explos~on or fire hazards ar~ present because of the type of process mator~als uséd 1~ the applications discu~ed ~bov , A ~, . 1042630 1In one embodiment of the invention, carrier means are mounted on the vibrator body for containing a suitable medium to receive the vibrational energy developed by the vibrator.
The vibrator is subjected to large amplitude vibrations sufficient to cause solid particulate matter contained in the carrier means to travel through the carrier in a fluidized condition. Thus, the vibrator of this invention can be used as a material transport apparatus, and in the preferred form of the invention, the vibrator body comprises a closed reaction 0 chamber for receiving a flow of gas to be contacted with a ~uitable particulate catalyst contaiped in the reaction chamber for promoting desired reactions~ between chemical components of the gas phase. The vibrational energy imparted to the reaction chamber causes the catalyst pàrticles to flow continuously in a fluidized condition from the reaction chamber through a suitable catalyst regeneration chamber and back through the reaction chamber.
These and other aspects of the invention will be more fully understood by referring to the following detailed description and the accompanying drawings.
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DRAWINGS
PIG. 1 is a frag~enta~y schematic elevation view, partly in cross-section, showing a mechanical vibrator according to 2 th$~ invention, FIG. 2 i8 a schematlc plan view illustrating a phase angle relationship between a pair of counterweights in the vibrator of PIG. l; ; "j I ~
FIG. 3 is an"enlarged fragmentary cross-sectional elevation 30 view illstrating partlculatc matter flowing in a fluidized ¢ondition through the tubular ~onduit of the vibrator ~hown in P~G. 1~ G
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FIG. 4 is a fragmentary schematic elevation view, partl~ in cross-section, illustrating a preferred use of the vibrator of FIG. 1 in a finishing or grinding mill;
FIG. 5 is a fragmentary semi-schematic perspective view illustrating the use of the vibrator of FIG. 1 in a system for regenerating a catalyst; and FIG. 6 (appearing on sheet 1 of the drawings) is a semi-schematic plan view, partly broken away, illustrating a particulate catalyst circulating in a fluidized condition through the catalyst regeneration system of FIG. 5.
FIG. 1 schematically illustrates a mechanical vibrator 10 having a vibrator body 12 which is resiliently supported by several radially spaced apart coil springs 14. Preferably, vibrator body 12 is mounted by three equidistantly spaced apart springs. An asymmetrically loaded, vertically extending, rigid rotatable shaft 16 is supported by the vibrator body. The top and bottom ends of shaft 16 carry vertically spaced apart counterweights 18 and 20, respectively, adapted to rotate with the shaft in corresponding horizontal planes. Shaft 16 is mounted to vibrator body 12 by a pair of vertically spaced apart anti-friction bearings 22 which allow the shaft 16 and counterweights to rotate independently of the vibrator body.
A variable speed electric motor 24 drives a rotary double-ended motor output shaft 26 which, in turn, is coupled to shaft 16 by a vertically extending, tubular, elongated torsion drive shaft 28. The torsion shaft preferably is tubular and of relatively small diameter and thus is relatively o . 1 104Z630 1 ¦ light in weight as well as having torsional and lateral ¦ flexibility and suitable torsional strength to transmit torques ¦ of the required magnitudc. By way of example, the tor~ion ¦ shaft in many applications can comprise a thin plastic tube ¦ approximately 3/32 inch in diameter.
During use of vibrator 10, motor 24 drives torsion shaft 28 which, in turn, rotates shaft 16 about its axis at-a constant angular velocity. This causes the spring supported body 12 and shaft 16 to vibrate as a unit, the vibration 0¦ consisting of small periodic movements that consist of either translations in the horizontal plane, or tipping of the vertical axis, or a combination of both, depending upon the mass of the rotating counterweights and their'angular l displacement (the angleoc shown in FIG. 2). The mass of the 15¦ counterweights i8 small compared to that of the spring supported ¦ body. Moreover, the torsion drive tube is kept somewhat slac~
¦ in its connection 30 to rigid shaft 16, so t~at angular and/or ¦ translational displacement of the spring supported body and ¦ rotating shaft assembly are not app~eciabiy affected by the 201 presence of the torsion shaft.
¦ One preferred use of vibrator 10 is in a vibrating finishing or grindlng mill 32 illustrated in FIG. 4~ Such a ¦ mill includes an annular open-topped 'vessel 34 carried by a l vibrator body 112 which is resiliently mounted on a base 36 2S¦ by coil springs 114. Finishing 4r grinding operations take place in the well ~nown manner by operating a drive motor 124 to rotate a vibrator shaft 116 and count~rweights 118, 120 to lmpart v~brat~on~ of a suitable frequency to vessel 34 and the materlal contained in the vessel.
~ `- o ~04Z630 1 The advantage of the -Qystem shown in FIG. 4 is that motor 124 is not integrated into the vibrating portion of the system. Most of the vibrational energy developed by the vibrator and vessel is absorbed by flexible tor~ion shaft 128 S and therefore is not transmitted to the motor. Thu~, the useful life of the motor is substantially inc~eased when compared with the prior art vibrators in which the motor is A~ integrated directly into the vibrating portion of the . ~ system. Moreover, if shaft bearings ~ need replacement, they can be readily changed without disturbing the motor.
Bearings ~ also can be readily changed at will in accordance with the particular application of the vibrator assembly.
I have constructed a vibrator in accordance with the model shown in FIG. 1 and have observed the motion of various 1 objects resulting from vibratory energy being imparted to them from vibrator 10. In one series of experimènts, a continuous circular tubular conduit 38 was supported around the bottom of vibrator body 12, and observations were made ; of the motions of variou~ solid particulate objects placed 2 inside the conduit and induced by ~he vibrating motion of vibrator body 12. It was observed that objects moved in a sy3tematic fashion within the conduit. The objects used included steel balls, lead balls, gran~lated sugar, table ~alt, flour, and irregular shapes of lead, plastic, and felt.
2 It wa~ also observed that conduit 38 could be raised at one end to form a helix and that objects could be moved uphill, ~.e. against gravity, through the helix.
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Il 1 In experiments conducted with vibrator 10, several distinct modes of material transport have been observed, and are as follows:
(1) In response to relatively small a~plitude S horizontal displacement and angular displacement of vibrator body 12 and relatively smali angular velocities of rotating shaft 16, particulate objects other than balls tend to slide along the bottom surfaçe of conduit 38. There was a.pronounced dependence upon the phase relationship between the two counterweights. For example, if the angleo~.shown in FIG. 2 was changed from positive (top weight leading the bottom weight in a counterclockwise direction of rotation, as.illustrated in PIG. 2) to negati~e ~top weight following the bottom lS weight in a countercloc~wise direction of rotation), the direction of material transport was reversed.
~2) In response to larger vibrational amplitudes and larger angular frequencies, ob~ects other than balls moved through the conduit in a "fluidized"
condition. That i8, at any cross-section of the conduit, the moving particles 38 were suspended in a random array illustrated in FIG. 3. The pI~cle v~t also was sensitive . to phase relationships (the angle ~ in FIG. 2) between the çounter-weights, since reversing the lead angles between the . counterweights resulted in a reversed fluidized flow.
Moreover, the type of fluidized flow appeared to be relat~vely ind-pendent of the particulate concentration up to the po~nt where the part~cle~ sub~tantially filled the tubc cros~-section.
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~ , 1 ~ . o 1 ¦ ~3) At still larger values of vibrational ¦ amplitude and angular rotation, but where the displace-¦ ment of the vibrator body in the vertical direction was ¦ kept within previous ranges, fluidized flow again wa~
5 ¦ observed with object-~ other than balls. In this ¦ instance, velocities of particle tra~smis~ion were large, ¦ but were ~ep~ent of angular relationships between the counterweights. That is, changing the values of the l angle ~ in FIG. 2 from positive to negative did not 10¦ change the direction of flow, which always remained in one direction, i.e. the direction of rotation of shaft 16.
(4) At moderate values of vibrational amplitude and rotational frequency, balls were transmitted through the conduit 38 in a whirling fashion. That is, the balls rolled on the inner diameter of the conduit in a helical path directed along the tangential centerIine of the conduit. The direction of ball translation again was the same for positive or negative values of the angle in FIG. 2, but the translational velocity was found to be zero when the top and bottom counterweights were aligned 80 that the angleo~-~s 180.
The fiuidized particle transport-provided by vibrator 10 can be used in a gas-solid phase fluidized bed reactor; By 2S way of example, a typical prior art fluidized bed reactor is used to carry out various physical or chemical reactions by suspending an otherwise static bed of solid particles in a stream of ga~. Vibrator lO provides a different type of . ', . .
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. 104Z630 1 fluidiz~d bed reactor in which the fluidized stream of particulate matter can be made to flow aqainst an air strQam ~as well as against gravity). For example, in my observations it wa~ noted that particles of table salt could be induced to flow in a fluidized condition against air streams hav~ng a nominal flow rate (velocity of gas stream in an empty tube) of at least 200 centimeters per second. Furthermore, the flow experiment was conducted with a plastic tube nearly completely filled with salt, i.e., its cross-sectional area 0 was nearly packed tlght, which corresponds to particulate concentrations found normally in commercial fluidized reactors. Thus, the vibrator assembly 10 can be used in certain small scale chemical treatment operations in which a solid particulate material can be reacted with a stream of 1 gas flowing countercurrent to the 1uidized flow of the part$culate material.
Referring to FIGS. S and 6, one preferred use o~ the material transport properties of vibrator 10 is in a gas-solid phase catalytic reactor 40 in which a dry solid partiçulate 2 catalyst i8 continuously circulated in a flu~dized cqndition from a reaction chamber through a catalyst regeneration chamber. The catalytic reactor includes a reaction chamber 41 in which a typical react~on takes place between gas components, catalyzed by ~a) particulate solid(s). The system shown in 25 FIGS. 5 and 6 will be described in the context of a single ~tage reactor-regenerator for treatlng automobile exhaust ga~e~, although it ~tlll be under~tood that the ~y~tem al~o can be uJed ln other ga8 pha~e, Bolid catAlyzed reaction~ ~or contlnuou~ly reg~nerating and/or cooling a parti¢ulato cataly~t.
' ~.~- 0 1 Reaction chambcr 41 is of tubular configuration and is affixed to a rigid base 42 which, in turn, i8 supported by three radially spaced apart coil springs 214 suspended from corresponding fixed brackets 44. Base 42 holds the tubular reaction chamber 41 in a substantially horizontal position.
Base 42 also supports an elongated tubular catalyst regeneration chambèr 46 in a substantially horizontal po~ition extending substantially parallel to reaction chamber 41. An elongated feed tube 48 i8 rigidly attached to ba~e 42 so as to extend between reaction chamber 41 and regeneration chamber 46. Feed tube 48 is held in a substantially horizontal position by base 42, and the ends of the feed tube open into corresponding front portion~ of the reaction chamber and the regeneration chamber. Similarly, a horizontally disposed elongated return tube 50 is attached to the base and extends between end portions of the regeneration chamber and the reaction chamber. As shown best in FIG. 6, a suitab~e solid particulate catalyst 52 i~ contained in the re~ction chamber.
A gas inlet tube 54 opens into a front portion of reaction chamber 41. A lead pipe 56 coming from the engine manifold is connected to inlet 54 by a flexible hose connection 57. An elongated gas exit tube 58 opens into an end portion of reaction chamber 41. A flexible hose connection 59 connects gas exit tube 58 with a remaining portion of the 2S system which will be described below. The flexible hose connections are made of a high temperature material having ~uff~cient flexib~llty to accommodate three-dimensional motion of the ~pr~ng-~upported ma~s reiative to the fixed portion~ of the 8ystem ~uch as supports 44 and lcad plpe 56). "
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~O~Z630 1 During use of the reactor, exhaust gases flow from lead pipe 56 into inlet 54 and then through reaction chamber 40 where certain components of the gas are reacted in the presence of catalyst 52. The gases which remain after c~ntact with the catalyst pass from the reaction chamber through exit tube 58.
During use, the spring-supported mass is vibrated at a sufficiently high amplitude and suitable frequ~ncy ~o impart fluidized motion to the catalyst. The fluidized catalyst particles travel in a continuous circulating path from the -reaction chamber through the regeneration chamber and back tothe reaction chamber. Vibrational motion of the spring-~upported mass is produced by a, vibrator assembly substantially as shown in FIG. 1. The vibrator assembly includes an elongated rigid shaft 216 similax to shaft 16 described above and mounted lS to base 42 via anti-friction bearings 222. Top and bottom counterweights 218 and 220, respectively, are carried by shaft 216 to rotate with the shaft ~ndependently of ~ase-42. A drive motor 224 i8 coupled to a vertically ex~ending tubular torsion' 'shaft 228 identical in construction tc shaft 28 discussed above.
20 ~he torsion shaft is engaged with the rigid shaft 216 in the manner described above in FIG. 1 80 that the drive motor will rotate ~haft 216 to vibrate the spring-supported mass.
The mass of counterweights 218, 220 and the phase angle oc between the counterweights are adjusted so tha~ relatively 2 large amplitude vibrations, with a suitable phase relationship betweén the translational and angular components, are imparted, to the spr~ng-~upported mass which, in turn, generates the continuous circulating flow of catalyst in a ~luidized condition. ~8 shown ~est in FIG. 6, the c~taly~t flow8 ln 30 a cloc~wis¢ dircction from xeact,ion . ,, . -`1 Il 104Z630 1 chamber 41 through feed tube 48, through regeneration chamber 46 and back through return tube 50 to the reaction chamber.
Preferably, a tubular furnace 60 is located in the regenera-tion chamber so that the circulating catalyst particles can pass through the furnace. A pair of electrical leads 62 supply electrical power to the tubular fu~nace. Gas flow for the treatment of the catalyst (such as by burning off carbon by the passage of air through the regeneration chamber) . can enter an open end 46a of the regeneration chamber.
Gaseous products from the catalyst treatment exit the regeneration chamber at an open end 46b. The method of us$ng high temperature txeatment to regenerate the catalyst in chamber 46 is shown by way of example only, since it is to be understood that other suitable methods of regenerating solid catalyst particles can be used without departing from the scope of the invention.
One high temperature treatment method consists of forming tubular furnace 60 from the same material as the catalyst particles and maintaining the furnace at a su~stantially 20 higher temperature than the catalyst particles. In use, the relatively cold catalyst particles impinge on the relatively high temperature surface of the tubuiar furnace and then rebound from the surface. The material and temperatures are both controlled 80 that mutual adhesion of the two contacting 25 ~urfaces i~ greater than the intrinsic strength of either materlal. Pre~erably, the particles are solid rather than belng porou~. As the partlcle~-pas~ through the furnace, 80me partlcles ~tlck to the surface of the furnace and then ' ' ,11 1 divide at a new parting line when rebounding, which cau~es a fresh layer ~on a microscopic scale) of material from the furnace surface to cover a portion of the rebounding particle's outer surface. Consequently, with each collision, a bit of S fresh catalyst surface is created. Complete regeneration of the particles can be achieved by this process by the continuous circulation of the particles through the!furnace.
It shouid be understood that the separate regeneration chamber could be used to cool or heat the solid catalyst particles to provide control of the temperature in the reaction chamber. In addition, two or more regeneration (heating or cooling or other treatments) circuits can be used in combination with one reaction chamber. The rates of circulation in each of the two or more regeneration circuits can be independently controlled, and in the case of a temperature controlling circuit, the rates of circulation could be controlled ~y a feedback coupling with a temperature sensing device placed either in the reaction chamber or in the gas stream which either enters or exits the reaction chamber.
Preferably, the flow of exhaust gas through reaction chamber 41 runs countercurxent to the flow of the catalyst through the reaction chamber. This relative flow produces good contact between thè exhaust gas and the catalyst. The volume of catalyst circulating through the system is 25 controlled 80 that feed tube 48 and return tube 50 are both mainta~ned in a fully packed conditlon during thç continuous c~rculation of the catalyst. ~his fully packed condition of the cataly~t part~cle~ provides an effect~ve ga~ seal at exit port 41a and inlet port 41b ~see PIG. 61 of the reaction . ..
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. I 104Z630 ¦ chamb~r to maintain gas flow through the reaction chamber and prevent the exhaust gas from going through feed tube 48 or return tube 50 to the regeneration chamber. The fully I packed condition of feed and return tubes 48 an~ S0, 5¦ respectively, can be maintained by suitable choice of their ¦ diameters (with respect to the reaction a~d re'generator tube diameters) and/or suitable positioning of, orifices-~n the feed and return tube entrances and exits.
Thus, the gas-solid phase catalytic reactor provides 0¦ means for continuously recirculating a catalyst through a separate regeneration chamber and back through a reaction chamber where the catalyst is reacted wi~h a stream of gas ~lowing through the reaction chamber The fluidized flow of catalyst through the reaction chamber i3 produced by means 5¦ independent of the gas flow, and the catalyst flows counter-current to the gas flow which aids in preventing unusually large flow rates'of gas'from blowing the catalyst particles out of-the reaction chamber. However, in some applications ¦ it may be desirable to provide means for trapping unusually 20 ¦ large surges of catalyst from the reaction chamber. FIG. 5 ¦ illustrates a presently preferred method of trapping large ~urges in the catalyst. The method contemplates adding a ¦cyclone separator 64 to the system. All exi,t gases from ¦reaction chamber 41 pass through gas exit tube 58 and are 25 ¦then circulated through the cyclone separator by an inlet ¦line 66 coupled to exit tube 58 by flexible hose connection 159~ All gases remaining after treatment by the catalyst in ¦the reaction chamber pas~ to the atmosphere from the cyclone ¦~eparator through an,exit tube 70. Any unusually large surges 30 ¦in the cataly~t caused by back-fi~ing of tho engino or other-¦wi~ unusually largo flow rate~ oP ga8 thro~,gh the reaction 1 chamber will pass through inlet tube 66 into the top of the cyclone separator and will then be returned by the separator to return tube 50 via a suitable bypass line 71 connected to the bottom of the cyclone separator by a flexible hose connection 72.
When compared with fixed-bed type catalytic reactors, the catalytic reactor of this invention has the advantage of being able to continuously regenerate the catalyst 80 that the useful life of the reactor is extended substantially.
Mpreover, the fluidized condition of the catalyst substantially prevents the occurrence of hot spot~ which tend to be a problem in fixed-bed reactors.
The reactor of this invention also has advantage~ over conventional fluidized bed reactors. For example, the reactor of this invention does not depend upon input gas flow conditions ~o obtain the fluidized motion of the particles. By way of contrast, the effective operation of a fluidized bed reactor would be extremely difficult where there are substantial fluctuations in the gas flow rate to the reactor as is the case 20 with exhaust gases of automobiles during normal operation.
That is, the reactor of this invention is espec~ally suitable in applications, such as in treating the exhaust gases of automobiles, where there are substanti~l fluctuations in the gas flow rate to the reactor. ~hat is, during normal operation 25 of an automobile, exhaust gases will pass through the reaction chamber at various flow rates, but these differing input gas flow rates will not affect the fluidized motion of the catalyst particles which obtain their flu~dized condition independently of the gas flow. ~hus, the reactor of this invention can 30 accommodate various surg¢~ in the rate of gas flow through the reactor without ~ubstantial ~nterruptions in the circulating flow of catalytic materi~l to and from the regeneration chamber, or ~lthout ~ub~t~ntl~l lolJ- o~ c~t~ly~t t0 'Gh~ he~.
Claims (37)
1. Catalyst regeneration apparatus comprising:
(a) a closed circuit for simultaneously utilizing and regenerating a particulate catalyst circulated through the closed circuit, the closed circuit including a reaction chamber of closed cross-section having a spaced apart inlet and outlet, a regeneration chamber of closed cross-section having a spaced apart inlet and outlet, and gas seal conduit means of closed cross-section in which the reaction chamber outlet communicates by a tubular feed conduit with the regenerator inlet, and the regenerator outlet communicates by a tubular return conduit with the reaction chamber inlet;
(b) means mounting the closed circuit in a substantially horizontal position;
(c) a predetermined quantity of a particulate catalyst contained in the closed circuit;
(d) means for introducing a stream of reactant gas to the reaction chamber;
(e) means for withdrawing said stream of reactant gas from the reaction chamber;
(f) means for passing said stream of reactant gas through the reaction chamber to contact the particulate catalyst contained in the reaction chamber prior to the gas being withdrawn from the reaction chamber to promote suitable reactions between components of the reactant gas;
(g) means for regenerating spent catalyst particles passing through the regeneration chamber; and (h) means for vibrating the horizontally disposed closed circuit as a unit to continuously circulate said catalyst particles in a fluidized, generally random cross-sectional dispersion through the closed circuit so that the particles travel in the reaction chamber and then through the feed conduit, the regeneration chamber, and the return conduit, and then back to the reaction chamber, to allow spent catalyst to be constantly regenerated from its passage through the regeneration means;
(i) said quantity of catalyst particles and the cross-sectional dimensions of the gas seal conduit means both being sufficient to cause the catalyst particles to circulate through said conduit means in a generally uniform, substantially completely filled cross-sectional dispersion to provide resis-tance to appreciable gas flow through the inlet and outlet openings of the reaction chamber so that the regeneration of the catalyst particles takes place in the regeneration chamber without being affected by reactions between the reactant gas and the fluidized catalyst particles circulating through the reaction chamber.
(a) a closed circuit for simultaneously utilizing and regenerating a particulate catalyst circulated through the closed circuit, the closed circuit including a reaction chamber of closed cross-section having a spaced apart inlet and outlet, a regeneration chamber of closed cross-section having a spaced apart inlet and outlet, and gas seal conduit means of closed cross-section in which the reaction chamber outlet communicates by a tubular feed conduit with the regenerator inlet, and the regenerator outlet communicates by a tubular return conduit with the reaction chamber inlet;
(b) means mounting the closed circuit in a substantially horizontal position;
(c) a predetermined quantity of a particulate catalyst contained in the closed circuit;
(d) means for introducing a stream of reactant gas to the reaction chamber;
(e) means for withdrawing said stream of reactant gas from the reaction chamber;
(f) means for passing said stream of reactant gas through the reaction chamber to contact the particulate catalyst contained in the reaction chamber prior to the gas being withdrawn from the reaction chamber to promote suitable reactions between components of the reactant gas;
(g) means for regenerating spent catalyst particles passing through the regeneration chamber; and (h) means for vibrating the horizontally disposed closed circuit as a unit to continuously circulate said catalyst particles in a fluidized, generally random cross-sectional dispersion through the closed circuit so that the particles travel in the reaction chamber and then through the feed conduit, the regeneration chamber, and the return conduit, and then back to the reaction chamber, to allow spent catalyst to be constantly regenerated from its passage through the regeneration means;
(i) said quantity of catalyst particles and the cross-sectional dimensions of the gas seal conduit means both being sufficient to cause the catalyst particles to circulate through said conduit means in a generally uniform, substantially completely filled cross-sectional dispersion to provide resis-tance to appreciable gas flow through the inlet and outlet openings of the reaction chamber so that the regeneration of the catalyst particles takes place in the regeneration chamber without being affected by reactions between the reactant gas and the fluidized catalyst particles circulating through the reaction chamber.
2. Apparatus according to claim 1 in which the vibrating means includes means for resiliently mounting the closed circuit, and rotatable counterweight means to impart vibrating motion to the closed circuit.
3. Apparatus according to claim 2 in which the rotatable counterweight means include a rotary shaft engaged with the closed circuit and adapted to rotate about its axis indepen-dently of the closed circuit, spaced apart counterweights at opposite ends of the rotary shaft to rotate with the shaft, and drive means coupled with the shaft to rotate the shaft and counterweights to impart vibrating motion to the closed circuit.
4. Apparatus according to claim 3 including means for adjusting the angular relationship between the counterweights to control the fluidized circulating motion of the catalyst particles.
5. Apparatus according to claims 1, 2 or 3 including means for adjusting the vibrational frequency of the vibratory motion imparted to the closed circuit to control the fluidized circulating motion of the catalyst particles.
6. Apparatus according to claim 3 including an elongated torsion shaft having both torsional and lateral flexibility, and means coupling the torsion shaft between the drive means and the rotary shaft so as to prevent substantial vibrational energy from being transmitted to the drive means.
7. Apparatus according to claims 1, 3 or 6 including separator means communicating with a discharge opening in the reaction chamber for trapping relatively large amplitude surges in catalytic material passing through said discharge opening, and means for returning the trapped catalytic material from said separator means to the reaction chamber.
8. Apparatus according to claim 1, 3 or 6 including a cyclone separator in communication with a discharge opening of the reaction chamber for trapping large amplitude surges of the catalytic material, and means for feeding trapped catalytic material from the cyclone separator back to the reaction chamber.
9. Apparatus according to claim 1, 3 or 6 in which the catalyst regeneration means comprises high temperature means in the regeneration chamber for heating the surface of catalyst particles being circulated through the regeneration chamber.
10. Apparatus according to claim 1, 3 or 6 in which the catalyst regeneration means includes means for introducing a flow of gas to the regeneration chamber, means for passing the flow of gas through the length of the regeneration chamber to contact the spent catalyst particles with the gas to regenerate the catalyst particles, and means for allowing the gas flow to exit the regeneration chamber to the atmosphere.
11. Apparatus according to claim 1, 3 or 6 in which the catalyst regeneration means comprises high temperature means in the regeneration chamber for heating the surface of catalyst particles being circulated through the regeneration chamber and in which the catalyst regeneration means includes means for introducing a flow of gas to the regeneration chamber, means for passing the flow of gas through the length of the regeneration chamber to contact the spent catalyst particles with the gas to regenerate the catalyst particles, and means for allowing the gas flow to exit the regeneration chamber to the atmosphere.
12. Apparatus according to claim 1, 3 or 6 in which the high temperature means includes a heatable surface positioned within the regeneration chamber so that catalyst particles traveling through the regeneration chamber impinge on the surface of the furnace, and means for heating the surface of the furnace to a temperature substantially greater than that of the catalyst particles, the surface of the furnace being of the same material as that of the catalyst and being adapted to separate from said surface to create fresh atomic layers on the catalyst particles in response to impingement of the particles on the said surface.
13. Apparatus according to claim 1, 3 or 6 in which the catalyst regeneration means comprises high temperature means in the regeneration chamber for heating the surface of catalyst particles being circulated through the regeneration chamber and wherein the high temperature means includes a heatable surface positioned within the regeneration chamber so that catalyst particles traveling through the regeneration chamber impinge on the surface of the furnace, and means for heating the surface of the furnace to a temperature substantially greater than that of the catalyst particles, the surface of the furnace being of the same material as that of the catalyst and being adapted to separate from said surface to create fresh atomic layers on the catalyst particles in response to impingement of the particles on said surface.
14. Apparatus according to claims 1, 3 or 4 in which the vibrating means cause the catalyst particles to travel in a preselected direction between the inlet and outlet of the reaction chamber; and including means for passing the stream of reactant gas through the reaction chamber in a direction opposite to the fluidized flow of catalyst particles therein.
15. In an exhaust system for treating exhaust gases, the improvement comprising:
(a) a closed circuit for simultaneously treating the exhaust gases with a particulate catalyst and for simultaneously regenerating the particulate catalyst, the closed circuit including a reaction chamber of closed cross-section having a spaced apart inlet and outlet, a regeneration chamber of closed cross-section having a spaced apart inlet and outlet, and gas seal conduit means of closed cross-section in which the reaction chamber outlet communicates by a tubular feed conduit with the regenerator inlet, and the regenerator outlet communicates by a tubular return conduit with the reaction chamber inlet;
(b) means mounting the closed circuit in a substantially horizontal position;
(c) a predetermined quantity of a particulate catalyst contained in the closed circuit;
(d) means for introducing a stream of said exhaust gas to the reaction chamber;
(e) means for withdrawing said stream of exhaust gas from the reaction chamber;
(f) means for passing said stream of exhaust gas through the reaction chamber to contact the particulate catalyst contained in the reaction chamber prior to the exhaust gas being withdrawn from the reaction chamber to promote suitable reactions between components of the exhaust gas;
(g) means for regenerating spent catalytic particles passing through the regeneration chamber; and (h) means for vibrating the horizontally disposed closed circuit as a unit to continuously circulate said catalyst particles in a fluidized, generally random cross-sectional dispersion through the closed circuit so that the particles travel in the reaction chamber and then through the feed conduit, the regeneration chamber and the return conduit, then back to the reaction chamber, to allow spent catalyst to be constantly regenerated from its passage through the regeneration means;
(i) said quantity of catalyst particles and the cross-sectional dimensions of the gas seal conduit means both being sufficient to cause the catalyst particles to circulate through said conduit means in a generally uniform, substantially completely filled cross-sectional dispersion to provide resistance to appreciable gas flow through the inlet and outlet openings of the reaction chamber so the regeneration of the catalyst particles takes place in the regeneration chamber without being affected by reactions between the exhaust gas and the fluidized catalyst particles circulating through the reaction chamber.
(a) a closed circuit for simultaneously treating the exhaust gases with a particulate catalyst and for simultaneously regenerating the particulate catalyst, the closed circuit including a reaction chamber of closed cross-section having a spaced apart inlet and outlet, a regeneration chamber of closed cross-section having a spaced apart inlet and outlet, and gas seal conduit means of closed cross-section in which the reaction chamber outlet communicates by a tubular feed conduit with the regenerator inlet, and the regenerator outlet communicates by a tubular return conduit with the reaction chamber inlet;
(b) means mounting the closed circuit in a substantially horizontal position;
(c) a predetermined quantity of a particulate catalyst contained in the closed circuit;
(d) means for introducing a stream of said exhaust gas to the reaction chamber;
(e) means for withdrawing said stream of exhaust gas from the reaction chamber;
(f) means for passing said stream of exhaust gas through the reaction chamber to contact the particulate catalyst contained in the reaction chamber prior to the exhaust gas being withdrawn from the reaction chamber to promote suitable reactions between components of the exhaust gas;
(g) means for regenerating spent catalytic particles passing through the regeneration chamber; and (h) means for vibrating the horizontally disposed closed circuit as a unit to continuously circulate said catalyst particles in a fluidized, generally random cross-sectional dispersion through the closed circuit so that the particles travel in the reaction chamber and then through the feed conduit, the regeneration chamber and the return conduit, then back to the reaction chamber, to allow spent catalyst to be constantly regenerated from its passage through the regeneration means;
(i) said quantity of catalyst particles and the cross-sectional dimensions of the gas seal conduit means both being sufficient to cause the catalyst particles to circulate through said conduit means in a generally uniform, substantially completely filled cross-sectional dispersion to provide resistance to appreciable gas flow through the inlet and outlet openings of the reaction chamber so the regeneration of the catalyst particles takes place in the regeneration chamber without being affected by reactions between the exhaust gas and the fluidized catalyst particles circulating through the reaction chamber.
16. The improvement according to claim 15 in which the vibrating means includes means for resiliently mounting the closed circuit, and rotatable counterweight means to impart vibrating motion to the closed circuit.
17. The improvement according to claim 16 in which the rotatable counterweight means include a rotary shaft engaged with the closed circuit and adapted to rotate about its axis independently of the closed circuit, spaced apart counterweights at opposite ends of the rotary shaft to rotate with the shaft, and drive means coupled with the shaft to rotate the shaft and counterweights to impart vibrating motion to the closed circuit.
18. The improvement according to claim 15, 16 or 17, in which the vibrating means cause the catalyst particles to travel in a preselected direction between the inlet and outlet of the reaction chamber; and including means for passing the stream of reactant gas through the reaction chamber in a direction opposite to the fluidized flow of catalyst particles therein.
19. The improvement according to claim 15, 16 or 17, including separator means communicating with a discharge opening in the reaction chamber for trapping relatively large amplitude surges in catalytic material passing through said discharge opening, and means for returning the trapped catalytic material from said separator means to the reaction chamber.
20. A method for carrying out gas phase reactions in the presence of a solid particulate catalyst and for continuously regenerating the catalyst so that the regeneration and reaction steps are isolated from each other, the method including the steps of:
(a) disposing a solid particulate catalyst in a closed circuit comprising a reaction chamber of closed cross-section having a spaced apart inlet and outlet, a regeneration chamber of closed cross-section having a spaced apart inlet and outlet, and gas seal means of closed cross-section in which said reaction chamber outlet communicates by a tubular feed conduit with said regenerator inlet, and said regenerator outlet communicates by a tubular return conduit with said reaction chamber inlet;
(b) mounting the closed circuit in a horizontal position and vibrating the closed circuit as a unit to impart circulating fluidized translatory motion to the catalyst particles to cause the particles to travel in a generally uniform random cross-sectional dispersion through the closed circuit so that the particles continuously travel in the reaction chamber and then through the feed conduit, the regeneration chamber, and the return conduit of the closed circuit, respectively, and then back to the reaction chamber;
(c) passing a stream of reactant gas through the reaction chamber and through the catalyst particles therein, the reactant gas flowing in a direction through the reaction chamber which is countercurrent to the flow of catalyst particles through the reaction chamber, for promoting suitable reactions between components of the reactant gas; and (d) regenerating the fluidized catalyst particles being continuously circulated through the regeneration chamber;
(e) the vibration further causing the catalyst particles to be circulated though the gas seal conduit means in a generally uniform, substantially completely filled cross-sectional dispersion to provide resistance to appreciable gas flow through the inlet and outlet openings of the reaction chamber so that regeneration of the catalyst particles occurs in the regeneration chamber without being affected by reactions between the reactant gas and the fluidized catalyst particles flowing through the reaction chamber.
(a) disposing a solid particulate catalyst in a closed circuit comprising a reaction chamber of closed cross-section having a spaced apart inlet and outlet, a regeneration chamber of closed cross-section having a spaced apart inlet and outlet, and gas seal means of closed cross-section in which said reaction chamber outlet communicates by a tubular feed conduit with said regenerator inlet, and said regenerator outlet communicates by a tubular return conduit with said reaction chamber inlet;
(b) mounting the closed circuit in a horizontal position and vibrating the closed circuit as a unit to impart circulating fluidized translatory motion to the catalyst particles to cause the particles to travel in a generally uniform random cross-sectional dispersion through the closed circuit so that the particles continuously travel in the reaction chamber and then through the feed conduit, the regeneration chamber, and the return conduit of the closed circuit, respectively, and then back to the reaction chamber;
(c) passing a stream of reactant gas through the reaction chamber and through the catalyst particles therein, the reactant gas flowing in a direction through the reaction chamber which is countercurrent to the flow of catalyst particles through the reaction chamber, for promoting suitable reactions between components of the reactant gas; and (d) regenerating the fluidized catalyst particles being continuously circulated through the regeneration chamber;
(e) the vibration further causing the catalyst particles to be circulated though the gas seal conduit means in a generally uniform, substantially completely filled cross-sectional dispersion to provide resistance to appreciable gas flow through the inlet and outlet openings of the reaction chamber so that regeneration of the catalyst particles occurs in the regeneration chamber without being affected by reactions between the reactant gas and the fluidized catalyst particles flowing through the reaction chamber.
21. The method according to claim 20 wherein said closed circuit is resiliently mounted to vibrate as a unit, and in which said closed circuit is engaged with the rotary shaft adapted to rotate about its axis independently of the closed circuit; and including spaced apart counterweights at opposite ends of the rotating shaft to rotate with the shaft;
and drive means coupled with the shaft; and including operating the drive means to rotate the shaft and counterweights to impart vibrating motion to said closed circuit.
and drive means coupled with the shaft; and including operating the drive means to rotate the shaft and counterweights to impart vibrating motion to said closed circuit.
22. The method according to claim 21 including the step of adjusting the mass of the counterweights, the angular relationship between the counterweights, and the vibrational frequency of the imparted vibratory motion in accordance with the type of catalyst present to produce the fluidized, circulating motion of the catalyst particles.
23. The method according to claims 20, 21 or 22 in which the regeneration chamber includes spaced apart first and second openings to the atmosphere, and including the steps of allowing gas for the treatment of catalyst particles to pass in through the first opening, through the regeneration chamber, and out through the second opening to the atmosphere.
24. The method according to claims 20, 21 or 22 including regenerating the catalyst particles by heating them during their passage through the regeneration chamber.
25. The method according to claims 20, 21, or 22 including vibrating the closed circuit to produce a combined horizontal translational motion and angular dis-placement of the closed circuit relative to the vertical axis of the closed circuit.
26. The method according to claims 20, 21 or 22 including regenerating the catalyst particles by cooling them during their passage through the regeneration chamber.
27. The method according to claims 20, 21 or 22 including a pair of separate catalyst regeneration chambers in each of which the catalyst particles are vibrated to circulate them in a fluidized condition through separate catalyst regeneration means; and including cooling the particles in one regenerating circuit and heating the particles in the other regenerating circuit.
28. The method according to claims 20, 21 or 22 including regenerating the catalyst particles by passing them into contact with the surface of a furnace in the regenerate chamber which is raised to a temperature substantially in excess of that of the catalyst particles, the furnace having a surface made from the same material as the catalyst, said material being adapted to separate from the furnace surface to create fresh atomic layers on the catalyst particles in response to impingement of the particles on said surface.
29. The method according to claims 20, 21 or 22 including introducing the steam of reactant gas to one portion of the reaction chamber and withdrawing the stream of reactant gas from another portion of the reaction chamber after contact with the catalyst particles.
30. Catalyst regeneration apparatus comprising:
(a) a closed circuit for simultaneously utilizing and regenerating a particulate catalyst circulated through the closed circuit, the closed circuit including a reaction chamber of closed cross-section having a spaced apart inlet and outlet, a regeneration chamber of closed cross-section having a spaced apart inlet and outlet, and gas seal conduit means of closed cross-section in which the reaction chamber outlet communicates by a tubular feed conduit with the regeneration inlet, and the regeneration outlet communicates by a tubular return conduit with the reaction chamber inlet, whereby a predetermined quantity of a particulate catalyst contained in the closed circuit can travel through the closed circuit in response to vibration thereof;
(b) means mounting the closed circuit in a substantially horizontal position;
(c) means for introducing a stream of reactant gas to the reaction chamber;
(d) means for withdrawing said stream of reactant gas from the reaction chamber;
(e) means for passing said stream of reactant gas through the reaction chamber to contact particulate catalyst contained therein prior to the gas being withdrawn from the reaction chamber to promote suitable reactions between components of the reactant gas;
(f) means for regenerating spent catalyst particles passing through the regeneration chamber;
(g) means for vibrating the horizontally disposed closed circuit as a unit to continuously circulate catalyst particles contained therein in a fluidized, generally random cross-sectional dispersion in a preselected direction between the inlet and outlet of the reaction chamber and then through the feed conduit, the regeneration chamber, and the return conduit, and then back to the reaction chamber, to allow spent catalyst to be constantly regenerated from its passage through the regeneration means; and (h) the cross-sectional dimensions of the gas seal conduit means being sufficient to enable catalyst particles circulating therethrough to travel through the conduit means in a generally uniform, substantially completely filled cross-sectional dispersion to provide resistance to appreciable gas flow through the inlet and outlet openings of the reaction chamber so that regeneration of the catalyst particles can take place in the regeneration chamber without being affected by reactions between the reactant gas and fluidized catalyst particles circulating through the reaction chamber.
(a) a closed circuit for simultaneously utilizing and regenerating a particulate catalyst circulated through the closed circuit, the closed circuit including a reaction chamber of closed cross-section having a spaced apart inlet and outlet, a regeneration chamber of closed cross-section having a spaced apart inlet and outlet, and gas seal conduit means of closed cross-section in which the reaction chamber outlet communicates by a tubular feed conduit with the regeneration inlet, and the regeneration outlet communicates by a tubular return conduit with the reaction chamber inlet, whereby a predetermined quantity of a particulate catalyst contained in the closed circuit can travel through the closed circuit in response to vibration thereof;
(b) means mounting the closed circuit in a substantially horizontal position;
(c) means for introducing a stream of reactant gas to the reaction chamber;
(d) means for withdrawing said stream of reactant gas from the reaction chamber;
(e) means for passing said stream of reactant gas through the reaction chamber to contact particulate catalyst contained therein prior to the gas being withdrawn from the reaction chamber to promote suitable reactions between components of the reactant gas;
(f) means for regenerating spent catalyst particles passing through the regeneration chamber;
(g) means for vibrating the horizontally disposed closed circuit as a unit to continuously circulate catalyst particles contained therein in a fluidized, generally random cross-sectional dispersion in a preselected direction between the inlet and outlet of the reaction chamber and then through the feed conduit, the regeneration chamber, and the return conduit, and then back to the reaction chamber, to allow spent catalyst to be constantly regenerated from its passage through the regeneration means; and (h) the cross-sectional dimensions of the gas seal conduit means being sufficient to enable catalyst particles circulating therethrough to travel through the conduit means in a generally uniform, substantially completely filled cross-sectional dispersion to provide resistance to appreciable gas flow through the inlet and outlet openings of the reaction chamber so that regeneration of the catalyst particles can take place in the regeneration chamber without being affected by reactions between the reactant gas and fluidized catalyst particles circulating through the reaction chamber.
31. Apparatus according to claim 30, including means for passing the stream of reactant gas through the reaction chamber in a direction opposite to fluidized flow of catalyst particles therein.
32. Apparatus according to claim 30 or 31, in which the vibrating means includes means resiliently mounting the closed circuit, and rotatable counterweight means to impart vibrating motion to the closed circuit.
33. Apparatus according to claim 30 or 31, in which the vibrating means comprises a body, means non-rotatably securing the closed circuit to the body, means resiliently mounting the body, and rotatable counterweight means secured to the body to vibrate the body to impart corresponding vibrating motion to the closed circuit.
34. Apparatus according to claim 30 or 31 in which the catalyst regeneration means includes means for passing a flow of gas through the length of the regeneration chamber to contact the spent catalyst particles with the gas to regenerate the catalyst particles.
35. Apparatus according to claim 30 or 31 in which the vibrating means includes means resiliently mounting the closed circuit, and rotatable counterweight means to impart vibrating motion to the closed circuit and in which the catalyst regeneration means includes means for passing a flow of gas through the length of the regeneration chamber to contact the spent catalyst particles with the gas to regenerate the catalyst particles.
36. Apparatus according to claim 30 or 31 in which the vibrating means includes means resiliently mounting the closed circuit, rotatable counterweight means to impart vibrating motion to the closed circuit, the rotatable counter-weight means including a rotary shaft engaged with the closed circuit and adapted to rotate about its axis independently of the closed circuit, spaced apart counterweights at opposite ends of the rotary shaft to rotate with the shaft, and drive means coupled with the rotary shaft to rotate the shaft and counterweights to impart vibrating motion to the closed circuit.
37. Apparatus according to claim 30 or 31 in which the catalyst regeneration means includes means for passing a flow of gas through the length of the regeneration chamber to contact the spent catalyst particles with the gas to regenerate the catalyst particles and wherein the vibrating means includes means resiliently mounting the closed circuit, rotatable counterweight means to impart vibrating motion to the closed circuit , the rotatable counterweight means including a rotary shaft engaged with the closed circuit and adapted to rotate about its axis independently of the closed circuit, spaced apart counterweights at opposite ends of the rotary shaft to rotate with the shaft, and drive means coupled with the rotary shaft to rotate the shaft and counterweights to impart vibrating motion to the closed circuit.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA230,137A CA1042630A (en) | 1975-06-25 | 1975-06-25 | Vibrating chemical reactor/regenerator |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA230,137A CA1042630A (en) | 1975-06-25 | 1975-06-25 | Vibrating chemical reactor/regenerator |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1042630A true CA1042630A (en) | 1978-11-21 |
Family
ID=4103441
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA230,137A Expired CA1042630A (en) | 1975-06-25 | 1975-06-25 | Vibrating chemical reactor/regenerator |
Country Status (1)
| Country | Link |
|---|---|
| CA (1) | CA1042630A (en) |
-
1975
- 1975-06-25 CA CA230,137A patent/CA1042630A/en not_active Expired
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