CA1026228A - Low temperature process for the separation of gaseous mixtures with reduced energy requirements - Google Patents

Low temperature process for the separation of gaseous mixtures with reduced energy requirements

Info

Publication number
CA1026228A
CA1026228A CA239,439A CA239439A CA1026228A CA 1026228 A CA1026228 A CA 1026228A CA 239439 A CA239439 A CA 239439A CA 1026228 A CA1026228 A CA 1026228A
Authority
CA
Canada
Prior art keywords
separation
low temperature
temperature process
energy requirements
reduced energy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA239,439A
Other languages
English (en)
French (fr)
Inventor
John A. Pryor
Howard C. Rowles
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Air Products and Chemicals Inc
Original Assignee
Air Products and Chemicals Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Products and Chemicals Inc filed Critical Air Products and Chemicals Inc
Application granted granted Critical
Publication of CA1026228A publication Critical patent/CA1026228A/en
Expired legal-status Critical Current

Links

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0252—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/04—Purification; Separation; Use of additives by distillation
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0204—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the feed stream
    • F25J3/0219—Refinery gas, cracking gas, coke oven gas, gaseous mixtures containing aliphatic unsaturated CnHm or gaseous mixtures of undefined nature
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0233—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of CnHm with 1 carbon atom or more
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0238—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of CnHm with 2 carbon atoms or more
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00—Processes or apparatus using separation by rectification
    • F25J2200/02—Processes or apparatus using separation by rectification in a single pressure main column system
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00—Processes or apparatus using separation by rectification
    • F25J2200/74—Refluxing the column with at least a part of the partially condensed overhead gas
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00—Processes or apparatus using separation by rectification
    • F25J2200/80—Processes or apparatus using separation by rectification using integrated mass and heat exchange, i.e. non-adiabatic rectification in a reflux exchanger or dephlegmator
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2210/00—Processes characterised by the type or other details of the feed stream
    • F25J2210/12—Refinery or petrochemical off-gas
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00—Refrigeration techniques used
    • F25J2270/04—Internal refrigeration with work-producing gas expansion loop
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/40—Ethylene production

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Separation By Low-Temperature Treatments (AREA)
CA239,439A 1974-11-27 1975-11-12 Low temperature process for the separation of gaseous mixtures with reduced energy requirements Expired CA1026228A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/527,516 US4002042A (en) 1974-11-27 1974-11-27 Recovery of C2 + hydrocarbons by plural stage rectification and first stage dephlegmation

Publications (1)

Publication Number Publication Date
CA1026228A true CA1026228A (en) 1978-02-14

Family

ID=24101773

Family Applications (1)

Application Number Title Priority Date Filing Date
CA239,439A Expired CA1026228A (en) 1974-11-27 1975-11-12 Low temperature process for the separation of gaseous mixtures with reduced energy requirements

Country Status (11)

Country Link
US (1) US4002042A (es)
JP (1) JPS5174981A (es)
BE (1) BE835982A (es)
BR (1) BR7507703A (es)
CA (1) CA1026228A (es)
DE (1) DE2552140C2 (es)
ES (1) ES443020A1 (es)
FR (1) FR2292761A1 (es)
GB (1) GB1509789A (es)
IT (1) IT1049866B (es)
NL (1) NL185453C (es)

Families Citing this family (51)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4331461A (en) * 1978-03-10 1982-05-25 Phillips Petroleum Company Cryogenic separation of lean and rich gas streams
DE2843982A1 (de) * 1978-10-09 1980-04-24 Linde Ag Verfahren zum zerlegen eines gasgemisches
US4270939A (en) * 1979-08-06 1981-06-02 Air Products And Chemicals, Inc. Separation of hydrogen containing gas mixtures
US4270940A (en) * 1979-11-09 1981-06-02 Air Products And Chemicals, Inc. Recovery of C2 hydrocarbons from demethanizer overhead
US4336046A (en) * 1980-09-12 1982-06-22 Tenneco Oil Company C4 Separation process
US4496381A (en) * 1983-02-01 1985-01-29 Stone & Webster Engineering Corp. Apparatus and method for recovering light hydrocarbons from hydrogen containing gases
US4519825A (en) * 1983-04-25 1985-05-28 Air Products And Chemicals, Inc. Process for recovering C4 + hydrocarbons using a dephlegmator
JPS61106523A (ja) * 1984-10-31 1986-05-24 Mitsui Eng & Shipbuild Co Ltd 炭化水素分解物の精製法
US4714487A (en) * 1986-05-23 1987-12-22 Air Products And Chemicals, Inc. Process for recovery and purification of C3 -C4+ hydrocarbons using segregated phase separation and dephlegmation
US4707170A (en) * 1986-07-23 1987-11-17 Air Products And Chemicals, Inc. Staged multicomponent refrigerant cycle for a process for recovery of C+ hydrocarbons
US4720294A (en) * 1986-08-05 1988-01-19 Air Products And Chemicals, Inc. Dephlegmator process for carbon dioxide-hydrocarbon distillation
US4732598A (en) * 1986-11-10 1988-03-22 Air Products And Chemicals, Inc. Dephlegmator process for nitrogen rejection from natural gas
US4720293A (en) * 1987-04-28 1988-01-19 Air Products And Chemicals, Inc. Process for the recovery and purification of ethylene
US4869740A (en) * 1988-05-17 1989-09-26 Elcor Corporation Hydrocarbon gas processing
US4854955A (en) * 1988-05-17 1989-08-08 Elcor Corporation Hydrocarbon gas processing
US4889545A (en) * 1988-11-21 1989-12-26 Elcor Corporation Hydrocarbon gas processing
US4900347A (en) * 1989-04-05 1990-02-13 Mobil Corporation Cryogenic separation of gaseous mixtures
US5507856A (en) * 1989-11-14 1996-04-16 Air Products And Chemicals, Inc. Hydrogen recovery by adsorbent membranes
US5354547A (en) * 1989-11-14 1994-10-11 Air Products And Chemicals, Inc. Hydrogen recovery by adsorbent membranes
US5035732A (en) * 1990-01-04 1991-07-30 Stone & Webster Engineering Corporation Cryogenic separation of gaseous mixtures
US5287703A (en) * 1991-08-16 1994-02-22 Air Products And Chemicals, Inc. Process for the recovery of C2 + or C3 + hydrocarbons
US5377490A (en) * 1994-02-04 1995-01-03 Air Products And Chemicals, Inc. Open loop mixed refrigerant cycle for ethylene recovery
US5361589A (en) * 1994-02-04 1994-11-08 Air Products And Chemicals, Inc. Precooling for ethylene recovery in dual demethanizer fractionation systems
US5379597A (en) * 1994-02-04 1995-01-10 Air Products And Chemicals, Inc. Mixed refrigerant cycle for ethylene recovery
DE19504555A1 (de) * 1995-02-11 1996-08-14 Huels Chemische Werke Ag Verfahren zur Spaltung von Tertiärbutylalkohol in einer Reaktionsdestillationskolonne
US5634354A (en) * 1996-05-08 1997-06-03 Air Products And Chemicals, Inc. Olefin recovery from olefin-hydrogen mixtures
US5768913A (en) * 1997-04-16 1998-06-23 Stone & Webster Engineering Corp. Process based mixed refrigerants for ethylene plants
US5802871A (en) * 1997-10-16 1998-09-08 Air Products And Chemicals, Inc. Dephlegmator process for nitrogen removal from natural gas
US5983665A (en) * 1998-03-03 1999-11-16 Air Products And Chemicals, Inc. Production of refrigerated liquid methane
US6343487B1 (en) 2001-02-22 2002-02-05 Stone & Webster, Inc. Advanced heat integrated rectifier system
US6487876B2 (en) 2001-03-08 2002-12-03 Air Products And Chemicals, Inc. Method for providing refrigeration to parallel heat exchangers
AU2002357302B2 (en) * 2001-12-18 2006-06-01 Fluor Technologies Corporation Combined recovery of hydrogen and hydrocarbon liquids from hydrogen-containing gases
US6931889B1 (en) 2002-04-19 2005-08-23 Abb Lummus Global, Randall Gas Technologies Cryogenic process for increased recovery of hydrogen
US20050154245A1 (en) * 2003-12-18 2005-07-14 Rian Reyneke Hydrogen recovery in a distributed distillation system
US7152428B2 (en) * 2004-07-30 2006-12-26 Bp Corporation North America Inc. Refrigeration system
PE20060989A1 (es) * 2004-12-08 2006-11-06 Shell Int Research Metodo y dispositivo para producir una corriente de gas natural liquido
EP1907778A1 (en) * 2005-07-28 2008-04-09 Ineos Usa Llc Recovery of carbon monoxide and hydrogen from hydrocarbon streams
US20090282865A1 (en) 2008-05-16 2009-11-19 Ortloff Engineers, Ltd. Liquefied Natural Gas and Hydrocarbon Gas Processing
US20100287982A1 (en) 2009-05-15 2010-11-18 Ortloff Engineers, Ltd. Liquefied Natural Gas and Hydrocarbon Gas Processing
US8309776B2 (en) * 2009-12-15 2012-11-13 Stone & Webster Process Technology, Inc. Method for contaminants removal in the olefin production process
US9021832B2 (en) * 2010-01-14 2015-05-05 Ortloff Engineers, Ltd. Hydrocarbon gas processing
KR101787335B1 (ko) 2010-06-30 2017-10-19 쉘 인터내셔날 리써취 마트샤피지 비.브이. 메탄을 포함하는 탄화수소 스트림의 처리 방법 및 이를 위한 장치
CN103159582B (zh) * 2013-03-21 2015-06-17 杭州杭氧股份有限公司 一种用于丙烷或混合烷烃催化脱氢制丙烯中的低温分离系统及方法
WO2015104153A1 (de) * 2014-01-07 2015-07-16 Linde Aktiengesellschaft Verfahren zur trennung eines wasserstoffhaltigen kohlenwasserstoffgemischs, trenneinrichtung und olefinanlage
US10551118B2 (en) 2016-08-26 2020-02-04 Ortloff Engineers, Ltd. Hydrocarbon gas processing
US10533794B2 (en) 2016-08-26 2020-01-14 Ortloff Engineers, Ltd. Hydrocarbon gas processing
US10551119B2 (en) 2016-08-26 2020-02-04 Ortloff Engineers, Ltd. Hydrocarbon gas processing
US11428465B2 (en) 2017-06-01 2022-08-30 Uop Llc Hydrocarbon gas processing
US11543180B2 (en) 2017-06-01 2023-01-03 Uop Llc Hydrocarbon gas processing
WO2020185649A1 (en) * 2019-03-11 2020-09-17 Uop Llc Hydrocarbon gas processing
CN115999328A (zh) * 2021-10-22 2023-04-25 中国石油化工股份有限公司 膜分离结合精馏制备乙烯的方法和系统

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2582068A (en) * 1948-12-30 1952-01-08 Elliott Co Method and apparatus for separating gases
US2880592A (en) * 1955-11-10 1959-04-07 Phillips Petroleum Co Demethanization of cracked gases
DE1252711B (de) * 1963-02-26 1967-10-26 Hitachi Ltd , Tokio Verfahren zum Rektifizieren von Olefin aus olefinreichen Gasgemischen unter Ausnutzung der durch verflüssigtes Methan gas gelieferten Kalte
US3186182A (en) * 1963-05-27 1965-06-01 Phillips Petroleum Co Low-temperature, low-pressure separation of gases
US3242682A (en) * 1963-09-23 1966-03-29 Eastman Kodak Co Method for separation of hydrocarbons
US3320754A (en) * 1964-09-25 1967-05-23 Lummus Co Demethanization in ethylene recovery with condensed methane used as reflux and heat exchange medium
US3398546A (en) * 1965-03-19 1968-08-27 Conch Int Methane Ltd Tail gas separation in plural stages employing liquid natural gas refrigerant
US3359743A (en) * 1966-04-29 1967-12-26 Nat Distillers Chem Corp Low temperature process for the recovery of ethane from a stripped natural gas stream
DE1551609A1 (de) * 1967-12-15 1972-03-02 Messer Griesheim Gmbh Verfahren zur Zerlegung von fluessigem Erdgas
US3625016A (en) * 1968-06-07 1971-12-07 Mc Donnell Douglas Corp Separation of hydrogen and hydrocarbon mixtures by plural stage distillation with heat exchange
BE758567A (fr) * 1969-11-07 1971-05-06 Fluor Corp Procede de recuperation d'ethylene a basse pression

Also Published As

Publication number Publication date
BE835982A (fr) 1976-03-16
DE2552140C2 (de) 1985-04-11
DE2552140A1 (de) 1976-08-12
JPS5174981A (es) 1976-06-29
BR7507703A (pt) 1976-08-31
FR2292761A1 (fr) 1976-06-25
FR2292761B1 (es) 1982-10-22
IT1049866B (it) 1981-02-10
NL185453B (nl) 1989-11-16
NL7513805A (nl) 1976-05-31
NL185453C (nl) 1990-04-17
GB1509789A (en) 1978-05-04
US4002042A (en) 1977-01-11
ES443020A1 (es) 1977-04-16

Similar Documents

Publication Publication Date Title
CA1026228A (en) Low temperature process for the separation of gaseous mixtures with reduced energy requirements
ZA754686B (en) Process for the preparation of high btu methane-containing gas
CA1004466A (en) Process for the production of high strength reducing gas
CA1027444A (en) Gas range
CA968280A (en) Absorption process for gas separation
AU499665B2 (en) Low temperature refrigeration process
YU90975A (en) Continuous process for the production of gaseous mixtures
CA1015772A (en) Process for the bromofluorination of methane
CA1018329A (en) Process for the preparation of a hydrogen-rich gas
CA1030556A (en) Process for the production of hydroxy-pivaldehyde
CA1023097A (en) Process for the preparation of carbodiimide-isocyanurate foams
ZA762747B (en) Improved process for the production of gaseous mixtures
AU509245B2 (en) Process for the preparation of hydrogen-rich gas
CA1030587A (en) Temperature controlled gas discharge device
ZA754972B (en) Process for the manufacture of bromine
ZA747700B (en) Methane-rich gas process
ZA747701B (en) Methane-rich gas process
CA1028686A (en) Heat exchange with gas/solids mixtures
CA1026097A (en) Process and arrangement for the production of natural gas
CA1025635A (en) Process for the manufacture of high-purity lithlium hexafluoroarsenate
CA1021358A (en) Process for the preparation of a methane-rich gas
CA1027505A (en) Transport of glass sheets at high temperatures
IL47245A (en) Process for the separation of gaseousmixtures
SU581951A1 (ru) Способ взаимодействи газа с жидкостью
CA1016430A (en) Gas producer arrangements